Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interac...Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.展开更多
Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the ...Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the disease.Measuring the hemodynamic factor like the blood pressure,the wall shear stress(WSS)and the oscillatory shear index(OSI)is,however,still beyond the capabilities of in-vivo measurement techniques.So the use of mathematical models and numerical simulations for the studies of the blood flow in arteries and,in general,of the cardiovascular system,both in physiological and pathological conditions,has received an increasing attention in the biomedical community during the last two decades.Indeed,such studies aims at enhancing the current knowledge of the physiology of the cardiovascular system,as well as providing reliable tools for the medical doctors to predict the natural course of pathologies and,possibly,the occurrence of cardiovascular accidents.The computational vascular fluid-structure interaction(FSI)methodology is a numerical simulation method which is used to explain the hemodynamic factors.The WSS on the luminal wall and the mechanical stress in the vascular wall are directly related to the location of the lesion,and the blood flow strongly interacts with the vascular wall motion.The arterial wall continually adapts to the charge of its mechanical environment(due to,for example,growth,atrophy,remodelling,repair,ageing,and disease)and consequently undergoes several irreversible processes.Primary acute mechanisms of vascularFSI numerical simulation seem to be associated with(1)the arterial histology and the patient-specific complex geometry,(2)the typical mechanical properties of the layer,(3)properties of the blood is assumed as Newtonian fluid or non-Newtonian fluid based on the scale ofthe diameter of a vessel,(4)residual stress in the zero-pressure configuration.The arterial system naturally function under permanent physiological loading conditions.Fung defined the residual stress and measured the opening angle which varies greatly along the aortic tree.Consequently,most of these systems never experience a stress-free state in their’service life’,so a stress and strain fields are present in any in vivo obtained patientspecific cardiovascular geometry.The residual stress always be ignored in FSI simulation or be assumed to equal zero,and the vivo patient-specific artery geometry is assumed as zero-pressure configuration.To define the in vivo stress state of artery,an inverse problem needs to be solved:the undeformed shape of a body or its stress state in its deformed state needs to be determined given the deformed configuration and the loads causing this deformation.The modular inverse elastostatics method is used to resolve the pressure-induced stress state for in vivo imaging based on cardiovascular modeling proposed by Peirlinck.Here,we build a living vessel FSI model based on 4 key factors.In order to get the universal simulation results,we focus on idealized geometries of the vessel that represent healthy(physiological)conditions of the cerebral vasculature.Blood can be assumed as the Newtonian fluid at this scale.The anisotropic hyperelastic constitutive law(Gasser-Holzapfel-Ogden)is used in zero-pressure configuration.Afterwards,we propose the material parameters for the different constitutive models and the computational configurations.We demonstrate the importance of introducing the residual stress into vascular blood flow modeling by performing a comparing zero-pressure configuration and no-resistance configuration.We get the conclusion that the zero-pressure status model has smaller displacement and larger stress distribution compared with no-resistance stress model.Hence,the methodology presented here will be particularly useful to study the mechanobiological processes in the healthy and diseased vascular wall.展开更多
Energetic materials face critical challenges in balancing energy density and safety,driving the development of low-sensitivity high-energy materials.Though vital for modern defense and civilian applications,low-sensit...Energetic materials face critical challenges in balancing energy density and safety,driving the development of low-sensitivity high-energy materials.Though vital for modern defense and civilian applications,low-sensitivity high-energy materials remain scarce,with 1,3,5-trinitro-2,4,6-triaminobenzene as the only deployed example.Planar lamellar energetic crystals,which utilize weak interlamellarπ-πstacking for mechanical energy dissipation,have shown significant promise.However,their rational design is constrained by insufficient understanding of intermolecular interaction synergy.This review synthesizes the structural features of planar lamellar energetic crystals,emphasizing three core elements:the single-atomic-thickness planar stacking architecture,the"strong intralamellar and weak interlamellar interaction"paradigm(key to balancing energy density and safety for low-sensitivity high-energy materials,LSHEMs),and the role of molecular planarity in reducing shear slip barriers.It categorizes design strategies into two frameworks:H–bonding dominated(single-component:cross-shaped assembly,strong H–bonding in high symmetric molecules;multi-component methods:tenon-and-mortise,acceptor-donor separation)and other intermolecular interactions(e.g.,π-πstacking-drivenπ-π2max model,π-hole recognition).Case studies in single/multi-component crystals confirm that these strategies tune interaction synergy to achieve target packing motifs.The review highlights that interaction engineering is pivotal for PLEC design,offering a targeted theoretical framework for rational development of LSHEMs(to address the scarcity of practical LSHEMs)and guiding future crystal engineering for energy-safety balanced systems.展开更多
With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Ni...With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.展开更多
By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts d...By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability.展开更多
Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dyn...Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies.展开更多
In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-...In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies.展开更多
Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interacti...Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interaction dynamics between the cotton plant host and V.dahliae pathogen pose a crucial predicament for effectively managing cotton Verticillium wilt.Nevertheless,the most cost-effective approach to controlling this disease involves breeding and cul-tivating resistant cotton varieties,demanding a meticulous analysis of the mechanisms underlying cotton’s resistance to Verticillium wilt and the identification of pivotal genes.These aspects constitute focal points in disease-resistance breeding programs.In this review,we comprehensively discuss genetic inheritance associated with Verticillium wilt resistance in cotton,the advancements in molecular markers for disease resistance,the functional investiga-tion of resistance genes in cotton,the analysis of pathogenicity genes in V.dahliae,as well as the intricate interplay between cotton and this fungus.Moreover,we delve into the future prospects of cutting-edge research on cotton Verticillium wilt,aiming to proffer valuable insights for the effective management of this devastating fungus.展开更多
Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blo...Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blossom piles, it is important to investigate the skin friction behavior of plum blossom pile foundations precluding any straightforward constitutive model. In this work, an analytic method dependent on the cross-sectional geometry and the vertical shearing effects is proposed by means of equilibrium analysis to calculate the effective vertical stress in the surrounding soil, the skin friction/negative skin friction, and the axial force/dragload of a plum blossom pile. Additionally, the curves of skin friction of piles are investigated with the same conditions. The results show that the curves of skin friction of piles deduced according to the developed analytic method agree well with the FEM results and related literature solution, which validates the solution. The axial force of the pile decreases with the increase of the shear action coefficient in the buried depth direction under the vertical concentrated load when considering the vertical shearing effects on the pile-soil interfaces.展开更多
In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefo...In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.展开更多
In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation...In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation mathematical model of fluid-structure interaction(FSI)was developed.Then,the transfer matrix method(TMM)was used to calculate the modal frequency,modal shape and frequency response.The results were compared with that in experiment to verify the correctness of the TMM and the results show that the fluid-structure coupling has a greater impact on the modal frequencies than the modal shape.Finally,the influence on the response spectrum of different damping ratios was studied and the results show that the natural frequency under different damping ratios has changed little but there is a big difference for the pressure spectrum.With the decreasing of damping ratio,the damping of the system on frequency spectrum is more and more significant and the dispersion and dissipation is more and more apparent.Therefore the appropriate damping ratio should be selected to minimize the effects of the vibration of the FSI.The results provide references for the theory research of FSI in the transient process.展开更多
The mechanism of lifeline system interaction is analyzed and the method and its corresponding result for categorizing the lifeline system in terms of interaction are presented. Various methods for the different kind o...The mechanism of lifeline system interaction is analyzed and the method and its corresponding result for categorizing the lifeline system in terms of interaction are presented. Various methods for the different kind of interaction are reviewed in this paper. For the function interaction of the lifeline system, an all-round study method is recommended. A WebGIS based aided decision-making method for the post-earthquake restoration of multi-lifeline system is also presented. Meanwhile, some key-points for lifeline system interaction are discussed.展开更多
Spin-orbit optical phenomena pertain to the wider class of electromagnetic effects originating from the interaction of the photon spin with the spatial structure and propagation characteristics of an optical wave,medi...Spin-orbit optical phenomena pertain to the wider class of electromagnetic effects originating from the interaction of the photon spin with the spatial structure and propagation characteristics of an optical wave,mediated by suitable optical media.There are many emerging photonic applications of spin-orbit interactions(SOI)of light,such as control of the optical wave propagation via the spin,enhanced optical manipulation,and generation of structured optical fields.Unfortunately,current applications are based on symmetric SOI,that is,the behaviours of polarized photons with two opposite spins are opposite,leading to the limit of spin-based multiplexers.The symmetry of SOI can be broken in our proposed metasurfaces,consisting of spatially varying birefringence,which can arbitrarily and independently build SOI for two opposite spins without reduction of optical energy usage.We obtain three kinds of dual-functional metasurfaces at visible and infrared wavelengths with high efficiency.Our concept of generation of asymmetric SOI for two spins,using anisotropic metasurfaces,will open new degrees of freedoms for building new types of spin-controlled multifunctional shared-aperture devices for the generation of complex structured optical fields.展开更多
In this study, a complex analysis of a man-weapon interaction based on experimental effort is presented.The attention is focused on how a shooter can influence on a rifle, opposite to generally considered in literatur...In this study, a complex analysis of a man-weapon interaction based on experimental effort is presented.The attention is focused on how a shooter can influence on a rifle, opposite to generally considered in literature rifle's impact on a shooter. It is shown, based on the kbk AKM weapon, that each support point of the rifle has an substantial impact on the system. It is said that identifying human reactions on weapon may let to describe gun movement and thus may be applied to weapon accuracy determination.展开更多
Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite ...Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.展开更多
Conventional artificial fish has some shortages on the interaction with environment, other fish, and the animator. This article proposes a multi-tier interaction control model of artificial fish, realizes the interact...Conventional artificial fish has some shortages on the interaction with environment, other fish, and the animator. This article proposes a multi-tier interaction control model of artificial fish, realizes the interaction model through integration of virtual reality technology and Markov sequence, and provides a virtual marine world to describe the interaction between artificial fish and the virtual environment and the interaction between the artificial fish and the animator. Simulation results show that the interaction model owns not only the basic characteristics of virtual biology, but also has high trueness interaction function.展开更多
The interaction between a flotation reagent and mineral surface not only depends on the bonding atom, but also depends on the adjacent atom of mineral surface, a flotation reagent and the medium in the system of flota...The interaction between a flotation reagent and mineral surface not only depends on the bonding atom, but also depends on the adjacent atom of mineral surface, a flotation reagent and the medium in the system of flotation. Energy equation of a reagent interacting with mineral surface has been deduced from this model. Results of the studies indicate that the interaction energy between mineral surface and a reagent is about several dozen kJ/mol, and the relationship between adsorbing concentration of xanthate on mineral surface and interaction energy is the exponent form.展开更多
基金Project(50678059) supported by the National Natural Science Foundation of China
文摘Long distance buried liquid-conveying pipeline is inevitable to cross faults and under earthquake action,it is necessary to calculate fluid-structure interaction(FSI) in finite element analysis under pipe-soil interaction.Under multi-action of site,fault movement and earthquake,finite element model of buried liquid-conveying pipeline for the calculation of fluid structure interaction was constructed through combinative application of ADINA-parasolid and ADINA-native modeling methods,and the direct computing method of two-way fluid-structure coupling was introduced.The methods of solid and fluid modeling were analyzed,pipe-soil friction was defined in solid model,and special flow assumption and fluid structure interface condition were defined in fluid model.Earthquake load,gravity and displacement of fault movement were applied,also model preferences.Finite element research on the damage of buried liquid-conveying pipeline was carried out through computing fluid-structure coupling.The influences of pipe-soil friction coefficient,fault-pipe angle,and liquid density on axial stress of pipeline were analyzed,and optimum parameters were proposed for the protection of buried liquid-conveying pipeline.
基金supported by the National Natural Science Foundation of China ( 11732001)
文摘Vascular diseases such as aneurysm,hemadostenosis,aortic dissection are the primary causes of people’s death around world.As a result,it is significant to improve our knowledge about them,which can help to treat the disease.Measuring the hemodynamic factor like the blood pressure,the wall shear stress(WSS)and the oscillatory shear index(OSI)is,however,still beyond the capabilities of in-vivo measurement techniques.So the use of mathematical models and numerical simulations for the studies of the blood flow in arteries and,in general,of the cardiovascular system,both in physiological and pathological conditions,has received an increasing attention in the biomedical community during the last two decades.Indeed,such studies aims at enhancing the current knowledge of the physiology of the cardiovascular system,as well as providing reliable tools for the medical doctors to predict the natural course of pathologies and,possibly,the occurrence of cardiovascular accidents.The computational vascular fluid-structure interaction(FSI)methodology is a numerical simulation method which is used to explain the hemodynamic factors.The WSS on the luminal wall and the mechanical stress in the vascular wall are directly related to the location of the lesion,and the blood flow strongly interacts with the vascular wall motion.The arterial wall continually adapts to the charge of its mechanical environment(due to,for example,growth,atrophy,remodelling,repair,ageing,and disease)and consequently undergoes several irreversible processes.Primary acute mechanisms of vascularFSI numerical simulation seem to be associated with(1)the arterial histology and the patient-specific complex geometry,(2)the typical mechanical properties of the layer,(3)properties of the blood is assumed as Newtonian fluid or non-Newtonian fluid based on the scale ofthe diameter of a vessel,(4)residual stress in the zero-pressure configuration.The arterial system naturally function under permanent physiological loading conditions.Fung defined the residual stress and measured the opening angle which varies greatly along the aortic tree.Consequently,most of these systems never experience a stress-free state in their’service life’,so a stress and strain fields are present in any in vivo obtained patientspecific cardiovascular geometry.The residual stress always be ignored in FSI simulation or be assumed to equal zero,and the vivo patient-specific artery geometry is assumed as zero-pressure configuration.To define the in vivo stress state of artery,an inverse problem needs to be solved:the undeformed shape of a body or its stress state in its deformed state needs to be determined given the deformed configuration and the loads causing this deformation.The modular inverse elastostatics method is used to resolve the pressure-induced stress state for in vivo imaging based on cardiovascular modeling proposed by Peirlinck.Here,we build a living vessel FSI model based on 4 key factors.In order to get the universal simulation results,we focus on idealized geometries of the vessel that represent healthy(physiological)conditions of the cerebral vasculature.Blood can be assumed as the Newtonian fluid at this scale.The anisotropic hyperelastic constitutive law(Gasser-Holzapfel-Ogden)is used in zero-pressure configuration.Afterwards,we propose the material parameters for the different constitutive models and the computational configurations.We demonstrate the importance of introducing the residual stress into vascular blood flow modeling by performing a comparing zero-pressure configuration and no-resistance configuration.We get the conclusion that the zero-pressure status model has smaller displacement and larger stress distribution compared with no-resistance stress model.Hence,the methodology presented here will be particularly useful to study the mechanobiological processes in the healthy and diseased vascular wall.
基金supported by the National Natural Science Foundation of China under Grant No.22505100.
文摘Energetic materials face critical challenges in balancing energy density and safety,driving the development of low-sensitivity high-energy materials.Though vital for modern defense and civilian applications,low-sensitivity high-energy materials remain scarce,with 1,3,5-trinitro-2,4,6-triaminobenzene as the only deployed example.Planar lamellar energetic crystals,which utilize weak interlamellarπ-πstacking for mechanical energy dissipation,have shown significant promise.However,their rational design is constrained by insufficient understanding of intermolecular interaction synergy.This review synthesizes the structural features of planar lamellar energetic crystals,emphasizing three core elements:the single-atomic-thickness planar stacking architecture,the"strong intralamellar and weak interlamellar interaction"paradigm(key to balancing energy density and safety for low-sensitivity high-energy materials,LSHEMs),and the role of molecular planarity in reducing shear slip barriers.It categorizes design strategies into two frameworks:H–bonding dominated(single-component:cross-shaped assembly,strong H–bonding in high symmetric molecules;multi-component methods:tenon-and-mortise,acceptor-donor separation)and other intermolecular interactions(e.g.,π-πstacking-drivenπ-π2max model,π-hole recognition).Case studies in single/multi-component crystals confirm that these strategies tune interaction synergy to achieve target packing motifs.The review highlights that interaction engineering is pivotal for PLEC design,offering a targeted theoretical framework for rational development of LSHEMs(to address the scarcity of practical LSHEMs)and guiding future crystal engineering for energy-safety balanced systems.
基金Supported by the Fundamental Research Funds for the Central Universities(2682023CX076)the Natural Science Foundation of Sich-uan,China(2024NSFSC1432)the National Natural Science Foundation of China(62301459).
基金supported by the Natural Science Foundation of Shanxi Province(202203021221155)the Foundation of National Key Laboratory of High Efficiency and Low Carbon Utilization of Coal(J23-24-902)。
文摘With ongoing global warming and increasing energy demands,the CH_(4)-CO_(2)reforming reaction(dry reforming of methane,DRM)has garnered significant attention as a promising carbon capture and utilization technology.Nickel-based catalysts are renowned for their outstanding activity and selectivity in this process.The impact of metal-support interaction(MSI),on Ni-based catalyst performance has been extensively researched and debated recently.This paper reviews the recent research progress of MSI on Ni-based catalysts and their characterization and modulation strategies in catalytic reactions.From the perspective of MSI,the effects of different carriers(metal oxides,carbon materials and molecular sieves,etc.)are introduced on the dispersion and surface structure of Ni active metal particles,and the effect of MSI on the activity and stability of DRM reactions on Ni-based catalysts is discussed in detail.Future research should focus on better understanding and controlling MSI to improve the performance and durability of nickel-based catalysts in CH_(4)-CO_(2)reforming,advancing cleaner energy technologies.
基金supported by the Petrochemical Research Institute Foundation(21-CB-09-01)the National Natural Science Foundation of China(22302186,22025205)+1 种基金the China Postdoctoral Science Foundation(2022M713030,2023T160618)the Fundamental Research Funds for the Central Universities(WK2060000058,WK2060000038).
文摘By simplifying catalyst-product separation and reducing phosphorus waste,heterogeneous hydroformylation offers a more sustainable alternative to homogeneous processes.However,heterogeneous hydroformylation catalysts developed thus far still suffer from the issues of much lower activity and metal leaching,which severely hinder their practical application.Here,we demonstrate that incorporating phosphorus(P)atoms into graphitic carbon nitride(PCN)supports facilitates charge transfer from Rh to the PCN support,thus largely enhancing electronic metal-support interactions(EMSIs).In the styrene hydroformylation reaction,the activity of Rh_(1)/PCN single-atom catalysts(SACs)with varying P contents exhibited a volcano-shaped relationship with P doping,where the Rh_(1)/PCN SAC with optimal P doping showed exceptional activity,approximately 5.8-and 3.3-fold greater than that of the Rh_(1)/g-C_(3)N_(4)SAC without P doping and the industrial homogeneous catalyst HRh(CO)(PPh_(3))_(3),respectively.In addition,the optimal Rh_(1)/PCN SAC catalyst also demonstrated largely enhanced multicycle stability without any visible metal aggregation owing to the increased EMSIs,which sharply differed from the severe metal aggregation of large nanoparticles on the Rh_(1)/g-C_(3)N_(4)SAC.Mechan-istic studies revealed that the enhanced catalytic performance could be attributed to electron-deficient Rh species,which reduced CO adsorption while simultaneously promoting alkene adsorption through increased EMSIs.These findings suggest that tuning EMSIs is an effective way to achieve SACs with high activity and durability.
文摘Ice-going ships play a crucial role in polar transportation and resource extraction.Different from the existing modeling approach which assumes that ships remain stationary,dynamic overset grid technology and DFBI(Dynamic Fluid-Body Interaction)method are employed in this paper to enable the free-running motion of the ship in modeling.A numerical model capable of simulating a ship navigating through pack ice area is proposed,which uses Computational Fluid Dynamics(CFD)method to solve the flow field and applies the Discrete Element Method(DEM)to simulate ship-ice and ice-ice interactions.Besides,the proposed high-precision method for generating pack ice area can be used in conjunction with the proposed numerical model.By comparing the numerical results with the available model test data and experimental observations,the effectiveness of the numerical model is validated,demonstrating its strong capability of predicting resistance and simulating ship navigation in pack ice,as well as its significant potential and applicability for further studies.
基金Supported in part by the National Natural Science Foundation of China(62401125)the Natural Science Foundation of Sichuan Province(2023NSFSC1376)the Fundamental Research Funds for the Central Universities(ZYGX2024J008)。
文摘In this paper,a scheme of commonly-resonated extended interaction circuit system based on high order TMn,mode is proposed to lock the phases of two extended interaction oscillators(EIOs)for generating high power at G-band.Two separate EIOs are coupled through a specific single-gap coupling field supported by a designed gap waveguide with length Lg,which form the phase-locked EIOs based on the commonly-resonated system.As a whole system,the system has been focused on with mode analysis based on different single-gap coupling fields,mode hopping,which present the variation of phase difference between the two-beam-wave interactions when changing Lg.To demonstrate the effectiveness of the proposed circuit system in producing the phase locking,we conducted particle-in-cell(PIC)simulations to show that the interesting mode hopping occurs with the phase difference of O and r between the output signals from two output ports,corresponding to the excitation of the TMn mode with different n.Simulation results show that 1)the oscillator can deliver two times of the output power obtained from one single oscillator at 220 GHz,2)the two EIOs can still deliver output signals with phase difference of O and when the currents of the two beams are different or the fabrication errors of the two EIO cavities are taken into account.The proposed scheme is promising in extending to phase locking between multiple EIOs,and generating higher power at millimeter-wave and higher frequencies.
基金supported by National Natural Science Foundation of China(32201752)Xinjiang Tianchi Talents Program (TCYC2023TP02)Key Project of the Natural Science Foundation of Xinjiang Production and Construction Corps (2024DA001)
文摘Verticillium wilt,caused by the infamous pathogen Verticillium dahliae,presents a primary constraint on cotton cul-tivation worldwide.The complexity of disease resistance in cotton and the largely unexplored interaction dynamics between the cotton plant host and V.dahliae pathogen pose a crucial predicament for effectively managing cotton Verticillium wilt.Nevertheless,the most cost-effective approach to controlling this disease involves breeding and cul-tivating resistant cotton varieties,demanding a meticulous analysis of the mechanisms underlying cotton’s resistance to Verticillium wilt and the identification of pivotal genes.These aspects constitute focal points in disease-resistance breeding programs.In this review,we comprehensively discuss genetic inheritance associated with Verticillium wilt resistance in cotton,the advancements in molecular markers for disease resistance,the functional investiga-tion of resistance genes in cotton,the analysis of pathogenicity genes in V.dahliae,as well as the intricate interplay between cotton and this fungus.Moreover,we delve into the future prospects of cutting-edge research on cotton Verticillium wilt,aiming to proffer valuable insights for the effective management of this devastating fungus.
基金Project(52325905) supported by the National Natural Science Foundation of ChinaProjects(DJ-HXGG-2023-04, DJHXGG-2023-16) supported by the Key Technology Research Projects of Power China。
文摘Plum blossom pile is a new type of special-shaped pile, which is proposed based on the principle of maximum perimeter with the same cross-sectional area. To advance this technique, primarily for the design of plum blossom piles, it is important to investigate the skin friction behavior of plum blossom pile foundations precluding any straightforward constitutive model. In this work, an analytic method dependent on the cross-sectional geometry and the vertical shearing effects is proposed by means of equilibrium analysis to calculate the effective vertical stress in the surrounding soil, the skin friction/negative skin friction, and the axial force/dragload of a plum blossom pile. Additionally, the curves of skin friction of piles are investigated with the same conditions. The results show that the curves of skin friction of piles deduced according to the developed analytic method agree well with the FEM results and related literature solution, which validates the solution. The axial force of the pile decreases with the increase of the shear action coefficient in the buried depth direction under the vertical concentrated load when considering the vertical shearing effects on the pile-soil interfaces.
基金Projects(52208369,52309138,52108320)supported by the National Natural Science Foundation of ChinaProjects(2023NSFSC0284,2025ZNSFSC0409)supported by the Sichuan Science and Technology Program,ChinaProject(U22468214)supported by the Joint Fund Project for Railway Basic Research by the National Natural Science Foundation of China and China State Railway Group Co.,Ltd.
文摘In the practical slope engineering,the stability of lower sliding mass(region A)with back tensile cracks of the jointed rock slope attracts more attentions,but the upper rock mass(region B)may also be unstable.Therefore,in this study,based on the stepped failure mode of bedding jointed rock slopes,considering the influence of the upper rock mass on the lower stepped sliding mass,the improved failure model for analyzing the interaction force(F_(AB))between two regions is constructed,and the safety factors(F_(S))of two regions and whole region are derived.In addition,this paper proposes a method to determine the existence of F_(AB) using their respective acceleration values(a_(A) and a_(B))when regions A and B are unstable.The influences of key parameters on two regions and the whole region are analyzed.The results show that the variation of the F_(AB) and F_(S) of two regions can be obtained accurately based on the improved failure model.The accuracy of the improved failure model is verified by comparative analysis.The research results can explain the interaction mechanism of two regions and the natural phenomenon of slope failure caused by the development of cracks.
文摘In consideration of the problem that the effect of conduit structure on water hammer has been ignored in the classical theory,the Poisson coupling between the fluid and the pipeline was studied and a fourteen-equation mathematical model of fluid-structure interaction(FSI)was developed.Then,the transfer matrix method(TMM)was used to calculate the modal frequency,modal shape and frequency response.The results were compared with that in experiment to verify the correctness of the TMM and the results show that the fluid-structure coupling has a greater impact on the modal frequencies than the modal shape.Finally,the influence on the response spectrum of different damping ratios was studied and the results show that the natural frequency under different damping ratios has changed little but there is a big difference for the pressure spectrum.With the decreasing of damping ratio,the damping of the system on frequency spectrum is more and more significant and the dispersion and dissipation is more and more apparent.Therefore the appropriate damping ratio should be selected to minimize the effects of the vibration of the FSI.The results provide references for the theory research of FSI in the transient process.
基金Shanghai Science and Technology Development Fund (01251203).
文摘The mechanism of lifeline system interaction is analyzed and the method and its corresponding result for categorizing the lifeline system in terms of interaction are presented. Various methods for the different kind of interaction are reviewed in this paper. For the function interaction of the lifeline system, an all-round study method is recommended. A WebGIS based aided decision-making method for the post-earthquake restoration of multi-lifeline system is also presented. Meanwhile, some key-points for lifeline system interaction are discussed.
基金supported by 973 Program of China (2013CBA01700)National Natural Science Funds (61622508, 61575032)
文摘Spin-orbit optical phenomena pertain to the wider class of electromagnetic effects originating from the interaction of the photon spin with the spatial structure and propagation characteristics of an optical wave,mediated by suitable optical media.There are many emerging photonic applications of spin-orbit interactions(SOI)of light,such as control of the optical wave propagation via the spin,enhanced optical manipulation,and generation of structured optical fields.Unfortunately,current applications are based on symmetric SOI,that is,the behaviours of polarized photons with two opposite spins are opposite,leading to the limit of spin-based multiplexers.The symmetry of SOI can be broken in our proposed metasurfaces,consisting of spatially varying birefringence,which can arbitrarily and independently build SOI for two opposite spins without reduction of optical energy usage.We obtain three kinds of dual-functional metasurfaces at visible and infrared wavelengths with high efficiency.Our concept of generation of asymmetric SOI for two spins,using anisotropic metasurfaces,will open new degrees of freedoms for building new types of spin-controlled multifunctional shared-aperture devices for the generation of complex structured optical fields.
文摘In this study, a complex analysis of a man-weapon interaction based on experimental effort is presented.The attention is focused on how a shooter can influence on a rifle, opposite to generally considered in literature rifle's impact on a shooter. It is shown, based on the kbk AKM weapon, that each support point of the rifle has an substantial impact on the system. It is said that identifying human reactions on weapon may let to describe gun movement and thus may be applied to weapon accuracy determination.
基金Projects(51304035,50974030)supported by the National Natural Science Foundation of ChinaProject(20110491512)supported by the Postdoctoral Science Foundation of China+2 种基金Project(20130042120034)supported by the Specialized Research Fund for the Doctoral Program of Higher Education(New Teachers),ChinaProject(120401008)supported by the Fundamental Research Funds for Central Universities,ChinaProject(L20150173)supported by the Scientific Research Fund of Liaoning Provincial Education Department,China
文摘Taking into consideration the gas compressibility and chemical reaction reversibility, a model was developed to study the interactions between gas flow and chemical reaction in porous media and resolved by the finite volume method on the basis of the gas-solid reaction aA(g)+bB(s)cC(g)+dD(s).The numerical analysis shows that the equilibrium constant is an important factor influencing the process of gas-solid reaction. The stoichiometric coefficients, molar masses of reactant gas, product gas and inert gas are the main factors influencing the density of gas mixture. The equilibrium constant influences the gas flow in porous media obviously when the stoichiometric coefficients satisfy a/c≠1.
基金the National Natural Science Foundation of China (60503024 60374032)
文摘Conventional artificial fish has some shortages on the interaction with environment, other fish, and the animator. This article proposes a multi-tier interaction control model of artificial fish, realizes the interaction model through integration of virtual reality technology and Markov sequence, and provides a virtual marine world to describe the interaction between artificial fish and the virtual environment and the interaction between the artificial fish and the animator. Simulation results show that the interaction model owns not only the basic characteristics of virtual biology, but also has high trueness interaction function.
文摘The interaction between a flotation reagent and mineral surface not only depends on the bonding atom, but also depends on the adjacent atom of mineral surface, a flotation reagent and the medium in the system of flotation. Energy equation of a reagent interacting with mineral surface has been deduced from this model. Results of the studies indicate that the interaction energy between mineral surface and a reagent is about several dozen kJ/mol, and the relationship between adsorbing concentration of xanthate on mineral surface and interaction energy is the exponent form.
