Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have re...Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have received increasing attention.In contrast to the conventional tube furnace method,the high-temperature shock(HTS)method enables ultra-fast thermal processing,superior atomic efficiency,and a streamlined synthesis protocol,offering a simplified method for the preparation of high-performance single-atom catalysts(SACs).The reports have shown that nickel-based SACs can be synthesized quickly and conveniently using the HTS method,making their application in CO_(2)reduction reactions(CO_(2)RR)a viable and promising avenue for further exploration.In this study,the effect of heating temperature,metal loading and different nitrogen(N)sources on the catalyst morphology,coordination environment and electrocatalytic performance were investigated.Under optimal conditions,0.05Ni-DCD-C-1050 showed excellent performance in reducing CO_(2)to CO,with CO selectivity close to 100%(−0.7 to−1.0 V vs RHE)and current density as high as 130 mA/cm^(2)(−1.1 V vs RHE)in a flow cell under alkaline environment.展开更多
Negative Poisson ratio(NPR)steel is a new material with high strength and toughness.This study conducted tensile tests at elevated temperatures to investigate the mechanical properties of NPR steel at high temperature...Negative Poisson ratio(NPR)steel is a new material with high strength and toughness.This study conducted tensile tests at elevated temperatures to investigate the mechanical properties of NPR steel at high temperatures.The stress−strain curve,ultimate strength,yield strength,modulus of elasticity,elongation after fracture,and percentage reduction of area of NPR steel bars were measured at 9 different temperatures ranging from 20 to 800℃.The experimental results indicate that high-temperature environments significantly affect the mechanical properties of NPR steel.However,compared to other types of steel,NPR steel exhibits better resistance to deformation.When the test temperature is below 700℃,NPR steel exhibits a ductile fracture characteristic,while at 800℃,it exhibits a brittle fracture characteristic.Finally,based on the experimental findings,a constitutive model suitable for NPR steel at high temperatures is proposed.展开更多
Cable-stayed bridges have been widely used in high-speed railway infrastructure.The accurate determination of cable’s representative temperatures is vital during the intricate processes of design,construction,and mai...Cable-stayed bridges have been widely used in high-speed railway infrastructure.The accurate determination of cable’s representative temperatures is vital during the intricate processes of design,construction,and maintenance of cable-stayed bridges.However,the representative temperatures of stayed cables are not specified in the existing design codes.To address this issue,this study investigates the distribution of the cable temperature and determinates its representative temperature.First,an experimental investigation,spanning over a period of one year,was carried out near the bridge site to obtain the temperature data.According to the statistical analysis of the measured data,it reveals that the temperature distribution is generally uniform along the cable cross-section without significant temperature gradient.Then,based on the limited data,the Monte Carlo,the gradient boosted regression trees(GBRT),and univariate linear regression(ULR)methods are employed to predict the cable’s representative temperature throughout the service life.These methods effectively overcome the limitations of insufficient monitoring data and accurately predict the representative temperature of the cables.However,each method has its own advantages and limitations in terms of applicability and accuracy.A comprehensive evaluation of the performance of these methods is conducted,and practical recommendations are provided for their application.The proposed methods and representative temperatures provide a good basis for the operation and maintenance of in-service long-span cable-stayed bridges.展开更多
The finite element method (FEM) and the boundary element method (BEM) are often adopted. However, they are not convenient to spatially vary thermal properties of functionally graded material (FGM). Therefore, the meth...The finite element method (FEM) and the boundary element method (BEM) are often adopted. However, they are not convenient to spatially vary thermal properties of functionally graded material (FGM). Therefore, the method of lines (MOL) is introduced to solve the temperature field of FGM. The basic idea of the method is to semi-discretize the governing equation into a system of ordinary differential equations (ODEs) defined on discrete lines by means of the finite difference method. The temperature field of FGM can be obtained by solving the ODEs. The functions of thermal properties are directly embodied in these equations and these properties are not discretized in the domain. Thus, difficulty of FEM and BEM is overcome by the method. As a numerical example, the temperature field of a plane problem is analyzed for FGMs through varying thermal conductivity coefficient by the MOL.展开更多
Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres befor...Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres before and after high temperature treatment(HTT) were characterized by X-ray diffractometry(XRD) ,scanning electronic microscopy(SEM) ,energy diffraction spectroscopy(EDS) ,and transmission electron microscopy(TEM) .The formation mechanism of carbon spheres was discussed.The results indicate that the carbon spheres convert to hollow polyhedron through HTT.Carbon spheres are composed of entangled and curve graphitic layers with short range order similar to cotton structure,and carbon polyhedron with dimension of 50-250 nm and shell thickness of 15-30 nm.The change of solid spheres to hollow polyhedron with branches gives a new evidence for formation mechanism of hollow carbon spheres.展开更多
The phenomenon of heat accumulation and transportation in the composite materials is a very typical and critical issue during drilling process.In this study,a three-dimensional temperature field prediction model is pr...The phenomenon of heat accumulation and transportation in the composite materials is a very typical and critical issue during drilling process.In this study,a three-dimensional temperature field prediction model is proposed using finite difference method,based on the partly homogenization hypothesis of material,to predict temperature field in the process of drilling unidirectional carbon fiber/epoxy(C/E)composites.According to the drilling feed motion,drilling process is divided into four stages to study the temperature distributing characteristics.The results show that the temperature distribution predicted by numerical study has a good agreement with the experimental results.The temperature increases with increasing the drilling depth,and the burn phenomena is observed due to the heat accumulation,especially at the drill exit.Due to the fiber orientation,an elliptical shape of the temperature field along the direction is found for both numerical and experimental studies of C/E composites drilling process.展开更多
A3D finite element model(FEM)with realistic field measurements of temperature distributions is proposed to investigate the thermal stress variation in the steel–concrete composite bridge deck system.First,a brief lit...A3D finite element model(FEM)with realistic field measurements of temperature distributions is proposed to investigate the thermal stress variation in the steel–concrete composite bridge deck system.First,a brief literaturereview indicates that traditional thermal stress calculation in suspension bridges is based on the2D plane structure with simplified temperature profiles on bridges.Thus,a3D FEM is proposed for accurate stress analysis.The focus is on the incorporation of full field arbitrary temperature profile for the stress analysis.Following this,the effect of realistic temperature distribution on the structure is investigated in detail and an example using field measurements of Aizhai Bridge is integrated with the proposed3D FEM model.Parametric studies are used to illustrate the effect of different parameters on the thermal stress distribution in the bridge structure.Next,the discussion and comparison of the proposed methodology and simplified calculation method in the standard is given.The calculation difference and their potential impact on the structure are shown in detail.Finally,some conclusions and recommendations for future bridge analysis and design are given based on the proposed study.展开更多
Given the increasing use of glass mat-reinforced thermoplastic(GMT)composites,the formability of GMT sheets is currently a topic of research.A new sheet forming process for solidified GMT was developed.In this process...Given the increasing use of glass mat-reinforced thermoplastic(GMT)composites,the formability of GMT sheets is currently a topic of research.A new sheet forming process for solidified GMT was developed.In this process,a GMT sheet was sandwiched by dummy metallic sheets during deep drawing.The dummy metallic sheets acted as protective materials and media for heating the GMT sheet.In this study,tensile tests of GMT specimens were carried out under different temperature conditions.The effect of temperature on the tensile deformation was analyzed.The effect of temperature on the deep drawing process of GMT sheets with dummy sheets was further investigated.Finite element method(FEM)was conducted to simulate the deep drawing process.In the drawing force rising stage,the law of drawing force with the depth of the drawing was analyzed using FEM and experiments.展开更多
This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investi...This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance.展开更多
It is well known that β-BBO is a new type nonlinear optical crystal discovered in our institute and now β-BBO is widely used in the fields of laser and nonlinear optics. However, there are still some inclusions in ...It is well known that β-BBO is a new type nonlinear optical crystal discovered in our institute and now β-BBO is widely used in the fields of laser and nonlinear optics. However, there are still some inclusions in β-BBO crystal grown by flux method. Using AEM technique, we have studied the shape, composition and structure of inclusions which is very helpful to the explanation of the formation of inclusions.展开更多
基金supported by the National Key R&D Program of China(2024YFB4106400)National Natural Science Foundation of China(22209200,52302331)。
文摘Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have received increasing attention.In contrast to the conventional tube furnace method,the high-temperature shock(HTS)method enables ultra-fast thermal processing,superior atomic efficiency,and a streamlined synthesis protocol,offering a simplified method for the preparation of high-performance single-atom catalysts(SACs).The reports have shown that nickel-based SACs can be synthesized quickly and conveniently using the HTS method,making their application in CO_(2)reduction reactions(CO_(2)RR)a viable and promising avenue for further exploration.In this study,the effect of heating temperature,metal loading and different nitrogen(N)sources on the catalyst morphology,coordination environment and electrocatalytic performance were investigated.Under optimal conditions,0.05Ni-DCD-C-1050 showed excellent performance in reducing CO_(2)to CO,with CO selectivity close to 100%(−0.7 to−1.0 V vs RHE)and current density as high as 130 mA/cm^(2)(−1.1 V vs RHE)in a flow cell under alkaline environment.
基金Projects(41702320,52104125)supported by the National Natural Science Foundation of ChinaProject(ZR2021MD005)+2 种基金supported by the Natural Science Foundation of Shandong Province,ChinaProject(TMduracon2022002)supported by the Engineering Research Center of Marine Environmental Concrete Technology,Ministry of Education,China。
文摘Negative Poisson ratio(NPR)steel is a new material with high strength and toughness.This study conducted tensile tests at elevated temperatures to investigate the mechanical properties of NPR steel at high temperatures.The stress−strain curve,ultimate strength,yield strength,modulus of elasticity,elongation after fracture,and percentage reduction of area of NPR steel bars were measured at 9 different temperatures ranging from 20 to 800℃.The experimental results indicate that high-temperature environments significantly affect the mechanical properties of NPR steel.However,compared to other types of steel,NPR steel exhibits better resistance to deformation.When the test temperature is below 700℃,NPR steel exhibits a ductile fracture characteristic,while at 800℃,it exhibits a brittle fracture characteristic.Finally,based on the experimental findings,a constitutive model suitable for NPR steel at high temperatures is proposed.
基金Project(2017G006-N)supported by the Project of Science and Technology Research and Development Program of China Railway Corporation。
文摘Cable-stayed bridges have been widely used in high-speed railway infrastructure.The accurate determination of cable’s representative temperatures is vital during the intricate processes of design,construction,and maintenance of cable-stayed bridges.However,the representative temperatures of stayed cables are not specified in the existing design codes.To address this issue,this study investigates the distribution of the cable temperature and determinates its representative temperature.First,an experimental investigation,spanning over a period of one year,was carried out near the bridge site to obtain the temperature data.According to the statistical analysis of the measured data,it reveals that the temperature distribution is generally uniform along the cable cross-section without significant temperature gradient.Then,based on the limited data,the Monte Carlo,the gradient boosted regression trees(GBRT),and univariate linear regression(ULR)methods are employed to predict the cable’s representative temperature throughout the service life.These methods effectively overcome the limitations of insufficient monitoring data and accurately predict the representative temperature of the cables.However,each method has its own advantages and limitations in terms of applicability and accuracy.A comprehensive evaluation of the performance of these methods is conducted,and practical recommendations are provided for their application.The proposed methods and representative temperatures provide a good basis for the operation and maintenance of in-service long-span cable-stayed bridges.
文摘The finite element method (FEM) and the boundary element method (BEM) are often adopted. However, they are not convenient to spatially vary thermal properties of functionally graded material (FGM). Therefore, the method of lines (MOL) is introduced to solve the temperature field of FGM. The basic idea of the method is to semi-discretize the governing equation into a system of ordinary differential equations (ODEs) defined on discrete lines by means of the finite difference method. The temperature field of FGM can be obtained by solving the ODEs. The functions of thermal properties are directly embodied in these equations and these properties are not discretized in the domain. Thus, difficulty of FEM and BEM is overcome by the method. As a numerical example, the temperature field of a plane problem is analyzed for FGMs through varying thermal conductivity coefficient by the MOL.
基金Project(2006CB600901) supported by the National Basic Research Program of ChinaProject(0991015) supported by Guangxi Natural Science Foundation,ChinaProject(200808MS083) supported by Guangxi Education Department Foundation,China
文摘Carbon spheres with size of 50-300 nm were synthesized via a solvent-thermal reaction with calcium carbide and chloroform as reactants in a sealed autoclave.The morphologies and microstructures of carbon spheres before and after high temperature treatment(HTT) were characterized by X-ray diffractometry(XRD) ,scanning electronic microscopy(SEM) ,energy diffraction spectroscopy(EDS) ,and transmission electron microscopy(TEM) .The formation mechanism of carbon spheres was discussed.The results indicate that the carbon spheres convert to hollow polyhedron through HTT.Carbon spheres are composed of entangled and curve graphitic layers with short range order similar to cotton structure,and carbon polyhedron with dimension of 50-250 nm and shell thickness of 15-30 nm.The change of solid spheres to hollow polyhedron with branches gives a new evidence for formation mechanism of hollow carbon spheres.
基金Projects(51475073,51605076,51875079)supported by the National Natural Science Foundation of ChinaProject(2017YFB1301701)supported by the National Key Research and Development Program of China
文摘The phenomenon of heat accumulation and transportation in the composite materials is a very typical and critical issue during drilling process.In this study,a three-dimensional temperature field prediction model is proposed using finite difference method,based on the partly homogenization hypothesis of material,to predict temperature field in the process of drilling unidirectional carbon fiber/epoxy(C/E)composites.According to the drilling feed motion,drilling process is divided into four stages to study the temperature distributing characteristics.The results show that the temperature distribution predicted by numerical study has a good agreement with the experimental results.The temperature increases with increasing the drilling depth,and the burn phenomena is observed due to the heat accumulation,especially at the drill exit.Due to the fiber orientation,an elliptical shape of the temperature field along the direction is found for both numerical and experimental studies of C/E composites drilling process.
基金Project(2015CB057701)supported by the National Basic Research Program of ChinaProject(51308071)supported by the National Natural Science Foundation of China+3 种基金Project(13JJ4057)supported by Natural Science Foundation of Hunan Province,ChinaProject(201408430155)supported by the Foundation of China Scholarship CouncilProject(2015319825120)supported by the Traffic Department of Applied Basic Research,ChinaProject(12K076)supported by the Open Foundation of Innovation Platform in Hunan Provincial Universities,China
文摘A3D finite element model(FEM)with realistic field measurements of temperature distributions is proposed to investigate the thermal stress variation in the steel–concrete composite bridge deck system.First,a brief literaturereview indicates that traditional thermal stress calculation in suspension bridges is based on the2D plane structure with simplified temperature profiles on bridges.Thus,a3D FEM is proposed for accurate stress analysis.The focus is on the incorporation of full field arbitrary temperature profile for the stress analysis.Following this,the effect of realistic temperature distribution on the structure is investigated in detail and an example using field measurements of Aizhai Bridge is integrated with the proposed3D FEM model.Parametric studies are used to illustrate the effect of different parameters on the thermal stress distribution in the bridge structure.Next,the discussion and comparison of the proposed methodology and simplified calculation method in the standard is given.The calculation difference and their potential impact on the structure are shown in detail.Finally,some conclusions and recommendations for future bridge analysis and design are given based on the proposed study.
基金Project(CG2016003001)supported by the Ministry of Human Resources and Social Security of China
文摘Given the increasing use of glass mat-reinforced thermoplastic(GMT)composites,the formability of GMT sheets is currently a topic of research.A new sheet forming process for solidified GMT was developed.In this process,a GMT sheet was sandwiched by dummy metallic sheets during deep drawing.The dummy metallic sheets acted as protective materials and media for heating the GMT sheet.In this study,tensile tests of GMT specimens were carried out under different temperature conditions.The effect of temperature on the tensile deformation was analyzed.The effect of temperature on the deep drawing process of GMT sheets with dummy sheets was further investigated.Finite element method(FEM)was conducted to simulate the deep drawing process.In the drawing force rising stage,the law of drawing force with the depth of the drawing was analyzed using FEM and experiments.
基金supported by the Scientific Research Foundation for High-level Talents of Anhui University of Science and Technology(2023yjrc51)the National Natural Science Foundation of China(22172184)+2 种基金the Foundation of State Key Laboratory of Coal Conversion(J24-25-603)the Fundamental Research Project of ICC-CAS(SCJC-DT-2023-01)Weiqiao-UCAS Special Projects on Low-Carbon Technology Development(GYY-DTFZ-2022-015)。
文摘This study explores the controllable synthesis of CuAlO_(2) using copper hydroxide and pseudo-boehmite powders as raw materials via a simple solid-phase ball milling method,along with its catalytic performance investigation in methanol steam reforming(MSR).Various catalysts were prepared under different conditions,such as calcination temperature,calcination atmosphere,and heating rate.Characterization techniques including BET,XRD,XPS,SEM and H2-TPR were employed to analyze the samples.The results revealed significant effects of calcination temperature on the phase compositions,specific surface area,reduction performance,and surface properties of the CA-T catalysts.Based on the findings,a synthesis route of CuAlO_(2) via the solid-phase method was proposed,highlighting the importance of high calcination temperature,nitrogen atmosphere,and low heating rate for CuAlO_(2) formation.Catalytic evaluation data demonstrated that CuAlO_(2) could catalyze MSR without pre-reduction,with the catalytic performance of CA-T catalysts being notably influenced by calcination temperature.Among the prepared catalysts,the CA-1100 catalyst exhibited the highest catalytic activity and stability.The findings of this study might be useful for the further study of the catalytic material for sustained release catalysis,including the synthesis of catalytic materials and the regulation of sustained release catalytic performance.
文摘It is well known that β-BBO is a new type nonlinear optical crystal discovered in our institute and now β-BBO is widely used in the fields of laser and nonlinear optics. However, there are still some inclusions in β-BBO crystal grown by flux method. Using AEM technique, we have studied the shape, composition and structure of inclusions which is very helpful to the explanation of the formation of inclusions.
