The intrinsic product polarization and intramolecular isotope effect of the S（~1D,~3P） ＋ HD reaction have been investigated on both the lowest singlet state（1A） and the triplet state（3A and 3A） potential energy...The intrinsic product polarization and intramolecular isotope effect of the S（~1D,~3P） ＋ HD reaction have been investigated on both the lowest singlet state（1A） and the triplet state（3A and 3A） potential energy surfaces by using quasi-classical trajectory and quantum mechanical methods.The calculations indicate that intramolecular isotope effects are different on the three electronic states.The stereodynamics study shows that the P（θr） distributions,P（φ r） distributions,and polarization-dependent differential cross sections（PDDCSs）（00） are sensitive to mass factor and the product angular momentum vectors are not only aligned but also oriented.展开更多
The autoionization branching ratios from Eu 4f76p1/26 d [J] autoionizing states to its 4f76s+(9So), 4f76s+(7So), and4f75d+(9Do) final ionic states are investigated with the combination of the three-step laser excitati...The autoionization branching ratios from Eu 4f76p1/26 d [J] autoionizing states to its 4f76s+(9So), 4f76s+(7So), and4f75d+(9Do) final ionic states are investigated with the combination of the three-step laser excitation and the velocity-map imaging technique. These different autoionizing states are excited via 4f76s6d8 DJ [J = 5/2, 7/2, and 9/2] intermediate states, respectively. The experimental photoelectron images are obtained, from which energy distributions of ejected electrons are achieved with the mathematical transformation. Furthermore, the energy dependence of the branching ratio is investigated within the autoionization resonance, by which population inversion is observed as an important characteristic.The J-dependence is also studied systematically. The validity of the well-known isolated core excitation technique used for obtaining the autoionization spectrum is also studied.展开更多
The branching ratios of ions and the angular distributions of electrons ejected from the Eu 4f^76p_（1/2）nd auto-ionizing states are investigated with the velocity-map-imaging technique.To populate the above auto-ion...The branching ratios of ions and the angular distributions of electrons ejected from the Eu 4f^76p_（1/2）nd auto-ionizing states are investigated with the velocity-map-imaging technique.To populate the above auto-ionizing states,the relevant bound Rydberg states have to be detected first.Two new bound Rydberg states are identified in the region between41150 cm^（-1）and 44580 cm^（-1）,from which auto-ionization spectra of the Eu 4f^76p_（1/2）nd states are observed with isolated core excitation method.With all preparations above,the branching ratios from the above auto-ionizing states to different final ionic states and the angular distributions of electrons ejected from these processes are measured systematically.Energy dependence of branching ratios and anisotropy parameters within the auto-ionization spectra are carefully analyzed,followed by a qualitative interpretation.展开更多
This work introduces the branching ratio(BR) method for determining relative spectral responses,which are needed routinely in laser induced breakdown spectroscopy(LIBS). Neutral and singly ionized Ti lines in the 250...This work introduces the branching ratio(BR) method for determining relative spectral responses,which are needed routinely in laser induced breakdown spectroscopy(LIBS). Neutral and singly ionized Ti lines in the 250–498 nm spectral range are investigated by measuring laser-induced micro plasma near a Ti plate and used to calculate the relative spectral response of an entire LIBS detection system. The results are compared with those of the conventional relative spectral response calibration method using a tungsten halogen lamp, and certain lines available for the BR method are selected. The study supports the common manner of using BRs to calibrate the detection system in LIBS setups.展开更多
This article deals with some properties of Galton-Watson branching processes in varying environments. A necessary and suffcient condition for relative recurrent state is presented, and a series of ratio limit properti...This article deals with some properties of Galton-Watson branching processes in varying environments. A necessary and suffcient condition for relative recurrent state is presented, and a series of ratio limit properties of the transition probabilities are showed.展开更多
In this work, the performance of free-space optical(FSO) communication system based on maximal ratio combining using binary phase shift keying subcarrier intensity modulation over Gamma-Gamma fading channels has been ...In this work, the performance of free-space optical(FSO) communication system based on maximal ratio combining using binary phase shift keying subcarrier intensity modulation over Gamma-Gamma fading channels has been studied systematically. Under identically or non-identically distributed branches, the analytical expressions for the bit error rate function of signal-to-noise are derived by expressing the modified Bessel function of second kind with Meijer G-function for dualand triple-branch systems, respectively. In terms of H-fox function, the new expressions have more general forms and are more efficient for computation. It is found that the dual-and triple-branch systems significantly outperform the direct link system under weak, moderate and strong turbulence conditions. Monte Carlo simulation is also provided to confirm the accuracy of the proposed model.展开更多
文摘The intrinsic product polarization and intramolecular isotope effect of the S（~1D,~3P） ＋ HD reaction have been investigated on both the lowest singlet state（1A） and the triplet state（3A and 3A） potential energy surfaces by using quasi-classical trajectory and quantum mechanical methods.The calculations indicate that intramolecular isotope effects are different on the three electronic states.The stereodynamics study shows that the P（θr） distributions,P（φ r） distributions,and polarization-dependent differential cross sections（PDDCSs）（00） are sensitive to mass factor and the product angular momentum vectors are not only aligned but also oriented.
基金supported by the National Natural Science Foundation of China(Grant No.11174218)
文摘The autoionization branching ratios from Eu 4f76p1/26 d [J] autoionizing states to its 4f76s+(9So), 4f76s+(7So), and4f75d+(9Do) final ionic states are investigated with the combination of the three-step laser excitation and the velocity-map imaging technique. These different autoionizing states are excited via 4f76s6d8 DJ [J = 5/2, 7/2, and 9/2] intermediate states, respectively. The experimental photoelectron images are obtained, from which energy distributions of ejected electrons are achieved with the mathematical transformation. Furthermore, the energy dependence of the branching ratio is investigated within the autoionization resonance, by which population inversion is observed as an important characteristic.The J-dependence is also studied systematically. The validity of the well-known isolated core excitation technique used for obtaining the autoionization spectrum is also studied.
基金Project supported by the National Natural Science Foundation of China(Grant No.11174218)
文摘The branching ratios of ions and the angular distributions of electrons ejected from the Eu 4f^76p_（1/2）nd auto-ionizing states are investigated with the velocity-map-imaging technique.To populate the above auto-ionizing states,the relevant bound Rydberg states have to be detected first.Two new bound Rydberg states are identified in the region between41150 cm^（-1）and 44580 cm^（-1）,from which auto-ionization spectra of the Eu 4f^76p_（1/2）nd states are observed with isolated core excitation method.With all preparations above,the branching ratios from the above auto-ionizing states to different final ionic states and the angular distributions of electrons ejected from these processes are measured systematically.Energy dependence of branching ratios and anisotropy parameters within the auto-ionization spectra are carefully analyzed,followed by a qualitative interpretation.
基金supported by the National Key Scientific Instrument and Equipment Development Projects of China (2014YQ120351)National Natural Science Foundation of China (11704372)Anhui Provincial Natural Science Foundation (1708085QF130)
文摘This work introduces the branching ratio(BR) method for determining relative spectral responses,which are needed routinely in laser induced breakdown spectroscopy(LIBS). Neutral and singly ionized Ti lines in the 250–498 nm spectral range are investigated by measuring laser-induced micro plasma near a Ti plate and used to calculate the relative spectral response of an entire LIBS detection system. The results are compared with those of the conventional relative spectral response calibration method using a tungsten halogen lamp, and certain lines available for the BR method are selected. The study supports the common manner of using BRs to calibrate the detection system in LIBS setups.
基金supported by NNSF of China(6053408070571079)Open Fundation of SKLSE of Wuhan University (2008-07-03)
文摘This article deals with some properties of Galton-Watson branching processes in varying environments. A necessary and suffcient condition for relative recurrent state is presented, and a series of ratio limit properties of the transition probabilities are showed.
基金supported by the National Natural Science Foundation of China (Grant No. 61671347)the Fundamental ResearchFunds for the Central Universities (Grant No. 20106151859 & 20106161859)supported by 111 Project of China (B08038)
文摘In this work, the performance of free-space optical(FSO) communication system based on maximal ratio combining using binary phase shift keying subcarrier intensity modulation over Gamma-Gamma fading channels has been studied systematically. Under identically or non-identically distributed branches, the analytical expressions for the bit error rate function of signal-to-noise are derived by expressing the modified Bessel function of second kind with Meijer G-function for dualand triple-branch systems, respectively. In terms of H-fox function, the new expressions have more general forms and are more efficient for computation. It is found that the dual-and triple-branch systems significantly outperform the direct link system under weak, moderate and strong turbulence conditions. Monte Carlo simulation is also provided to confirm the accuracy of the proposed model.
