Grainy electrolytic manganese dioxide was prepared by electrodeposition in a 0.9 mol/L MnSO4 and 2.5 mol/LH2SO4 solution. The structure, particle size and appearance of the grainy electrolytic manganese dioxide were d...Grainy electrolytic manganese dioxide was prepared by electrodeposition in a 0.9 mol/L MnSO4 and 2.5 mol/LH2SO4 solution. The structure, particle size and appearance of the grainy electrolytic manganese dioxide were determined by powder X-ray diffraction, laser particle size analysis and scanning electron micrographs measurements. Current density has important effects on cell voltage, anodic current efficiency and particle size of the grainy electrolytic manganese dioxide, and the optimum current density is 30 A/dm2. The grainy electrolytic manganese dioxide electrodeposited under the optimum conditions consists of γ-MnO2 with an orthorhombic lattice structure; the grainy electrolytic manganese dioxide has a spherical or sphere-like appearance and a narrow particle size distribution with an average particle diameter of 7.237 μm.展开更多
The use of design method considering a coil temperature to maximize the thrust density of a double side coreless permanent magnet linear synchronous motor(PMLSM) was presented.The optimal current density where the coi...The use of design method considering a coil temperature to maximize the thrust density of a double side coreless permanent magnet linear synchronous motor(PMLSM) was presented.The optimal current density where the coil temperature reaches an allowable temperature with heat analysis was applied to a magnetic circuit design.Changing optimal current density is verified whenever the design parameters of the motor are altered.The design parameters of the motor were applied to thrust calculation.In this way,the optimal model,which is a reversal of the existing design method,is deduced.The results were compared with the experimental data to verify their validity.When the convection heat transfer coefficient is applied to other models,the results of the analysis and test values show good concordance.The method proposed has some limitations.展开更多
The influences of the mask wall angle on the current density distribution,shape of the evolving cavity and machining accuracy were investigated in electrochemical machining(ECM) by mask.A mathematical model was develo...The influences of the mask wall angle on the current density distribution,shape of the evolving cavity and machining accuracy were investigated in electrochemical machining(ECM) by mask.A mathematical model was developed to predict the shape evolution during the ECM by mask.The current density distribution is sensitive to mask wall angle.The evolution of cavity is determined by the current density distribution of evolving workpiece surface.The maximum depth is away from the center of holes machined,which leads to the island appearing at the center of cavity for mask wall angles greater than or equal to 90°(β≥90°).The experimental system was established and the simulation results were experimentally verified.The results indicate that the simulation results of cavity shape are consistent with the actual ones.The experiments also show that the repetition accuracy of matrix-hole for β≥90° is higher than that for β<90°.A hole taper is diminished,and the machining accuracy is improved with the mask wall angle increasing.展开更多
Non Pt based metals and alloys as electrode materials for methyl alcohol fuel cells have been investigated w ith an aim of finding high electrocatalytic surface property for the faster electrode reactions.Electrodes w...Non Pt based metals and alloys as electrode materials for methyl alcohol fuel cells have been investigated w ith an aim of finding high electrocatalytic surface property for the faster electrode reactions.Electrodes w ere fabricated by electrodeposition on pure Al foil,from an electrolyte of Ni,Co,Fe salts.The optimum condition of electrodeposition w ere found out by a series of experiments,varying the chemistry of the electrolyte,pH valve,temperature,current and cell potential.Polarization study of the coated Ni-Co or Ni-CoFe alloy on pure Al w as found to exhibit high exchange current density,indicating an improved electro catalytic surface w ith faster charge-discharge reactions at anode and cathode and low overvoltage.Electrochemical impedance studies on coated and uncoated surface clearly show ed that the polarization resistance and impedance w ere decreased by Ni-Co or Ni-Co-Fe coating.X-ray diffraction(XRD),energy dispersive X-ray spectroscopy(EDX)and atomic absorption spectroscopy(AAS)studies confirmed the presence of alloying elements and constituents of the alloy.The morphology of the deposits from scanning electron microscope(SEM)images indicated that the electrode surface w as a three dimensional space w hich increased the effective surface area for the electrode reactions to take place.展开更多
The exploding foil,which is a main influence factor of exploding foil initiator(EFI),was studied to improve the utilization rate of energy in EFI.The burst currents of three bridge foils with different shapes were mea...The exploding foil,which is a main influence factor of exploding foil initiator(EFI),was studied to improve the utilization rate of energy in EFI.The burst currents of three bridge foils with different shapes were measured,and the sensitivity of initiation charge made of HNS-IV was tested by slappers.The test results show that,for O-shaped bridge foil,the burst current density is maximal,and the initiating voltage at 50% of firing probability of HNS-IV is minimal.The O-shaped bridge foil can be used to improve the utilization rate of energy in EFI and reduce the firing energy.展开更多
According to time-sharing valuation principle (TSVP) of power supply, the relationships of current density and current efficiency at different acidities are obtained based on the processed data of electrolytic deposit...According to time-sharing valuation principle (TSVP) of power supply, the relationships of current density and current efficiency at different acidities are obtained based on the processed data of electrolytic deposition process of zinc (EDPZ) with the least square method (LSM). Thus an optimal model of time-sharing power supply system for EDPZ is established, which has been optimized by use of an improved efficient simulated annealing algorithm (SAA). Practical results show that industrial and mining enterprises can obtain enormous economic benefits every year.展开更多
文摘Grainy electrolytic manganese dioxide was prepared by electrodeposition in a 0.9 mol/L MnSO4 and 2.5 mol/LH2SO4 solution. The structure, particle size and appearance of the grainy electrolytic manganese dioxide were determined by powder X-ray diffraction, laser particle size analysis and scanning electron micrographs measurements. Current density has important effects on cell voltage, anodic current efficiency and particle size of the grainy electrolytic manganese dioxide, and the optimum current density is 30 A/dm2. The grainy electrolytic manganese dioxide electrodeposited under the optimum conditions consists of γ-MnO2 with an orthorhombic lattice structure; the grainy electrolytic manganese dioxide has a spherical or sphere-like appearance and a narrow particle size distribution with an average particle diameter of 7.237 μm.
基金Work supported by the Second Stage of Brain Korea 21 ProjectsChangwon National University in 2009-2010
文摘The use of design method considering a coil temperature to maximize the thrust density of a double side coreless permanent magnet linear synchronous motor(PMLSM) was presented.The optimal current density where the coil temperature reaches an allowable temperature with heat analysis was applied to a magnetic circuit design.Changing optimal current density is verified whenever the design parameters of the motor are altered.The design parameters of the motor were applied to thrust calculation.In this way,the optimal model,which is a reversal of the existing design method,is deduced.The results were compared with the experimental data to verify their validity.When the convection heat transfer coefficient is applied to other models,the results of the analysis and test values show good concordance.The method proposed has some limitations.
基金Project(50635040) supported by the National Natural Science Foundation of ChinaProject(2009AA044205) supported by the National High Technology Research and Development ProgramProject(BK2008043) supported by the Jiangsu Provincial Natural Science Foundation,China
文摘The influences of the mask wall angle on the current density distribution,shape of the evolving cavity and machining accuracy were investigated in electrochemical machining(ECM) by mask.A mathematical model was developed to predict the shape evolution during the ECM by mask.The current density distribution is sensitive to mask wall angle.The evolution of cavity is determined by the current density distribution of evolving workpiece surface.The maximum depth is away from the center of holes machined,which leads to the island appearing at the center of cavity for mask wall angles greater than or equal to 90°(β≥90°).The experimental system was established and the simulation results were experimentally verified.The results indicate that the simulation results of cavity shape are consistent with the actual ones.The experiments also show that the repetition accuracy of matrix-hole for β≥90° is higher than that for β<90°.A hole taper is diminished,and the machining accuracy is improved with the mask wall angle increasing.
文摘Non Pt based metals and alloys as electrode materials for methyl alcohol fuel cells have been investigated w ith an aim of finding high electrocatalytic surface property for the faster electrode reactions.Electrodes w ere fabricated by electrodeposition on pure Al foil,from an electrolyte of Ni,Co,Fe salts.The optimum condition of electrodeposition w ere found out by a series of experiments,varying the chemistry of the electrolyte,pH valve,temperature,current and cell potential.Polarization study of the coated Ni-Co or Ni-CoFe alloy on pure Al w as found to exhibit high exchange current density,indicating an improved electro catalytic surface w ith faster charge-discharge reactions at anode and cathode and low overvoltage.Electrochemical impedance studies on coated and uncoated surface clearly show ed that the polarization resistance and impedance w ere decreased by Ni-Co or Ni-Co-Fe coating.X-ray diffraction(XRD),energy dispersive X-ray spectroscopy(EDX)and atomic absorption spectroscopy(AAS)studies confirmed the presence of alloying elements and constituents of the alloy.The morphology of the deposits from scanning electron microscope(SEM)images indicated that the electrode surface w as a three dimensional space w hich increased the effective surface area for the electrode reactions to take place.
文摘The exploding foil,which is a main influence factor of exploding foil initiator(EFI),was studied to improve the utilization rate of energy in EFI.The burst currents of three bridge foils with different shapes were measured,and the sensitivity of initiation charge made of HNS-IV was tested by slappers.The test results show that,for O-shaped bridge foil,the burst current density is maximal,and the initiating voltage at 50% of firing probability of HNS-IV is minimal.The O-shaped bridge foil can be used to improve the utilization rate of energy in EFI and reduce the firing energy.
文摘According to time-sharing valuation principle (TSVP) of power supply, the relationships of current density and current efficiency at different acidities are obtained based on the processed data of electrolytic deposition process of zinc (EDPZ) with the least square method (LSM). Thus an optimal model of time-sharing power supply system for EDPZ is established, which has been optimized by use of an improved efficient simulated annealing algorithm (SAA). Practical results show that industrial and mining enterprises can obtain enormous economic benefits every year.
