Highly dispersed palladium nanoparticles were synthesized in the presence of immobilized ionic liquid on mesoporous silica SBA-15.PdNPs(2.4 nm)_me-Im@SBA-15 catalyst was prepared by the reduction using NaBH_4 as the r...Highly dispersed palladium nanoparticles were synthesized in the presence of immobilized ionic liquid on mesoporous silica SBA-15.PdNPs(2.4 nm)_me-Im@SBA-15 catalyst was prepared by the reduction using NaBH_4 as the reducing agent with controlled feed rate and has been investigated as ligand-free catalyst for Suzuki–Miyaura cross-coupling reaction at room temperature in aqueous solution under air.PdNPs catalyst was also prepared in situ from PdCl4_me-Im@SBA-15 during the reaction and demonstrated high activity and stability towards nitrobenzene hydrogenation at high temperature. Both catalysts were reusable at least for four recycle processes without significant loss in activity with simple procedure. The catalysts were characterized by TEM, EXAFS, FTIR and XPS.展开更多
This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significan...This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significantly increasing the insertion loss of the filter.Based on this,the article proposes an eightcavity ceramic waveguide filter design for 5G base stations.It also presents a detailed discussion on the influence of the cross-coupling slot lengths L2 and L4 on the transmission zeros positions during the filter optimization process and the relevant change rules.For the proposed optimized filter,the observed performance indicators include the center frequency of 3.5 GHz,working bandwidth of 200 MHz,an insertion loss of≤2.0 dB,return loss of≥19 dB,and out-of-band nearend suppression and out-of-band far-end suppression of≥39 dB and≥63 dB,respectively.The test performance results obtained for the sample,with structural parameters as per the simulation model,were in good agreement with the simulation results.展开更多
When fault occurs on cross-coupling autotransformer(AT)power supply traction network,the up-line and down-line feeder circuit breakers in the traction substation trip at the same time without selectivity,which leads t...When fault occurs on cross-coupling autotransformer(AT)power supply traction network,the up-line and down-line feeder circuit breakers in the traction substation trip at the same time without selectivity,which leads to an extended power failure.Based on equivalent circuit and Kirchhoff’s current law,the feeder current characteristic in the substation,AT station and sectioning post when T-R fault,F-R fault,and T-F fault occur are analyzed and their expressions are obtained.When the traction power supply system is equipped with wide-area protection measurement and control system,the feeder protection device in each station collects the feeder currents in other two stations through the wide-area protection channel and a wide-area current differential protection scheme based on the feeder current characteristic is proposed.When a short-circuit fault occurs in the power supply arm,all the feeder protection devices in each station receive the feeder currents with time stamp in other two stations.After data synchronous processing and logic judgment,the fault line of the power supply arm can be identified and isolated quickly.The simulation result based on MATLAB/Simulink shows that the power supply arm protection scheme based on wide-area current differential has good fault discrimination ability under different fault positions,transition resistances,and fault types.The verification of measured data shows that the novel protection scheme will not be affected by the special working conditions of the electrical multiple unit(EMU),and reliability,selectivity,and rapidity of relay protection are all improved.展开更多
Six N-alkyl-4＇-methyl-1,1＇-biphenyl-2-sulfonamides were synthesized facilely and efficiently from low cost and readily available benzenesulfonyl chloride and C1-C4 fatty amines via linking DoM reaction with Suzuki r...Six N-alkyl-4＇-methyl-1,1＇-biphenyl-2-sulfonamides were synthesized facilely and efficiently from low cost and readily available benzenesulfonyl chloride and C1-C4 fatty amines via linking DoM reaction with Suzuki reaction.The structures of the new compounds synthesized were confirmed by elemental analysis,IR,1H NMR and MS.This new method makes a feature of low cost and readily available starting material,fewer steps,mild condition,easiness to operate and higher yield.展开更多
It is difficult for the traditional pan-tilt-zoom(PTZ)system driven by electromagnetic motor to meet the growing demand for video surveillance system.The key challenge is high positioning accuracy,high dynamic perform...It is difficult for the traditional pan-tilt-zoom(PTZ)system driven by electromagnetic motor to meet the growing demand for video surveillance system.The key challenge is high positioning accuracy,high dynamic performance and miniaturization of the PTZ system.Here a PTZ system driven by two degree-of-freedom obeliskshaped ultrasonic motor with single stator is presented,and its intelligent control algorithm is studied.The structure and driving mechanism of the presented PTZ system are analyzed by both simulation and experiment.To solve the complex nonlinear factors,e.g.time-variation,dead zone,the fuzzy PID control algorithm and the variable gain cross-coupled control strategy are combined to improve the control performance.The results show that the proposed algorithm has faster response,higher precision than traditional control algorithm,and it also has a good robustness to prevent the effect of interference.展开更多
基金the financial support from the Institute for Quantum Chemical Exploration(IQCE)
文摘Highly dispersed palladium nanoparticles were synthesized in the presence of immobilized ionic liquid on mesoporous silica SBA-15.PdNPs(2.4 nm)_me-Im@SBA-15 catalyst was prepared by the reduction using NaBH_4 as the reducing agent with controlled feed rate and has been investigated as ligand-free catalyst for Suzuki–Miyaura cross-coupling reaction at room temperature in aqueous solution under air.PdNPs catalyst was also prepared in situ from PdCl4_me-Im@SBA-15 during the reaction and demonstrated high activity and stability towards nitrobenzene hydrogenation at high temperature. Both catalysts were reusable at least for four recycle processes without significant loss in activity with simple procedure. The catalysts were characterized by TEM, EXAFS, FTIR and XPS.
基金supported by the National Natural Science Fund Joint Fund Project(No.U21B2068)the Major Science and Technology Innovation Project of WenZhou(No.ZG2021014).
文摘This article introduces the design theory of ceramic waveguide filter and proposes a new type of negative coupling structure with a conical throughhole,which has fine-adjustment of negative coupling without significantly increasing the insertion loss of the filter.Based on this,the article proposes an eightcavity ceramic waveguide filter design for 5G base stations.It also presents a detailed discussion on the influence of the cross-coupling slot lengths L2 and L4 on the transmission zeros positions during the filter optimization process and the relevant change rules.For the proposed optimized filter,the observed performance indicators include the center frequency of 3.5 GHz,working bandwidth of 200 MHz,an insertion loss of≤2.0 dB,return loss of≥19 dB,and out-of-band nearend suppression and out-of-band far-end suppression of≥39 dB and≥63 dB,respectively.The test performance results obtained for the sample,with structural parameters as per the simulation model,were in good agreement with the simulation results.
基金supported by the Natural Science Foundation of Sichuan Province(No.2022NSFSC0405).
文摘When fault occurs on cross-coupling autotransformer(AT)power supply traction network,the up-line and down-line feeder circuit breakers in the traction substation trip at the same time without selectivity,which leads to an extended power failure.Based on equivalent circuit and Kirchhoff’s current law,the feeder current characteristic in the substation,AT station and sectioning post when T-R fault,F-R fault,and T-F fault occur are analyzed and their expressions are obtained.When the traction power supply system is equipped with wide-area protection measurement and control system,the feeder protection device in each station collects the feeder currents in other two stations through the wide-area protection channel and a wide-area current differential protection scheme based on the feeder current characteristic is proposed.When a short-circuit fault occurs in the power supply arm,all the feeder protection devices in each station receive the feeder currents with time stamp in other two stations.After data synchronous processing and logic judgment,the fault line of the power supply arm can be identified and isolated quickly.The simulation result based on MATLAB/Simulink shows that the power supply arm protection scheme based on wide-area current differential has good fault discrimination ability under different fault positions,transition resistances,and fault types.The verification of measured data shows that the novel protection scheme will not be affected by the special working conditions of the electrical multiple unit(EMU),and reliability,selectivity,and rapidity of relay protection are all improved.
文摘Six N-alkyl-4＇-methyl-1,1＇-biphenyl-2-sulfonamides were synthesized facilely and efficiently from low cost and readily available benzenesulfonyl chloride and C1-C4 fatty amines via linking DoM reaction with Suzuki reaction.The structures of the new compounds synthesized were confirmed by elemental analysis,IR,1H NMR and MS.This new method makes a feature of low cost and readily available starting material,fewer steps,mild condition,easiness to operate and higher yield.
基金supported by the National Natural Science Foundation of China (No.51205193)the Research Fund for Doctoral Program of the Ministry of Education(No.20123218120037)
文摘It is difficult for the traditional pan-tilt-zoom(PTZ)system driven by electromagnetic motor to meet the growing demand for video surveillance system.The key challenge is high positioning accuracy,high dynamic performance and miniaturization of the PTZ system.Here a PTZ system driven by two degree-of-freedom obeliskshaped ultrasonic motor with single stator is presented,and its intelligent control algorithm is studied.The structure and driving mechanism of the presented PTZ system are analyzed by both simulation and experiment.To solve the complex nonlinear factors,e.g.time-variation,dead zone,the fuzzy PID control algorithm and the variable gain cross-coupled control strategy are combined to improve the control performance.The results show that the proposed algorithm has faster response,higher precision than traditional control algorithm,and it also has a good robustness to prevent the effect of interference.
