WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content o...WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.展开更多
In this study, two thermal barrier coatings based on YSZ were produced by using a commercially available agglomerated and sintered powder and a special spray powder prepared by high energy ball milling. Both thermal b...In this study, two thermal barrier coatings based on YSZ were produced by using a commercially available agglomerated and sintered powder and a special spray powder prepared by high energy ball milling. Both thermal barrier coatings exhibited similar overall porosities, but significantly different microstructures. Application of the special spray powder prepared by high energy ball milling led to a microstructure with numerous inclusions of semi-molten agglomerates, which introduced a plethora of clusters of fine pores into the coating and several more microstructural defects. This microstructure resulted in a significantly better thermal shock behavior compared to the conventional thermal barrier coating. The heat treatment of both thermal barrier coatings atθ=1150℃for t=100 h led to a sintering of both coatings. The results were reduced overall porosity and significantly increased fracture toughness. A correlation between the fracture toughness of both coatings after the heat treatment and the thermal shock life time could not be identified.展开更多
基金Project(2021YFC2801904)supported by the National Key R&D Program of ChinaProject(KY10100230067)supported by the Basic Product Innovation Research Project,China+3 种基金Projects(52271130,52305344)supported by the National Natural Science Foundation of ChinaProjects(ZR2020ME017,ZR2020QE186)supported by the Natural Science Foundation of Shandong Province,ChinaProjects(AMGM2024F11,AMGM2021F10,AMGM2023F06)supported by the Science Fund of Shandong Laboratory of Advanced Materials and Green Manufacturing at Yantai,ChinaProject(KY90200210015)supported by Leading Scientific Research Project of China National Nuclear Corporation(CNNC),China。
文摘WC particles reinforced CoCrFeNiMo high-entropy alloy(HEA)composite coatings were prepared on Cr12MoV steel successfully by laser cladding technology to improve the wear resistance of substrates.Effect of WC content on microstructure and wear property of the composite coatings was studied in detail.Large numbers of carbides with four main types:primary carbide crystals,eutectic structures,massive crystals growing along the periphery of the remaining WC particles and incompletely fused WC particles,were found to exist in the WC/CoCrFeNiMo composite coatings.With increasing WC content,the microhardness of coatings is gradually improved while the average friction coefficients follow the opposite trend due to solid solution strengthening and second phase strengthening effect.The maximum microhardness and minimum friction coefficient are HV_(0.2)689.7 and 0.72,respectively,for the composite coating with 30 wt.%WC,the wear resistance of the substrate is improved significantly,the wear mechanisms are spalling wear and abrasive wear due to their high microhardness.
基金the German Science Foundation (DFG) for financially supporting the research work within the scope of the DFG projects ZH205/2-1 and BO1979/32-2
文摘In this study, two thermal barrier coatings based on YSZ were produced by using a commercially available agglomerated and sintered powder and a special spray powder prepared by high energy ball milling. Both thermal barrier coatings exhibited similar overall porosities, but significantly different microstructures. Application of the special spray powder prepared by high energy ball milling led to a microstructure with numerous inclusions of semi-molten agglomerates, which introduced a plethora of clusters of fine pores into the coating and several more microstructural defects. This microstructure resulted in a significantly better thermal shock behavior compared to the conventional thermal barrier coating. The heat treatment of both thermal barrier coatings atθ=1150℃for t=100 h led to a sintering of both coatings. The results were reduced overall porosity and significantly increased fracture toughness. A correlation between the fracture toughness of both coatings after the heat treatment and the thermal shock life time could not be identified.
