Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance fo...Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.展开更多
Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accident...Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accidents during its storage and usage in ammunition.In this work,two kinds of insensitive step ladderstructured nitrocellulose(LNC)with different nitrogen contents were synthesized.The products were characterized by FT-IR,Raman,XRD,SEM,elemental analysis,TGA,DSC,accelerating rate calorimeter analysis(ARC),and drop weight test to study their molecular structure,thermal characteristics and desensitization performance.Compared with raw nitrocellulose,LNC has a sharper exothermic peak in the DSC and ARC curves.The H50values of the two kinds of LNC increased from 25.76 to 30.01 cm for low nitrogen content and from 18.02 to 21.84 cm for high nitrogen content,respectively.The results show that the ladder-structure of LNC which provides regular molecular arrangement and a soft buffer made with polyethylene glycol could affect the energy releasing process of LNC and reduce the sensitivity of LNC.Insensitive LNC provides an alternative to be used as a binder in insensitive propellants formulation.展开更多
In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal agin...In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.展开更多
An innovative flat heat pipe radiator was put forward, and it has the features of high efficiency of heat dissipation, compact construction, low thermal resistance, light weight, low cost, and anti-dust-deposition. Th...An innovative flat heat pipe radiator was put forward, and it has the features of high efficiency of heat dissipation, compact construction, low thermal resistance, light weight, low cost, and anti-dust-deposition. The thermal analysis of the flat heat pipe radiator for cooling high-power light emitting diode （LED） array was conducted. The thermal characteristics of the flat heat pipe radiator under the different heat loads and incline angles were investigated experimentally in natural convection. An electro-thermal conversion method was used to measure the junction temperature of the LED chips. It is found that the integral temperature distribution of the flat heat pipe radiator is reasonable and uniform. The total thermal resistance of the flat heat pipe radiator varies in the range of 0.38-0.45 K/W. The junction temperatures of LED chips with the flat heat pipe radiator and with the aluminum board at the same forward current of 0.35 A are 52.5 and 75.2 ℃, respectively.展开更多
The stability of cemented backfill mass is important to keep miners and equipment safe in underground backfill miming.The stress-strain behavior, resistivity and thermal infrared(TIR) characteristics of backfill mass ...The stability of cemented backfill mass is important to keep miners and equipment safe in underground backfill miming.The stress-strain behavior, resistivity and thermal infrared(TIR) characteristics of backfill mass under uniaxial compression were investigated. The monitoring system consisted of a TIR observation system, a stress-strain monitoring system and a resistivity measurement system. Precursory information for impending failure of cemented backfill mass was collected, including TIR, strain and resistivity precursors. The sensitivity and difference of different monitoring information to the same failure event were compared.The results show that the time-space evolution process of the resistivity and TIR is basically the same as the whole process from compression deformation to failure of backfill mass, and the time variation of resistivity and TIR is obviously characterized by stage.The resistivity precursor turns out earlier than the TIR and the strain. The resistivity relation with loading compression is anti-symmetry, decreasing as the compression stress increases before the peak strength of backfill mass. However, when the backfill mass enters into the phase of failure, the resistivity starts to increase as the stress increases. The change of the resistivity growth direction can be regarded as the resistivity-caution-point for the failure of backfill mass under uniaxial compression. It is also indicated that the TIR information mainly represents the surface temperature evolution in the process of compression before the backfill enters into the plastic-yield state. It can be a valuable tool to obtain the precursors for failure of cemented backfill mass for backfill mines.展开更多
基金Project(51825802)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProject(2018YFE0106100)supported by the National Key R&D Program of China。
文摘Passive house has been constructed in China on a large-scale over the past couple years for its great energy saving potential.However,research indicates that there is a significant discrepancy in energy performance for heating and cooling between passive houses in different climate zones.Therefore,this research develops a comparative analysis on the energy saving potential of passive houses with the conventional around China.A sensitivity analysis of thermal characteristics of building envelope(insulation of exterior walls and windows,and airtightness)on energy consumption is further carried out to improve the climate adaptability of passive house.Moreover,the variation of energy consumption under different heat gain intensity is also compared,to evaluate the effects of envelope thermal characteristics comprehensively.Results suggest that the decrease of exterior wall insulation leads to the greatest increase in energy consumption,especially in severe cold zone in China.However,the optimal insulation may change with the internal heat gain intensity,for instance,the decrease of insulation(from 0.4 to 1.0 W/(m^(2)·K))could reduce the energy consumption by 4.65 kW·h/(m^(2)·a)when the heat gain increases to 20 W/m^(2)for buildings in Hot Summer and Cold Winter zone in China.
基金supported in part by the National Natural Science Foundation of China(No.22075146)。
文摘Nitrocellulose,or cellulose nitrate,has received considerable interest due to its various applications,such as propellants,coating agents and gas generators.However,its high mechanical sensitivity caused many accidents during its storage and usage in ammunition.In this work,two kinds of insensitive step ladderstructured nitrocellulose(LNC)with different nitrogen contents were synthesized.The products were characterized by FT-IR,Raman,XRD,SEM,elemental analysis,TGA,DSC,accelerating rate calorimeter analysis(ARC),and drop weight test to study their molecular structure,thermal characteristics and desensitization performance.Compared with raw nitrocellulose,LNC has a sharper exothermic peak in the DSC and ARC curves.The H50values of the two kinds of LNC increased from 25.76 to 30.01 cm for low nitrogen content and from 18.02 to 21.84 cm for high nitrogen content,respectively.The results show that the ladder-structure of LNC which provides regular molecular arrangement and a soft buffer made with polyethylene glycol could affect the energy releasing process of LNC and reduce the sensitivity of LNC.Insensitive LNC provides an alternative to be used as a binder in insensitive propellants formulation.
基金supported by the National Key Laboratory of Energetic Materials, China (Grant No. 2023-LB-036-09).
文摘In order to analyze the influences of storage aging on the safety of typical elemental explosives,the aged cyclotrimethylene trinitramine(RDX)and cyclotetramethylene tetranitramine(HMX)were prepared by isothermal aging tests.The reaction thresholds of aged RDX and HMX under any ignition probability were studied by Langlie-Optimal D method.The thermal decomposition characteristics of RDX and HMX after aging were analyzed by DSC and ARC.Experimental results showed that compared with unaged RDX and HMX,on the one hand,the critical impact energy and critical friction of RDX and HMX aged for 14,28,and 56 days are significantly reduced at an explosion probability of 50%,0.01%,and 0.0001%,respectively.With the increase of aging time,the mechanical sensitivity of RDX and HMX increases obviously.On the other hand,the initial decomposition temperature of RDX and HMX after 56 days of aging decreases,the decomposition heat decreases,the activation energy increases,and the reaction difficulty increases.
基金Project(50876016) support by the National Natural Science Foundation of China
文摘An innovative flat heat pipe radiator was put forward, and it has the features of high efficiency of heat dissipation, compact construction, low thermal resistance, light weight, low cost, and anti-dust-deposition. The thermal analysis of the flat heat pipe radiator for cooling high-power light emitting diode （LED） array was conducted. The thermal characteristics of the flat heat pipe radiator under the different heat loads and incline angles were investigated experimentally in natural convection. An electro-thermal conversion method was used to measure the junction temperature of the LED chips. It is found that the integral temperature distribution of the flat heat pipe radiator is reasonable and uniform. The total thermal resistance of the flat heat pipe radiator varies in the range of 0.38-0.45 K/W. The junction temperatures of LED chips with the flat heat pipe radiator and with the aluminum board at the same forward current of 0.35 A are 52.5 and 75.2 ℃, respectively.
基金Projects(51504256,51004109)supported by the National Natural Science Foundation of ChinaProject(zdsys006)supported by State Key Laboratory of Safety and Health for Metal Mines,ChinaProject(2013BAB02B04)supported by the National Science and Technology Support Plan,China
文摘The stability of cemented backfill mass is important to keep miners and equipment safe in underground backfill miming.The stress-strain behavior, resistivity and thermal infrared(TIR) characteristics of backfill mass under uniaxial compression were investigated. The monitoring system consisted of a TIR observation system, a stress-strain monitoring system and a resistivity measurement system. Precursory information for impending failure of cemented backfill mass was collected, including TIR, strain and resistivity precursors. The sensitivity and difference of different monitoring information to the same failure event were compared.The results show that the time-space evolution process of the resistivity and TIR is basically the same as the whole process from compression deformation to failure of backfill mass, and the time variation of resistivity and TIR is obviously characterized by stage.The resistivity precursor turns out earlier than the TIR and the strain. The resistivity relation with loading compression is anti-symmetry, decreasing as the compression stress increases before the peak strength of backfill mass. However, when the backfill mass enters into the phase of failure, the resistivity starts to increase as the stress increases. The change of the resistivity growth direction can be regarded as the resistivity-caution-point for the failure of backfill mass under uniaxial compression. It is also indicated that the TIR information mainly represents the surface temperature evolution in the process of compression before the backfill enters into the plastic-yield state. It can be a valuable tool to obtain the precursors for failure of cemented backfill mass for backfill mines.
