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Poly(lactic acid)/Poly(butylene adipate-co-terephthalate)films with simultaneous high oxygen barrier and fast degradation properties
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作者 Mengjing Yang Yuxi Mao +4 位作者 Penghui Zhang Jie Li Zeming Tong Zhenguo Liu Yanhui Chen 《Green Energy & Environment》 SCIE EI CAS 2025年第1期1-10,共10页
Although poly(lactic acid)(PLA)is a good environmentally-friendly bio-degradable polymer which is used to substitute traditional petrochemical-based polymer packaging films,the barrier properties of PLA films are stil... Although poly(lactic acid)(PLA)is a good environmentally-friendly bio-degradable polymer which is used to substitute traditional petrochemical-based polymer packaging films,the barrier properties of PLA films are still insufficient for high-barrier packaging applications.In this study,oxygen scavenger hydroxyl-terminated polybutadiene(HTPB)and cobalt salt catalyst were incorporated into the PLA/poly(butylene adipate-co-terephthalate)(PLA/PBAT),followed by melting extrusion and three-layer co-extrusion blown film process to prepare the composite films.The oxygen permeability coefficient of the composite film combined with 6 wt%oxygen scavenger and 0.4 wt%catalyst was decreased significantly from 377.00 cc·mil·m^(-2)·day^(-1)·0.1 MPa^(-1) to 0.98 cc·mil·m^(-2)·day^(-1)·0.1 MPa^(-1),showing a remarkable enhancement of 384.69 times compared with the PLA/PBAT composite film.Meanwhile,the degradation behavior of the composite film was also accelerated,exhibiting a mass loss of nearly 60%of the original mass after seven days of degradation in an alkaline environment,whereas PLA/PBAT composite film only showed a mass loss of 32%.This work has successfully prepared PLA/PBAT composite films with simultaneously improved oxygen barrier property and degradation behavior,which has great potential for high-demanding green chemistry packaging industries,including food,agricultural,and military packaging. 展开更多
关键词 Barrier property Oxygen scavenging Blow molding Eco-packaging Degradable composite film
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Graphene Oxide on Rheological and Self-healing Properties of Modified Asphalt
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作者 LIU Qinbao ZHAO Yan +1 位作者 GAO Honggang YAN Luchun 《材料科学与工程学报》 北大核心 2025年第1期80-89,共10页
Graphene oxide nanomaterials are increasingly used in various fields due to their superior properties.In order to study the influence of graphene oxide additives on the performance of modified asphalt,in this study,gr... Graphene oxide nanomaterials are increasingly used in various fields due to their superior properties.In order to study the influence of graphene oxide additives on the performance of modified asphalt,in this study,graphene oxide modified asphalt was prepared and characteristics was studied including the high deformation resistance performance and the self-healing property of modified asphalt.Functional groups and morphology of graphene oxide modified asphalt were described by Fourier transform infrared spectroscopy.The high deformation resistance performance and self-healing effect of asphalt samples were obtained through dynamic slear rheometer(DSR)test.Results shows that graphene oxide dispersions improve the performance of asphalt relatively well compared to graphene oxide powder.There is no chemical reaction between graphene oxide and asphalt,but physical connection.The addition of graphene oxide improved the high deformation resistance of modified asphalt and expedited the self-healing ability of asphalt under fatigue load. 展开更多
关键词 Graphene Oxide Modified asphalt Rheological property SELF-HEALING
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Molecular simulation study of the microstructures and properties of pyridinium ionic liquid[HPy][BF_(4)]mixed with acetonitrile
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作者 XU Jian-Qiang MA Zhao-Peng +2 位作者 CHENG Si LIU Zhi-Cong ZHU Guang-Lai 《原子与分子物理学报》 CAS 北大核心 2025年第4期27-32,共6页
The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this wo... The microstructures and thermodynamic properties of mixed systems comprising pyridinium ionic liquid[HPy][BF_(4)]and acetonitrile at different mole fractions were studied using molecular dynamics simulation in this work.The following properties were determined:density,self-diffusion coefficient,excess molar volume,and radial distribution function.The results show that with an increase in the mole fraction of[HPy][BF_(4)],the self-diffusion coefficient decreases.Additionally,the excess molar volume initially decreases,reaches a minimum,and then increases.The rules of radial distribution functions(RDFs)of characteristic atoms are different.With increasing the mole fraction of[HPy][BF_(4)],the first peak of the RDFs of HA1-F decreases,while that of CT6-CT6 rises at first and then decreases.This indicates that the solvent molecules affect the polar and non-polar regions of[HPy][BF_(4)]differently. 展开更多
关键词 Pyridinium ionic liquids Thermodynamic properties Molecular dynamics simulation Radial distribution functions
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Evaluation of physicochemical and functional properties of protein isolates from 5 edible mushroom species
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作者 Zheng Qian Mengdie Yang +4 位作者 Xiao Chen Qiping Zhan Lei Zhong Qiuhui Hu Liyan Zhao 《Food Science and Human Wellness》 2025年第2期671-682,共12页
Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities.To reinforce their applications in functional food development,this study... Edible mushroom proteins are the promising ones with the advantages of complete essential amino acid profile and multiple functional activities.To reinforce their applications in functional food development,this study comprehensively evaluated the physicochemical and functional properties of protein isolates from 5 mushroom species,i.e.,Pleurotus eryngii(PEP),Pleurotus ostreatus(POP),Lentinula edodes(LEP),Flammulina velutipes(FVP)and Hypsizygus marmoreus(HMP).Results showed that PEP,LEP,FVP,POP and HMP exhibited better protein solubility(PS),water holding capacity(WHC),emulsification activity index(EAI),and foaming capacity(FC)than those of soybean protein and pea protein isolates(PPI).PEP(51.95%)and POP(49.15%)had a higher amount ofβ-sheet structure.Principal component analysis and correlation analysis showed that the seven proteins could be divided into 3 clusters,and WHC,EAI and FC were significantly positively correlated with PS andβ-sheet.The least gelation concentration of PEP(16%)and FVP(16%)at p H 6.0 and 7.0 was similar to PPI,and PEP showed better hardness,springiness and rheological properties than other proteins gels.Overall,our study showed that 5 edible mushroom proteins possessed excellent functionalities(except for gelling capacity),which provided novel insights on unexploited sources of mushroom proteins used as protein-based foods in the food industry. 展开更多
关键词 Edible mushroom proteins Physicochemical properties Functional properties Gelling properties
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Stable structures and properties of Ru_(2)Al_(5)
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作者 Jing Luo Meiguang Zhang +1 位作者 Xiaofei Jia Qun Wei 《Chinese Physics B》 2025年第1期414-420,共7页
Novel ordered intermetallic compounds have stimulated much interest.Ru–Al alloys are a prominent class of hightemperature structural materials,but the experimentally reported crystal structure of the intermetallic Ru... Novel ordered intermetallic compounds have stimulated much interest.Ru–Al alloys are a prominent class of hightemperature structural materials,but the experimentally reported crystal structure of the intermetallic Ru_(2)Al_(5) phase remains elusive and debatable.To resolve this controversy,we extensively explored the crystal structures of Ru_(2)Al_(5) using first-principles calculations combined with crystal structure prediction technique.Among the calculated x-ray diffraction patterns and lattice parameters of five candidate Ru2Al5structures,those of the orthorhombic Pmmn structure best aligned with recent experimental results.The structural stabilities of the five Ru_(2)Al_(5)structures were confirmed through formation energy,elastic constants,and phonon spectrum calculations.We also comprehensively analyzed the mechanical and electronic properties of the five candidates.This work can guide the exploration of novel ordered intermetallic compounds in Ru–Al alloys. 展开更多
关键词 crystal structure prediction mechanical properties first-principles calculations
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A Novel Property of Generalized Fibonacci Sequence in Grids
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作者 YANG Zi-xian BAI Jian-chao 《Chinese Quarterly Journal of Mathematics》 2025年第1期103-110,共8页
Fibonacci sequence,generated by summing the preceding two terms,is a classical sequence renowned for its elegant properties.In this paper,leveraging properties of generalized Fibonacci sequences and formulas for conse... Fibonacci sequence,generated by summing the preceding two terms,is a classical sequence renowned for its elegant properties.In this paper,leveraging properties of generalized Fibonacci sequences and formulas for consecutive sums of equidistant sub-sequences,we investigate the ratio of the sum of numbers along main-diagonal and sub-diagonal of odd-order grids containing generalized Fibonacci sequences.We show that this ratio is solely dependent on the order of the grid,providing a concise and splendid identity. 展开更多
关键词 Generalized Fibonacci sequence Fibonacci identity Odd-order grid Geometric property
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Structural and transport properties of(Mg,Fe)SiO_(3) at high temperature and high pressure
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作者 Shu Huang Zhiyang Xiang +5 位作者 Shi He Luhan Yin Shihe Zhang Chen Chen Kaihua He Cheng Lu 《Chinese Physics B》 2025年第3期123-129,共7页
(Mg,Fe)SiO_(3) is primarily located in the mantle and has a substantial impact on geophysical and geochemical processes.Here,we employ molecular dynamics simulations to investigate the structural and transport propert... (Mg,Fe)SiO_(3) is primarily located in the mantle and has a substantial impact on geophysical and geochemical processes.Here,we employ molecular dynamics simulations to investigate the structural and transport properties of(Mg,Fe)SiO_(3) with varying iron contents at temperatures up to 5000 K and pressures up to 135 GPa.We thoroughly examine the effects of pressure,temperature,and iron content on the bond lengths,coordination numbers,viscosities,and electrical conductivities of(Mg,Fe)SiO_(3).Our calculations indicate that the increase of pressure leads to the shortening of the O-O and Mg-O bond lengths,while the Si-O bond lengths exhibit the initial increase with pressure up to 40 GPa,after which they are almost unchanged.The coordination numbers of Si transition from four-fold to six-fold and eventually reach eight-fold coordination at 135 GPa.The enhanced pressure causes the decrease of the diffusion coefficients and the increase of the viscosities of(Mg,Fe)SiO_(3).The increased temperatures slightly decrease the coordination numbers and viscosities,as well as obviously increase the diffusion coefficients and electrical conductivities of(Mg,Fe)SiO_(3).Additionally,iron doping facilitates the diffusion of Si and O,reduces the viscosities,and enhances the electrical conductivities of(Mg,Fe)SiO_(3).These findings advance fundamental understanding of the structural and transport properties of(Mg,Fe)SiO_(3) under high temperature and high pressure,which provide novel insights for unraveling the complexities of geological processes within the Earth's mantle. 展开更多
关键词 (Mg Fe)SiO_(3) structural and transport properties molecular dynamics simulations high temperature and high pressure
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Preparation of Alumina Abrasion-Resistant Ceramic Grinding Ball with Spent FCC Equilibrium Catalyst 被引量:4
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作者 Liang Zhiyu Yan Guiyang +2 位作者 Zheng Liuping Weng Xiulan Huang Zheqiang 《China Petroleum Processing & Petrochemical Technology》 SCIE CAS 2010年第4期23-29,共7页
The chemical composition, structure and thermal stability of the spent FCC equilibrium catalyst from an oil refinery were characterized by XRD, FT-IR, DTA-TG, BET, complete chemical analysis, SEM, and XRF. The spent F... The chemical composition, structure and thermal stability of the spent FCC equilibrium catalyst from an oil refinery were characterized by XRD, FT-IR, DTA-TG, BET, complete chemical analysis, SEM, and XRF. The spent FCC equilibrium catalyst, clay, barium carbonate, and talc were used as the main raw materials to prepare the alumina abrasion-resistant ceramic balls to be used in the powder grinding mill for manufacture of architecture tiles. The results showed that after proper formulation study, the spent FCC equilibrium catalyst could replace industrial alumina to prepare high performance grinding balls. Meanwhile, the various performance indices of the grinding ball could meet the quality standard for similar products, and additionally, the energy saving effect was achieved in the operation of the grinding section, resulting in a successful comprehensive utilization of solid wastes. 展开更多
关键词 spent FCC equilibrium catalyst ALUMINA abrasion-resistant ceramic ball solid waste UTILIZATION
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Physical,mechanical and thermal properties of vacuum sintered HUST-1 lunar regolith simulant 被引量:2
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作者 Wenbin Han Yan Zhou +2 位作者 Lixiong Cai Cheng Zhou Lieyun Ding 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1243-1257,共15页
Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and th... Establishing a base on the Moon is one of the new goals of human lunar exploration in recent years.Sintered lunar regolith is one of the most potential building materials for lunar bases.The physical,mechanical and thermal properties of sintered lunar regolith are vital performance indices for the structural design of a lunar base and analysis of many critical mechanical and thermal issues.In this study,the HUST-1 lunar regolith simulant(HLRS)was sintered at 1030,1040,1050,1060,1070,and 1080℃.The effect of sintering temperature on the compressive strength was investigated,and the exact value of the optimum vacuum sintering temperature was determined between 1040 and 1060℃.Then,the microstructure and material composition of vacuum sintered HLRS at different temperatures were characterized.It was found that the sintering temperature has no significant effect on the mineral composition in the temperature range of 1030-1080℃.Besides,the heat capacity,thermal conductivity,and coefficient of thermal expansion(CTE)of vacuum sintered HLRS at different temperatures were investigated.Specific heat capacity of sintered samples increases with the increase of test temperature within the temperature range from-75 to 145℃.Besides,the thermal conductivity of the sintered sample is proportional to density.Finally,the two temperatures of 1040 and 1050℃were selected for a more detailed study of mechanical properties.The results showed that compressive strength of sintered sample is much higher than tensile strength.This study reveals the effects of sintering temperature on the physical,mechanical and thermal properties of vacuum sintered HLRS,and these material parameters will provide support for the construction of future lunar bases. 展开更多
关键词 Lunar base Lunar regolith simulant Vacuum sintering Physical properties Mechanical properties Thermal properties
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Machine learning applications on lunar meteorite minerals:From classification to mechanical properties prediction 被引量:1
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作者 Eloy Peña-Asensio Josep M.Trigo-Rodríguez +2 位作者 Jordi Sort Jordi Ibáñez-Insa Albert Rimola 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1283-1292,共10页
Amid the scarcity of lunar meteorites and the imperative to preserve their scientific value,nondestructive testing methods are essential.This translates into the application of microscale rock mechanics experiments an... Amid the scarcity of lunar meteorites and the imperative to preserve their scientific value,nondestructive testing methods are essential.This translates into the application of microscale rock mechanics experiments and scanning electron microscopy for surface composition analysis.This study explores the application of Machine Learning algorithms in predicting the mineralogical and mechanical properties of DHOFAR 1084,JAH 838,and NWA 11444 lunar meteorites based solely on their atomic percentage compositions.Leveraging a prior-data fitted network model,we achieved near-perfect classification scores for meteorites,mineral groups,and individual minerals.The regressor models,notably the KNeighbor model,provided an outstanding estimate of the mechanical properties—previously measured by nanoindentation tests—such as hardness,reduced Young’s modulus,and elastic recovery.Further considerations on the nature and physical properties of the minerals forming these meteorites,including porosity,crystal orientation,or shock degree,are essential for refining predictions.Our findings underscore the potential of Machine Learning in enhancing mineral identification and mechanical property estimation in lunar exploration,which pave the way for new advancements and quick assessments in extraterrestrial mineral mining,processing,and research. 展开更多
关键词 METEORITES MOON MINERALOGY Machine learning Mechanical properties
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Formation of Tianwen-1 landing crater and mechanical properties of Martian soil near the landing site 被引量:2
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作者 Xinshuo Chen Zhaobin Zhang +7 位作者 Juan Li Shouding Li Tao Xu Bo Zheng Xiukuo Sun Yanfang Wu Yiming Diao Xiao Li 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第9期1293-1303,共11页
After landing in the Utopia Planitia,Tianwen-1 formed the deepest landing crater on Mars,approximately 40 cm deep,exposing precious information about the mechanical properties of Martian soil.We established numerical ... After landing in the Utopia Planitia,Tianwen-1 formed the deepest landing crater on Mars,approximately 40 cm deep,exposing precious information about the mechanical properties of Martian soil.We established numerical models for the plume-surface interaction(PSI)and the crater formation based on Computational Fluid Dynamics(CFD)methods and the erosion model modified from Roberts’Theory.Comparative studies of cases were conducted with different nozzle heights and soil mechanical properties.The increase in cohesion and internal friction angle leads to a decrease in erosion rate and maximum crater depth,with the cohesion having a greater impact.The influence of the nozzle height is not clear,as it interacts with the position of the Shock Diamond to jointly control the erosion process.Furthermore,we categorized the evolution of landing craters into the dispersive and the concentrated erosion modes based on the morphological characteristics.Finally,we estimated the upper limits of the Martian soil’s mechanical properties near Tianwen-1 landing site,with the cohesion ranging from 2612 to 2042 Pa and internal friction angle from 25°to 41°. 展开更多
关键词 Tianwen-1 Plume-surface interaction Landing crater formation Martian soil mechanical properties Numerical simulation
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Hydrothermal treatment of pearl millet grains:Effects on nutritional composition,antinutrients and flour properties 被引量:1
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作者 P.Prashanth T.Jayasree Joshi +1 位作者 Shagolshem Mukta Singh P.Srinivasa Rao 《Grain & Oil Science and Technology》 CAS 2024年第2期87-95,共9页
Pearl millet(Pennisetum glaucum)is one of the major millets with high nutritional properties.This crop exhibits exceptional resilience to drought and high temperatures.However,the processing of pearl millet poses a si... Pearl millet(Pennisetum glaucum)is one of the major millets with high nutritional properties.This crop exhibits exceptional resilience to drought and high temperatures.However,the processing of pearl millet poses a significant challenge due to its high lipid content,enzyme activity,and presence of antinutrients.Consequently,it becomes imperative to enhance the quality and prolong the shelf life of pearl millet flour by employing suitable technologies.Hydrothermal treatment in the food industry has long been seen as promising due to its potential to reduce microbial load,inactivate enzymes,and improve nutrient retention.This study aims to investigate the effects of hydrothermal treatment on the quality characteristics of pearl millet.The independent variables of the study were soaking temperature(35,45,55℃),soaking time(2,3,4 h),and steaming time(5,10,15 min).Treatment conditions had a statistically significant effect on nutrient retention.Major antinutrients like tannins and phytates were reduced by 0.99% to 5.94% and 0.36% to 6.00%,respectively,after the treatment.Lipase activity decreased significantly up to 10% with the treatment conditions.The findings of this study could potentially encourage the use of pearl millet flour in the production of various food items and promote the application of hydrothermal treatment in the field of food processing. 展开更多
关键词 Pearl millet Hydrothermal treatment Nutritional properties ANTINUTRIENTS
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Effect of sodium starch octenyl succinate-based Pickering emulsion on the physicochemical properties of hairtail myofibrillar protein gel subjected to multiple freeze-thaw cycles 被引量:1
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作者 Huinan Wang Jiaxin Zhang +3 位作者 Xinran Liu Jinxiang Wang Xuepeng Li Jianrong Li 《Food Science and Human Wellness》 SCIE CSCD 2024年第2期1018-1028,共11页
A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles... A Pickering emulsion based on sodium starch octenyl succinate(SSOS)was prepared and its effects on the physicochemical properties of hairtail myofibrillar protein gels(MPGs)subjected to multiple freeze-thaw(F-T)cycles were investigated.The whiteness,water-holding capacity,storage modulus(G')and texture properties of the MPGs were significantly improved by adding 1%-2%Pickering emulsion(P<0.05).Meanwhile,Raman spectral analysis demonstrated that Pickering emulsion promoted the transformation of secondary structure,enhanced hydrogen bonds and hydrophobic interactions,and promoted the transition of disulfide bond conformation from g-g-g to g-g-t and t-g-t.At an emulsion concentration of 2%,theα-helix content decreased by 10.37%,while theβ-sheet content increased by 7.94%,compared to the control.After F-T cycles,the structure of the MPGs was destroyed,with an increase in hardness and a decrease in whiteness and water-holding capacity,however,the quality degradation of MPGs was reduced with 1%-2%Pickering emulsion.These findings demonstrated that SSOS-Pickering emulsions,as potential fat substitutes,can enhance the gel properties and the F-T stability of MPGs. 展开更多
关键词 Pickering emulsion Myofibrillar protein Gel properties Freeze-thaw stability Intermolecular interactions
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Recent research in mechanical properties of geopolymer-based ultrahigh-performance concrete:A review 被引量:1
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作者 G.Murali 《Defence Technology(防务技术)》 SCIE EI CAS CSCD 2024年第2期67-88,共22页
Due to the growing need for sustainable and ultra-high-strength construction materials,scientists have created an innovative ultra-high-performance concrete called Geopolymer based ultra-highperformance concrete(GUHPC... Due to the growing need for sustainable and ultra-high-strength construction materials,scientists have created an innovative ultra-high-performance concrete called Geopolymer based ultra-highperformance concrete(GUHPC).Besides,in the last few decades,there have been a lot of explosions and ballistic attacks around the world,which have killed many civilians and fighters in border areas.In this context,this article reviews the fresh state and mechanical properties of GUHPC.Firstly,the ingredients of GUHPC and fresh properties such as setting time and flowability are briefly covered.Secondly,the review of compressive strength,flexure strength,tensile strength and modulus of elasticity of fibrous GUHPC.Thirdly,the blast and projectile impact resistance performance was reviewed.Finally,the microstructural characteristics were reviewed using the scanning electron microscope and X-ray Powder Diffraction.The review outcome reveals that the mechanical properties were increased when 30%silica fume was added to a higher dose of steel fibre to improve the microstructure of GUHPC.It is hypothesized that the brittleness of GUHPC was mitigated by adding 1.5%steel fibre reinforcement,which played a role in the decrease of contact explosion cratering and spalling.Removing the need for cement in GUHPC was a key factor in the review,indicating a promising potential for lowering carbon emissions.However,GUHPC research is still in its early stages,so more study is required before its full potential can be utilized. 展开更多
关键词 Mechanical properties BLAST Projectile impact FIBRE GEOPOLYMER Silica fume Alkaline activators
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Preparation of lactic acid bacteria compound starter cultures based on pasting properties and its improvement of glutinous rice flour and dough 被引量:1
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作者 Dengyu Wang Linlin Liu +4 位作者 Bing Wang Wenjian Xie Yanguo Shi Na Zhang Hongchen Fan 《Food Science and Human Wellness》 SCIE CAS CSCD 2024年第4期2090-2101,共12页
The effects of 5 lactic acid bacteria(LAB)fermentation on the pasting properties of glutinous rice flour were compared,and suitable fermentation strains were selected based on the changes of viscosity,setback value,an... The effects of 5 lactic acid bacteria(LAB)fermentation on the pasting properties of glutinous rice flour were compared,and suitable fermentation strains were selected based on the changes of viscosity,setback value,and breakdown value to prepare LAB compound starter cultures.The results revealed that Latilactobacillus sakei HSD004 and Lacticaseibacillus rhamnosus HSD005 had apparent advantages in increasing the viscosity and reducing the setback and breakdown values of glutinous rice flour.In particular,the compound starter created using the two abovementioned LAB in the ratio of 3:1 had better performance than that using a single LAB in improving the pasting properties and increasing the water and oil absorption capacity of glutinous rice flour.Moreover,the gelatinization enthalpy of the fermented samples increased significantly.For frozen glutinous rice dough stored for 28 days,the viscoelasticity of frozen dough prepared by compound starter was better than that of control dough,and the freezable water content was lower than that of control dough.These results indicate that compound LAB fermentation is a promising technology in the glutinous rice-based food processing industry,which has significance for its application. 展开更多
关键词 Glutinous rice flour Glutinous rice dough Lactic acid bacteria compound starter cultures Pasting properties VISCOELASTICITY
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Microdynamic mechanical properties and fracture evolution mechanism of monzogabbro with a true triaxial multilevel disturbance method 被引量:1
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作者 Zhi Zheng Bin Deng +3 位作者 Hong Liu Wei Wang Shuling Huang Shaojun Li 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第3期385-411,共27页
The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the... The far-field microdynamic disturbance caused by the excavation of deep mineral resources and underground engineering can induce surrounding rock damage in high-stress conditions and even lead to disasters.However,the mechanical properties and damage/fracture evolution mechanisms of deep rock induced by microdynamic disturbance under three-dimensional stress states are unclear.Therefore,a true triaxial multilevel disturbance test method is proposed,which can completely simulate natural geostress,excavation stress redistribution(such as stress unloading,concentration and rotation),and subsequently the microdynamic disturbance triggering damaged rock failure.Based on a dynamic true triaxial test platform,true triaxial microdynamic disturbance tests under different frequency and amplitudes were carried out on monzogabbro.The results show that increasing amplitude or decreasing frequency diminishes the failure strength of monzogabbro.Deformation modulus gradually decreases during disturbance failure.As frequency and amplitude increase,the degradation rate of deformation modulus decreases slightly,disturbance dissipated energy increases significantly,and disturbance deformation anisotropy strengthens obviously.A damage model has been proposed to quantitatively characterize the disturbance-induced damage evolution at different frequency and amplitude under true triaxial stress.Before disturbance failure,the micro-tensile crack mechanism is dominant,and the micro-shear crack mechanism increases significantly at failure.With the increase of amplitude and frequency,the micro-shear crack mechanism increases.When approaching disturbance failure,the acoustic emission fractal dimension changes from a stable value to local large oscillation,and finally increases sharply to a high value at failure.Finally,the disturbance-induced failure mechanism of surrounding rock in deep engineering is clearly elucidated. 展开更多
关键词 True triaxial disturbance test Mechanical properties Fracture evolution mechanism Disturbance-induced damage evolution Failure mechanism and precursor
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Effect of dry-wet cycles on dynamic properties and microstructures of sandstone:Experiments and modelling 被引量:1
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作者 Hai Pu Qingyu Yi +3 位作者 Andrey P.Jivkov Zhengfu Bian Weiqiang Chen Jiangyu Wu 《International Journal of Mining Science and Technology》 SCIE EI CAS CSCD 2024年第5期655-679,共25页
Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned mines.Its realization requires better understanding of the dynamic performance and durability of reservoir rock.Thi... Underground pumped storage power plant(UPSP)is an innovative concept for space recycling of abandoned mines.Its realization requires better understanding of the dynamic performance and durability of reservoir rock.This paper conducted ultrasonic detection,split Hopkinson pressure bar(SHPB)impact,mercury intrusion porosimetry(MIP),and backscatter electron observation(BSE)tests to investigate the dynamical behaviour and microstructure of sandstone with cyclical dry-wet damage.A coupling FEM-DEM model was constructed for reappearing mesoscopic structure damage.The results show that dry-wet cycles decrease the dynamic compressive strength(DCS)with a maximum reduction of 39.40%,the elastic limit strength is reduced from 41.75 to 25.62 MPa.The sieved fragments obtain the highest crack growth rate during the 23rd dry-wet cycle with a predictable life of 25 cycles for each rock particle.The pore fractal features of the macropores and micro-meso pores show great differences between the early and late cycles,which verifies the computational statistics analysis of particle deterioration.The numerical results show that the failure patterns are governed by the strain in pre-peak stage and the shear cracks are dominant.The dry-wet cycles reduce the energy transfer efficiency and lead to the discretization of force chain and crack fields. 展开更多
关键词 Underground pumped storage power plant Dry-wet cycles Split Hopkinson pressure bar Macro and micro properties FEM-DEM coupling model Damage characterization
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Unveiling the tailorable electrochemical properties of zeolitic imidazolate framework-derived Ni-doped LiCoO_(2) for lithium-ion batteries in half/full cells 被引量:1
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作者 Jian-En Zhou Yiqing Liu +6 位作者 Zhijian Peng Quanyi Ye Hua Zhong Xiaoming Lin Ronghua Zeng Yongbo Wu Jiaye Ye 《Journal of Energy Chemistry》 SCIE EI CAS CSCD 2024年第6期229-242,I0006,共15页
As a prevailing cathode material of lithium-ion batteries(LIBs),LiCoO_(2)(LCO)still encounters the tricky problems of structural collapse,whose morphological engineering and cation doping are crucial for surmounting t... As a prevailing cathode material of lithium-ion batteries(LIBs),LiCoO_(2)(LCO)still encounters the tricky problems of structural collapse,whose morphological engineering and cation doping are crucial for surmounting the mechanical strains and alleviating phase degradation upon cycling.Hereinafter,we propose a strategy using a zeolitic imidazolate framework(ZIF)as the self-sacrificing template to directionally prepare a series of LiNi_(0.1)Co_(0.9)O_(2)(LNCO)with tailorable electrochemical properties.The rational selection of sintering temperature imparts the superiority of the resultant products in lithium storage,during which the sample prepared at 700℃(LNCO-700)outperforms its counterparts in cyclability(156.8 mA h g^(-1)at 1 C for 200 cycles in half cells,1 C=275 mA g^(-1))and rate capability due to the expedited ion/electron transport and the strengthen mechanical robustness.The feasibility of proper Ni doping is also divulged by half/full cell tests and theoretical study,during which LNCO-700(167 mA h g^(-1)at 1 C for 100 cycles in full cells)surpasses LCO-700 in battery performance due to the mitigated phase deterioration,stabilized layered structu re,ameliorated electro nic co nductivity,a nd exalted lithium sto rage activity.This work systematically unveils tailorable electrochemical behaviors of LNCO to better direct their practical application. 展开更多
关键词 Lithium-ion batteries Zeolitic imidazolate framework LiNi_(0.1)Co_(0.9)O_(2) Electrochemical properties
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Thermal and textural properties of extruded rice affect its cooking performances and the texture of the steamed extruded rice
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作者 Yulong Wang Lingjie Jiang +5 位作者 Kangru Cui Zhonghua Gu Yunfei Yang Renyong Zhao Xinwei Wang Hongxin Jiang 《Grain & Oil Science and Technology》 CAS 2024年第4期237-245,共9页
Extruded rice has increasingly gained popularity in the market due to its convenience and acceptable texture.The objective of this study was to understand how the physicochemical,thermal,and textural properties of the... Extruded rice has increasingly gained popularity in the market due to its convenience and acceptable texture.The objective of this study was to understand how the physicochemical,thermal,and textural properties of the extruded rice affected its cooking properties and texture of the cooked one.It was found that air trapped in the grains during extrusion reduced the transparency of extruded rice.More air trapped in the grains reduced the true density of the extruded rice,which in turn decreased the hardness of extruded rice.A looser internal structure of extruded rice grain,as indicated by the lower true density,resulted in a faster hydration and shorter optimum cooking time.Extruded rices showed two thermal-transition peaks,with peak 1 from 93.3℃ to 112.8℃ and peak 2 from 107.5℃ to 132.5℃.The increased hardness of extruded rice led to increases in its thermaltransition temperatures,longer optimum steaming time,and decreases in its water absorption and cooking loss,which resulted in an increase in the hardness and a reduction in the adhesiveness of the steamed one.This study provides insights into the key factors determining the eating quality of extruded rice,which is beneficial for food scientists in developing premium extruded rice. 展开更多
关键词 Extruded rice Textural properties Cooking properties Thermal properties Pasting properties
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Influences of divalent ion substitution on the magnetic and dielectric properties of W-type barium ferrite
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作者 何诗悦 刘若水 +3 位作者 刘煦婕 叶先平 王利晨 沈保根 《Chinese Physics B》 SCIE EI CAS CSCD 2024年第6期480-486,共7页
Saturation magnetization,magneto-crystalline anisotropy field,and dielectric properties are closely related to microwave devices applied at different frequencies.For regulating the magnetic and dielectric properties o... Saturation magnetization,magneto-crystalline anisotropy field,and dielectric properties are closely related to microwave devices applied at different frequencies.For regulating the magnetic and dielectric properties of W-type barium ferrites,single-phase BaMe_(2)Fe_(16)O_(27)(Me=Fe,Mn,Zn,Ni,Co) with different Me ions were synthesized by the high-temperature solid-state method.The saturation magnetization(Ms) range from 47.77 emu/g to 95.34 emu/g and the magnetic anisotropy field(H_a) range from 10700.60 Oe(1 Oe=79.5775 A·m^(-1)) to 13739.57 Oe,depending on the type of cation substitution in the hexagonal lattice.The dielectric permittivity and dielectric loss decrease with increasing frequency of the AC electric field in the low-frequency region,while they almost remain constant in the high-frequency region.The charac teristics of easy regulation and preparation make it a potential candidate for use in microwave device applications. 展开更多
关键词 W-type hexaferrite Raman spectra magnetic properties dielectric properties
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