The effects of SN5040 and polyethylene glycol（PEG） individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The ad...The effects of SN5040 and polyethylene glycol（PEG） individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The adsorption mechanism of these dispersants was detected by zeta potential, isothermal absorption and FTIR analysis. It is found that SN5040 is superior for stabilizing nano-TiO2 in aqueous suspension to PEG in basic region, and the optimum mass fraction of SN5040 addition is 3%. In the case of NaCl addition, the optimum value increases with .the increase of NaCl concentration in the solution. When the mixture of SN5040 and PEG is employed, the antagonism appears preponderant. When SN5040 and PEG are added sequentially, the synergistic reaction takes place. The synergistic reaction can be attributed to the mechanism that PEG adsorption decreases the electronic repulsion between SN5040 molecules, which results in the increase of SN5040 adsorption density. PEG is adsorbed by the interaction with the pre-adsorbed SN5040 layer. Furthermore, the modified inner wall latex paint with well dispersed nano-YiO2 suspension is endowed with excellent ultraviolet absorption and antibacterial properties.展开更多
Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water pote...Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses.However,ignorance of salinity may result in overestimation of stability,and the design may not be as conservative as thought.Therefore,this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions.Second,the measured parameters are used for stability analyses of a railway embankment in an area subjected to regional rainfall incident.Eventually,a numerical parametric study is carried out to explore the significance of different rainfall schemes,construction patterns,and anisotropic permeability on the factor of safety.Results reveal that desalinization suppresses the water retention capability,which in turn results in a tremendous declination of unsaturated hydraulic conductivity.Despite the natural saline embankment,rainfall can hardly infiltrate into the desalinated embankment due to the lower conductivity.Therefore,the factor of safety for natural saline conditions drops notably,while only marginal changes occur in the case of the desalinated embankment.展开更多
基金Project(04GK2007) supported by Hunan Industrial Key Project of Science and Technology
文摘The effects of SN5040 and polyethylene glycol（PEG） individually and in combination on the dispersion stability of nano-TiO2 aqueous suspension were investigated by ultraviolet-visible absorption spectroscopy. The adsorption mechanism of these dispersants was detected by zeta potential, isothermal absorption and FTIR analysis. It is found that SN5040 is superior for stabilizing nano-TiO2 in aqueous suspension to PEG in basic region, and the optimum mass fraction of SN5040 addition is 3%. In the case of NaCl addition, the optimum value increases with .the increase of NaCl concentration in the solution. When the mixture of SN5040 and PEG is employed, the antagonism appears preponderant. When SN5040 and PEG are added sequentially, the synergistic reaction takes place. The synergistic reaction can be attributed to the mechanism that PEG adsorption decreases the electronic repulsion between SN5040 molecules, which results in the increase of SN5040 adsorption density. PEG is adsorbed by the interaction with the pre-adsorbed SN5040 layer. Furthermore, the modified inner wall latex paint with well dispersed nano-YiO2 suspension is endowed with excellent ultraviolet absorption and antibacterial properties.
基金the Iran’s National Elites Foundation and the Research Grant Office at Sharif University Technology for supporting this research by way of “Dr Kazemi-Ashtiani Award” and grant “G970902”,respectively。
文摘Natural soils contain a certain amount of salt in the form of dissolved ions or electrically charged atoms,originated from the long-term erosion by acidic rainwater.The dissolved salt poses an extra osmotic water potential being normally neglected in laboratory measurements and numerical analyses.However,ignorance of salinity may result in overestimation of stability,and the design may not be as conservative as thought.Therefore,this research aims to first experimentally examine the influence of pore water salinity on water retention curve and saturated permeability of natural dispersive loess under saline and desalinated conditions.Second,the measured parameters are used for stability analyses of a railway embankment in an area subjected to regional rainfall incident.Eventually,a numerical parametric study is carried out to explore the significance of different rainfall schemes,construction patterns,and anisotropic permeability on the factor of safety.Results reveal that desalinization suppresses the water retention capability,which in turn results in a tremendous declination of unsaturated hydraulic conductivity.Despite the natural saline embankment,rainfall can hardly infiltrate into the desalinated embankment due to the lower conductivity.Therefore,the factor of safety for natural saline conditions drops notably,while only marginal changes occur in the case of the desalinated embankment.
