The current single-atom catalysts(SACs)for medicine still suffer from the limited active site density.Here,we develop a synthetic method capable of increasing both the metal loading and mass-specific activity of SACs ...The current single-atom catalysts(SACs)for medicine still suffer from the limited active site density.Here,we develop a synthetic method capable of increasing both the metal loading and mass-specific activity of SACs by exchanging zinc with iron.The constructed iron SACs(h^(3)-FNC)with a high metal loading of 6.27 wt%and an optimized adjacent Fe distance of~4 A exhibit excellent oxidase-like catalytic performance without significant activity decay after being stored for six months and promising antibacterial effects.Attractively,a“density effect”has been found at a high-enough metal doping amount,at which individual active sites become close enough to interact with each other and alter the electronic structure,resulting in significantly boosted intrinsic activity of single-atomic iron sites in h^(3)-FNCs by 2.3 times compared to low-and medium-loading SACs.Consequently,the overall catalytic activity of h^(3)-FNC is highly improved,with mass activity and metal mass-specific activity that are,respectively,66 and 315 times higher than those of commercial Pt/C.In addition,h^(3)-FNCs demonstrate efficiently enhanced capability in catalyzing oxygen reduction into superoxide anion(O_(2)·^(−))and glutathione(GSH)depletion.Both in vitro and in vivo assays demonstrate the superior antibacterial efficacy of h^(3)-FNCs in promoting wound healing.This work presents an intriguing activity-enhancement effect in catalysts and exhibits impressive therapeutic efficacy in combating bacterial infections.展开更多
Salt cavern energy storage technology contributes to energy reserves and renewable energy scale-up.This study focuses on salt cavern gas storage in Jintan to assess the long-term stability of its surrounding rock unde...Salt cavern energy storage technology contributes to energy reserves and renewable energy scale-up.This study focuses on salt cavern gas storage in Jintan to assess the long-term stability of its surrounding rock under frequent operation.The fatigue test results indicate that stress holding significantly reduces fatigue life,with the magnitude of stress level outweighing the duration of holding time in determining peak strain.Employing a machine learning approach,the impact of various factors on fatigue life and peak strain was quantified,revealing that higher stress limits and stress holding adversely impact the fatigue index,whereas lower stress limits and rate exhibit a positive effect.A novel fatigue-creep composite damage constitutive model is constructed,which is able to consider stress magnitude,rate,and stress holding.The model,validated through multi-path tests,accurately captures the elasto-viscous behavior of salt rock during loading,unloading,and stress holding.Sensitivity analysis further reveals the time-and stress-dependent behavior of model parameters,clarifying that strain changes stem not only from stress variations but are also influenced by alterations in elasto-viscous parameters.This study provides a new method for the mechanical assessment of salt cavern gas storage surrounding rocks.展开更多
The attenuation of the acoustic activity in marble specimens under uniaxial compressive loadingunloading loops is quantified in juxtaposition to that of the electric activity.In parallel,the existence of"pre-fail...The attenuation of the acoustic activity in marble specimens under uniaxial compressive loadingunloading loops is quantified in juxtaposition to that of the electric activity.In parallel,the existence of"pre-failure indiceso"warning about entrance into a critical stage,that of impending fracture,is explored.The acoustic activity is quantified in terms of the normalized number of acoustic hits,their average rate of production and their cumulative energy,and,the cumulative counts and their average rate of change.The electric activity is studied in terms of the pressure stimulated currents and the electric charge released.The analysis revealed that the acoustic and electric activities are linearly correlated to each other,suggesting that they are different manifestations of the same damage mechanisms.In addition,Kaiser's effect,governing the acoustic activity,is found to govern,also,the electric activity.Moreover,it is concluded that entrance into the critical stage is safely predicted by means of a simple criterion,based on the evolution of the average rate of change of the normalized cumulative counts in the natural time domain.These predictions are almost identical with those of the criterion based on the "varianceo" and the "entropies" of the time series of acoustic events in this domain.展开更多
It is important to analyze the damage evolution process of surrounding rock under different water content for the stability of engineering rock mass.Based on digital speckle correlation(DSCM),acoustic emission(AE)and ...It is important to analyze the damage evolution process of surrounding rock under different water content for the stability of engineering rock mass.Based on digital speckle correlation(DSCM),acoustic emission(AE)and electromagnetic radiation(EMR),uniaxial hierarchical cyclic loading and unloading tests were carried out on sandstones with different fracture numbers under dry,natural and saturated water content,to explore the fracture propagation,failure precursor characteristics and damage response mechanism under the influence of water content effect.The results show that with the increase of water content,the peak stress and crack initiation stress decrease gradually,and the decreases are 15.28%-21.11%and 17.64%-23.04%,respectively.The peak strain and crack initiation strain increase gradually,and the increases are 19.85%-44.53%and 19.15%-41.94%,respectively.The precracked rock with different water content is mainly characterized by tensile failure at different loading stages.However,with the increase of water content,the proportion of shear cracks gradually increases,while acoustic emission events gradually decrease,the dissipative energy and energy storage limits of the rock under peak load gradually decrease,and the charge signal increases significantly,which is because the lubrication effect of water reduces the friction coefficient between crack surfaces.展开更多
The damage evolution process of non-penetrating cracks often causes some unexpected engineering disasters.Gypsum specimens containing non-penetrating crack(s)are used to study the damage evolution and characteristics ...The damage evolution process of non-penetrating cracks often causes some unexpected engineering disasters.Gypsum specimens containing non-penetrating crack(s)are used to study the damage evolution and characteristics under cyclic loading.The results show that under cyclic loading,the relationship between the number of non-penetrating crack(s)and the characteristic parameters(cyclic number,peak stress,peak strain,failure stress,and failure strain)of the pre-cracked specimens can be represented by a decreasing linear function.The damage evolution equation is fitted by calibrating the accumulative plastic strain for each cycle,and the damage constitutive equation is proposed by the concept of effective stress.Additionally,non-penetrating cracks are more likely to cause uneven stress distribution,damage accumulation,and local failure of specimen.The local failure can change the stress distribution and relieve the inhibition of non-penetrating crack extension and eventually cause a dramatic destruction of the specimen.Therefore,the evolution process caused by non-penetrating cracks can be regarded as one of the important reasons for inducing rockburst.These results are expected to improve the understanding of the process of spalling formation and rockburst and can be used to analyze the stability of rocks or rock structures.展开更多
A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator co...A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator combined with high-pressure flexible bladder was proposed,and the numerical model of the loading device based on flexible bladder was established.The design and analysis method of high-pressure flexible bladder based on aramid-fiber reinforced thermoplastic polyurethane was proposed to break through the surface pressure loading technology of ship structures.The surface pressure loading system based on flexible bladder was developed.The ultimate strength verification test of the box girder under the combined action of bending moment and pressure was carried out to systematically verify the feasibility and applicability of the loading system.The results show that the surface pressure loading technology can be used well for applying uniform pressure to ship structures.Compared with the traditional surface loading methods,the improved device can be applied with horizontal constant pressure load,with rapid response and safe process,and the pressure load is always stable with the increase of the bending moment load during the test.The requirement for uniform loading in the comprehensive strength test of large structural models is satisfied and the accuracy of the test results is improved by this system.展开更多
By combination of the transient Raman spectroscopic measurement and the density functional theoretical calculations,the structural evolution and stability of TATB under shock compression was investigated.Due to the im...By combination of the transient Raman spectroscopic measurement and the density functional theoretical calculations,the structural evolution and stability of TATB under shock compression was investigated.Due to the improvement in synchronization control between two-stage light gas gun and the transient Raman spectra acquisition,as well as the sample preparation,the Raman peak of the N-O mode of TATB was firstly observed under shock pressure up to 13.6 GPa,noticeably higher than the upper limit of 8.5 GPa reported in available literatures.By taking into account of the continuous shift of the main peak and other observed Raman peaks,we did not distinguish any structural transition or any new species.Moreover,both the present Raman spectra and the time-resolved radiation of TATB during shock loading showed that TATB exhibits higher chemical stability than previous declaration.To reveal the detailed structural response and evolution of TATB under compression,the density functional theoretical calculations were conducted,and it was found that the pressure make N-O bond lengths shorter,nitro bond angles larger,and intermolecular and intra-molecular hydrogen bond interactions enhanced.The observed red shift of Raman peak was ascribed to the abnormal enhancement of H-bound effect on the scissor vibration mode of the nitro group.展开更多
In this study, the influence of opening parameters on the ultimate strength of perforated plates subjected to extreme cyclic loading in the presence of material kinematic hardening and isotro pic hardening was analyze...In this study, the influence of opening parameters on the ultimate strength of perforated plates subjected to extreme cyclic loading in the presence of material kinematic hardening and isotro pic hardening was analyzed. It is found that the ultimate strength of the perforated plates decreases rapidly and stabilizes in the first four cycles. Plates with oblong openings have a greater ultimate strength compared to plates with rectangular openings, while the relative strengthening ratio decreases over the duration of the cycle. The location of the openings is also an important parameter that affects the strength of the structure, as the plates with openings close to the edges in the longitudinal direction have higher strengths, while in the transverse direction the strengths are higher when the openings are close to the center. Among the three opening-strengthening methods compared, the Carling stiffener method maintains a better strengthening effect under cyclic loads for many periods.展开更多
Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,F...Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,Fangshan granite(FG)specimens were exposed to microwave irradiation and heat treatment.The damage of FG specimens induced by these two methods was compared using X-ray CT scanning and ultrasonic wave method.The temperatures of FG after microwave irradiation and thermal treatment were effectively evaluated using a newly proposed technique.A novelty method for precisely determining the geometric features of fragments is developed to estimate the fragmentation energy.Thus,the dynamic uniaxial compressive strength(UCS),the dynamic fragmentation characteristics,and the fragmentation energy of FG after these two pretreatment methods can be reasonably compared.The noticeable distinction of loading rate effect on the dynamic UCS of FG between these two pretreatment methods is first observed.A relationship is established between the dynamic UCS and the damage induced by microwave irradiation and heat treatment.Moreover,fragmentation energy fan analysis is introduced to accurately compare the fragmentation properties of FG after two pretreatment methods in dynamic compression tests.展开更多
This paper investigates the three-dimensional crack propagation and damage evolution process of metallic column shells under internal explosive loading.The calibration of four typical failure parameters for 40CrMnSiB ...This paper investigates the three-dimensional crack propagation and damage evolution process of metallic column shells under internal explosive loading.The calibration of four typical failure parameters for 40CrMnSiB steel was conducted through experiments and subsequently applied to simulations.The numerical simulation results employing the four failure criteria were compared with the differences and similarities observed in freeze-recovery tests and ultra-high-speed tests.This analysis addressed the critical issue of determining failure criteria for the fracture of a metal shell under internal explosive loads.Building upon this foundation,the damage parameter D_(c),linked to the cumulative crack density,was defined based on the evolution characteristics of a substantial number of cracks.The relationship between the damage parameter and crack velocity over time was established,and the influence of the internal central pressure on the damage parameter and crack velocity was investigated.Variations in the fracture modes were found under different failure criteria,with the principal strain failure criterion proving to be the most effective for simulating 3D crack propagation in a pure shear fracture mode.Through statistical analysis of the shell penetration fracture radius data,it was determined that the fracture radius remained essentially constant during the crack evolution process and could be considered a constant.The propagation velocity of axial cracks ranged between 5300 m/s and 12600 m/s,surpassing the Rayleigh wave velocity of the shell material and decreasing linearly with time.The increase in shell damage exhibited an initial rapid phase,followed by deceleration,demonstrating accelerated damage during the propagation stage of the blast wave and decelerated damage after the arrival of the rarefaction wave.This study provides an effective approach for investigating crack propagation and damage evolution.The derived crack propagation and damage evolution law serves as a valuable reference for the development of crack velocity theory and the construction of shell damage evolution modes.展开更多
For the first time, the isogeometric analysis(IGA) approach is used to model and analyze free and forced vibrations of doubly-curved magneto-electro-elastic(MEE) composite shallow shell resting on the visco-Pasternak ...For the first time, the isogeometric analysis(IGA) approach is used to model and analyze free and forced vibrations of doubly-curved magneto-electro-elastic(MEE) composite shallow shell resting on the visco-Pasternak foundation in a hygro-temperature environment. The doubly-curved MEE shallow shell types include spherical shallow shell, cylindrical shallow shell, saddle shallow shell, and elliptical shallow shell subjected to blast load are investigated. The Maxwell equation and electromagnetic boundary conditions are used to determine the vary of the electric and magnetic potentials. The MEE shallow shell's equations of motion are derived from Hamilton's principle and refined higher-order shear theory. Then, the IGA method is used to derive the laws of natural frequencies and dynamic responses of the shell under various boundary conditions. The accuracy of the model and method is verified through reliable numerical comparisons. Aside from this, the impact of the input parameters on the free and forced vibration of the doubly-curved MEE shallow shell is examined in detail. These results may be useful in the design and manufacture of military structures such as warships, fighter aircraft, drones and missiles.展开更多
To further investigate the forming mechanism and springback characteristics of strips under multi-square punch forming (MSPF) considering partial-unloading effects, a series of concave form ing tests of strips are con...To further investigate the forming mechanism and springback characteristics of strips under multi-square punch forming (MSPF) considering partial-unloading effects, a series of concave form ing tests of strips are conducted on the MSPF machine. This paper aims to reveal the physical mecha nism of the elastic-plastic deformation in the MSPF process considering the effect of the forming ap proaches, and derive appropriate mathematical interpretations. The theoretical model is firstly estab lished to analyse the concave forming mechanism and springback characteristics of the strip, and its accuracy is then validated by experimental data. The forming history and load evolutions are depicted to explore the required forming capacity through the proposed analytical method. Besides, the paramet ric studies are carried out to discuss their effects on the springback of the strip. The results suggest that the deformation paths of the strip are influenced by the forming approach, and the springback of the strip in convex forming is larger than that in concave forming.展开更多
With the increase of underground engineering construction depth,the phenomenon of surrounding rock sudden failure caused by supporting structure failure occurs frequently.The conventional unloading con-fining pressure...With the increase of underground engineering construction depth,the phenomenon of surrounding rock sudden failure caused by supporting structure failure occurs frequently.The conventional unloading con-fining pressure(CUCP)test cannot simulate the plastic yielding and instantaneous unloading process of supporting structure to rock.Thus,a high stress loading-instantaneous unloading confining pressure(HSL-IUCP)test method was proposed and applied by considering bolt’s fracture under stress.The wall thickness of confining pressure plates and the material of bolts were changed to realize different confin-ing pressure loading stiffness(CPLS)and lateral maximum allowable deformation(LMAD).The superio-rity of HSL-ICPU method is verified compared with CUCP.The rock failure mechanism caused by sudden failure of supporting structure is obtained.The results show that when CPLS increases from 1.35 to 2.33 GN/m,rock’s peak strength and elastic modulus increase by 25.18%and 23.70%,respectively.The fracture characteristics change from tensile failure to tensile-shear mixed failure.When LMAD decreases from 0.40 to 0.16 mm,rock’s residual strength,peak strain,and residual strain decrease by 91.80%,16.94%,and 21.92%,respectively,and post-peak drop modulus increases by 140.47%.The test results obtained by this method are closer to rock’s real mechanical response characteristics compared with CUCP.展开更多
Challenges associated with path-following control for commercial displacement vessels under varying loading and draught conditions are addressed in this study.Adaptive control with the adaptation law technique is used...Challenges associated with path-following control for commercial displacement vessels under varying loading and draught conditions are addressed in this study.Adaptive control with the adaptation law technique is used to mitigate the adverse effects of uncertainty and unmodeled parameters on path-following,particularly in the presence of ocean disturbances.The proposed adaptive path-following control estimates the effect of unmodeled parameters and dynamic behavior by the state estimator.Then,the proposed structure adjusts the gains of the L1 controller.The indirect L1 control is used in the main controller,and stability proof is provided based on Lyapunov theory.The adaptive path-following control is proposed for the underactuated-very large crude carrier 2(VLCC2)as a benchmark vessel.Hydrodynamic coefficients for full load and ballast conditions are determined using empirical formulas.Simulations are conducted in these loading conditions,accounting for a twoknot ocean current,two-knot wind,and waves up to sea state 5.Results highlight that the fixed structure,such as the PID controller,fails to deliver satisfactory performance due to significant variations in the vessel’s mass,inertia,and draught.By contrast,the adaptive path-following control demonstrates robustness under varying conditions by effectively estimating the vessel’s unmodeled parameters.展开更多
Ice-breaking methods have become increasingly significant with the ongoing development of the polar regions.Among many ice-breaking methods,ice-breaking that utilizes a moving load is unique compared with the common c...Ice-breaking methods have become increasingly significant with the ongoing development of the polar regions.Among many ice-breaking methods,ice-breaking that utilizes a moving load is unique compared with the common collision or impact methods.A moving load can generate flexural-gravity waves(FGWs),under the influence of which the ice sheet undergoes deformation and may even experience structural damage.Moving loads can be divided into above-ice loads and underwater loads.For the above-ice loads,we discuss the characteristics of the FGWs generated by a moving load acting on a complete ice sheet,an ice sheet with a crack,and an ice sheet with a lead of open water.For underwater loads,we discuss the influence on the ice-breaking characteristics of FGWs of the mode of motion,the geometrical features,and the trajectory of motion of the load.In addition to discussing the status of current research and the technical challenges of ice-breaking by moving loads,this paper also looks ahead to future research prospects and presents some preliminary ideas for consideration.展开更多
Load forecasting is of great significance to the development of new power systems.With the advancement of smart grids,the integration and distribution of distributed renewable energy sources and power electronics devi...Load forecasting is of great significance to the development of new power systems.With the advancement of smart grids,the integration and distribution of distributed renewable energy sources and power electronics devices have made power load data increasingly complex and volatile.This places higher demands on the prediction and analysis of power loads.In order to improve the prediction accuracy of short-term power load,a CNN-BiLSTMTPA short-term power prediction model based on the Improved Whale Optimization Algorithm(IWOA)with mixed strategies was proposed.Firstly,the model combined the Convolutional Neural Network(CNN)with the Bidirectional Long Short-Term Memory Network(BiLSTM)to fully extract the spatio-temporal characteristics of the load data itself.Then,the Temporal Pattern Attention(TPA)mechanism was introduced into the CNN-BiLSTM model to automatically assign corresponding weights to the hidden states of the BiLSTM.This allowed the model to differentiate the importance of load sequences at different time intervals.At the same time,in order to solve the problem of the difficulties of selecting the parameters of the temporal model,and the poor global search ability of the whale algorithm,which is easy to fall into the local optimization,the whale algorithm(IWOA)was optimized by using the hybrid strategy of Tent chaos mapping and Levy flight strategy,so as to better search the parameters of the model.In this experiment,the real load data of a region in Zhejiang was taken as an example to analyze,and the prediction accuracy(R2)of the proposed method reached 98.83%.Compared with the prediction models such as BP,WOA-CNN-BiLSTM,SSA-CNN-BiLSTM,CNN-BiGRU-Attention,etc.,the experimental results showed that the model proposed in this study has a higher prediction accuracy.展开更多
To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based sim...To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based simulation(NNS)method with higher accuracy and better efficiency was proposed.The NNS method consisted of three main steps.First,the parameters of blast loads,including the peak pressures and impulses of cylindrical charges with different aspect ratios(L/D)at different stand-off distances and incident angles were obtained by two-dimensional numerical simulations.Subsequently,incident shape factors of cylindrical charges with arbitrary aspect ratios were predicted by a neural network.Finally,reflected shape factors were derived and implemented into the subroutine of the ABAQUS code to modify the CONWEP model,including modifications of impulse and overpressure.The reliability of the proposed NNS method was verified by related experimental results.Remarkable accuracy improvement was acquired by the proposed NNS method compared with the unmodified CONWEP model.Moreover,huge efficiency superiority was obtained by the proposed NNS method compared with the CEL method.The proposed NNS method showed good accuracy when the scaled distance was greater than 0.2 m/kg^(1/3).It should be noted that there is no need to generate a new dataset again since the blast loads satisfy the similarity law,and the proposed NNS method can be directly used to simulate the blast loads generated by different cylindrical charges.The proposed NNS method with high efficiency and accuracy can be used as an effective method to analyze the dynamic response of structures under blast loads,and it has significant application prospects in designing protective structures.展开更多
The protective bulkhead of the large surface warship need to be designed working in the membrane mode. In this paper, a formula is derived for calculating the plastic deformation of the protective bulkhead subjected t...The protective bulkhead of the large surface warship need to be designed working in the membrane mode. In this paper, a formula is derived for calculating the plastic deformation of the protective bulkhead subjected to blast loading by the energy method, and the ultimate capability of the protective bulkhead can be calculated. The design demand of the protective bulkhead is discussed. The calculation is compared with external experiments, which indicates that the formula is of great application value.展开更多
The damage properties of two types of rocks under dynamic loading are studied. The shock induced experiments are done using planar impact technique on the one? stage light gas gun, and the ultrasonic tests on the da...The damage properties of two types of rocks under dynamic loading are studied. The shock induced experiments are done using planar impact technique on the one? stage light gas gun, and the ultrasonic tests on the damaged rocks have been made by use of the ultrasonic pulse? transmission method. The shock induced damage of rock is related to the shock speed and the attenuation coefficient of sonic wave, and the latter reflects the damage degree in rock fairly well. The attenuation coefficient α can be used as main damage parameter for constructing damage model of rock under dynamic loading.展开更多
An improved understanding of fatigue behavior of a cast aluminum alloy（2-AS5U3G-Y35）in very high cycle regime is developed through the ultrasonic fatigue test in axial and torsion loading.The new developed torsion f...An improved understanding of fatigue behavior of a cast aluminum alloy（2-AS5U3G-Y35）in very high cycle regime is developed through the ultrasonic fatigue test in axial and torsion loading.The new developed torsion fatigue system is presented.The effects of loading condition and frequency on the very high cycle fatigue（VHCF）are investigated.The cyclic loading in axial and torsion at 35 Hz and 20 kHz with stress ratio R=-1 is used respectively to demonstrate the effect of loading condition.S-N curves show that the fatigue failure occurs in the range of 105—1010 cycles in axial or torsion loading and the asymptote of S-N curve is inclined,but no fatigue limit exists under the torsion and axial loading condition.The fatigue fracture surface shows that the fatigue crack initiates from the specimen surface subjected to the cyclic torsion loading.It is different from the fatigue fracture characteristic in axial loading in which fatigue crack initiates from subsurface defect in very high cycle regime.The fatigue initiation is on the maximum shear plane,the overall crack orientation is on a typical spiral 45° to the fracture plane and it is the maximum principle stress plane.The clear shear strip in the torsion fatigue fracture surface shows that the torsion fracture is the shear fracture.展开更多
基金supported by the National Key Research and Development Program of China(Grant No.2022YFB3804500)the National Natural Science Foundation of China(Grant No.52202352,22335006)+4 种基金the Shanghai Municipal Health Commission(Grant No.20224Y0010)the CAMS Innovation Fund for Medical Sciences(Grant No.2021-I2M-5-012)the Basic Research Program of Shanghai Municipal Government(Grant No.21JC1406000)the Fundamental Research Funds for the Central Universities(Grant No.22120230237,2023-3-YB-11,22120220618)the Basic Research Program of Shanghai Municipal Government(23DX1900200).
文摘The current single-atom catalysts(SACs)for medicine still suffer from the limited active site density.Here,we develop a synthetic method capable of increasing both the metal loading and mass-specific activity of SACs by exchanging zinc with iron.The constructed iron SACs(h^(3)-FNC)with a high metal loading of 6.27 wt%and an optimized adjacent Fe distance of~4 A exhibit excellent oxidase-like catalytic performance without significant activity decay after being stored for six months and promising antibacterial effects.Attractively,a“density effect”has been found at a high-enough metal doping amount,at which individual active sites become close enough to interact with each other and alter the electronic structure,resulting in significantly boosted intrinsic activity of single-atomic iron sites in h^(3)-FNCs by 2.3 times compared to low-and medium-loading SACs.Consequently,the overall catalytic activity of h^(3)-FNC is highly improved,with mass activity and metal mass-specific activity that are,respectively,66 and 315 times higher than those of commercial Pt/C.In addition,h^(3)-FNCs demonstrate efficiently enhanced capability in catalyzing oxygen reduction into superoxide anion(O_(2)·^(−))and glutathione(GSH)depletion.Both in vitro and in vivo assays demonstrate the superior antibacterial efficacy of h^(3)-FNCs in promoting wound healing.This work presents an intriguing activity-enhancement effect in catalysts and exhibits impressive therapeutic efficacy in combating bacterial infections.
基金supported by the National Natural Science Foundation of China(Nos.52374078,U24A20616 and 52074043)the Sichuan-Chongqing Science and Technology Innovation Cooperation Program Project(No.2024TIAD-CYKJCXX0011)the Fundamental Research Funds for the Central Universities(No.2023CDJKYJH021)。
文摘Salt cavern energy storage technology contributes to energy reserves and renewable energy scale-up.This study focuses on salt cavern gas storage in Jintan to assess the long-term stability of its surrounding rock under frequent operation.The fatigue test results indicate that stress holding significantly reduces fatigue life,with the magnitude of stress level outweighing the duration of holding time in determining peak strain.Employing a machine learning approach,the impact of various factors on fatigue life and peak strain was quantified,revealing that higher stress limits and stress holding adversely impact the fatigue index,whereas lower stress limits and rate exhibit a positive effect.A novel fatigue-creep composite damage constitutive model is constructed,which is able to consider stress magnitude,rate,and stress holding.The model,validated through multi-path tests,accurately captures the elasto-viscous behavior of salt rock during loading,unloading,and stress holding.Sensitivity analysis further reveals the time-and stress-dependent behavior of model parameters,clarifying that strain changes stem not only from stress variations but are also influenced by alterations in elasto-viscous parameters.This study provides a new method for the mechanical assessment of salt cavern gas storage surrounding rocks.
文摘The attenuation of the acoustic activity in marble specimens under uniaxial compressive loadingunloading loops is quantified in juxtaposition to that of the electric activity.In parallel,the existence of"pre-failure indiceso"warning about entrance into a critical stage,that of impending fracture,is explored.The acoustic activity is quantified in terms of the normalized number of acoustic hits,their average rate of production and their cumulative energy,and,the cumulative counts and their average rate of change.The electric activity is studied in terms of the pressure stimulated currents and the electric charge released.The analysis revealed that the acoustic and electric activities are linearly correlated to each other,suggesting that they are different manifestations of the same damage mechanisms.In addition,Kaiser's effect,governing the acoustic activity,is found to govern,also,the electric activity.Moreover,it is concluded that entrance into the critical stage is safely predicted by means of a simple criterion,based on the evolution of the average rate of change of the normalized cumulative counts in the natural time domain.These predictions are almost identical with those of the criterion based on the "varianceo" and the "entropies" of the time series of acoustic events in this domain.
基金financially supported by National Natural Science Foundation of China(No.52304136)Young Talent of Lifting Engineering for Science and Technology in Shandong,China(No.SDAST2024QTA060)Key Project of Research and Development in Liaocheng(No.2023YD02)。
文摘It is important to analyze the damage evolution process of surrounding rock under different water content for the stability of engineering rock mass.Based on digital speckle correlation(DSCM),acoustic emission(AE)and electromagnetic radiation(EMR),uniaxial hierarchical cyclic loading and unloading tests were carried out on sandstones with different fracture numbers under dry,natural and saturated water content,to explore the fracture propagation,failure precursor characteristics and damage response mechanism under the influence of water content effect.The results show that with the increase of water content,the peak stress and crack initiation stress decrease gradually,and the decreases are 15.28%-21.11%and 17.64%-23.04%,respectively.The peak strain and crack initiation strain increase gradually,and the increases are 19.85%-44.53%and 19.15%-41.94%,respectively.The precracked rock with different water content is mainly characterized by tensile failure at different loading stages.However,with the increase of water content,the proportion of shear cracks gradually increases,while acoustic emission events gradually decrease,the dissipative energy and energy storage limits of the rock under peak load gradually decrease,and the charge signal increases significantly,which is because the lubrication effect of water reduces the friction coefficient between crack surfaces.
基金supported by the National Natural Science Foundation of China(Nos.52204092 and 52274203).
文摘The damage evolution process of non-penetrating cracks often causes some unexpected engineering disasters.Gypsum specimens containing non-penetrating crack(s)are used to study the damage evolution and characteristics under cyclic loading.The results show that under cyclic loading,the relationship between the number of non-penetrating crack(s)and the characteristic parameters(cyclic number,peak stress,peak strain,failure stress,and failure strain)of the pre-cracked specimens can be represented by a decreasing linear function.The damage evolution equation is fitted by calibrating the accumulative plastic strain for each cycle,and the damage constitutive equation is proposed by the concept of effective stress.Additionally,non-penetrating cracks are more likely to cause uneven stress distribution,damage accumulation,and local failure of specimen.The local failure can change the stress distribution and relieve the inhibition of non-penetrating crack extension and eventually cause a dramatic destruction of the specimen.Therefore,the evolution process caused by non-penetrating cracks can be regarded as one of the important reasons for inducing rockburst.These results are expected to improve the understanding of the process of spalling formation and rockburst and can be used to analyze the stability of rocks or rock structures.
文摘A hull structure is prone to local deformation and damage due to the pressure load on the surface.How to simulate surface pressure is an important issue in ship structure test.The loading mode of hydraulic actuator combined with high-pressure flexible bladder was proposed,and the numerical model of the loading device based on flexible bladder was established.The design and analysis method of high-pressure flexible bladder based on aramid-fiber reinforced thermoplastic polyurethane was proposed to break through the surface pressure loading technology of ship structures.The surface pressure loading system based on flexible bladder was developed.The ultimate strength verification test of the box girder under the combined action of bending moment and pressure was carried out to systematically verify the feasibility and applicability of the loading system.The results show that the surface pressure loading technology can be used well for applying uniform pressure to ship structures.Compared with the traditional surface loading methods,the improved device can be applied with horizontal constant pressure load,with rapid response and safe process,and the pressure load is always stable with the increase of the bending moment load during the test.The requirement for uniform loading in the comprehensive strength test of large structural models is satisfied and the accuracy of the test results is improved by this system.
基金supported by the National Natural Science Foundation of China(Grant Nos.12072299,11902276)the Natural Science Foundation of Sichuan Province(Grant No.2022NSFSC1802)+1 种基金the Basic Research Project of Southwest Jiaotong University(Grant No.2682023ZTPY009)the National Key Laboratory for Shock Wave and Detonation Physics of China(Grant No.JCKYS2019212007)。
文摘By combination of the transient Raman spectroscopic measurement and the density functional theoretical calculations,the structural evolution and stability of TATB under shock compression was investigated.Due to the improvement in synchronization control between two-stage light gas gun and the transient Raman spectra acquisition,as well as the sample preparation,the Raman peak of the N-O mode of TATB was firstly observed under shock pressure up to 13.6 GPa,noticeably higher than the upper limit of 8.5 GPa reported in available literatures.By taking into account of the continuous shift of the main peak and other observed Raman peaks,we did not distinguish any structural transition or any new species.Moreover,both the present Raman spectra and the time-resolved radiation of TATB during shock loading showed that TATB exhibits higher chemical stability than previous declaration.To reveal the detailed structural response and evolution of TATB under compression,the density functional theoretical calculations were conducted,and it was found that the pressure make N-O bond lengths shorter,nitro bond angles larger,and intermolecular and intra-molecular hydrogen bond interactions enhanced.The observed red shift of Raman peak was ascribed to the abnormal enhancement of H-bound effect on the scissor vibration mode of the nitro group.
文摘In this study, the influence of opening parameters on the ultimate strength of perforated plates subjected to extreme cyclic loading in the presence of material kinematic hardening and isotro pic hardening was analyzed. It is found that the ultimate strength of the perforated plates decreases rapidly and stabilizes in the first four cycles. Plates with oblong openings have a greater ultimate strength compared to plates with rectangular openings, while the relative strengthening ratio decreases over the duration of the cycle. The location of the openings is also an important parameter that affects the strength of the structure, as the plates with openings close to the edges in the longitudinal direction have higher strengths, while in the transverse direction the strengths are higher when the openings are close to the center. Among the three opening-strengthening methods compared, the Carling stiffener method maintains a better strengthening effect under cyclic loads for many periods.
基金supported by the National Natural Science Foundation of China(Nos.51879184 and 12172253).
文摘Understanding the effects of microwave irradiation and thermal treatment on the dynamic compression and fragmentation properties of rocks is essential to quantify energy consumption in rock engineering.In this study,Fangshan granite(FG)specimens were exposed to microwave irradiation and heat treatment.The damage of FG specimens induced by these two methods was compared using X-ray CT scanning and ultrasonic wave method.The temperatures of FG after microwave irradiation and thermal treatment were effectively evaluated using a newly proposed technique.A novelty method for precisely determining the geometric features of fragments is developed to estimate the fragmentation energy.Thus,the dynamic uniaxial compressive strength(UCS),the dynamic fragmentation characteristics,and the fragmentation energy of FG after these two pretreatment methods can be reasonably compared.The noticeable distinction of loading rate effect on the dynamic UCS of FG between these two pretreatment methods is first observed.A relationship is established between the dynamic UCS and the damage induced by microwave irradiation and heat treatment.Moreover,fragmentation energy fan analysis is introduced to accurately compare the fragmentation properties of FG after two pretreatment methods in dynamic compression tests.
基金supported by the National Natural Science Foundation of China (Grant No.12302437)Natural Science Foundation of Jiangsu Province (BK20230939)China Postdoctoral Science Foundation (2021M701710)。
文摘This paper investigates the three-dimensional crack propagation and damage evolution process of metallic column shells under internal explosive loading.The calibration of four typical failure parameters for 40CrMnSiB steel was conducted through experiments and subsequently applied to simulations.The numerical simulation results employing the four failure criteria were compared with the differences and similarities observed in freeze-recovery tests and ultra-high-speed tests.This analysis addressed the critical issue of determining failure criteria for the fracture of a metal shell under internal explosive loads.Building upon this foundation,the damage parameter D_(c),linked to the cumulative crack density,was defined based on the evolution characteristics of a substantial number of cracks.The relationship between the damage parameter and crack velocity over time was established,and the influence of the internal central pressure on the damage parameter and crack velocity was investigated.Variations in the fracture modes were found under different failure criteria,with the principal strain failure criterion proving to be the most effective for simulating 3D crack propagation in a pure shear fracture mode.Through statistical analysis of the shell penetration fracture radius data,it was determined that the fracture radius remained essentially constant during the crack evolution process and could be considered a constant.The propagation velocity of axial cracks ranged between 5300 m/s and 12600 m/s,surpassing the Rayleigh wave velocity of the shell material and decreasing linearly with time.The increase in shell damage exhibited an initial rapid phase,followed by deceleration,demonstrating accelerated damage during the propagation stage of the blast wave and decelerated damage after the arrival of the rarefaction wave.This study provides an effective approach for investigating crack propagation and damage evolution.The derived crack propagation and damage evolution law serves as a valuable reference for the development of crack velocity theory and the construction of shell damage evolution modes.
文摘For the first time, the isogeometric analysis(IGA) approach is used to model and analyze free and forced vibrations of doubly-curved magneto-electro-elastic(MEE) composite shallow shell resting on the visco-Pasternak foundation in a hygro-temperature environment. The doubly-curved MEE shallow shell types include spherical shallow shell, cylindrical shallow shell, saddle shallow shell, and elliptical shallow shell subjected to blast load are investigated. The Maxwell equation and electromagnetic boundary conditions are used to determine the vary of the electric and magnetic potentials. The MEE shallow shell's equations of motion are derived from Hamilton's principle and refined higher-order shear theory. Then, the IGA method is used to derive the laws of natural frequencies and dynamic responses of the shell under various boundary conditions. The accuracy of the model and method is verified through reliable numerical comparisons. Aside from this, the impact of the input parameters on the free and forced vibration of the doubly-curved MEE shallow shell is examined in detail. These results may be useful in the design and manufacture of military structures such as warships, fighter aircraft, drones and missiles.
文摘To further investigate the forming mechanism and springback characteristics of strips under multi-square punch forming (MSPF) considering partial-unloading effects, a series of concave form ing tests of strips are conducted on the MSPF machine. This paper aims to reveal the physical mecha nism of the elastic-plastic deformation in the MSPF process considering the effect of the forming ap proaches, and derive appropriate mathematical interpretations. The theoretical model is firstly estab lished to analyse the concave forming mechanism and springback characteristics of the strip, and its accuracy is then validated by experimental data. The forming history and load evolutions are depicted to explore the required forming capacity through the proposed analytical method. Besides, the paramet ric studies are carried out to discuss their effects on the springback of the strip. The results suggest that the deformation paths of the strip are influenced by the forming approach, and the springback of the strip in convex forming is larger than that in concave forming.
基金the National Natural Science Foundation of China(Nos.52374218,52174122 and 52374094)Outstanding Youth Fund of Shandong Natural Science Foundation(No.ZR2022YQ49)Taishan Scholar Project in Shandong Province(Nos.tspd20210313 and tsqn202211150).
文摘With the increase of underground engineering construction depth,the phenomenon of surrounding rock sudden failure caused by supporting structure failure occurs frequently.The conventional unloading con-fining pressure(CUCP)test cannot simulate the plastic yielding and instantaneous unloading process of supporting structure to rock.Thus,a high stress loading-instantaneous unloading confining pressure(HSL-IUCP)test method was proposed and applied by considering bolt’s fracture under stress.The wall thickness of confining pressure plates and the material of bolts were changed to realize different confin-ing pressure loading stiffness(CPLS)and lateral maximum allowable deformation(LMAD).The superio-rity of HSL-ICPU method is verified compared with CUCP.The rock failure mechanism caused by sudden failure of supporting structure is obtained.The results show that when CPLS increases from 1.35 to 2.33 GN/m,rock’s peak strength and elastic modulus increase by 25.18%and 23.70%,respectively.The fracture characteristics change from tensile failure to tensile-shear mixed failure.When LMAD decreases from 0.40 to 0.16 mm,rock’s residual strength,peak strain,and residual strain decrease by 91.80%,16.94%,and 21.92%,respectively,and post-peak drop modulus increases by 140.47%.The test results obtained by this method are closer to rock’s real mechanical response characteristics compared with CUCP.
文摘Challenges associated with path-following control for commercial displacement vessels under varying loading and draught conditions are addressed in this study.Adaptive control with the adaptation law technique is used to mitigate the adverse effects of uncertainty and unmodeled parameters on path-following,particularly in the presence of ocean disturbances.The proposed adaptive path-following control estimates the effect of unmodeled parameters and dynamic behavior by the state estimator.Then,the proposed structure adjusts the gains of the L1 controller.The indirect L1 control is used in the main controller,and stability proof is provided based on Lyapunov theory.The adaptive path-following control is proposed for the underactuated-very large crude carrier 2(VLCC2)as a benchmark vessel.Hydrodynamic coefficients for full load and ballast conditions are determined using empirical formulas.Simulations are conducted in these loading conditions,accounting for a twoknot ocean current,two-knot wind,and waves up to sea state 5.Results highlight that the fixed structure,such as the PID controller,fails to deliver satisfactory performance due to significant variations in the vessel’s mass,inertia,and draught.By contrast,the adaptive path-following control demonstrates robustness under varying conditions by effectively estimating the vessel’s unmodeled parameters.
基金Supported by the National Natural Science Foundation of China(Nos.52192693,52192690,52371270,U20A20327)the National Key Research and Development Program of China(Nos.2021YFC2803400).
文摘Ice-breaking methods have become increasingly significant with the ongoing development of the polar regions.Among many ice-breaking methods,ice-breaking that utilizes a moving load is unique compared with the common collision or impact methods.A moving load can generate flexural-gravity waves(FGWs),under the influence of which the ice sheet undergoes deformation and may even experience structural damage.Moving loads can be divided into above-ice loads and underwater loads.For the above-ice loads,we discuss the characteristics of the FGWs generated by a moving load acting on a complete ice sheet,an ice sheet with a crack,and an ice sheet with a lead of open water.For underwater loads,we discuss the influence on the ice-breaking characteristics of FGWs of the mode of motion,the geometrical features,and the trajectory of motion of the load.In addition to discussing the status of current research and the technical challenges of ice-breaking by moving loads,this paper also looks ahead to future research prospects and presents some preliminary ideas for consideration.
文摘Load forecasting is of great significance to the development of new power systems.With the advancement of smart grids,the integration and distribution of distributed renewable energy sources and power electronics devices have made power load data increasingly complex and volatile.This places higher demands on the prediction and analysis of power loads.In order to improve the prediction accuracy of short-term power load,a CNN-BiLSTMTPA short-term power prediction model based on the Improved Whale Optimization Algorithm(IWOA)with mixed strategies was proposed.Firstly,the model combined the Convolutional Neural Network(CNN)with the Bidirectional Long Short-Term Memory Network(BiLSTM)to fully extract the spatio-temporal characteristics of the load data itself.Then,the Temporal Pattern Attention(TPA)mechanism was introduced into the CNN-BiLSTM model to automatically assign corresponding weights to the hidden states of the BiLSTM.This allowed the model to differentiate the importance of load sequences at different time intervals.At the same time,in order to solve the problem of the difficulties of selecting the parameters of the temporal model,and the poor global search ability of the whale algorithm,which is easy to fall into the local optimization,the whale algorithm(IWOA)was optimized by using the hybrid strategy of Tent chaos mapping and Levy flight strategy,so as to better search the parameters of the model.In this experiment,the real load data of a region in Zhejiang was taken as an example to analyze,and the prediction accuracy(R2)of the proposed method reached 98.83%.Compared with the prediction models such as BP,WOA-CNN-BiLSTM,SSA-CNN-BiLSTM,CNN-BiGRU-Attention,etc.,the experimental results showed that the model proposed in this study has a higher prediction accuracy.
基金financially supported by the National Natural Science Foundation of China(Grant Nos.52271317 and 52071149)the Fundamental Research Funds for the Central Universities(HUST:2019kfy XJJS007)。
文摘To address the problems of low accuracy by the CONWEP model and poor efficiency by the Coupled Eulerian-Lagrangian(CEL)method in predicting close-range air blast loads of cylindrical charges,a neural network-based simulation(NNS)method with higher accuracy and better efficiency was proposed.The NNS method consisted of three main steps.First,the parameters of blast loads,including the peak pressures and impulses of cylindrical charges with different aspect ratios(L/D)at different stand-off distances and incident angles were obtained by two-dimensional numerical simulations.Subsequently,incident shape factors of cylindrical charges with arbitrary aspect ratios were predicted by a neural network.Finally,reflected shape factors were derived and implemented into the subroutine of the ABAQUS code to modify the CONWEP model,including modifications of impulse and overpressure.The reliability of the proposed NNS method was verified by related experimental results.Remarkable accuracy improvement was acquired by the proposed NNS method compared with the unmodified CONWEP model.Moreover,huge efficiency superiority was obtained by the proposed NNS method compared with the CEL method.The proposed NNS method showed good accuracy when the scaled distance was greater than 0.2 m/kg^(1/3).It should be noted that there is no need to generate a new dataset again since the blast loads satisfy the similarity law,and the proposed NNS method can be directly used to simulate the blast loads generated by different cylindrical charges.The proposed NNS method with high efficiency and accuracy can be used as an effective method to analyze the dynamic response of structures under blast loads,and it has significant application prospects in designing protective structures.
文摘The protective bulkhead of the large surface warship need to be designed working in the membrane mode. In this paper, a formula is derived for calculating the plastic deformation of the protective bulkhead subjected to blast loading by the energy method, and the ultimate capability of the protective bulkhead can be calculated. The design demand of the protective bulkhead is discussed. The calculation is compared with external experiments, which indicates that the formula is of great application value.
文摘The damage properties of two types of rocks under dynamic loading are studied. The shock induced experiments are done using planar impact technique on the one? stage light gas gun, and the ultrasonic tests on the damaged rocks have been made by use of the ultrasonic pulse? transmission method. The shock induced damage of rock is related to the shock speed and the attenuation coefficient of sonic wave, and the latter reflects the damage degree in rock fairly well. The attenuation coefficient α can be used as main damage parameter for constructing damage model of rock under dynamic loading.
基金Supported by the National Natural Science Foundation of China(50775182)the Scientific Research Foundation for the Returned Scholars of the Ministry of Education of China~~
文摘An improved understanding of fatigue behavior of a cast aluminum alloy（2-AS5U3G-Y35）in very high cycle regime is developed through the ultrasonic fatigue test in axial and torsion loading.The new developed torsion fatigue system is presented.The effects of loading condition and frequency on the very high cycle fatigue（VHCF）are investigated.The cyclic loading in axial and torsion at 35 Hz and 20 kHz with stress ratio R=-1 is used respectively to demonstrate the effect of loading condition.S-N curves show that the fatigue failure occurs in the range of 105—1010 cycles in axial or torsion loading and the asymptote of S-N curve is inclined,but no fatigue limit exists under the torsion and axial loading condition.The fatigue fracture surface shows that the fatigue crack initiates from the specimen surface subjected to the cyclic torsion loading.It is different from the fatigue fracture characteristic in axial loading in which fatigue crack initiates from subsurface defect in very high cycle regime.The fatigue initiation is on the maximum shear plane,the overall crack orientation is on a typical spiral 45° to the fracture plane and it is the maximum principle stress plane.The clear shear strip in the torsion fatigue fracture surface shows that the torsion fracture is the shear fracture.
