Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable p...Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m（PEG）/m（RF） and the （relative） molecular mass of PEG on the pore structure and electric double layer capacitance（EDLC） performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach （755 m2/g） and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels.展开更多
A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-di...A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-dibromobutane and pyrrolidine, and subsequent ion exchange pathway with KOH followed by neutralization reaction via HBF4 in the system of ethanol solution. 1H NMR, 13 C NMR, FI-IR and XPS analyses showed the structure of SBP-BF4. The as-obtained SBP-BF4 was dissolved in AN and used as the electrolyte for supercapacitor. Electrochemical measurements demonstrate that, compared with commercial electrolyte TEMA-BF4/AN, SBP-BF4/AN exhibits high ionic conductivity, lower resistance and improved cycling performance, which is due to its smaller ion size and stable symmetry structure.展开更多
In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance...In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance tomography(ECT)is a technique for visualizing two-phase flow in a pipe or closed container.In this paper,a visual detection method was proposed by image reconstruction of core,laminar,bubble and annular flow based on ECT technology,which reflects distribution of slurry in deep filling pipeline and measures the degree of blockage.There is an error between the measured and the real two-phase flow distribution due to two factors,which are immature image reconstruction algorithm of ECT and difference of flow patterns leading to degrees of error.In this paper,convolutional neural networks(CNN)is used to recognize flow patterns,and then the optimal image is calculated by the improved particle swarm optimization(PSO)algorithm with weights using simulated annealing strategy,and the fitness function is improved based on the results of the shallow neural network.Finally,the reconstructed binary image is further processed to obtain the position,size and direction of the blocked pipe.The realization of this method provides technical support for pipeline detection technology.展开更多
Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is ...Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is first application of the method to visualization of water flow in soil.We describe the principles behind the method,and then demonstrate its use with a simple laboratory infiltration experiment.32 ECVT sensors were installed on the sides of an empty PVC column.Water was poured into the column at a constant rate,and ECVT data were collected every second.The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second.Data were analyzed to give bulk average water contents,which proved consistent with the water supply rates.Data were also analyzed to give 3D images(216 voxels) allowing visualization of the water distribution during the experiments.Result of this work shows that water infiltration into the soil,wall flow,progress of the unstable wetting front and the final water distribution are clearly visible.展开更多
The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can...The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can not be implemented and the data from this sensor may be unreliable due to the sensor pipe interior wall abrasion during pneumatic transport,so the solids concentration calculated from the reconstructed image based on these data will be highly inaccurate.The simulations show that, the inter-electrode relative capacitance variation of electrode pair spacing 1 is the most sensitive to the abrasion of sensor pipe interior wall, so this relative capacitance variation when the sensor is filled with air can be used as an indicator demanding offline system recalibration when the wall abrasion goes significant.Furthermore, while the pipe interior wall abrasion is not very serious, online correcting measured inter-electrode capacitance with wall capacitance variation can improve the accuracy of concentration calculation.展开更多
特高压直流换流阀的电磁场和电磁兼容性是其研制过程中的关键问题,国内外学者对此进行了系统研究。中国电力科学研究院成功研制出中国首个具有完全自主知识产权的800 kV/4 750 A特高压直流（ultra high voltage directcurrent,UHVDC）...特高压直流换流阀的电磁场和电磁兼容性是其研制过程中的关键问题,国内外学者对此进行了系统研究。中国电力科学研究院成功研制出中国首个具有完全自主知识产权的800 kV/4 750 A特高压直流（ultra high voltage directcurrent,UHVDC）换流阀。针对电磁场和电磁兼容问题,利用三维电场边界元法实现换流阀寄生参数的提取,通过理论计算、数值仿真及试验测试等多种手段,对瞬态电磁干扰等问题提出了解决方案,为换流阀的研制和工程应用提供了必要的技术支撑。总结了上述领域的研究成果,对未来特高压直流换流阀电磁兼容领域的研究课题与解决方案提出了一些建议和设想。展开更多
文摘Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m（PEG）/m（RF） and the （relative） molecular mass of PEG on the pore structure and electric double layer capacitance（EDLC） performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach （755 m2/g） and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels.
基金Project(51371198)supported by the National Natural Science Foundation of China
文摘A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-dibromobutane and pyrrolidine, and subsequent ion exchange pathway with KOH followed by neutralization reaction via HBF4 in the system of ethanol solution. 1H NMR, 13 C NMR, FI-IR and XPS analyses showed the structure of SBP-BF4. The as-obtained SBP-BF4 was dissolved in AN and used as the electrolyte for supercapacitor. Electrochemical measurements demonstrate that, compared with commercial electrolyte TEMA-BF4/AN, SBP-BF4/AN exhibits high ionic conductivity, lower resistance and improved cycling performance, which is due to its smaller ion size and stable symmetry structure.
基金Project(51704229)supported by the National Natural Science Foundation of ChinaProject(2018YQ2-01)supported by the Outstanding Youth Science Fund of Xi’an University of Science and Technology,China。
文摘In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance tomography(ECT)is a technique for visualizing two-phase flow in a pipe or closed container.In this paper,a visual detection method was proposed by image reconstruction of core,laminar,bubble and annular flow based on ECT technology,which reflects distribution of slurry in deep filling pipeline and measures the degree of blockage.There is an error between the measured and the real two-phase flow distribution due to two factors,which are immature image reconstruction algorithm of ECT and difference of flow patterns leading to degrees of error.In this paper,convolutional neural networks(CNN)is used to recognize flow patterns,and then the optimal image is calculated by the improved particle swarm optimization(PSO)algorithm with weights using simulated annealing strategy,and the fitness function is improved based on the results of the shallow neural network.Finally,the reconstructed binary image is further processed to obtain the position,size and direction of the blocked pipe.The realization of this method provides technical support for pipeline detection technology.
文摘Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is first application of the method to visualization of water flow in soil.We describe the principles behind the method,and then demonstrate its use with a simple laboratory infiltration experiment.32 ECVT sensors were installed on the sides of an empty PVC column.Water was poured into the column at a constant rate,and ECVT data were collected every second.The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second.Data were analyzed to give bulk average water contents,which proved consistent with the water supply rates.Data were also analyzed to give 3D images(216 voxels) allowing visualization of the water distribution during the experiments.Result of this work shows that water infiltration into the soil,wall flow,progress of the unstable wetting front and the final water distribution are clearly visible.
文摘The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can not be implemented and the data from this sensor may be unreliable due to the sensor pipe interior wall abrasion during pneumatic transport,so the solids concentration calculated from the reconstructed image based on these data will be highly inaccurate.The simulations show that, the inter-electrode relative capacitance variation of electrode pair spacing 1 is the most sensitive to the abrasion of sensor pipe interior wall, so this relative capacitance variation when the sensor is filled with air can be used as an indicator demanding offline system recalibration when the wall abrasion goes significant.Furthermore, while the pipe interior wall abrasion is not very serious, online correcting measured inter-electrode capacitance with wall capacitance variation can improve the accuracy of concentration calculation.
文摘特高压直流换流阀的电磁场和电磁兼容性是其研制过程中的关键问题,国内外学者对此进行了系统研究。中国电力科学研究院成功研制出中国首个具有完全自主知识产权的800 kV/4 750 A特高压直流（ultra high voltage directcurrent,UHVDC）换流阀。针对电磁场和电磁兼容问题,利用三维电场边界元法实现换流阀寄生参数的提取,通过理论计算、数值仿真及试验测试等多种手段,对瞬态电磁干扰等问题提出了解决方案,为换流阀的研制和工程应用提供了必要的技术支撑。总结了上述领域的研究成果,对未来特高压直流换流阀电磁兼容领域的研究课题与解决方案提出了一些建议和设想。
