Generation of polydisperse KCl aerosol with a new salt aerosol generator was investigated, Special attention was paid on particles with diameters between 3 and 10 μm. The main improvement consists of the different ro...Generation of polydisperse KCl aerosol with a new salt aerosol generator was investigated, Special attention was paid on particles with diameters between 3 and 10 μm. The main improvement consists of the different routes of KCl solution droplets. In traditional generators, the solution droplets travel through one cylinder; while in the case analyzed here, after spray atomization, the droplets travel through two cylinders in series. The first cylinder was fed with warm air and the second one with cold air. In such way, the complete evaporation of the water from the droplets can be ensured. The influencing factors of the generated aerosol size distribution were investigated. The data measured show that the concentration of generated aerosol becomes higher both increasing the flow rate of the KCI solution injected in the first cylinder and increasing the concentration in the solution. The temperature of solution influences mainly the generation of smaller KCI particles （0,3-3 μm）. The amount of hot air used in the generation process increases the concentration of larger KC1 particles （〉3 μm） while cold air does not have the same effect. The aerosol generator is able to generate KC1 aerosol stably. This instrument can be used effectively for testing air filters for automotive.展开更多
Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of th...Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security.展开更多
基金Project(2010EME006) supported by Open Fund of the Key Laboratory of Environmental Medicine Engineering of Ministry of Education of China Project(51008063) supported by the National Natural Science Foundation of China+1 种基金 Project(3203000601) supported by the Postdoctoral Key Research Program from Southeast University, China Project(2011BAJ03B05) supported by the National Science and Technology Pillar Program during the 12th Five-Year Plan Period of China
文摘Generation of polydisperse KCl aerosol with a new salt aerosol generator was investigated, Special attention was paid on particles with diameters between 3 and 10 μm. The main improvement consists of the different routes of KCl solution droplets. In traditional generators, the solution droplets travel through one cylinder; while in the case analyzed here, after spray atomization, the droplets travel through two cylinders in series. The first cylinder was fed with warm air and the second one with cold air. In such way, the complete evaporation of the water from the droplets can be ensured. The influencing factors of the generated aerosol size distribution were investigated. The data measured show that the concentration of generated aerosol becomes higher both increasing the flow rate of the KCI solution injected in the first cylinder and increasing the concentration in the solution. The temperature of solution influences mainly the generation of smaller KCI particles （0,3-3 μm）. The amount of hot air used in the generation process increases the concentration of larger KC1 particles （〉3 μm） while cold air does not have the same effect. The aerosol generator is able to generate KC1 aerosol stably. This instrument can be used effectively for testing air filters for automotive.
基金supported by the Preparation and Characterization of Fogging Agents,Cooperative Project of China(Grant No.1900030040)Preparation and Test of Fogging Agents,Cooperative Project of China(Grant No.2200030085)。
文摘Water-based aerosol is widely used as an effective strategy in electro-optical countermeasure on the battlefield used to the preponderance of high efficiency,low cost and eco-friendly.Unfortunately,the stability of the water-based aerosol is always unsatisfactory due to the rapid evaporation and sedimentation of the aerosol droplets.Great efforts have been devoted to improve the stability of water-based aerosol by using additives with different composition and proportion.However,the lack of the criterion and principle for screening the effective additives results in excessive experimental time consumption and cost.And the stabilization time of the aerosol is still only 30 min,which could not meet the requirements of the perdurable interference.Herein,to improve the stability of water-based aerosol and optimize the complex formulation efficiently,a theoretical calculation method based on thermodynamic entropy theory is proposed.All the factors that influence the shielding effect,including polyol,stabilizer,propellant,water and cosolvent,are considered within calculation.An ultra-stable water-based aerosol with long duration over 120 min is obtained with the optimal fogging agent composition,providing enough time for fighting the electro-optic weapon.Theoretical design guideline for choosing the additives with high phase transition temperature and low phase transition enthalpy is also proposed,which greatly improves the total entropy change and reduce the absolute entropy change of the aerosol cooling process,and gives rise to an enhanced stability of the water-based aerosol.The theoretical calculation methodology contributes to an abstemious time and space for sieving the water-based aerosol with desirable performance and stability,and provides the powerful guarantee to the homeland security.
