The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditiona...The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.展开更多
Taking wall-flow diesel particulate filter(DPF) as the research objective and separately assuming its filtering wall to be composed of numerous spherical or cylindrical elements, two different mathematical models of s...Taking wall-flow diesel particulate filter(DPF) as the research objective and separately assuming its filtering wall to be composed of numerous spherical or cylindrical elements, two different mathematical models of steady filtration for wall-flow diesel particulate filter were developed and verified by experiments as well as numerically solved. Furthermore, the effects of the macroand micro-structural parameters of filtering wall and exhaust-flow characteristic parameters on trapping efficiency were also analyzed and researched. The results show that: 1) The two developed mathematical models are consistent with the prediction of variation of particulate size; the influence of various factors on the steady trapping efficiency is exactly the same. Compared to model 2, model 1 is more suitable for describing the steady filtration process of wall-flow diesel particulate filter; 2)The major influencing factors on steady trapping efficiency of wall-flow diesel particulate filter are the macro-and micro-structural parameters of filtering wall; and the secondary influencing factors are the exhaust-flow characteristic parameters and macro-structural parameters of filter; 3)The steady trapping efficiency will be improved by increasing filter body volume, pore density as well as wall thickness and by decreasing exhaust-flow, but effects will be weakened when particulate size exceeds a certain critical value; 4) The steady trapping efficiency will be significantly improved by increasing exhaust-flow temperature and filtering wall thickness, but effects will be also weakened when particulate size exceeds a certain critical value; 5) The steady trapping efficiency will approximately linearly increase with reducing porosity, micropore aperture and pore width.展开更多
The pretreatment for the removal of small molecules from poly(acrylic acid) sodium (PAAS) solution by continuous diafiltration was investigated using ultrafiltration membrane. The effects of PAAS concentration, pH, tr...The pretreatment for the removal of small molecules from poly(acrylic acid) sodium (PAAS) solution by continuous diafiltration was investigated using ultrafiltration membrane. The effects of PAAS concentration, pH, trans-membrane pressure and pretreatment time on the permeate concentration and permeate flux were studied. The results show that the necessary pretreatment time (NPT) increases with PAAS concentration, decreases with TMP. The change trend of permeate flux with time is affected by pH. The permeate fluxes rapidly decrease from the start, and then increase gradually to stable values at pH 5.0, pH 7.0 and pH 9.3. However, it decreases gradually with time till a state value at pH 3.0 (iso-electric point, IEP). The removal of small molecules is easy at pH greater than iso-electric point (IEP). The change of filtration potential with time indicates the similar trend to that of permeation concentration, but the former is more convenient for indication of NPT.展开更多
Humic substances (especially fulvic acid (FA)) are the major components of natural organic matter (NOM) that widely exist in drinking water source. Due to their potential effects on public health,the removal of FA was...Humic substances (especially fulvic acid (FA)) are the major components of natural organic matter (NOM) that widely exist in drinking water source. Due to their potential effects on public health,the removal of FA was one of the main concerns during the water treatment. Therefore,the contact filtration of FA by using aluminum sulfate as coagulant on the basis of jar tests was carried out. The effects of pH and coagulant dosage on the FA removal and the development of head loss were investigated. The results show that the range of pH value during the FA contact filtration can be effectively influenced by the dosage of aluminum sulfate,and the high aluminum sulfate dosage is an important factor that can result in early filter breakthrough. The FA filtration by deep-bed filtration or by membrane filtration is sometimes disparate under the same coagulation conditions. The choice of aluminum sulfate dosage by the method of membrane filtration,i.e. the "true color measurement",may result in inappropriate filter run,whereas it can be determined with simple jar tests by observing the formation of micro flocs. Considering the effects of pH on aluminum sulfate dosage and FA removal,the optimal pH range of 5.5?6.0 is suggested.展开更多
文摘The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.
基金Projects(5117604551276056)supported by the National Natural Science Foundation of China+1 种基金Projects(201208430262201306130031)supported by the National Studying Abroad Foundation of the China Scholarship Council
文摘Taking wall-flow diesel particulate filter(DPF) as the research objective and separately assuming its filtering wall to be composed of numerous spherical or cylindrical elements, two different mathematical models of steady filtration for wall-flow diesel particulate filter were developed and verified by experiments as well as numerically solved. Furthermore, the effects of the macroand micro-structural parameters of filtering wall and exhaust-flow characteristic parameters on trapping efficiency were also analyzed and researched. The results show that: 1) The two developed mathematical models are consistent with the prediction of variation of particulate size; the influence of various factors on the steady trapping efficiency is exactly the same. Compared to model 2, model 1 is more suitable for describing the steady filtration process of wall-flow diesel particulate filter; 2)The major influencing factors on steady trapping efficiency of wall-flow diesel particulate filter are the macro-and micro-structural parameters of filtering wall; and the secondary influencing factors are the exhaust-flow characteristic parameters and macro-structural parameters of filter; 3)The steady trapping efficiency will be improved by increasing filter body volume, pore density as well as wall thickness and by decreasing exhaust-flow, but effects will be weakened when particulate size exceeds a certain critical value; 4) The steady trapping efficiency will be significantly improved by increasing exhaust-flow temperature and filtering wall thickness, but effects will be also weakened when particulate size exceeds a certain critical value; 5) The steady trapping efficiency will approximately linearly increase with reducing porosity, micropore aperture and pore width.
基金Projects(21176264,21476265)supported by the National Natural Science Foundation of China
文摘The pretreatment for the removal of small molecules from poly(acrylic acid) sodium (PAAS) solution by continuous diafiltration was investigated using ultrafiltration membrane. The effects of PAAS concentration, pH, trans-membrane pressure and pretreatment time on the permeate concentration and permeate flux were studied. The results show that the necessary pretreatment time (NPT) increases with PAAS concentration, decreases with TMP. The change trend of permeate flux with time is affected by pH. The permeate fluxes rapidly decrease from the start, and then increase gradually to stable values at pH 5.0, pH 7.0 and pH 9.3. However, it decreases gradually with time till a state value at pH 3.0 (iso-electric point, IEP). The removal of small molecules is easy at pH greater than iso-electric point (IEP). The change of filtration potential with time indicates the similar trend to that of permeation concentration, but the former is more convenient for indication of NPT.
基金Project(2009ZX07424-004) supported by the Water Special Program of China
文摘Humic substances (especially fulvic acid (FA)) are the major components of natural organic matter (NOM) that widely exist in drinking water source. Due to their potential effects on public health,the removal of FA was one of the main concerns during the water treatment. Therefore,the contact filtration of FA by using aluminum sulfate as coagulant on the basis of jar tests was carried out. The effects of pH and coagulant dosage on the FA removal and the development of head loss were investigated. The results show that the range of pH value during the FA contact filtration can be effectively influenced by the dosage of aluminum sulfate,and the high aluminum sulfate dosage is an important factor that can result in early filter breakthrough. The FA filtration by deep-bed filtration or by membrane filtration is sometimes disparate under the same coagulation conditions. The choice of aluminum sulfate dosage by the method of membrane filtration,i.e. the "true color measurement",may result in inappropriate filter run,whereas it can be determined with simple jar tests by observing the formation of micro flocs. Considering the effects of pH on aluminum sulfate dosage and FA removal,the optimal pH range of 5.5?6.0 is suggested.
