A new technology was developed to recover multiple valuable elements from the spent Al2O3-based catalyst by X-ray phase analysis and exploratory experiments. The experimental results show that in the condition of roas...A new technology was developed to recover multiple valuable elements from the spent Al2O3-based catalyst by X-ray phase analysis and exploratory experiments. The experimental results show that in the condition of roasting temperature of 750℃ and roasting time of 30 min, molar ratio of Na2O to Al2O3 of 1.2, the leaching rates of alumina, vanadium and molybdenum in the spent catalyst are 97.2%, 95.8% and 98.9%, respectively. Vanadium and molybdenum in sodium aluminate solution can be recovered by precipitators A and B, and the precipitation rates of vanadium and molybdenum are 94.8% and 92.6%. Al（OH）3 was prepared from sodium aluminate solution in the carbonation decomposition process, and the purity of Al2O3 is 99.9% after calcination, the recovery of alumina reaches 90.6% in the whole process; the Ni-Co concentrate was leached by sulfuric acid, a nickel recovery of 98.2% and cobalt recovery over 98.5% can be obtained under the experimental condition of 30% H2SO4, 80℃, reaction time 4 h, mass ratio of liquid to solid 8, stirring rate 800r/min.展开更多
Bayan Obo deposit in Inner Mongolia,China is not only the largest Iron-LREE-niobium deposit known in the world but also a giant fluorite deposit.Banded and streaky fluorite-rich REE-iron ores,bastnasiteapatite -pyroxe...Bayan Obo deposit in Inner Mongolia,China is not only the largest Iron-LREE-niobium deposit known in the world but also a giant fluorite deposit.Banded and streaky fluorite-rich REE-iron ores,bastnasiteapatite -pyroxene-fluorite ores,high-Fe,REEs,and fluorite ores,monazite(bastnaesite)-fluorite(low-Fe, high REE) ores etc.are widely disseminated in the Main and the East ore bodies.In 1985,proven展开更多
Kaolin ores in Huichang contains these minerals of quartz sand, kaolin, mica and feldspars. In order to recover these valuable resources, some experiments of screening, classification, magnetic separation, grinding an...Kaolin ores in Huichang contains these minerals of quartz sand, kaolin, mica and feldspars. In order to recover these valuable resources, some experiments of screening, classification, magnetic separation, grinding and flotation are carried out on the basis of the kaolin ore properties. The test results indicate that quartz sand concentrate can be directly obtained when vibrating screen size used is 10 meshes. Materials that are smaller than the screen hole are injected to hydraulic cyclones which controlling classification size is 325 meshes; kaolin concentrate containing above 33.70% Al2O3 and 0.37% Fe2O3 can be well beneficiated from the overflow through magnetic separation with one stage rougher and cleaner to remove iron. On the other hand, the hydrocyclone spigot flow to grinding and flotation with one stage rougher and two scavengers, mica and feldspars concentrate can be beneficiated in sequence. Therefore, these valuable minerals of kaolin ores can be realized comprehensive utilization.展开更多
Tailings produced in a concentration plant are the discharge of solid wastes after grinding ore into size and selecting useful components in the specific economic and technological condition. According to statistics, ...Tailings produced in a concentration plant are the discharge of solid wastes after grinding ore into size and selecting useful components in the specific economic and technological condition. According to statistics, for the mining of metal ore, non-metallic ore, coal, clay, etc, the production of tailings of the world is up to 100 million tons per year. The number of existing tailing piles is 12718 in China, of which the construction ones are 1526, accounting for 12% of the total, and the closed tailing piles are 1024, accounting for 8%. As of 2007, the national total tailings accumulation is 8.046 billion tons. The non-ferrous metal mining is one of the largest discharge of solid wastes industries because of its low comprehensive recovery rate. For example, the beneficiation and recovery rate of non-ferrous metal mine is from 50% to 60% in China, which is lower 10% to 15% than developed countries, and the associated non-ferrous metal recovery rate is 40%, which is lower 20% than developed countries. On the utilization of duns, Poland is 90% to 100%, United States, Australia, France, Canada, Belgium and other countries followed, while China is only about 20%. The utilization of fly ash is to 100% in Japan and Denmark, France is 65%, UK is 55%, and China is just 45%. Quantities of waste rock, waste slag, and waste water have occupied land, destructed vegetation, deteriorated the soil and water quality, and caused land subsidence, landslides, mud-flow and other geological disasters. Therefore, the comprehensive utilization of resources is the right choice of mining sustainable development, environment protection, resource conservation, economic and social development.展开更多
In common,the waste heat of the flue gas is recovered and utilized to heat the low temperature feedwater by installing the low temperature economizer(LTE),which can save the steam extracted from the steam turbine and ...In common,the waste heat of the flue gas is recovered and utilized to heat the low temperature feedwater by installing the low temperature economizer(LTE),which can save the steam extracted from the steam turbine and then increase the unit output.However,restricted by the low temperature of waste flue gas,the energy-saving efect is inconspicuous.Based on the common waste heat utilization system of the flue gas.展开更多
基金Project(2003 UDBEA00C020) supported by the Collaborative Project of School and Province of Yunnan Province
文摘A new technology was developed to recover multiple valuable elements from the spent Al2O3-based catalyst by X-ray phase analysis and exploratory experiments. The experimental results show that in the condition of roasting temperature of 750℃ and roasting time of 30 min, molar ratio of Na2O to Al2O3 of 1.2, the leaching rates of alumina, vanadium and molybdenum in the spent catalyst are 97.2%, 95.8% and 98.9%, respectively. Vanadium and molybdenum in sodium aluminate solution can be recovered by precipitators A and B, and the precipitation rates of vanadium and molybdenum are 94.8% and 92.6%. Al（OH）3 was prepared from sodium aluminate solution in the carbonation decomposition process, and the purity of Al2O3 is 99.9% after calcination, the recovery of alumina reaches 90.6% in the whole process; the Ni-Co concentrate was leached by sulfuric acid, a nickel recovery of 98.2% and cobalt recovery over 98.5% can be obtained under the experimental condition of 30% H2SO4, 80℃, reaction time 4 h, mass ratio of liquid to solid 8, stirring rate 800r/min.
文摘Bayan Obo deposit in Inner Mongolia,China is not only the largest Iron-LREE-niobium deposit known in the world but also a giant fluorite deposit.Banded and streaky fluorite-rich REE-iron ores,bastnasiteapatite -pyroxene-fluorite ores,high-Fe,REEs,and fluorite ores,monazite(bastnaesite)-fluorite(low-Fe, high REE) ores etc.are widely disseminated in the Main and the East ore bodies.In 1985,proven
文摘Kaolin ores in Huichang contains these minerals of quartz sand, kaolin, mica and feldspars. In order to recover these valuable resources, some experiments of screening, classification, magnetic separation, grinding and flotation are carried out on the basis of the kaolin ore properties. The test results indicate that quartz sand concentrate can be directly obtained when vibrating screen size used is 10 meshes. Materials that are smaller than the screen hole are injected to hydraulic cyclones which controlling classification size is 325 meshes; kaolin concentrate containing above 33.70% Al2O3 and 0.37% Fe2O3 can be well beneficiated from the overflow through magnetic separation with one stage rougher and cleaner to remove iron. On the other hand, the hydrocyclone spigot flow to grinding and flotation with one stage rougher and two scavengers, mica and feldspars concentrate can be beneficiated in sequence. Therefore, these valuable minerals of kaolin ores can be realized comprehensive utilization.
基金Project jointly supported by the National Basic Research Program of China (Grant No. 2007CB411401)the Special Fund of State Key Laboratory of Ore Deposit Geochemistry and the National Natural Science Foundation of China (Grant No.40773035)
文摘Tailings produced in a concentration plant are the discharge of solid wastes after grinding ore into size and selecting useful components in the specific economic and technological condition. According to statistics, for the mining of metal ore, non-metallic ore, coal, clay, etc, the production of tailings of the world is up to 100 million tons per year. The number of existing tailing piles is 12718 in China, of which the construction ones are 1526, accounting for 12% of the total, and the closed tailing piles are 1024, accounting for 8%. As of 2007, the national total tailings accumulation is 8.046 billion tons. The non-ferrous metal mining is one of the largest discharge of solid wastes industries because of its low comprehensive recovery rate. For example, the beneficiation and recovery rate of non-ferrous metal mine is from 50% to 60% in China, which is lower 10% to 15% than developed countries, and the associated non-ferrous metal recovery rate is 40%, which is lower 20% than developed countries. On the utilization of duns, Poland is 90% to 100%, United States, Australia, France, Canada, Belgium and other countries followed, while China is only about 20%. The utilization of fly ash is to 100% in Japan and Denmark, France is 65%, UK is 55%, and China is just 45%. Quantities of waste rock, waste slag, and waste water have occupied land, destructed vegetation, deteriorated the soil and water quality, and caused land subsidence, landslides, mud-flow and other geological disasters. Therefore, the comprehensive utilization of resources is the right choice of mining sustainable development, environment protection, resource conservation, economic and social development.
文摘In common,the waste heat of the flue gas is recovered and utilized to heat the low temperature feedwater by installing the low temperature economizer(LTE),which can save the steam extracted from the steam turbine and then increase the unit output.However,restricted by the low temperature of waste flue gas,the energy-saving efect is inconspicuous.Based on the common waste heat utilization system of the flue gas.
