Understanding the adsorption behavior of heavy metals and metalloids on clay minerals is essential for remediating heavy metal-contaminated soils.The adsorption of heavy metals and metalloids on illite(001)and sodium ...Understanding the adsorption behavior of heavy metals and metalloids on clay minerals is essential for remediating heavy metal-contaminated soils.The adsorption of heavy metals and metalloids on illite(001)and sodium montmorillonite(Na-MMT)(001)surfaces was investigated using first-principles calculations in this study,especially As atom and H_(3)AsO_(3) molecule.The adsorption energies of the As atom were−1.94 eV on the illite(001)and−0.56 eV on the Na-MMT(001),whereas,the adsorption energies of the H_(3)AsO_(3) molecule were−1.40 eV on illite(001)and−1.01 eV on Na-MMT(001).The above results indicate that the adsorption was more energetically favorable on illite(001).Additionally,compared to Na-MMT(001),there were more significant interactions between the atoms/molecules on the illite(001).After As atom and H_(3)AsO_(3) molecule adsorption,the electrons were transferred from mineral surface atoms to the adsorbates on both illite(001)and Na-MMT(001)surfaces.Moreover,the adsorption of As atom on illite(001)and Na-MMT(001)surfaces were more energy favorable compared to Hg,Cd,and Cr atoms.Overall,this work provides new insights into the adsorption behavior of As atoms and As molecules on illite and Na-MMT.The results indicate that illite rich soils are more prone to contamination by arsenic compared to soils primarily composed of Na-MMT minerals.展开更多
This study investigates the application of Gurney and flight of fragment equations,typically used to predict metal fragment velocities,in modeling the water jet behavior.Three shotgun cartridge sizes were used as the ...This study investigates the application of Gurney and flight of fragment equations,typically used to predict metal fragment velocities,in modeling the water jet behavior.Three shotgun cartridge sizes were used as the energy source:2.59 g,5.83 g,and 7.13 g.Two configurations were tested:standard(full-barrel water load)and"negative 8"(partial water load).High-speed footage captured water column velocities,and Gurney models,including infinitely tamped and open-faced configurations,combined with the flight of fragment model were used to assess prediction accuracy.Results showed charge strength significantly affects water column velocity,with higher strengths yielding greater stability and velocity retention over distance.The infinitely tamped Gurney model closely predicted experimental velocities,deviating by as little as 1.4%for standard charges and 2.8% for negative 8 charges.Additionally,interesting dynamics such as a 1-2°rise in jet height and the rear overtaking the front was observed.These findings have significant implications for optimizing PAN disruptors and enhancing performance in high-velocity fluid applications and explosive breaching systems.展开更多
To enhance the resolution of parameter estimation with limited samples received by a short passive array, an iterative nonparametric algorithm for estimating the frequencies and direction-of-arrivals （DOAs） of signa...To enhance the resolution of parameter estimation with limited samples received by a short passive array, an iterative nonparametric algorithm for estimating the frequencies and direction-of-arrivals （DOAs） of signals is proposed. The cost function is constructed using 12-norm Gaussian entropy combined with an additional constraint, 12-norm constraint or linear constraint. By minimizing the cost functions in the temporal and the spatial dimensions using corresponding iteration algorithms respectively, the sparse discrete Fourier transforms （DFTs） of temporal and spatial samples are obtained to represent the extrapolated sequences with much larger sizes than the original samples. Then frequency and angle estimates are obtained by performing the traditional simple methods on the extrapolated sequences. It is shown that the proposed algorithm offers increased resolution and significantly reduced sidelobes compared with the periodogram and beamforming based methods. And it achieves high precision compared with the high-resolution method with lower computational burden. Some numerical simulations and real data processing results are presented to verify the effectiveness of the method.展开更多
Temporal-spatial cross-correlation analysis of non-stationary wind speed time series plays a crucial role in wind field reconstruction as well as in wind pattern recognition.Firstly,the near-surface wind speed time se...Temporal-spatial cross-correlation analysis of non-stationary wind speed time series plays a crucial role in wind field reconstruction as well as in wind pattern recognition.Firstly,the near-surface wind speed time series recorded at different locations are studied using the detrended fluctuation analysis(DFA),and the corresponding scaling exponents are larger than 1.This indicates that all these wind speed time series have non-stationary characteristics.Secondly,concerning this special feature( i.e.,non-stationarity)of wind signals,a cross-correlation analysis method,namely detrended cross-correlation analysis(DCCA) coefficient,is employed to evaluate the temporal-spatial cross-correlations between non-stationary time series of different anemometer pairs.Finally,experiments on ten wind speed data synchronously collected by the ten anemometers with equidistant arrangement illustrate that the method of DCCA cross-correlation coefficient can accurately analyze full-scale temporal-spatial cross-correlation between non-stationary time series and also can easily identify the seasonal component,while three traditional cross-correlation techniques(i.e.,Pearson coefficient,cross-correlation function,and DCCA method) cannot give us these information directly.展开更多
为改善传统N-Calculator模型的局限性,加强食物氮足迹核算结果与环境影响的联系,提高活性氮管理预见性,将N-Calculator模型与食物系统养分流动(Nutrient Flows in Food Chains,Environment and Resources Use,NUFER)模型进行耦合,以估...为改善传统N-Calculator模型的局限性,加强食物氮足迹核算结果与环境影响的联系,提高活性氮管理预见性,将N-Calculator模型与食物系统养分流动(Nutrient Flows in Food Chains,Environment and Resources Use,NUFER)模型进行耦合,以估算我国2001—2020年人均食物氮足迹,建立组合预测体系。结果显示:2001—2020年,我国人均食物氮足迹由16.04 kg N/a增至18.95 kg N/a;全国食物氮足迹由20.47 Mt N/a增至26.76 Mt N/a;居民饮食结构正由以植物源食物为主的低氮消费模式转向以动物源食物为主的高氮消费模式;食物生产过程产生的活性氮的最终归宿为大气(64.3%)、水体和深层土壤(35.7%);我国食物氮足迹与人均可支配收入、城市化率、动物源食物消费氮占比呈正相关性,与恩格尔系数呈负相关性;未来10 a我国人均食物氮足迹呈增长趋势,预测结果显示年均增幅为0.16 kg N/a。展开更多
In order to improve the infrared detection and discrimination ability of the smart munition to the dynamic armor target under the complex background,the multi-line array infrared detection system is established based ...In order to improve the infrared detection and discrimination ability of the smart munition to the dynamic armor target under the complex background,the multi-line array infrared detection system is established based on the combination of the single unit infrared detector.The surface dimension features of ground armored targets are identified by size calculating solution algorithm.The signal response value and the value of size calculating are identified by the method of fuzzy recognition to make the fuzzy classification judgment for armored target.According to the characteristics of the target signal,a custom threshold de-noising function is proposed to solve the problem of signal preprocessing.The multi-line array infrared detection can complete the scanning detection in a large area in a short time with the characteristics of smart munition in the steady-state scanning stage.The method solves the disadvantages of wide scanning interval and low detection probability of single unit infrared detection.By reducing the scanning interval,the number of random rendezvous in the infrared feature area of the upper surface is increased,the accuracy of the size calculating is guaranteed.The experiments results show that in the fuzzy recognition method,the size calculating is introduced as the feature operator,which can improve the recognition ability of the ground armor target with different shape size.展开更多
The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ...The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ient of offsprings can be calculated by those of parents. The deducing process of numerator relationship is simple and clear comparing with path analysis. An example shows the usage of these formulas.展开更多
The blockage effectiveness problem for the runway cut-blanked modes of intelligence missile is described using probability integral method,when entry angle error and open cabin position error exist. On the condition o...The blockage effectiveness problem for the runway cut-blanked modes of intelligence missile is described using probability integral method,when entry angle error and open cabin position error exist. On the condition of determined open cabin position error,the allowable range of entry angle error is inversely calculated with interdiction probability. The calculated results indicate that the method mentioned can estimate the intelligence missile interdiction efficiency to the runway and the range of entry angle error,which provides available basis for analyzing the intelligence missile attack assignment on the way.展开更多
In order to describe the characteristics of dynamic traffic flow and improve the robustness of its multiple applications, a dynamic traffic temporal-spatial model(DTTS) is established. With consideration of the tempor...In order to describe the characteristics of dynamic traffic flow and improve the robustness of its multiple applications, a dynamic traffic temporal-spatial model(DTTS) is established. With consideration of the temporal correlation, spatial correlation and historical correlation, a basic DTTS model is built. And a three-stage approach is put forward for the simplification and calibration of the basic DTTS model. Through critical sections pre-selection and critical time pre-selection, the first stage reduces the variable number of the basic DTTS model. In the second stage, variable coefficient calibration is implemented based on basic model simplification and stepwise regression analysis. Aimed at dynamic noise estimation, the characteristics of noise are summarized and an extreme learning machine is presented in the third stage. A case study based on a real-world road network in Beijing, China, is carried out to test the efficiency and applicability of proposed DTTS model and the three-stage approach.展开更多
Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmeth...Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmethyl)butane(bib)by a hydrothermal method,respectively.X⁃ray crystallography reveals a 2D network constructed by six⁃coordinated Ni(Ⅱ)centers,bib,and Hpdc2-ligands in complex 1,while a 2D network is built by Ni(Ⅱ)and bib ligands in 2.Furthermore,the quantum⁃chemical calculations have been performed on‘molecular fragments’extracted from the crystal structure of 1 using the PBE0/LANL2DZ method in Gaussian 16 and the VASP program.CCDC:2343794,1;2343798,2.展开更多
The calculation model for the relaxation loss of concrete mentioned in the Code for Design of Highway Reinforced Concrete and Prestressed Concrete Bridges and Culverts(JTG D62—2004) was modified according to experime...The calculation model for the relaxation loss of concrete mentioned in the Code for Design of Highway Reinforced Concrete and Prestressed Concrete Bridges and Culverts(JTG D62—2004) was modified according to experimental data. Time-varying relaxation loss was considered in the new model. Moreover, prestressed reinforcement with varying lengths(caused by the shrinkage and creep of concrete) might influence the final values and the time-varying function of the forecast relaxation loss. Hence, the effects of concrete shrinkage and creep were considered when calculating prestress loss, which reflected the coupling relation between these effects and relaxation loss in concrete. Hence, the forecast relaxation loss of prestressed reinforcement under the effects of different initial stress levels at any time point can be calculated using the modified model. To simplify the calculation, the integral expression of the model can be changed into an algebraic equation. The accuracy of the result is related to the division of the periods within the ending time of deriving the final value of the relaxation loss of prestressed reinforcement. When the time division is reasonable, result accuracy is high. The modified model works excellently according to the comparison of the test results. The calculation result of the modified model mainly reflects the prestress loss values of prestressed reinforcement at each time point, which confirms that adopting the finding in practical applications is reasonable.展开更多
Thermodynamic calculation is the theoretical basis for the study of initiation and detonation,as well as the prerequisite for forecasting the detonation performance of unknown explosives.Based on the VLWR(Virial-Wu)th...Thermodynamic calculation is the theoretical basis for the study of initiation and detonation,as well as the prerequisite for forecasting the detonation performance of unknown explosives.Based on the VLWR(Virial-Wu)thermodynamic code,this paper introduced the universal solid equation of state(EOS)VINET.In order to truly reflect the compressibility of nanocarbon under the extremely high-temperature and high-pressure environment in detonation,an SVM(support vector machine)was utilized to optimize the input parameters of carbon.The detonation performance of several explosives with different densities was calculated by the optimized universal EOS,and the results show that the thermodynamic code coupled with the universal solid EOS VINET can predict the detonation performance parameters of explosives well.To investigate the application of the thermodynamic code with the improved VINET EOS in the working capacity of explosives,the interrelationship between pressure P-particle velocity u and pressure P-volume V were computed for the detonation products of TNT and HMX-based PBX(HMX:binder:insensitive agent=95:4.3:0.7)in the CJ isentropic state.A universal curve proposed by Cooper was used to compared the computed isentropic state,where the ratio of pressure to CJ state were plotted against the ratio of velocity to CJ state.The parameters of the JWL(Jones-Wilkins-Lee)EOS for detonation products were obtained by fitting the P-V curve.The cylinder tests of TNT and HMX-based PBX were numerically simulated using the LS-DYNA,it is verified that,within a certain range,the improved algorithm has superiority in describing the working capacity of explosives.展开更多
基金Project(22376221)supported by the National Natural Science Foundation of ChinaProject(2024JJ2074)supported by the Natural Science Foundation of Hunan Province,ChinaProject(2023QNRC001)supported by the Young Elite Scientists Sponsorship Program by CAST。
文摘Understanding the adsorption behavior of heavy metals and metalloids on clay minerals is essential for remediating heavy metal-contaminated soils.The adsorption of heavy metals and metalloids on illite(001)and sodium montmorillonite(Na-MMT)(001)surfaces was investigated using first-principles calculations in this study,especially As atom and H_(3)AsO_(3) molecule.The adsorption energies of the As atom were−1.94 eV on the illite(001)and−0.56 eV on the Na-MMT(001),whereas,the adsorption energies of the H_(3)AsO_(3) molecule were−1.40 eV on illite(001)and−1.01 eV on Na-MMT(001).The above results indicate that the adsorption was more energetically favorable on illite(001).Additionally,compared to Na-MMT(001),there were more significant interactions between the atoms/molecules on the illite(001).After As atom and H_(3)AsO_(3) molecule adsorption,the electrons were transferred from mineral surface atoms to the adsorbates on both illite(001)and Na-MMT(001)surfaces.Moreover,the adsorption of As atom on illite(001)and Na-MMT(001)surfaces were more energy favorable compared to Hg,Cd,and Cr atoms.Overall,this work provides new insights into the adsorption behavior of As atoms and As molecules on illite and Na-MMT.The results indicate that illite rich soils are more prone to contamination by arsenic compared to soils primarily composed of Na-MMT minerals.
基金supported and funded internally through Dr. Catherine Johnson's research funds at Missouri S&T
文摘This study investigates the application of Gurney and flight of fragment equations,typically used to predict metal fragment velocities,in modeling the water jet behavior.Three shotgun cartridge sizes were used as the energy source:2.59 g,5.83 g,and 7.13 g.Two configurations were tested:standard(full-barrel water load)and"negative 8"(partial water load).High-speed footage captured water column velocities,and Gurney models,including infinitely tamped and open-faced configurations,combined with the flight of fragment model were used to assess prediction accuracy.Results showed charge strength significantly affects water column velocity,with higher strengths yielding greater stability and velocity retention over distance.The infinitely tamped Gurney model closely predicted experimental velocities,deviating by as little as 1.4%for standard charges and 2.8% for negative 8 charges.Additionally,interesting dynamics such as a 1-2°rise in jet height and the rear overtaking the front was observed.These findings have significant implications for optimizing PAN disruptors and enhancing performance in high-velocity fluid applications and explosive breaching systems.
基金supported by the Program for New Century Excellent Talents in University (NCET-06-0856)the National Natural Science Foundation of China (60772068)
文摘To enhance the resolution of parameter estimation with limited samples received by a short passive array, an iterative nonparametric algorithm for estimating the frequencies and direction-of-arrivals （DOAs） of signals is proposed. The cost function is constructed using 12-norm Gaussian entropy combined with an additional constraint, 12-norm constraint or linear constraint. By minimizing the cost functions in the temporal and the spatial dimensions using corresponding iteration algorithms respectively, the sparse discrete Fourier transforms （DFTs） of temporal and spatial samples are obtained to represent the extrapolated sequences with much larger sizes than the original samples. Then frequency and angle estimates are obtained by performing the traditional simple methods on the extrapolated sequences. It is shown that the proposed algorithm offers increased resolution and significantly reduced sidelobes compared with the periodogram and beamforming based methods. And it achieves high precision compared with the high-resolution method with lower computational burden. Some numerical simulations and real data processing results are presented to verify the effectiveness of the method.
基金Projects(61271321,61573253,61401303)supported by the National Natural Science Foundation of ChinaProject(14ZCZDSF00025)supported by Tianjin Key Technology Research and Development Program,China+1 种基金Project(13JCYBJC17500)supported by Tianjin Natural Science Foundation,ChinaProject(20120032110068)supported by Doctoral Fund of Ministry of Education of China
文摘Temporal-spatial cross-correlation analysis of non-stationary wind speed time series plays a crucial role in wind field reconstruction as well as in wind pattern recognition.Firstly,the near-surface wind speed time series recorded at different locations are studied using the detrended fluctuation analysis(DFA),and the corresponding scaling exponents are larger than 1.This indicates that all these wind speed time series have non-stationary characteristics.Secondly,concerning this special feature( i.e.,non-stationarity)of wind signals,a cross-correlation analysis method,namely detrended cross-correlation analysis(DCCA) coefficient,is employed to evaluate the temporal-spatial cross-correlations between non-stationary time series of different anemometer pairs.Finally,experiments on ten wind speed data synchronously collected by the ten anemometers with equidistant arrangement illustrate that the method of DCCA cross-correlation coefficient can accurately analyze full-scale temporal-spatial cross-correlation between non-stationary time series and also can easily identify the seasonal component,while three traditional cross-correlation techniques(i.e.,Pearson coefficient,cross-correlation function,and DCCA method) cannot give us these information directly.
文摘为改善传统N-Calculator模型的局限性,加强食物氮足迹核算结果与环境影响的联系,提高活性氮管理预见性,将N-Calculator模型与食物系统养分流动(Nutrient Flows in Food Chains,Environment and Resources Use,NUFER)模型进行耦合,以估算我国2001—2020年人均食物氮足迹,建立组合预测体系。结果显示:2001—2020年,我国人均食物氮足迹由16.04 kg N/a增至18.95 kg N/a;全国食物氮足迹由20.47 Mt N/a增至26.76 Mt N/a;居民饮食结构正由以植物源食物为主的低氮消费模式转向以动物源食物为主的高氮消费模式;食物生产过程产生的活性氮的最终归宿为大气(64.3%)、水体和深层土壤(35.7%);我国食物氮足迹与人均可支配收入、城市化率、动物源食物消费氮占比呈正相关性,与恩格尔系数呈负相关性;未来10 a我国人均食物氮足迹呈增长趋势,预测结果显示年均增幅为0.16 kg N/a。
基金This work was supported by the National Natural Science Foundation of China(No.11804263)the Program for Innovative Science and Research Team of Xi’an Technological University.
文摘In order to improve the infrared detection and discrimination ability of the smart munition to the dynamic armor target under the complex background,the multi-line array infrared detection system is established based on the combination of the single unit infrared detector.The surface dimension features of ground armored targets are identified by size calculating solution algorithm.The signal response value and the value of size calculating are identified by the method of fuzzy recognition to make the fuzzy classification judgment for armored target.According to the characteristics of the target signal,a custom threshold de-noising function is proposed to solve the problem of signal preprocessing.The multi-line array infrared detection can complete the scanning detection in a large area in a short time with the characteristics of smart munition in the steady-state scanning stage.The method solves the disadvantages of wide scanning interval and low detection probability of single unit infrared detection.By reducing the scanning interval,the number of random rendezvous in the infrared feature area of the upper surface is increased,the accuracy of the size calculating is guaranteed.The experiments results show that in the fuzzy recognition method,the size calculating is introduced as the feature operator,which can improve the recognition ability of the ground armor target with different shape size.
文摘The iterative formulas of inbreeding and relationship coefficients were put forward by using numerator elationship. It is suitable for any none - generation - overlap pedigree. The inbreeding and relationship coeffi- ient of offsprings can be calculated by those of parents. The deducing process of numerator relationship is simple and clear comparing with path analysis. An example shows the usage of these formulas.
文摘The blockage effectiveness problem for the runway cut-blanked modes of intelligence missile is described using probability integral method,when entry angle error and open cabin position error exist. On the condition of determined open cabin position error,the allowable range of entry angle error is inversely calculated with interdiction probability. The calculated results indicate that the method mentioned can estimate the intelligence missile interdiction efficiency to the runway and the range of entry angle error,which provides available basis for analyzing the intelligence missile attack assignment on the way.
基金Project(2014BAG01B0403)supported by the National High-Tech Research and Development Program of China
文摘In order to describe the characteristics of dynamic traffic flow and improve the robustness of its multiple applications, a dynamic traffic temporal-spatial model(DTTS) is established. With consideration of the temporal correlation, spatial correlation and historical correlation, a basic DTTS model is built. And a three-stage approach is put forward for the simplification and calibration of the basic DTTS model. Through critical sections pre-selection and critical time pre-selection, the first stage reduces the variable number of the basic DTTS model. In the second stage, variable coefficient calibration is implemented based on basic model simplification and stepwise regression analysis. Aimed at dynamic noise estimation, the characteristics of noise are summarized and an extreme learning machine is presented in the third stage. A case study based on a real-world road network in Beijing, China, is carried out to test the efficiency and applicability of proposed DTTS model and the three-stage approach.
文摘Two new coordination polymers,[Ni(Hpdc)(bib)(H_(2)O)]_(n)(1)and{[Ni(bib)_(3)](ClO_(4))_(2)}_(n)(2),were prepared by mixing Ni^(2+),3,5⁃pyrazoledicarboxylic acid(H3pdc)/p⁃nitrobenzoic acid and 1,4⁃bis(imidazol⁃1⁃ylmethyl)butane(bib)by a hydrothermal method,respectively.X⁃ray crystallography reveals a 2D network constructed by six⁃coordinated Ni(Ⅱ)centers,bib,and Hpdc2-ligands in complex 1,while a 2D network is built by Ni(Ⅱ)and bib ligands in 2.Furthermore,the quantum⁃chemical calculations have been performed on‘molecular fragments’extracted from the crystal structure of 1 using the PBE0/LANL2DZ method in Gaussian 16 and the VASP program.CCDC:2343794,1;2343798,2.
基金Project(51551801)supported by the National Natural Science Foundation of ChinaProject(14JJ4062)supported by the Natural Science Foundation of Hunan Province,China
文摘The calculation model for the relaxation loss of concrete mentioned in the Code for Design of Highway Reinforced Concrete and Prestressed Concrete Bridges and Culverts(JTG D62—2004) was modified according to experimental data. Time-varying relaxation loss was considered in the new model. Moreover, prestressed reinforcement with varying lengths(caused by the shrinkage and creep of concrete) might influence the final values and the time-varying function of the forecast relaxation loss. Hence, the effects of concrete shrinkage and creep were considered when calculating prestress loss, which reflected the coupling relation between these effects and relaxation loss in concrete. Hence, the forecast relaxation loss of prestressed reinforcement under the effects of different initial stress levels at any time point can be calculated using the modified model. To simplify the calculation, the integral expression of the model can be changed into an algebraic equation. The accuracy of the result is related to the division of the periods within the ending time of deriving the final value of the relaxation loss of prestressed reinforcement. When the time division is reasonable, result accuracy is high. The modified model works excellently according to the comparison of the test results. The calculation result of the modified model mainly reflects the prestress loss values of prestressed reinforcement at each time point, which confirms that adopting the finding in practical applications is reasonable.
基金the financial support from the National Natural Science Foundation of China(No.11902298)the National Key Research and Development Program of China(No.2017YFC0804701)。
文摘Thermodynamic calculation is the theoretical basis for the study of initiation and detonation,as well as the prerequisite for forecasting the detonation performance of unknown explosives.Based on the VLWR(Virial-Wu)thermodynamic code,this paper introduced the universal solid equation of state(EOS)VINET.In order to truly reflect the compressibility of nanocarbon under the extremely high-temperature and high-pressure environment in detonation,an SVM(support vector machine)was utilized to optimize the input parameters of carbon.The detonation performance of several explosives with different densities was calculated by the optimized universal EOS,and the results show that the thermodynamic code coupled with the universal solid EOS VINET can predict the detonation performance parameters of explosives well.To investigate the application of the thermodynamic code with the improved VINET EOS in the working capacity of explosives,the interrelationship between pressure P-particle velocity u and pressure P-volume V were computed for the detonation products of TNT and HMX-based PBX(HMX:binder:insensitive agent=95:4.3:0.7)in the CJ isentropic state.A universal curve proposed by Cooper was used to compared the computed isentropic state,where the ratio of pressure to CJ state were plotted against the ratio of velocity to CJ state.The parameters of the JWL(Jones-Wilkins-Lee)EOS for detonation products were obtained by fitting the P-V curve.The cylinder tests of TNT and HMX-based PBX were numerically simulated using the LS-DYNA,it is verified that,within a certain range,the improved algorithm has superiority in describing the working capacity of explosives.
