With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting...With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting speed on solidification structure in ultrasonic field were also analyzed. The experiment and simulation results show that the solidification structure of the ingot is homogeneously distributed, and its grain size is obviously refined at ultrasonic power of 240 W. The average grain sizes, which can be seen from the Leica microscope, are less than 100 μm. When the casting speed is 45-50 mm/min, the best grain refinement is obtained.展开更多
The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum st...The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum strip treated by ultrasonic was studied. The results show that ultrasonic treatment can refine the grain of the roll casting aluminum strips and make the structure of the strips more homogeneous. The effect is the best when the power of ultrasonic is 300 W and the incident angle of the guide rod is 45、. The mechanism of acoustic cavitations and acoustic flow on grain refinement was also discussed. The heat effect of intensity ultrasonic was studied. The present problems during ultrasonic roll casting process, such as the imperfect cooling system, the inaccurate calculation of ultrasonic energy, and the shape and position of the guide rod to be improved were pointed out.展开更多
The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases inv...The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases involved in the iron were determined. The notch toughness, macrohardness and the fractograph of the samples are compared and their performance was determined, which mainly depends on the matrix structure. Relatively good comprehensive properties can be obtained in the tempering state. Improvements have been made on the commonly used tempering standard. Tempering for a short period at low temperature can improve the materials′ service performance obviously.展开更多
Solidification structure is critical in the control of the mechanical properties and quality during the continuous casting process. The thermo-physical properties of 13 Cr steel added some rare metals, such as Mo, V, ...Solidification structure is critical in the control of the mechanical properties and quality during the continuous casting process. The thermo-physical properties of 13 Cr steel added some rare metals, such as Mo, V, Nb, are measured to better understand the solidification structure of 13 Cr bloom. A computational model using CA-FE(cellular automation-finite element) method coupled with heat transfer model is developed to describe the solidification structure in continuous casting process. It is found that the calculated solidification structure is in good agreement with the observed data. The influence of casting speed and superheat on the solidification structure of the bloom is studied in detail. In order to obtain more equiaxed crystal ratio and low degree of the segregation in the bloom, the optimized casting speed 0.6 m/min and superheat less than 25 °C are determined for the caster. Using the optimized manufacturing parameters, these samples are 60% with the equiaxed zone ratio of 8%–10% and below the degree of segregation 1.05.展开更多
A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of...A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.展开更多
The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2...The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.展开更多
Talin-1 head(hereinafter referred to as TH)is the head structure of talin protein,which contains a four-point-one-protein/ezrin/radixin/moesin(FERM)domain.Its F1 domain contains an unstructured loop of 30 amino acids(...Talin-1 head(hereinafter referred to as TH)is the head structure of talin protein,which contains a four-point-one-protein/ezrin/radixin/moesin(FERM)domain.Its F1 domain contains an unstructured loop of 30 amino acids(139-168),which does not interact with other domains.Because TH doesn’t get the crystal structure and whether the unstructured loop has obvious influence on the TH secondary structure,therefore,the truncated talin-1 headΔ139-168(hereinafter referred to as THΔ)was constructed and its structure and the impact of stability after truncation were analyzed.Molecular biology and structural biology methods were used to construct prokaryotic expression vectors of TH and THΔ,explore and optimize the expression conditions of recombinants,and they were purified by affinity chromatography and FPLC gel filtration chromatography.Finally,a large number of stable,high-purity protein samples were prepared successfully.The physicochemical properties and structural stability of the proteins were investigated by dynamic light scattering and circular dichroism.The results showed that the THΔsecondary structure of the truncated body did not change significantly,the structural stability was enhanced and the resistance to guanidine hydrochloride and high temperature was stronger.展开更多
基金Project(2010CB731700) supported by the National Basic Research Program of China
文摘With the experiment and finite element simulation, the influences of power ultrasonic on the solidification structure of 7050 aluminum alloy ingot in semi-continuous casting were researched, and the effects of casting speed on solidification structure in ultrasonic field were also analyzed. The experiment and simulation results show that the solidification structure of the ingot is homogeneously distributed, and its grain size is obviously refined at ultrasonic power of 240 W. The average grain sizes, which can be seen from the Leica microscope, are less than 100 μm. When the casting speed is 45-50 mm/min, the best grain refinement is obtained.
基金Projects(IRT0549) supported by Program for Changjiang Scholars and Innovative Research Team in University, China
文摘The experiment of ultrasonic treatment of roll casting aluminum strip on plane twin-roll cast-roller with double-heads ultrasonic tools was carried out, and the metallographic structure of the roll casting aluminum strip treated by ultrasonic was studied. The results show that ultrasonic treatment can refine the grain of the roll casting aluminum strips and make the structure of the strips more homogeneous. The effect is the best when the power of ultrasonic is 300 W and the incident angle of the guide rod is 45、. The mechanism of acoustic cavitations and acoustic flow on grain refinement was also discussed. The heat effect of intensity ultrasonic was studied. The present problems during ultrasonic roll casting process, such as the imperfect cooling system, the inaccurate calculation of ultrasonic energy, and the shape and position of the guide rod to be improved were pointed out.
文摘The structure and properties of high chromium white cast iron in different treatment states were studied. Using X ray diffraction method, observing their metallograph and measuring their microhardness, the phases involved in the iron were determined. The notch toughness, macrohardness and the fractograph of the samples are compared and their performance was determined, which mainly depends on the matrix structure. Relatively good comprehensive properties can be obtained in the tempering state. Improvements have been made on the commonly used tempering standard. Tempering for a short period at low temperature can improve the materials′ service performance obviously.
基金Projects(51274057,51474057) supported by the National Natural Science Foundation of ChinaProject(2012AA03A508) supported by the High-tech Research and Development Program of China
文摘Solidification structure is critical in the control of the mechanical properties and quality during the continuous casting process. The thermo-physical properties of 13 Cr steel added some rare metals, such as Mo, V, Nb, are measured to better understand the solidification structure of 13 Cr bloom. A computational model using CA-FE(cellular automation-finite element) method coupled with heat transfer model is developed to describe the solidification structure in continuous casting process. It is found that the calculated solidification structure is in good agreement with the observed data. The influence of casting speed and superheat on the solidification structure of the bloom is studied in detail. In order to obtain more equiaxed crystal ratio and low degree of the segregation in the bloom, the optimized casting speed 0.6 m/min and superheat less than 25 °C are determined for the caster. Using the optimized manufacturing parameters, these samples are 60% with the equiaxed zone ratio of 8%–10% and below the degree of segregation 1.05.
基金Project(51004031) supported by the National Natural Science Foundation of ChinaProject(50925415) supported by the National Outstanding Young Scientist Foundation of China+1 种基金Project(20100042120012) supported by the Special Research Fund for Doctoral Programs of Ministry of Education of ChinaProject(N090402022) supported by the Fundamental Research Funds for the Central Universities of China
文摘A three-dimensional finite-element model of slab continuous casting mold was conducted to clarify the effect of cooling structure on thermal behavior of copper plates. The results show that temperature distribution of hot surface is mainly governed by cooling structure and heat-transfer conditions. For hot surface centricity, maximum surface temperature promotions are 30 ℃and 15 ℃ with thickness increments of copper plates of 5 mm and nickel layers of 1 ram, respectively. The surface temperature without nickel layers is depressed by 10 ℃ when the depth increment of water slots is 2 mm and that with nickel layers adjacent to and away from mold outlet is depressed by 7℃ and 5 ℃, respectively. The specific trend of temperature distribution of transverse sections of copper plates is nearly free of cooling structure, but temperature is changed and its law is similar to the corresponding surface temperature.
基金The Ministry of Science and Higher Education of the Russian Federation(Agreement with Zelinsky Institute of Organic Chemistry RAS No 075-15-2020-803).
文摘The work addresses to the study of the molecular and crystal structure and properties of a new energyintensive compound 3,6-bis(2,2,2-trinitroethylnitramino)-1,2,4,5-tetrazine(NBTAT),first obtained by the authors in 2020.NBTAT compound crystallizes in the monoclinic system,space group P2(1)/n,density at room temperature 1.939 g/cm^(3).The energies of crystal packing and pairwise intermolecular interactions in NBTAT and its unnitrated analogue BTAT were calculated,and their comparative analysis was carried out.The enthalpy of formation of NBTAT molecules was calculated by quantum-chemical methods using Gaussian 09,and the enthalpy of formation of NBTAT in the solid phase(618 kJ/mol)was estimated.The energy capabilities of NBTAT as an oxidizer of solid composite propellants are estimated.It is shown that in metal-free compositions NBTAT is significantly superior to ammonium perchlorate(AP),dinitramide ammonium salt(ADN),HMX,BTAT at all stages of rocket systems,and is comparable to the superdense CL-20 yielding to the latter at the lower stages and slightly winning at the upper stages.
基金Supported by the Scientific Research Personnel of Northeast Agricultural University(518001)。
文摘Talin-1 head(hereinafter referred to as TH)is the head structure of talin protein,which contains a four-point-one-protein/ezrin/radixin/moesin(FERM)domain.Its F1 domain contains an unstructured loop of 30 amino acids(139-168),which does not interact with other domains.Because TH doesn’t get the crystal structure and whether the unstructured loop has obvious influence on the TH secondary structure,therefore,the truncated talin-1 headΔ139-168(hereinafter referred to as THΔ)was constructed and its structure and the impact of stability after truncation were analyzed.Molecular biology and structural biology methods were used to construct prokaryotic expression vectors of TH and THΔ,explore and optimize the expression conditions of recombinants,and they were purified by affinity chromatography and FPLC gel filtration chromatography.Finally,a large number of stable,high-purity protein samples were prepared successfully.The physicochemical properties and structural stability of the proteins were investigated by dynamic light scattering and circular dichroism.The results showed that the THΔsecondary structure of the truncated body did not change significantly,the structural stability was enhanced and the resistance to guanidine hydrochloride and high temperature was stronger.
