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Research on damage characteristics and constitutive model of rock mass under true triaxial cyclic loading based on acoustic emission
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作者 LI Ying-ming FAN Chao-tao +6 位作者 DONG Chun-liang ZHAO Guang-ming MENG Xiang-rui WANG Xiang-jun SHI Wen-qiu WU Xin-wen GAO Jiang-huai 《Journal of Central South University》 2025年第5期1938-1954,共17页
Aiming at the problem of deep surrounding rock instability induced by roadway excavation or mining disturbance,the true triaxial loading system was used to conduct graded cyclic maximum principal stress σ_(1) and int... Aiming at the problem of deep surrounding rock instability induced by roadway excavation or mining disturbance,the true triaxial loading system was used to conduct graded cyclic maximum principal stress σ_(1) and intermediate principal stress σ_(2) tests on sandstone to simulate the effect of mining stress in actual underground engineering.The influences of each principal stress cycle on the mechanical properties,acoustic emission(AE)characteristics,and fracture characteristics of sandstone were analyzed.The damage characteristics of sandstone under true triaxial cyclic loading were studied.Furthermore,the damage constitutive model of rock mass under true triaxial cyclic loading was established based on AE cumulative ringing count.The quantitative investigation was conducted on cumulative-damage changes in circulating sandstone,which elucidated the mechanism of damage deterioration in sandstone subjected to true triaxial cyclic loading.The results show that the influence of the graded cycleσ_(1) on limit maximum principal strain ɛ_(1max) and limit minimum principal strainɛ_(3max) was significantly greater than that of the limit intermediate principal strain ɛ_(2max).Graded cycleσ_(2) had a greater impact onɛ_(2max) and a smaller impact onɛ_(3max).The elasticity modulus of sandstone decreased exponentially with the increased cyclic load amplitude,while the Poisson ratio increased linearly.b of AE showed a trend of increasing,decreasing,slightly fluctuating,and finally decreasing during cyclingσ_(1).b showed a trend of slight fluctuation,large fluctuation,and finally increase during cyclingσ_(2).Sandstone specimens experienced mainly tensile failure,tensile-shear composite failure,and mainly shear failure with increased initialσ_(2) orσ_(3).This was determined by analyzing the rise angle-average frequency of the AE parameter,corresponding to the rock specimens from splitting failure to shear failure.Besides,the mechanical damage behavior of sandstone under true triaxial cyclic loading could be well described by the established constitutive model.At the same time,it was found that the sandstone damage variable decreased with increasedσ_(2) during cyclingσ_(1).The damage variable decreased first and then increased with increasedσ_(3) during cyclingσ_(2). 展开更多
关键词 rock mechanics true triaxial cyclic principal stress acoustic emission constitutive model damage variable
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Damage and fracture behavior and spatio-temporal evolution of acoustic emission of sandstone before and after laser radiation
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作者 GAO Ming-zhong LIU Jun-jun +6 位作者 LIChun-xiang YANG Ben-gao LI Fei ZHOU Xue-min YANG Lei YANG Zun-dong XIE Jing 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第9期3264-3280,共17页
Laser technology holds significant promise for enhancing rock-breaking efficiency.Experimental investigations were carried out on sandstone subjected to laser radiation,aiming to elucidate its response mechanism to su... Laser technology holds significant promise for enhancing rock-breaking efficiency.Experimental investigations were carried out on sandstone subjected to laser radiation,aiming to elucidate its response mechanism to such radiation.The uniaxial compressive strength of sandstone notably decreases by 22.1%–54.7%following exposure to a 750 W laser for 30 s,indicating a substantial weakening effect.Furthermore,the elastic modulus and Poisson ratio of sandstone exhibit an average decrease of 33.7%and 25.9%,respectively.Simultaneously,laser radiation reduces the brittleness of sandstone,increases the dissipated energy proportion,and shifts the failure mode from tensile to tension-shear composite failure.Following laser radiation,both the number and energy of acoustic emission events in the sandstone register a substantial increase,with a more dispersed distribution of these events.In summary,laser radiation induces notable damage to the mechanical properties of sandstone,leading to a substantial decrease in elastic energy storage capacity.Laser rock breaking technology is expected to be applied in hard rock breaking engineering to significantly reduce the difficulty of rock breaking and improve rock breaking efficiency. 展开更多
关键词 laser rock breaking efficient drilling acoustic emission mechanical damage strength reduction
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Application of acoustic emission (AE) technique in crack monitor during fatigue test of pump rods 被引量:3
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作者 XIA Yong-fa LI Hai-ling 《材料与冶金学报》 CAS 2007年第1期60-63,共4页
关键词 水泵杆 机械疲劳 声音散射法 裂缝 监测
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Acoustic emission characteristics of rock under impact loading 被引量:11
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作者 刘希灵 李夕兵 +2 位作者 洪亮 尹土兵 饶蒙 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第9期3571-3577,共7页
Acoustic emission tests were performed using a split Hopkinson pressure bar system(SHPB) on 50-mm-diameter bars of granite, limestone, sandstone and skarn. The results show that the amplitude distribution of hits is n... Acoustic emission tests were performed using a split Hopkinson pressure bar system(SHPB) on 50-mm-diameter bars of granite, limestone, sandstone and skarn. The results show that the amplitude distribution of hits is not well centralized around 50 d B, and that some hits with large amplitudes, usually larger than 70 d B, occur in the early stages of each test, which is different from the findings from static and low-loading-rate tests. Furthermore, the dominant frequency range of the recorded acoustic emission waveforms is between 300 k Hz and 500 k Hz, and frequency components higher than 500 k Hz are not significant. The hit with the largest values of amplitude, counts, signal strength, and absolute energy in each test, displays a waveform with similar frequency characteristics and greater correlation with the waveform obtained from the elastic input bar of the split Hopkinson pressure bar system compared with the waveforms of the other hits. This indicates that the hit with the largest values of amplitude, counts, signal strength, and absolute energy is generated by elastic wave propagation instead of fracture within the rock specimen. 展开更多
关键词 ROCK acoustic emissionae split Hopkinson pressure bar(SHPB) hit driven features frequency characteristics correlation analysis
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Application of quantum neural networks in localization of acoustic emission 被引量:6
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作者 Aidong Deng Li Zhao Wei Xin 《Journal of Systems Engineering and Electronics》 SCIE EI CSCD 2011年第3期507-512,共6页
Due to defects of time-difference of arrival localization,which influences by speed differences of various model waveforms and waveform distortion in transmitting process,a neural network technique is introduced to ca... Due to defects of time-difference of arrival localization,which influences by speed differences of various model waveforms and waveform distortion in transmitting process,a neural network technique is introduced to calculate localization of the acoustic emission source.However,in back propagation(BP) neural network,the BP algorithm is a stochastic gradient algorithm virtually,the network may get into local minimum and the result of network training is dissatisfactory.It is a kind of genetic algorithms with the form of quantum chromosomes,the random observation which simulates the quantum collapse can bring diverse individuals,and the evolutionary operators characterized by a quantum mechanism are introduced to speed up convergence and avoid prematurity.Simulation results show that the modeling of neural network based on quantum genetic algorithm has fast convergent and higher localization accuracy,so it has a good application prospect and is worth researching further more. 展开更多
关键词 acoustic emissionae LOCALIZATION quantum genetic algorithm(QGA) back propagation(BP) neural network.
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Acoustic emission precursors of static and dynamic instability for coarse-grained hard rock 被引量:17
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作者 SU Guo-shao GAN Wei +1 位作者 ZHAI Shao-bin ZHAO Guo-fu 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第10期2883-2898,共16页
To investigate the acoustic emission(AE)precursors of coarse-grained hard rock instability,an experimental study on the rockburst and slabbing process of granite was carried out using a true triaxial test system.The e... To investigate the acoustic emission(AE)precursors of coarse-grained hard rock instability,an experimental study on the rockburst and slabbing process of granite was carried out using a true triaxial test system.The evolution of the AE signals was monitored and analyzed in terms of the AE hit rate,fractal dimension of the AE hit number,AE count rate,b-value,dominant frequency and microcrack type.The test results show that after rock slabbing occurs,the AE precursors that can be used to predict the final dynamic instability(rockburst)are as follows:indicators such as the AE hit rate and AE count rate suddenly increase and then suddenly decrease;the AE hit rate exhibits a“quiet period”;during the“quiet period”,a small number of high-amplitude and low-frequency hits occur,and the signals corresponding to shear fracture continue to increase.The AE precursors for the final static instability(spalling)are as follows:both the AE hit rate and the b-value continuously decrease,and intermittent sudden increases appear in the high-frequency hits or the AE count rate. 展开更多
关键词 ROCKBURST slabbing SPALLING acoustic emission true triaxial test
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Experimental investigation on synergetic prediction of granite rockburst using rock failure time and acoustic emission energy 被引量:17
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作者 WANG Chun-lai CAO Cong +3 位作者 LI Chang-feng CHUAI Xiao-sheng ZHAO Guang-ming LU Hui 《Journal of Central South University》 SCIE EI CAS CSCD 2022年第4期1262-1273,共12页
The frequent occurrence of rockburst and the difficulty in predicting were considered in deep engineering and underground engineering.In this work,laboratory experiments on rockburst under true triaxial conditions wer... The frequent occurrence of rockburst and the difficulty in predicting were considered in deep engineering and underground engineering.In this work,laboratory experiments on rockburst under true triaxial conditions were carried out with granite samples.Combined with the deformation characteristics of granite,acoustic emission(AE)technology was well applied in revealing the evolution law of micro-cracks in the process of rockburst.Based on the comprehensive analysis of acoustic emission parameters such as impact,ringing and energy,the phased characteristics of crack propagation and damage evolution in granite were obtained,which were consistent with the stages of rock deformation and failure.Subsequently,based on the critical point theory,the accelerated release characteristics of acoustic emission energy during rockburst were analyzed.Based on the damage theory,the damage evolution model of rock under different loading conditions was proposed,and the prediction interval of rock failure time was ascertained concurrently.Finally,regarding damage as an intermediate variable,the synergetic prediction model of rock failure time was constructed.The feasibility and validity of model were verified. 展开更多
关键词 ROCKBURST acoustic emission energy damage failure time synergetic prediction
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Rock burst proneness prediction by acoustic emission test during rock deformation 被引量:14
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作者 张志镇 高峰 尚晓吉 《Journal of Central South University》 SCIE EI CAS 2014年第1期373-380,共8页
Rock burst is a severe disaster in mining and underground engineering,and it is important to predict the rock burst risk for minimizing the loss during the constructing process.The rock burst proneness was connected w... Rock burst is a severe disaster in mining and underground engineering,and it is important to predict the rock burst risk for minimizing the loss during the constructing process.The rock burst proneness was connected with the acoustic emission(AE) parameter in this work,which contributes to predicting the rock burst risk using AE technique.Primarily,a rock burst proneness index is proposed,and it just depends on the heterogeneous degree of rock material.Then,the quantificational formula between the value of rock burst proneness index and the accumulative AE counts in rock sample under uniaxial compression with axial strain increases is developed.Finally,three kinds of rock samples,i.e.,granite,limestone and sandstone are tested about variation of the accumulative AE counts under uniaxial compression,and the test data are fitted well with the theoretic formula. 展开更多
关键词 rock mechanics rock burst proneness PREDICTION accumulative acoustic emission counts Weibull statistical distribution
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Effect of heterogeneity on mechanical and acoustic emission characteristics of rock specimen 被引量:8
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作者 李术才 李国莹 《Journal of Central South University》 SCIE EI CAS 2010年第5期1119-1124,共6页
The influence of heterogeneity on mechanical and acoustic emission characteristics of rock specimen under uniaxial compress was studied with numerical simulation methods.Weibull distribution function was adopted to de... The influence of heterogeneity on mechanical and acoustic emission characteristics of rock specimen under uniaxial compress was studied with numerical simulation methods.Weibull distribution function was adopted to describe the mesoscopic heterogeneity of rocks.The failure process of heterogeneous rock specimen under uniaxial loading was simulated using FLAC 3D software.Five schemes were adopted to investigate the influence of heterogeneity.The results demonstrate that as the homogeneity increases,the peak strength and brittleness of rocks increase,and the macro elastic modulus improves as well.Heterogeneity has great influence on macro elastic modulus and strength when the homogeneity coefficient is less than 20.0.The volume expansion is not so obvious when the homogeneity increases.As the homogeneity coefficient increases the acoustic emissions modes change from swarm shock to main shock.When the homogeneity coefficient is high,the cumulative acoustic emission events-axial strain curve is gentle before the rock failure.The numerical results agree with the previously numerical results and earlier experimental measurements. 展开更多
关键词 HETEROGENEITY acoustic emission strain softening numerical simulation uniaxial compression elastic modulus
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Monitoring damage evolution of steel strand using acoustic emission technique and rate process theory 被引量:4
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作者 邓扬 刘扬 冯东明 《Journal of Central South University》 SCIE EI CAS 2014年第9期3692-3697,共6页
Utilizing the acoustic emission(AE) technique, an experimental investigation into the damage evolution for steel strand under axial tension was described. The damage evolution model for steel stand relating the damage... Utilizing the acoustic emission(AE) technique, an experimental investigation into the damage evolution for steel strand under axial tension was described. The damage evolution model for steel stand relating the damage evolution to acoustic emission parameters was proposed by incorporating the AE rate process theory. The AE monitoring results indicate that damages occur in both elastic and plastic phases of steel strand. In elastic phase, AE signals are mainly sent out from the micro damage due to the surface friction among the wires of steel strand, while in plastic phase, AE signals emitted from the plastic deformation of wires. In addition, the AE cumulative parameters curves closely resemble the loading curve. The AE cumulative parameters curves can well describe the damage evolution process including the damage occurrence and damage development for steel strands. It is concluded that the AE technique is an effective and useful nondestructive technique for evaluating the damage characteristics of steel strand. 展开更多
关键词 acoustic emission rate process theory steel strand damage evolution model surface friction
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Experimental study on acoustic emission characteristics of jointed rock mass by double disc cutter 被引量:5
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作者 LIN Qi-bin CAO Ping +3 位作者 LI Kai-hui CAO Ri-hong ZHOU Ke-ping DENG Hong-wei 《Journal of Central South University》 SCIE EI CAS CSCD 2018年第2期357-367,共11页
The characteristics of joints are crucial factors which influence the penetration efficiency of tunnel boring machine(TBM).Based on the theoretical study,numerical simulation and experimental research,many researchers... The characteristics of joints are crucial factors which influence the penetration efficiency of tunnel boring machine(TBM).Based on the theoretical study,numerical simulation and experimental research,many researchers have studied the interaction between TBM disc cutters and jointed rock mass.However,in most of these works,the effect of joint on rock fragmentation by double disc cutter has been scarcely investigated.Thus,the effects of joint orientation and joint space on rock fragmentation by double disc cutter are highlighted in this study.During the test,jointed concrete specimens are adopted to simulate jointed rock mass.Improved RYL-600rock shear rheological instrument was employed during the indentation process under disc cutters,and acoustic emission location system was used to analyze the rock damage and physical deterioration.The results show that there are four failure modes and three modes of crack initiation and propagation in jointed rock mass.It is concluded that the existing joint planes have obviously restrained the crack initiation and propagation during the rock fragmentation process.The results also indicate that samples are damaged most seriously when joint orientation equals60°,which is proved to be the optimum joint orientation in TBM penetration. 展开更多
关键词 tunnel boring machine (TBM) jointed rock mass rock fragmentation crack propagation acoustic emission
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Feasibility analysis for monitoring fatigue crack in hydraulic turbine blades using acoustic emission technique 被引量:2
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作者 王向红 朱昌明 +1 位作者 毛汉领 黄振峰 《Journal of Central South University》 SCIE EI CAS 2009年第3期444-450,共7页
In order to investigate the feasibility of monitoring the fatigue cracks in turbine blades using acoustic emission (AE) technique, the AE characteristics of fatigue crack growth were studied in the laboratory. And the... In order to investigate the feasibility of monitoring the fatigue cracks in turbine blades using acoustic emission (AE) technique, the AE characteristics of fatigue crack growth were studied in the laboratory. And the characteristics were compared with those of background noise received from a real hydraulic turbine unit. It is found that the AE parameters such as the energy and duration can qualitatively describe the fatigue state of the blades. The correlations of crack propagation rates and acoustic emission count rates vs stress intensity factor (SIF) range are also obtained. At the same time, for the specimens of 20SiMn under the given testing conditions, it is noted that the rise time and duration of events emitted from the fatigue process are lower than those from the background noise; amplitude range is 49-74 dB, which is lower than that of the noise (90-99 dB); frequency range of main energy of crack signals is higher than 60 kHz while that in the noise is lower than 55 kHz. Thus, it is possible to extract the useful crack signals from the noise through appropriate signal processing methods and to represent the crack status of blade materials by AE parameters. As a result, it is feasible to monitor the safety of runners using AE technique. 展开更多
关键词 FATIGUE CRACK acoustic emission hydraulic turbine BLADE
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BiScO_(3)-BiFeO_(3)-PbTiO_(3)-BaTiO_(3) high-temperature piezoelectric ceramic and its application on high-temperature acoustic emission sensor 被引量:2
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作者 FENG Chao FENG Yun-yun +4 位作者 FAN Meng-jia GENG Chao-hui LIN Xiu-juan YANG Chang-hong HUANG Shi-feng 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第12期3747-3756,共10页
Piezoelectric ceramic based high-temperature acoustic emission(AE)sensor is required urgently in the structural health monitoring of high-temperature fields.In this research,a series of 0.45(BiSc_(x)O_(3)-BiFe_(1-x)O_... Piezoelectric ceramic based high-temperature acoustic emission(AE)sensor is required urgently in the structural health monitoring of high-temperature fields.In this research,a series of 0.45(BiSc_(x)O_(3)-BiFe_(1-x)O_(3))-0.48PbTiO_(3)-0.07BaTiO_(3)(BSc_(x)Fe_(1-x)-PT-BT,n(Sc)/n(Fe)=0.4/0.6-0.6/0.4)ceramics with both high Curie temperature and large piezoelectric constant were presented.The structure and electrical properties of BSc_(x)Fe_(1-x)-PT-BT ceramics as a function of n(Sc)/n(Fe)have been systematically investigated.All the ceramics possess a perovskite structure,and the phase approaches from the rhombohedral toward the tetragonal phase with the decrease of n(Sc)/n(Fe).The BSc_(0.5)Fe_(0.5)-PT-BT and BSc_(0.5)Fe_(0.5)-PT-BT piezoelectric ceramics exhibit good piezoelectricity(d_(33)=250-281 pC/N),high Curie temperature(T_(C)=430-450℃)and excellent temperature stability.These improvements are greatly attributed to the balance between rhombohedral and tetragonal phase near morphotropic phase boundary with dense microstructure of ceramics.AE sensor based BSc_(0.5)Fe_(0.5)-PT-BT piezoelectric ceramic was designed,prepared and tested.The high-temperature stability of AE sensor was characterized through pencil-lead breaking with in situ high-temperature test.The noise of AE sensor is less than 40 dB,and the acoustic signal is up to 90 dB at 200℃.As a result,AE sensors based on BSc_(x)Fe_(1-x)-PT-BT piezoelectric ceramics are expected to be applied into the structural health monitoring of high temperature fields. 展开更多
关键词 piezoelectric ceramics high temperature morphotropic phase boundary phase transition acoustic emission sensor
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Application of Acoustic Emission Technology in Offshore Platform Monitoring
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作者 Jia Lele Ma Lanqing +1 位作者 Li Xiao Yang Guo'an 《仪器仪表学报》 EI CAS CSCD 北大核心 2013年第S1期130-133,共4页
As the offshore life and production base,the offshore platform plays an important role in offshore oil exploitation.The acoustic emission(AE)technology can be applied to damage detection and early warning of the offsh... As the offshore life and production base,the offshore platform plays an important role in offshore oil exploitation.The acoustic emission(AE)technology can be applied to damage detection and early warning of the offshore platform,and then can effectively guarantee the safe operation of the offshore platform,prevent accidents and casualties.The steel jacket offshore platform is currently the most widely used in shallow sea oil field of our country.Considering the complex structure of the steel jacket offshore platform and using AE technology,this paper has carried on research on effects of the pipe diameter size,the welding angle on the AE signal propagation characteristics,and at the same time,influence of the marine environment(seawater temperature,salinity)on the AE testing.These research contents have very important reference value for the application of the AE technology in offshore platform monitoring. 展开更多
关键词 acoustic emission OFFSHORE PLATFORM steel JACKET SIGNAL analysis
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Acoustical properties of a 3D printed honeycomb structure filled with nanofillers:Experimental analysis and optimization for emerging applications
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作者 Jeyanthi Subramanian Vinoth kumar Selvaraj +3 位作者 Rohan Singh Ilangovan S Naresh Kakur Ruban Whenish 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第5期248-258,共11页
The novelty of this research lies in the successful fabrication of a 3D-printed honeycomb structure filled with nanofillers for acoustic properties,utilizing an impedance tube setup in accordance with ASTM standard E ... The novelty of this research lies in the successful fabrication of a 3D-printed honeycomb structure filled with nanofillers for acoustic properties,utilizing an impedance tube setup in accordance with ASTM standard E 1050-12.The Creality Ender-3,a 3D printer,was used for printing the honeycomb structures,and polylactic acid(PLA)material was employed for their construction.The organic,inorganic,and polymeric compounds within the composites were identified using fourier transformation infrared(FTIR)spectroscopy.The structure and homogeneity of the samples were examined using a field emission scanning electron microscope(FESEM).To determine the sound absorption coefficient of the 3D printed honeycomb structure,numerous samples were systematically developed using central composite design(CCD)and analysed using response surface methodology(RSM).The RSM mathematical model was established to predict the optimum values of each factor and noise reduction coefficient(NRC).The optimum values for an NRC of 0.377 were found to be 1.116 wt% carbon black,1.025 wt% aluminium powder,and 3.151 mm distance between parallel edges.Overall,the results demonstrate that a 3Dprinted honeycomb structure filled with nanofillers is an excellent material that can be utilized in various fields,including defence and aviation,where lightweight and acoustic properties are of great importance. 展开更多
关键词 3D printing Honeycomb structure acousticS Field emission scanning electron microscope Response surface methodology
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电感耦合等离子体原子发射光谱(ICP-AES)法测定锆英砂选矿流程样品中8种主次成分
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作者 刘闫 孙启亮 +3 位作者 张丽萍 倪文山 张宏丽 刘磊 《中国无机分析化学》 北大核心 2025年第6期858-866,共9页
锆英砂是一种难以分解的矿物,且其中Zr、Ti、Hf等元素易水解,准确分析其选矿流程样品中的元素含量对采选和评价锆矿资源具有指导作用。实验筛选出最优前处理方法,采用碳酸钠-硼酸熔融,稀盐酸-酒石酸溶液微热提取,优化了熔剂用量、熔融... 锆英砂是一种难以分解的矿物,且其中Zr、Ti、Hf等元素易水解,准确分析其选矿流程样品中的元素含量对采选和评价锆矿资源具有指导作用。实验筛选出最优前处理方法,采用碳酸钠-硼酸熔融,稀盐酸-酒石酸溶液微热提取,优化了熔剂用量、熔融时间、熔融温度等实验条件,建立了电感耦合等离子体原子发射光谱(ICP-AES)法测定锆英砂选矿流程样品中Zr、Ti、Hf、Fe、Mn、Sn、Ba、Al的分析方法。采用基体匹配法克服了测试过程中的基体干扰,优选了Zr 339.198 nm、Ti 336.121 nm、Hf 277.336 nm、Fe 259.940 nm、Mn 257.610 nm、Sn 189.989 nm、Ba 233.527 nm、Al 396.152 nm为分析谱线。实验结果表明,各元素校准曲线的相关系数在0.9993~0.9999,方法检出限为0.0008~0.011μg/g,测定下限为0.003~0.034μg/g。按照实验方法对GBW07156、GBW07157中Zr、Ti、Hf、Fe、Mn、Sn、Ba、Al进行准确度与精密度考察,得出相对标准偏差(RSD,n=9)为0.56%~3.4%,加标回收率为95.0%~104%。同时对锆英砂选矿流程样品进行分析,相对标准偏差(RSD,n=9)为0.94%~3.2%,加标回收率在95.0%~105%。经与其他测定方法比对,结果表明,方法可实现Zr、Ti、Hf、Fe、Mn、Sn、Ba、Al共8种元素的准确测定,可为评价锆英砂选矿流程样品提供理论依据。 展开更多
关键词 锆英砂 碳酸钠 硼砂 电感耦合等离子体原子发射光谱(ICP-aeS)
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碱熔-电感耦合等离子体原子发射光谱法(ICP-AES)法测定锡矿中的锡、硅、锌、铜、铁、铅、砷、铋、锑 被引量:1
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作者 郑程 陈雯 +2 位作者 周峰 毛林夏 张鸟飞 《中国无机分析化学》 北大核心 2025年第2期264-270,共7页
为解决锡矿石主次元素常规分析法流程长、过程复杂、成本高、仅能单元素测定等问题,通过考察熔剂种类、混合溶剂比例、熔剂与试样质量比例、熔样温度、熔样时间等条件,建立了电感耦合等离子体原子发射光谱法(ICP-AES)法同时测定锡矿中... 为解决锡矿石主次元素常规分析法流程长、过程复杂、成本高、仅能单元素测定等问题,通过考察熔剂种类、混合溶剂比例、熔剂与试样质量比例、熔样温度、熔样时间等条件,建立了电感耦合等离子体原子发射光谱法(ICP-AES)法同时测定锡矿中锡、硅、锌、铜、铁、铅、砷、铋、锑等9种主次元素的方法。实验表明,采用混合熔剂(四硼酸锂∶偏硼酸锂为1∶4)与试样质量比为20∶1,在铂坩埚中1050℃熔融60 min,60 mL盐酸(1+2)溶液中加热浸取,各元素标准工作曲线的线性相关系数均大于0.9999,方法检出限为0.004~0.08μg/mL,测定标准物质的相对标准偏差在1.0%~5.5%,相对误差在0~9.2%。方法检出限低、精密度好、准确度高,能够满足难溶锡矿中多种元素的同时测定。 展开更多
关键词 锡矿 碱熔 四硼酸锂 偏硼酸锂 电感耦合等离子体原子发射光谱法(ICP-aeS)
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高温灼烧-电感耦合等离子体原子发射光谱(ICP-AES)法测定石墨精矿中的钙、镁、铝、铁、钾、钠
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作者 韩晓 孙计先 方迪 《中国无机分析化学》 北大核心 2025年第8期1210-1216,共7页
偏硼酸锂熔融石墨矿的方法虽然避免了高温灼烧易挥发元素的损耗,但引入的锂基体不仅干扰钠的测定,且不适合石墨精矿中钙、镁、铝、铁、钾、钠较低含量的测定。将试料高温灼烧至无黑色后,加入盐酸、氢氟酸和高氯酸,低温加热冒白烟至湿盐... 偏硼酸锂熔融石墨矿的方法虽然避免了高温灼烧易挥发元素的损耗,但引入的锂基体不仅干扰钠的测定,且不适合石墨精矿中钙、镁、铝、铁、钾、钠较低含量的测定。将试料高温灼烧至无黑色后,加入盐酸、氢氟酸和高氯酸,低温加热冒白烟至湿盐状,加入盐酸浸取定容,采用电感耦合等离子体原子发射光谱法(ICP-AES)测定石墨精矿中的钙、镁、铝、铁、钾、钠。实验发现要确保试料在马弗炉中灼烧至无黑色为止,才能完全消除碳元素对待测元素测定的影响。钙、镁、铝、铁、钾、钠质量浓度在1.00~10.00μg/mL时与发射强度呈线性关系,相关系数为0.999 99,方法检出限均小于0.10μg/mL。按照方法测定5个石墨精矿样品中钙、镁、铝、铁、钾、钠,采用格拉布斯检验方法检验11次测定结果无异常值;加标回收率为90.2%~104%。方法快速有效地解决了石墨精矿中的杂质元素的测定难题,可用于测定钙、镁、铝、铁、钾、钠质量分数0.010%~1.00%的石墨精矿样品,同时对石墨矿中其他不易挥发元素的测定提供新思路。 展开更多
关键词 高温灼烧 电感耦合等离子体原子发射光谱法(ICP-aeS) 石墨精矿
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基于AE-BP模型的杨木胶合板应力损伤识别
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作者 刘佳 于孟言 +3 位作者 高珊 陈昱龙 冯蔓萱 杜鑫宇 《中南林业科技大学学报》 CAS CSCD 北大核心 2024年第4期169-179,共11页
【目的】利用声发射(AE)技术对应力损伤全过程中的杨木胶合板进行无损检测,并利用BP神经网络对AE检测结果进行识别,以提高胶合板损伤检测精度。【方法】以市场占有量较高的托盘用杨木胶合板作为研究对象,在联合AE和应力损伤试验过程中,... 【目的】利用声发射(AE)技术对应力损伤全过程中的杨木胶合板进行无损检测,并利用BP神经网络对AE检测结果进行识别,以提高胶合板损伤检测精度。【方法】以市场占有量较高的托盘用杨木胶合板作为研究对象,在联合AE和应力损伤试验过程中,提取6个AE特征参数,利用声发射RA-AF联合分析法区分杨木胶合板产生裂纹的类型,采用K-均值聚类分析方法确定损伤演化程度和AE特征参数之间的对应关系,利用BP神经网络建立损伤识别模型,并对识别网络进行测试训练。【结果】AE信号幅度和上升时间可有效地表征杨木胶合板应力损伤从微裂纹萌生、产生宏观裂纹至完全断裂的损伤演化过程;通过RA-AF联合分析发现:杨木胶合板在应力损伤试验第一阶段主要为剪切破坏损伤,第二、三阶段主要为拉伸破坏损伤;通过K-均值聚类分析发现损伤类型与AE峰值频率之间的存在较强对应关系,可有效的表征不同的损伤类型:在31 kHz内为基体开裂,在31~100 kHz内为脱胶分层,大于100 kHz为纤维断裂;构建AE-BP神经网络模型对应力损伤类型训练样本的拟合优度是95.94%,测试集的拟合优度是98.89%,模型总拟合优度是96.51%,网络训练效果较好。【结论】在应力承载AE监测过程中,通过构建AE-BP模型,可对杨木胶合板产生的未知损伤进行有效检测并准确识别。 展开更多
关键词 杨木胶合板 声发射 BP神经网络 损伤识别
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Stress-strain-acoustic responses in failure process of coal rock with different height to diameter ratios under uniaxial compression 被引量:13
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作者 GUO Yu-xia ZHAO Yong-hui +3 位作者 WANG Sheng-wei FENG Guo-rui ZHANG Yu-jiang RAN Hong-yu 《Journal of Central South University》 SCIE EI CAS CSCD 2021年第6期1724-1736,共13页
Residual coal pillars play an important role in mining the adjacent coal seam safely,managing the gobs and maintaining the stability of abandoned coal mines.The height to diameter ratio(H/D)affects the stability of re... Residual coal pillars play an important role in mining the adjacent coal seam safely,managing the gobs and maintaining the stability of abandoned coal mines.The height to diameter ratio(H/D)affects the stability of residual coal pillars.In this study,uniaxial compressive tests of coal specimens with five H/D(2.0,1.5,1.0,0.8 and 0.6)were performed,and the stress,strain and acoustic emission(AE)were monitored.Results show that the uniaxial compressive strength(UCS)and peak strain increase with H/D decreasing.An empirical equation is proposed to calculate the UCS based on the H/D.The AE activities during coal failure process can be separated into four periods.The span of quiet period and rapid decline period shorten with H/D decreasing.The smaller the H/D is,the more complicated the failure characteristics of coal will be.The failure form of coal with H/D of 2.0,1.5,and 1.0 is primarily shear failure,while splitting failure along the axial direction is the mainly mode when H/D is 0.8 or 0.6.The initiation,expansion,aggregation and connection of micro-cracks can be reflected by the real-time spatial evolution of AE event points. 展开更多
关键词 residual coal pillar height to diameter ratio uniaxial compression acoustic emission micro-crack evolution
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