This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This researc...This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This research examines the flow of a three-layered viscous fluid,considering the combined influence of heat and solutal buoyancy driven Rayleigh-Bénard convection,as well as thermal and solutal Marangoni convection.The homotopy perturbation method is used to examine and simulate complex fluid flow and transport phenomena,providing important understanding of the fundamental physics and assisting in the optimization of various battery configurations.The inquiry examines the primary elements that influence Marangoni convection and its impact on battery performance,providing insights on possible enhancements in energy storage devices.The findings indicate that the velocity profiles shown graphically exhibit a prominent core zone characterized by the maximum speed,which progressively decreases as it approaches the walls of the channel.This study enhances our comprehension of fluid dynamics and the transmission of heat and mass in intricate systems,which has substantial ramifications for the advancement of sustainable energy solutions.展开更多
During the storage of composite propellants, the migration of plasticizers and other unbonded additives at the interfaces of liner adhesives has garnered significant attention in understanding liner failure mechanisms...During the storage of composite propellants, the migration of plasticizers and other unbonded additives at the interfaces of liner adhesives has garnered significant attention in understanding liner failure mechanisms, aging processes, and safety performance. However, there is currently no non-destructive and quantitative detection method for migration of plasticizers in propellant liner. In this study, we developed a HTPB sensing liner by incorporating conductive fillers-namely carbon black(CB), carbon nanotubes(CNTs), and graphene nanoplatelets(GNP)-into the HTPB matrix. The synergistic interaction between CNTs and GNP facilitates the formation of a tunneling conductive network that imparts electrical conductivity to the HTPB liner. To elucidate the functional relationship between conductivity and nitroglycerin(NG) migration, we applied the HTPB sensing liner onto double base propellant surfaces and measured both the conductivity of the sensing layer and NG migration during a 71°C accelerated aging experiment. The results shows that when CNTs/GNP content reaches 3wt%, there is an exponential correlation between conductivity and NG migration with a fitting degree of 0.9652;the average response sensitivity of ΔR/R0 relative to NG migration is calculated as 41.69, with an average deviation of merely5.67% between NG migrations derived from conductivity fittings compared to those obtained via TGA testing results. Overall, this sensing liner exhibits excellent capabilities for detecting NG migration nondestructively and quantitatively while offering a novel approach for assessing interfacial component migrations as well as debonding defects in propellants-a promising avenue for future self-monitoring strategies regarding propellant integrity.展开更多
In this study,magneto-hydrodynamics (MHD) mixed convection effects of Al2O3-water nanofluid flow over a backward-facing step were investigated numerically for various electrical conductivity models of nanofluids.A uni...In this study,magneto-hydrodynamics (MHD) mixed convection effects of Al2O3-water nanofluid flow over a backward-facing step were investigated numerically for various electrical conductivity models of nanofluids.A uniform external magnetic field was applied to the flow and strength of magnetic field was varied with different values of dimensionless parameter Hartmann number (Ha=0,10,20,30,40).Three different electrical conductivity models were used to see the effects of MHD nanofluid flow.Besides,five different inclination angles between 0°-90° is used for the external magnetic field.The problem geometry is a backward-facing step which is used in many engineering applications where flow separation and reattachment phenomenon occurs.Mixed type convective heat transfer of backward-facing step was examined with various values of Richardson number (Ri=0.01,0.1,1,10) and four different nanoparticle volume fractions (Ф=0.01,0.015,0.020,0.025) considering different electrical conductivity models.Finite element method via commercial code COMSOL was used for computations.Results indicate that the addition of nanoparticles enhanced heat transfer significantly.Also increasing magnetic field strength and inclination angle increased heat transfer rate.Effects of different electrical conductivity models were also investigated and it was observed that they have significant effects on the fluid flow and heat transfer characteristics in the presence of magnetic field.展开更多
The effects of contents of AlF3 and Al2O3, and temperature on electrical conductivity of （Na3AlF6-40%K3AlF6）- AlF3-Al2O3 were studied by continuously varying cell censtant （CVCC） technique. The results show that t...The effects of contents of AlF3 and Al2O3, and temperature on electrical conductivity of （Na3AlF6-40%K3AlF6）- AlF3-Al2O3 were studied by continuously varying cell censtant （CVCC） technique. The results show that the conductivities of melts increase with the increase of temperature, but by different extents. Every increasing 10 ℃ results in an increase of 1.85 × 10^-2, 1.86× 10^-2, 1.89 × 10^-2 and 2.20 × 10^-2 S/cm in conductivity for the （Na3AlF6-40%K3AlF6）-AlF3 melts containing 0%, 20%, 24%, and 30% AlF3, respectively. An increase of every 10 ℃ in temperature results an increase about 1.89× 10^-2, 1.94 × 10^-2, 1.95 × 10^-2, 1.99× 10^-2 and 2.10× 10^-2 S/cm for （Na3AlF6-40%K3AlF6）-AlF3-Al2O3 melts containing 0%, 1%, 2%, 3% and 4% Al2O3, respectively. The activation energy of conductance was calculated based on Arrhenius equation. Every increasing 1% of AlF3 results in a decrease of 0.019 and 0.020 S/cm in conductivity for （Na3AlF6-40%K3AlF6）-AlF3 melts at 900 and 1 000 ℃, respectively. Every increase of 1% Al2O3 results in a decrease of 0.07 S/cm in conductivity for （Na3AlF6-40%K3AlF6）-AlF3-Al2O3 melts. The activation energy of conductance increases with the increase in content of AlF3 and Al2O3.展开更多
In order to predict and control the properties of Cu-Cr-Sn-Zn alloy,a model of aging processes via an artificial neural network(ANN) method to map the non-linear relationship between parameters of aging process and th...In order to predict and control the properties of Cu-Cr-Sn-Zn alloy,a model of aging processes via an artificial neural network(ANN) method to map the non-linear relationship between parameters of aging process and the hardness and electrical conductivity properties of the Cu-Cr-Sn-Zn alloy was set up.The results show that the ANN model is a very useful and accurate tool for the property analysis and prediction of aging Cu-Cr-Sn-Zn alloy.Aged at 470-510 ℃ for 4-1 h,the optimal combinations of hardness 110-117(HV) and electrical conductivity 40.6-37.7 S/m are available respectively.展开更多
The electrical conductivity of Cu-Li alloys was studied. And the distribution of electrons near Fermi surface was detected by synchrotron radiation instrument. The results show that the electrical conductivity of Cu-L...The electrical conductivity of Cu-Li alloys was studied. And the distribution of electrons near Fermi surface was detected by synchrotron radiation instrument. The results show that the electrical conductivity of Cu-Li alloys decreases from 5.22 X 10(-9) S/m to 3.69 X 10(-9) S/m with the increase of Li content. Li can decrease the oxygen, sulfur and other impurities content in commercial Cu, but Li dissolved in Cu lattice leads to distortion of Cu lattice from 0.005%-0.050%, affects the valence band of Cu, increases the binding energy of surface electron, and decreases the electron density of Fermi surface simultaneously. So the electrical conductivity decreases gradually with the increase of Li content.展开更多
Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of ...Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of metal Cu on the electrical conductivity were investigated especially. The results indicate that the metallic phase Cu distributes evenly in 10NiO-NiFe2O4 ceramic matrix. The mechanism of electrical conductivity of Cu/(10NiO-NiFe2O4) cermets obeys the rule of electrical mechanism of semiconductor, the electrical conductivity for cermet containing 5% Cu increases from 2.70 to 20.41 S/cm with temperature increasing from 200 to 900 ℃. The change trend of electrical conductivity with temperature is similar with each other and it increases with increasing temperature and content of metal Cu. At 960 ℃, the electrical conductivity of cermet increases from 2.88 to 82.65 S/cm with the content of metal Cu increasing from 0 to 20%.展开更多
xNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets and those doped with 1% BaO （mass fraction） were prepared by cold isostatic pressing at 200 MPa and sintering in nitrogen atmosphere at 1 473 K. The effects of BaO addition ...xNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets and those doped with 1% BaO （mass fraction） were prepared by cold isostatic pressing at 200 MPa and sintering in nitrogen atmosphere at 1 473 K. The effects of BaO addition on relative density, microstructure and electric conductivity of cermets were investigated. The results show that relative densities ofxNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 473 K in nitrogen atmosphere are increased by 0.49%, 1.45% and 2.99% compared with those of the undoped BaO cermets, respectively. Moreover, the electric conductivities （21.98, 28.37 and 50.10 S/cm） of xNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 233 K are improved compared with those （18.70, 22.79 and 39.58 S/cm） of xNi/lONiO-NiFe2O4 cermets （x=5, 10, 17）, respectively. This indicates that perhaps the addition of BaO or formation of BaFe204 and Ba2Fe2O5 has an active effect on electric conductivities ofxNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets.展开更多
Nanoqueous phase liquid(NAPL) simulator is a powerful and popular mathematical model for modeling the flow and transport of non-aqueous phase liquids in subsurface,but the testing of its feasibility under water table ...Nanoqueous phase liquid(NAPL) simulator is a powerful and popular mathematical model for modeling the flow and transport of non-aqueous phase liquids in subsurface,but the testing of its feasibility under water table fluctuation has received insufficient attention.The feature in a column test was tested through two cycles of water table fluctuation.The sandy medium in the column was initially saturated,and each cycle of water table fluctuation consisted of one water table falling and one rising,resulting in a drainage and an imbibition of the medium,respectively.It was found that the difference between the simulated and measured results in the first drainage of the column test was minor.However,with the propagation of the water table fluctuations,the simulation errors increased,and the simulation accuracy was not acceptable except for the first drainage in the two fluctuation cycles.The main reason was proved to be the estimation method of residual saturation used in this simulator.Also,based on the column tests,it was assumed that the resulting residual saturation from an incomplete imbibition process was a constant,with a value equal to that of the residual value resulting from the main imbibition process.The results obtained after modifying NAPL simulator with this assumption were found to be more accurate in the first cycle of water table fluctuation,but this accuracy decreased rapidly in the second one.It is concluded that NAPL simulator is not adequate in the case of LNAPL migration under water table fluctuation in sandy medium,unless a feasible assumption to estimate residual saturation is put forward.展开更多
This study presents a comprehensive comparison of the electro-osmosis treatments of heavy metal contaminated soil using electrokinetic geosynthetics(EKG)and iron electrodes in terms of both theoretical analysis and ex...This study presents a comprehensive comparison of the electro-osmosis treatments of heavy metal contaminated soil using electrokinetic geosynthetics(EKG)and iron electrodes in terms of both theoretical analysis and experimental research.The variation in the electrical parameters was analyzed,and the results show linear relationships between temperature and conductivity and between the soil and pore water conductivities.The average cathode contact resistance of iron is60%smaller than that of EKG,whereas the average anode contact resistance of EKG is56%smaller than that of iron.The values of the power consumption per unit mass of contaminants for EKG and iron are1.895and1.989kJ/g,respectively.After electro-osmosis,the number of soil pores increased,but the average area decreased,with an average area of0.9100–1.0504μm^2.Based on microstructure analysis,we obtained higher electroosmotic efficiency and realized the effective analysis and utilization between macroscopic and microscopic parameters.展开更多
Electrical conductivity(EC)is considered as the most important indicator for assessment of groundwater quality.Determination of suitable interpolation method for derivation of groundwater quality variables map such as...Electrical conductivity(EC)is considered as the most important indicator for assessment of groundwater quality.Determination of suitable interpolation method for derivation of groundwater quality variables map such as EC is dependent on region conditions and existence of enough data.For determining groundwater EC,341 groundwater samples were randomly collected from the central regions of Guilan province,paddy soils,in northern Iran.Interpolation methods including inverse distance weighting(IDW),global polynomial interpolation(GPI),local polynomial interpolation(LPI),radial basis function(RBF),ordinary kriging(OK)and empirical Bayesian Kriging(EBK)were used to generate spatial distribution of groundwater EC.The results indicate that EBK is a superior method with the least RMSE,MAE and the highest R 2.The generated maps can be used to identify the regions in the studied area where groundwater could be allowed to be extracted and utilized by farmers to reduce adverse effect of the scarcity of surface water.展开更多
In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied ...In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied voltages and flow rates.The results showed that to obtain stable cone-jet mode spraying and hence gain better monodispersity of droplets,electrical conductivity,viscosity and surface tension of the liquid are important controlling factors.The stable cone-jet mode could be easily established for liquids having shear viscosities in the range from 80 to 1 400 mPa·s and surface tensions below 65 mN·m-1.In contrast,methylcellulose aqueous solutions with shear viscosities ranging from 10 to 540 mPa·s and moderate surface tensions(50~56 mN·m-1)generated more complicated spraying modes.However,fine TiO2 powder(a few micrometers in size)could be prepared using the EA method from its precursor solutions.展开更多
A water-in-oil (W/O) microemulsion composed of Triton X-100, n-hexanol, n-hexane and water solution with hydrochloric acid was prepared. K3Fe(CN)6 was added in as a water-soluble electroactive probe, and its electroch...A water-in-oil (W/O) microemulsion composed of Triton X-100, n-hexanol, n-hexane and water solution with hydrochloric acid was prepared. K3Fe(CN)6 was added in as a water-soluble electroactive probe, and its electrochemical behavior was investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). It is found that the H+ concentration of the water phase has a great effect on the conductivity of the W/O microemulsion, and hence influences the electrochemical behavior of K3Fe(CN)6. When the pH value of water phase is about 7, the electrical conductivity of the W/O microemulsion is only 1.2×10-6 S/cm, and K3Fe(CN)6 almost cannot react at the glassy carbon electrode. But when the H+ concentration is more than 3 mol/L, the W/O microemulsion has a good electrical conductivity and K3Fe(CN)6 shows good electrochemical performance in it. The results of CV and EIS studies indicate that the electrochemical behavior of Fe(CN)63-/Fe(CN)64- in the W/O microemulsion is different from that in the aqueous solution. This may be due to the unique liquid structure of the W/O microemulsion and the unique mass transfer in the W/O microemulsion.展开更多
基金Project(52276068)supported by the National Natural Science Foundation of China。
文摘This study examines the intricate occurrences of thermal and solutal Marangoni convection in three-layered flows of viscous fluids,with a particular emphasis on their relevance to renewable energy systems.This research examines the flow of a three-layered viscous fluid,considering the combined influence of heat and solutal buoyancy driven Rayleigh-Bénard convection,as well as thermal and solutal Marangoni convection.The homotopy perturbation method is used to examine and simulate complex fluid flow and transport phenomena,providing important understanding of the fundamental physics and assisting in the optimization of various battery configurations.The inquiry examines the primary elements that influence Marangoni convection and its impact on battery performance,providing insights on possible enhancements in energy storage devices.The findings indicate that the velocity profiles shown graphically exhibit a prominent core zone characterized by the maximum speed,which progressively decreases as it approaches the walls of the channel.This study enhances our comprehension of fluid dynamics and the transmission of heat and mass in intricate systems,which has substantial ramifications for the advancement of sustainable energy solutions.
基金funded by Zhijian Laboratory Open Fund,Rocket Force University of Engineering(Grant No.2023-ZJSYS-KF01-03).
文摘During the storage of composite propellants, the migration of plasticizers and other unbonded additives at the interfaces of liner adhesives has garnered significant attention in understanding liner failure mechanisms, aging processes, and safety performance. However, there is currently no non-destructive and quantitative detection method for migration of plasticizers in propellant liner. In this study, we developed a HTPB sensing liner by incorporating conductive fillers-namely carbon black(CB), carbon nanotubes(CNTs), and graphene nanoplatelets(GNP)-into the HTPB matrix. The synergistic interaction between CNTs and GNP facilitates the formation of a tunneling conductive network that imparts electrical conductivity to the HTPB liner. To elucidate the functional relationship between conductivity and nitroglycerin(NG) migration, we applied the HTPB sensing liner onto double base propellant surfaces and measured both the conductivity of the sensing layer and NG migration during a 71°C accelerated aging experiment. The results shows that when CNTs/GNP content reaches 3wt%, there is an exponential correlation between conductivity and NG migration with a fitting degree of 0.9652;the average response sensitivity of ΔR/R0 relative to NG migration is calculated as 41.69, with an average deviation of merely5.67% between NG migrations derived from conductivity fittings compared to those obtained via TGA testing results. Overall, this sensing liner exhibits excellent capabilities for detecting NG migration nondestructively and quantitatively while offering a novel approach for assessing interfacial component migrations as well as debonding defects in propellants-a promising avenue for future self-monitoring strategies regarding propellant integrity.
文摘In this study,magneto-hydrodynamics (MHD) mixed convection effects of Al2O3-water nanofluid flow over a backward-facing step were investigated numerically for various electrical conductivity models of nanofluids.A uniform external magnetic field was applied to the flow and strength of magnetic field was varied with different values of dimensionless parameter Hartmann number (Ha=0,10,20,30,40).Three different electrical conductivity models were used to see the effects of MHD nanofluid flow.Besides,five different inclination angles between 0°-90° is used for the external magnetic field.The problem geometry is a backward-facing step which is used in many engineering applications where flow separation and reattachment phenomenon occurs.Mixed type convective heat transfer of backward-facing step was examined with various values of Richardson number (Ri=0.01,0.1,1,10) and four different nanoparticle volume fractions (Ф=0.01,0.015,0.020,0.025) considering different electrical conductivity models.Finite element method via commercial code COMSOL was used for computations.Results indicate that the addition of nanoparticles enhanced heat transfer significantly.Also increasing magnetic field strength and inclination angle increased heat transfer rate.Effects of different electrical conductivity models were also investigated and it was observed that they have significant effects on the fluid flow and heat transfer characteristics in the presence of magnetic field.
基金Project(2005CB623703) supported by the Major State Basic Research and Development Program of ChinaProject(2008AA030503) supported by the National High-Tech Research and Development Program of ChinaProject(GUIKEJI 0639032) supported by Applied Basic Research in Guangxi Province, China
文摘The effects of contents of AlF3 and Al2O3, and temperature on electrical conductivity of （Na3AlF6-40%K3AlF6）- AlF3-Al2O3 were studied by continuously varying cell censtant （CVCC） technique. The results show that the conductivities of melts increase with the increase of temperature, but by different extents. Every increasing 10 ℃ results in an increase of 1.85 × 10^-2, 1.86× 10^-2, 1.89 × 10^-2 and 2.20 × 10^-2 S/cm in conductivity for the （Na3AlF6-40%K3AlF6）-AlF3 melts containing 0%, 20%, 24%, and 30% AlF3, respectively. An increase of every 10 ℃ in temperature results an increase about 1.89× 10^-2, 1.94 × 10^-2, 1.95 × 10^-2, 1.99× 10^-2 and 2.10× 10^-2 S/cm for （Na3AlF6-40%K3AlF6）-AlF3-Al2O3 melts containing 0%, 1%, 2%, 3% and 4% Al2O3, respectively. The activation energy of conductance was calculated based on Arrhenius equation. Every increasing 1% of AlF3 results in a decrease of 0.019 and 0.020 S/cm in conductivity for （Na3AlF6-40%K3AlF6）-AlF3 melts at 900 and 1 000 ℃, respectively. Every increase of 1% Al2O3 results in a decrease of 0.07 S/cm in conductivity for （Na3AlF6-40%K3AlF6）-AlF3-Al2O3 melts. The activation energy of conductance increases with the increase in content of AlF3 and Al2O3.
基金Project(2006AA03Z528) supported by the National High-Tech Research and Development Program of ChinaProject(102102210174) supported by the Science and Technology Research Project of Henan Province,ChinaProject(2008ZDYY005) supported by Special Fund for Important Forepart Research in Henan University of Science and Technology
文摘In order to predict and control the properties of Cu-Cr-Sn-Zn alloy,a model of aging processes via an artificial neural network(ANN) method to map the non-linear relationship between parameters of aging process and the hardness and electrical conductivity properties of the Cu-Cr-Sn-Zn alloy was set up.The results show that the ANN model is a very useful and accurate tool for the property analysis and prediction of aging Cu-Cr-Sn-Zn alloy.Aged at 470-510 ℃ for 4-1 h,the optimal combinations of hardness 110-117(HV) and electrical conductivity 40.6-37.7 S/m are available respectively.
文摘The electrical conductivity of Cu-Li alloys was studied. And the distribution of electrons near Fermi surface was detected by synchrotron radiation instrument. The results show that the electrical conductivity of Cu-Li alloys decreases from 5.22 X 10(-9) S/m to 3.69 X 10(-9) S/m with the increase of Li content. Li can decrease the oxygen, sulfur and other impurities content in commercial Cu, but Li dissolved in Cu lattice leads to distortion of Cu lattice from 0.005%-0.050%, affects the valence band of Cu, increases the binding energy of surface electron, and decreases the electron density of Fermi surface simultaneously. So the electrical conductivity decreases gradually with the increase of Li content.
基金Project(2005CB623703) supported by the National Basic Research and Development Program of China
文摘Cu/(10NiO-NiFe2O4) cermets containing mass fractions of Cu of 5%, 10%, 15% and 20% were prepared, and their electrical conductivities were measured at different temperatures. The effects of temperature and content of metal Cu on the electrical conductivity were investigated especially. The results indicate that the metallic phase Cu distributes evenly in 10NiO-NiFe2O4 ceramic matrix. The mechanism of electrical conductivity of Cu/(10NiO-NiFe2O4) cermets obeys the rule of electrical mechanism of semiconductor, the electrical conductivity for cermet containing 5% Cu increases from 2.70 to 20.41 S/cm with temperature increasing from 200 to 900 ℃. The change trend of electrical conductivity with temperature is similar with each other and it increases with increasing temperature and content of metal Cu. At 960 ℃, the electrical conductivity of cermet increases from 2.88 to 82.65 S/cm with the content of metal Cu increasing from 0 to 20%.
基金Project(2005CB623703) supported by the National Basic Research Program of ChinaProject(50721003) supported by the National Natural Science Fund for Innovation Group of ChinaProject(2008AA030501) supported by the National High-Tech Research and Development Program of China
文摘xNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets and those doped with 1% BaO （mass fraction） were prepared by cold isostatic pressing at 200 MPa and sintering in nitrogen atmosphere at 1 473 K. The effects of BaO addition on relative density, microstructure and electric conductivity of cermets were investigated. The results show that relative densities ofxNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 473 K in nitrogen atmosphere are increased by 0.49%, 1.45% and 2.99% compared with those of the undoped BaO cermets, respectively. Moreover, the electric conductivities （21.98, 28.37 and 50.10 S/cm） of xNi/10NiO-NiFe2O4 cermets （x=5, 10, 17） doped with 1% BaO at 1 233 K are improved compared with those （18.70, 22.79 and 39.58 S/cm） of xNi/lONiO-NiFe2O4 cermets （x=5, 10, 17）, respectively. This indicates that perhaps the addition of BaO or formation of BaFe204 and Ba2Fe2O5 has an active effect on electric conductivities ofxNi/10NiO-NiFe2O4 （x=5, 10, 17） cermets.
基金Project(41072182)supported by the National Natural Science Foundation of ChinaProject(2010Z1-E101)supported by Science and Technology Program of Guangzhou City,China+1 种基金Project(20100103)supported by Science and Technology Program of Daya Bay,Huizhou City,ChinaProject(2012A030700008)supported by the Science and Technology Planning Program of Guangdong Province,China
文摘Nanoqueous phase liquid(NAPL) simulator is a powerful and popular mathematical model for modeling the flow and transport of non-aqueous phase liquids in subsurface,but the testing of its feasibility under water table fluctuation has received insufficient attention.The feature in a column test was tested through two cycles of water table fluctuation.The sandy medium in the column was initially saturated,and each cycle of water table fluctuation consisted of one water table falling and one rising,resulting in a drainage and an imbibition of the medium,respectively.It was found that the difference between the simulated and measured results in the first drainage of the column test was minor.However,with the propagation of the water table fluctuations,the simulation errors increased,and the simulation accuracy was not acceptable except for the first drainage in the two fluctuation cycles.The main reason was proved to be the estimation method of residual saturation used in this simulator.Also,based on the column tests,it was assumed that the resulting residual saturation from an incomplete imbibition process was a constant,with a value equal to that of the residual value resulting from the main imbibition process.The results obtained after modifying NAPL simulator with this assumption were found to be more accurate in the first cycle of water table fluctuation,but this accuracy decreased rapidly in the second one.It is concluded that NAPL simulator is not adequate in the case of LNAPL migration under water table fluctuation in sandy medium,unless a feasible assumption to estimate residual saturation is put forward.
基金Project(51378469)supported by the National Natural Science Foundation of ChinaProject(2017C33034)supported by the Application Research of Public Welfare Technology in Zhejiang Province,China+1 种基金Project(LQ18E080001)supported by the Zhejiang Provincial Natural Science Foundation,ChinaProject(12017A610304)supported by the Natural Science Foundation of Ningbo City,China
文摘This study presents a comprehensive comparison of the electro-osmosis treatments of heavy metal contaminated soil using electrokinetic geosynthetics(EKG)and iron electrodes in terms of both theoretical analysis and experimental research.The variation in the electrical parameters was analyzed,and the results show linear relationships between temperature and conductivity and between the soil and pore water conductivities.The average cathode contact resistance of iron is60%smaller than that of EKG,whereas the average anode contact resistance of EKG is56%smaller than that of iron.The values of the power consumption per unit mass of contaminants for EKG and iron are1.895and1.989kJ/g,respectively.After electro-osmosis,the number of soil pores increased,but the average area decreased,with an average area of0.9100–1.0504μm^2.Based on microstructure analysis,we obtained higher electroosmotic efficiency and realized the effective analysis and utilization between macroscopic and microscopic parameters.
文摘Electrical conductivity(EC)is considered as the most important indicator for assessment of groundwater quality.Determination of suitable interpolation method for derivation of groundwater quality variables map such as EC is dependent on region conditions and existence of enough data.For determining groundwater EC,341 groundwater samples were randomly collected from the central regions of Guilan province,paddy soils,in northern Iran.Interpolation methods including inverse distance weighting(IDW),global polynomial interpolation(GPI),local polynomial interpolation(LPI),radial basis function(RBF),ordinary kriging(OK)and empirical Bayesian Kriging(EBK)were used to generate spatial distribution of groundwater EC.The results indicate that EBK is a superior method with the least RMSE,MAE and the highest R 2.The generated maps can be used to identify the regions in the studied area where groundwater could be allowed to be extracted and utilized by farmers to reduce adverse effect of the scarcity of surface water.
文摘In the present study,electrostatic atomization(EA)behavior of several test liquids having much higher viscosities(1 400 mPa·s)than have previously been studied was investigated by spraying at a series of applied voltages and flow rates.The results showed that to obtain stable cone-jet mode spraying and hence gain better monodispersity of droplets,electrical conductivity,viscosity and surface tension of the liquid are important controlling factors.The stable cone-jet mode could be easily established for liquids having shear viscosities in the range from 80 to 1 400 mPa·s and surface tensions below 65 mN·m-1.In contrast,methylcellulose aqueous solutions with shear viscosities ranging from 10 to 540 mPa·s and moderate surface tensions(50~56 mN·m-1)generated more complicated spraying modes.However,fine TiO2 powder(a few micrometers in size)could be prepared using the EA method from its precursor solutions.
基金Projects(20673036, J0830415) supported by the National Natural Science Foundation of ChinaProjects(05JT1026, 2007JT2013) supported by the Science Technology Project of Hunan Province, China
文摘A water-in-oil (W/O) microemulsion composed of Triton X-100, n-hexanol, n-hexane and water solution with hydrochloric acid was prepared. K3Fe(CN)6 was added in as a water-soluble electroactive probe, and its electrochemical behavior was investigated by cyclic voltammetry (CV) and electrochemical impedance spectroscopy (EIS). It is found that the H+ concentration of the water phase has a great effect on the conductivity of the W/O microemulsion, and hence influences the electrochemical behavior of K3Fe(CN)6. When the pH value of water phase is about 7, the electrical conductivity of the W/O microemulsion is only 1.2×10-6 S/cm, and K3Fe(CN)6 almost cannot react at the glassy carbon electrode. But when the H+ concentration is more than 3 mol/L, the W/O microemulsion has a good electrical conductivity and K3Fe(CN)6 shows good electrochemical performance in it. The results of CV and EIS studies indicate that the electrochemical behavior of Fe(CN)63-/Fe(CN)64- in the W/O microemulsion is different from that in the aqueous solution. This may be due to the unique liquid structure of the W/O microemulsion and the unique mass transfer in the W/O microemulsion.
