Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular st...Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.展开更多
Atmospheric effects on interferometric synthetic aperture radar(InSAR) measurements are quantitatively studied based on a tandem pair of SAR data and a month-long continuous GPS tracking data obtained at six stations....Atmospheric effects on interferometric synthetic aperture radar(InSAR) measurements are quantitatively studied based on a tandem pair of SAR data and a month-long continuous GPS tracking data obtained at six stations. Differential atmospheric signals extracted from the SAR data for two selected areas show apparent power law characteristics. The RMS values of the signals are 2.04 and 3.66 rad respectively for the two areas. These differential delays can potentially cause in the two areas peak-to-peak deformation errors of 3.64 and 6.52cm, respectively, at the 95% confidence level and Gaussian distribution. The respective potential peak-to-peak DEM errors are 123 and 221 m. The GPS tropospheric total zenith delays estimate indicates that a peak-to-peak error of about 7.8cm can potentially be caused in a SAR interferogram with only 1 d interval at the 95% confidence level. The error increases to about 9.6cm for 10 d interval. The potential peak-to-peak DEM and deformation errors estimated from GPS total zenith delay measurements are however quite similar to those estimated from InSAR data. This provides us with a useful tool to pre-estimate the potential atmospheric effects in a SAR interferogram before we order the SAR images. Nevertheless, the results reveal that even in a small area the atmospheric delays can obscure centimetre level ground displacements and introduce a few hundred meters of errors to derived DEM.展开更多
The delay vehicles experience at signalized intersections is one of the most important indicators for measuring intersection performance. The interpretation of delay variability evolvement at intersections gives a com...The delay vehicles experience at signalized intersections is one of the most important indicators for measuring intersection performance. The interpretation of delay variability evolvement at intersections gives a comprehensive insight into arterial traffic operation. Thus, an analytical model is proposed to investigate delay variability at coordinated intersections. Two different flow rates are assumed for both effective red and green periods in cumulative curves, through which the effect of signal coordination is incorporated in delay estimation. Then, an analogy of Markov chain process is used to explore the mechanism of stochastic overflow queue at signalized intersections. Numerical case studies show that with the decrease of arrival proportions during green, the shape of delay distribution in both undersaturation and oversaturation cases shifts faster towards higher values, implying that the coordination effect between paired intersections has a great effect on the delay distribution. As for delay fluctuation range, favorable coordination is demonstrated to be able to weaken the variability of delay estimates especially for undersaturation conditions.展开更多
文摘Thermally activated delayed fluorescence(TADF)molecules have outstanding potential for applications in organic light-emitting diodes(OLEDs).Due to the lack of systematic studies on the correlation between molecular structure and luminescence properties,TADF molecules are far from meeting the needs of practical applications in terms of variety and number.In this paper,three twisted TADF molecules are studied and their photophysical properties are theoretically predicted based on the thermal vibrational correlation function method combined with multiscale calculations.The results show that all the molecules exhibit fast reverse intersystem crossing(RISC)rates(kRISC),predicting their TADF luminescence properties.In addition,the binding of DHPAzSi as the donor unit with different acceptors can change the dihedral angle between the ground and excited states,and the planarity of the acceptors is positively correlated with the reorganization energy,a property that has a strong influence on the non-radiative process.Furthermore,a decrease in the energy of the molecular charge transfer state and an increase in the kRISC were observed in the films.This study not only provides a reliable explanation for the observed experimental results,but also offers valuable insights that can guide the design of future TADF molecules.
文摘Atmospheric effects on interferometric synthetic aperture radar(InSAR) measurements are quantitatively studied based on a tandem pair of SAR data and a month-long continuous GPS tracking data obtained at six stations. Differential atmospheric signals extracted from the SAR data for two selected areas show apparent power law characteristics. The RMS values of the signals are 2.04 and 3.66 rad respectively for the two areas. These differential delays can potentially cause in the two areas peak-to-peak deformation errors of 3.64 and 6.52cm, respectively, at the 95% confidence level and Gaussian distribution. The respective potential peak-to-peak DEM errors are 123 and 221 m. The GPS tropospheric total zenith delays estimate indicates that a peak-to-peak error of about 7.8cm can potentially be caused in a SAR interferogram with only 1 d interval at the 95% confidence level. The error increases to about 9.6cm for 10 d interval. The potential peak-to-peak DEM and deformation errors estimated from GPS total zenith delay measurements are however quite similar to those estimated from InSAR data. This provides us with a useful tool to pre-estimate the potential atmospheric effects in a SAR interferogram before we order the SAR images. Nevertheless, the results reveal that even in a small area the atmospheric delays can obscure centimetre level ground displacements and introduce a few hundred meters of errors to derived DEM.
基金Project(51278455)supported by the National Natural Science Foundation of ChinaProject(2012M521175)supported by the National Science Foundation for Post-doctoral Scientists of ChinaProject(Bsh1202056)supported by and the Excellent Postdoctoral Science Foundation of Zhejiang Province,China
文摘The delay vehicles experience at signalized intersections is one of the most important indicators for measuring intersection performance. The interpretation of delay variability evolvement at intersections gives a comprehensive insight into arterial traffic operation. Thus, an analytical model is proposed to investigate delay variability at coordinated intersections. Two different flow rates are assumed for both effective red and green periods in cumulative curves, through which the effect of signal coordination is incorporated in delay estimation. Then, an analogy of Markov chain process is used to explore the mechanism of stochastic overflow queue at signalized intersections. Numerical case studies show that with the decrease of arrival proportions during green, the shape of delay distribution in both undersaturation and oversaturation cases shifts faster towards higher values, implying that the coordination effect between paired intersections has a great effect on the delay distribution. As for delay fluctuation range, favorable coordination is demonstrated to be able to weaken the variability of delay estimates especially for undersaturation conditions.
