Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-d...Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as guest molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.展开更多
The buckling behavior of single layer space structure is very sensitive. The joint rigidity, moreover, is one of the main factors of stability which may determine the entire failure behavior. Thus, the reasonable stif...The buckling behavior of single layer space structure is very sensitive. The joint rigidity, moreover, is one of the main factors of stability which may determine the entire failure behavior. Thus, the reasonable stiffness of joint system, which is neither total pin assumption nor perfect fix condition, is very important to apply to the real single layer space one. Therefore, the purpose of this work was to investigate the buckling behavior of single layer space structure, using the development of the upgraded stiffness matrix for the joint rigidity. To derive tangential stiffness matrix, a displacement function was assumed using translational and rotational displacement at the node. The geometrical nonlinear analysis was simulated not only with perfect model but also with imperfect one. As a result, the one and two free nodal numerical models were investigated using derived stiffness matrix. It was figured out that the buckling load increases in proportion to joint rigidity with rise-span ratio. The stability of numerical model is very sensitive with the initial imperfection, responding of bifurcation in the structure.展开更多
The in-phase and quadrature-phase imbalance (IQI) is one of the major radio frequency impairments existing in orthogonal frequency division multiplexing (OFDM) systems with direct-conversion transceivers. During the t...The in-phase and quadrature-phase imbalance (IQI) is one of the major radio frequency impairments existing in orthogonal frequency division multiplexing (OFDM) systems with direct-conversion transceivers. During the transmission of the communication signal, the impact of IQI is coupled with channel impulse responses (CIR), which makes the traditional channel estimation schemes ineffective. A decoupled estimation scheme is proposed to separately estimate the frequency-dependent IQI and wireless channel. Firstly, the generalized channel model is built to separate the parameters of IQI and wireless channel. Then an iterative estimation scheme of frequency-dependent IQI is designed at the initial stage of communication. Finally, based on the estimation result of IQI, the least square algorithm is utilized to estimate the channel-related parameters at each time of channel variation. Compared with the joint estimation schemes of IQI and channel, the proposed decoupled estimation scheme requires much lower training overhead at each time of channel variation. Simulation results demonstrate the good estimation performance of the proposed scheme.展开更多
Pile foundation is widely used in the offshore engineering. The pile can be seriously destroyed by the soil liquefaction during strong earthquakes. The potentials of liquefaction and damages of pile foundation due to ...Pile foundation is widely used in the offshore engineering. The pile can be seriously destroyed by the soil liquefaction during strong earthquakes. The potentials of liquefaction and damages of pile foundation due to the liquefaction can be reduced by the implementation of the drainage in the liquefiable foundation. A patented pile technology, named rigidity-drain pile, was introduced. The partial section of the pile body was filled by materials with higher penetrability which forms some effective drainage channels in the pile. The principles and construction methods were presented. 3D models for both rigidity-drain pile and ordinary pile were built in FLAC3D code. The dynamic loadings were applied on the bottom of the model. According to the numerical results, in the case of the rigidity-drain pile, the water in the relevant distance range around the pile flows toward the pile drainage, the contour of the pore pressure shows a funnel form. Contrast to the ordinary pile, the rigidity-drain pile can dissipate the accumulated excess pore water, maintain effective stress and obviously reduce the possibility of surrounding soil liquefaction.展开更多
文摘Five cadmium naphthalene-diphosphonates,formulated as[Cd_(1.5)(1,4-ndpaH_(2))2(4,4'-bpyH)(4,4'-bpy)0.5(H_(2)O)_(2)]2(1),[Cd(1,4-ndpaH_(2))(1,4-bib)0.5(H_(2)O)](2),[Cd(1,4-ndpaH3)2(1,2-dpe)(H_(2)O)]·(1,2-dpe)·7H_(2)O(3),(1,2-bixH)[Cd3(1,4-ndpaH)(1,4-ndpaH_(2))2(H_(2)O)_(2)](4),and[Cd(1,4-ndpaH_(2))(H_(2)O)]·H_(2)O(5),have been synthesized from the selfassembly reactions of 1,4-naphthalenediphosphonic acid(1,4-ndpaH4)with Cd(NO3)2·4H_(2)O by introducing auxiliary ligands with variation of rigidity,such as 4,4'-bipyridine(4,4'-bpy),1,4-bis(1-imidazolyl)benzene(1,4-bib),1,2-di(4-pyridyl)ethylene(1,2-dpe),1,3-di(4-pyridyl)propane(1,3-dpp),and bis(imidazol-1-ylmethyl)benzene(1,2-bix),respectively.Structure resolution by single-crystal X-ray diffraction reveals that compound 1 possesses a layered framework,in which the{Cd3(PO2)2}trimers made up of corner-sharing two{CdO4N2}and one{CdO6}octahedra are connected by phosphonate groups,forming a ribbon,which are cross-linked by 4,4'-bipy ligands,forming a 2D layer.Compound 2 shows a 3D open-framework structure,where chains of corner-sharing{CdO4N}trigonal bipyramids and{PO3C}tetrahedra are cross-linked by 1,4-bib and/or phosphonate groups.A 1D ladder-like chain structure is found in compound 3,where the ladder-like chains made up of corner-sharing{CdO5N}octahedra and{PO3C}tetra hedra are connected by 1,4-ndpaH_(2)^(2-).Both compounds 4 and 5 obtained by the introduction of flexible ligands during the synthesis show a 2D layered structure,which is formed by ligand crosslinking double metal chains.Interestingly,In 4,flexible 1,2-bix was singly protonated,as guest molecules,filled between layer and layer,while flexible ligand 1,3-dpp is absent in 5.Photophysical measurements indicate that compounds 1-5 show ligand-centered emissions.
基金Project(12 High-tech Urban C11) supported by High-tech Urban Development Program of Ministry of Land,Transport and Maritime Affairs,Korea
文摘The buckling behavior of single layer space structure is very sensitive. The joint rigidity, moreover, is one of the main factors of stability which may determine the entire failure behavior. Thus, the reasonable stiffness of joint system, which is neither total pin assumption nor perfect fix condition, is very important to apply to the real single layer space one. Therefore, the purpose of this work was to investigate the buckling behavior of single layer space structure, using the development of the upgraded stiffness matrix for the joint rigidity. To derive tangential stiffness matrix, a displacement function was assumed using translational and rotational displacement at the node. The geometrical nonlinear analysis was simulated not only with perfect model but also with imperfect one. As a result, the one and two free nodal numerical models were investigated using derived stiffness matrix. It was figured out that the buckling load increases in proportion to joint rigidity with rise-span ratio. The stability of numerical model is very sensitive with the initial imperfection, responding of bifurcation in the structure.
基金supported by the National Natural Science Foundation of China(6140123261471200+4 种基金6150124861501254)the China Postdoctoral Science Foundation(2014M561692)the Jiangsu Province Postdoctoral Science Foundation(1402087C)the NUPTSF(NY213063)
文摘The in-phase and quadrature-phase imbalance (IQI) is one of the major radio frequency impairments existing in orthogonal frequency division multiplexing (OFDM) systems with direct-conversion transceivers. During the transmission of the communication signal, the impact of IQI is coupled with channel impulse responses (CIR), which makes the traditional channel estimation schemes ineffective. A decoupled estimation scheme is proposed to separately estimate the frequency-dependent IQI and wireless channel. Firstly, the generalized channel model is built to separate the parameters of IQI and wireless channel. Then an iterative estimation scheme of frequency-dependent IQI is designed at the initial stage of communication. Finally, based on the estimation result of IQI, the least square algorithm is utilized to estimate the channel-related parameters at each time of channel variation. Compared with the joint estimation schemes of IQI and channel, the proposed decoupled estimation scheme requires much lower training overhead at each time of channel variation. Simulation results demonstrate the good estimation performance of the proposed scheme.
基金Project (50639010) supported by the National Natural Science Foundation of China
文摘Pile foundation is widely used in the offshore engineering. The pile can be seriously destroyed by the soil liquefaction during strong earthquakes. The potentials of liquefaction and damages of pile foundation due to the liquefaction can be reduced by the implementation of the drainage in the liquefiable foundation. A patented pile technology, named rigidity-drain pile, was introduced. The partial section of the pile body was filled by materials with higher penetrability which forms some effective drainage channels in the pile. The principles and construction methods were presented. 3D models for both rigidity-drain pile and ordinary pile were built in FLAC3D code. The dynamic loadings were applied on the bottom of the model. According to the numerical results, in the case of the rigidity-drain pile, the water in the relevant distance range around the pile flows toward the pile drainage, the contour of the pore pressure shows a funnel form. Contrast to the ordinary pile, the rigidity-drain pile can dissipate the accumulated excess pore water, maintain effective stress and obviously reduce the possibility of surrounding soil liquefaction.
