The characteristics and formation mechanisms of the mixed siliciclastic-carbonate reservoirs of the Paleogene Shahejie Formation in the central Bohai Sea were examined based on polarized light microscopy and scanning ...The characteristics and formation mechanisms of the mixed siliciclastic-carbonate reservoirs of the Paleogene Shahejie Formation in the central Bohai Sea were examined based on polarized light microscopy and scanning electron microscopy observations, X-ray diffrac- tometry, carbon and oxygen stable isotope geochemistry, and integrated fluid inclusion analysis. High-quality reservoirs are mainly distributed in Type I and Type II mixed siliciclastic-carbonate sediments, and the dominant pore types include residual primary intergranular pores and intrafossil pores, feldspar dissolution pores mainly devel- oped in Type II sediments. Type I mixed sediments are characterized by precipitation of early pore-lining dolo- mite, relatively weak mechanical compaction during deep burial, and the occurrence of abundant oil inclusions in high-quality reservoirs. Microfacies played a critical role in the formation of the mixed reservoirs, and high-quality reservoirs are commonly found in high-energy environ- ments, such as fan delta underwater distributary channels, mouth bars, and submarine uplift beach bars. Abundant intrafossil pores were formed by bioclastic decay, and secondary pores due to feldspar dissolution further enhance reservoir porosity. Mechanical compaction was inhibited by the precipitation of pore-lining dolomite formed during early stage, and oil emplacement has further led to the preservation of good reservoir quality.展开更多
Achieving a thorough understanding of how primary sedimentary granularity drives considerable heterogeneity in internal reservoir attributes of terrigenous fine-grained deposits is of great significance.We investigate...Achieving a thorough understanding of how primary sedimentary granularity drives considerable heterogeneity in internal reservoir attributes of terrigenous fine-grained deposits is of great significance.We investigated the quantitative differentiation and its corresponding driving forces of physical reservoir properties and pore-structure characteristics of silty-mud sediments in the Upper Triassic Xujiahe Formation(SW China)using a multi-method approach.The results show that the micro-mesopore volume and surface area of mudstones/shales are apparently higher than those of silty mudstones and a remarkable threefold rise in average permeability also presents.Extensively distributed bitumen pores occurring mostly along brittle mineral grains or forming clay-organic complexes make considerable contributions to shrinking microcracks.Furthermore,an evidently higher concentration of clay minerals in mudstone/shale reservoirs is primarily responsible for development of the two types of clay intercrystalline pores distributed along grain aggregates and between well-oriented platelets.These two major causes facilitate the formation of micro-bedding fractures/non-bedding micro fractures and connected fracture and pore-fracture networks,and also high-quality argillaceous reservoirs by strongly enhancing storage spaces and seepage capacities.Finally,a conceptual model is established for interpreting a differential reservoir-forming mechanism and corresponding two-sided effects on petrophysical and reservoir quality properties for continental silty-mud sediments.展开更多
This paper deals with the recovery of ilmenite mineral from red sediments of badlands topography and suggested flowsheet with material balance.The results of these investigations reveal that the red sediment samples c...This paper deals with the recovery of ilmenite mineral from red sediments of badlands topography and suggested flowsheet with material balance.The results of these investigations reveal that the red sediment samples contain 33.2%total heavy mineral,in which ilmenite mineral concentrate is 28.71%(by weight).The ilmenite concentrate recovered from red sediment sample by physical benefciation process,which included scrubbing,desliming,gravity concentration,magnetic and electrostatic separation,contains 99.41%grade with 97.3%recovery.The ilmenite mineral concentrate recovered from red sediments is also suitable for industrial applications.The characterization studies on ilmenite reveal that the TiO2percentage is marginally increasing from 46.69%to 47.86%with increasing magnetic intensity from0.46 to 1.55 T.展开更多
The chemical and physical properties of nitrogen and phosphorus as well as their concentrations in the over- lying water, pore-water and sediments in Huainan segment of the Huaihe river were analyzed. The chemical for...The chemical and physical properties of nitrogen and phosphorus as well as their concentrations in the over- lying water, pore-water and sediments in Huainan segment of the Huaihe river were analyzed. The chemical forms of phosphorus in sediments were differentiated by a sequential fraction method. The results revealed that the NH+4 -N content in pore-water of 6 surface sediments is obviously higher than that in overlying water, indicating that there is a dynamic tendency of releasing NH+4 -N from sediment into overlying water. Chemical compound of nitrogen differs among segments of the river, while phosphorus has no such difference. Calcium bound phosphate (Ca-P) and iron bound phosphate (Fe-P) accounts for 60 % of the total phosphorus, and occluded-P (O-P) accounts for less than 20 %. Our findings indicate that 1) industrial waste water and domestic sewage have contributed to the excessive nu- trient salts in Huaihe river, 2) decreased water flow during low water periods, and the interaction between sediments and overlying water disturbed by transport ships accelerate nutrient salt releasing into overlying water, which results in eutrophication of the river.展开更多
Based on Carcione-Leclaire model,the time-splitting high-order staggered-grid finite-difference algorithm is proposed and constructed for understanding wave propagation mechanisms in gas hydrate-bearing sediments.Thre...Based on Carcione-Leclaire model,the time-splitting high-order staggered-grid finite-difference algorithm is proposed and constructed for understanding wave propagation mechanisms in gas hydrate-bearing sediments.Three compressional waves and two shear waves,as well as their energy distributions are investigated in detail.In particular,the influences of the friction coefficient between solid grains and gas hydrate and the viscosity of pore fluid on wave propagation are analyzed.The results show that our proposed numerical simulation algorithm proposed in this paper can effectively solve the problem of stiffness in the velocity-stress equations and suppress the grid dispersion,resulting in higher accuracy compared with the result of the Fourier pseudospectral method used by Carcione.The excitation mechanisms of the five wave modes are clearly revealed by the results of simulations.Besides,it is pointed that,the wave diffusion of the second kind of compressional and shear waves is influenced by the friction coefficient between solid grains and gas hydrate,while the diffusion of the third compressional wave is controlled by the fluid viscosity.Finally,two fluid-solid(gas-hydrate formation)models are constructed to study the mode conversion of various waves.The results show that the reflection,transmission,and transformation of various waves occur on the interface,forming a very complicated wave field,and the energy distribution of various converted waves in different phases is different.It is demonstrated from our studies that,the unconventional waves,such as the second and third kinds of compressional waves may be converted into conventional waves on an interface.These propagation mechanisms provide a concrete wave attenuation explanation in inhomogeneous media.展开更多
This study investigated the occurrence and distribution of 15 phthalate esters (PAEs) in sediments collected from Qixinghe wetlands, northeast China. Total concentration of PAEs in all sediments ranged from 128.41 to ...This study investigated the occurrence and distribution of 15 phthalate esters (PAEs) in sediments collected from Qixinghe wetlands, northeast China. Total concentration of PAEs in all sediments ranged from 128.41 to 502.79 mu g kg(-1), with the mean value of 284.61 mu g kg(-1). PAEs significantly differed among wetland types; the average PAEs concentration of surface sediments were as follows: Phragmites australis wetland (PAW, 419.87 +/- 73.61 mu g kg(-1)) > Carex lasiocarpa wetland (CLW, 304.18 +/- 56.47 mu g kg(-1)) > Deyeuxia angustifolia wetland (DAW, 129.78 +/- 18.24 mu g kg(-1)). Dimethyl phthalate (DMP), diisobutyl phthalate, di-n-butyl phthalate, and di-(2-ethylhexyl) phthalate (DEHP) were found in all sediments, DEHP was the most abundant PAEs congeners with concentrations varying from 37.62 to 294.9 mu g kg(-1). DMP and DEHP exhibited relatively higher concentrations in CLW and PAW wetlands than in DAW, indicating that the different deoxidization and biodegradation conditions could have important implications for the distribution patterns of PAEs in wetland sediments. The variation of PAEs concentrations in horizontal and vertical sediments with wetland types could be attributed to the migration of contaminants by surface water, groundwater and atmospheric deposition. The occurrence and distribution of PAEs in wetlands also suggests that contamination in natural ecosystems should not be overlooked.展开更多
Taking the Cambrian Yuertus Formation outcrop profiles in the Aksu-Keping-Wushi areas of northwestern Tarim Basin as examples, the depositional environments of organic rich fine sediment were analyzed by examining the...Taking the Cambrian Yuertus Formation outcrop profiles in the Aksu-Keping-Wushi areas of northwestern Tarim Basin as examples, the depositional environments of organic rich fine sediment were analyzed by examining the outcrop profiles macroscopically and microscopically. The study reveals that:(1) The lower part of the Yuertus Formation consists of organic-rich fine sediment or thin rhythmic interbeds of organic-rich fine sediment and siliceous sediment, the formation transforms to terrigenous diamictic grain shoal and inverse grading carbonate rocks upward.(2) The thin limestone interbedded with dark shale rhythmically has inverse grading.(3) The thin-bedded siliceous rock has metasomatic residual granular texture, stromatolithic structure and cementation fabric in vugs.(4) There are iron crust layers at the top of the shallowing diamictic grain shoal, beneath which exposed karst signs, such as karrens, dissolved fissures, sack-like vugs, near surface karst(plastic) breccia, breccia inside the karst system and terrigenous clastic fillings, can be seen.(5) Both the outcrops and seismic profiles show that organic-rich fine sediments above the unconformities or exposed surfaces are characterized by overlapping. The organic-rich fine sediment of the Cambrian Yuertus Formation was deposited in the anoxic-suboxidized restricted gulf lagoon environment, and its formation was controlled by high paleoproductivity and poor oxygen exchange jointly, then a shallow-water overlapping sedimentary model has been established. The results will help enrich and improve the sedimentary theory of organic-rich fine sediments.展开更多
We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy me...We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.展开更多
To reveal additional effects of aquatic macrophytes on biogeochemical properties of onshore lake phosphorus and to investigate the ecological response of reed communities to this phosphorus,sediments from the Meiliang...To reveal additional effects of aquatic macrophytes on biogeochemical properties of onshore lake phosphorus and to investigate the ecological response of reed communities to this phosphorus,sediments from the Meiliangwan onshore reed area of Lake Taihu were sampled by using a columnar sampler (D=8 cm) on September 18,October 17 and December 3,2003. The samples were compared with those from macrophyte-free areas. The collected samples were dried naturally at room temperature,ground and screened with a 100 mesh sieve. The HClO4-H2SO4 digesting and H2SO4-H2O2 heating digesting methods were used to analyze the total amount of phosphorus (TP) contained in sedi-ments of the reed area and in tissues of reed roots and stems. The result shows: 1) the level of TP,from both the reed area sediment and the reference samples,is highest during the vigorous growing stage and lowest during the slow growing stage. The difference between the two levels is statistically significant (p<0.01); 2) the top layer (0-2 cm) of the sediment from the area without higher aquatic macrophytes and the sediment (4-7 cm) in the central reed area show peak values of phosphorus enrichment; 3) the phosphorus enrichment of different parts of reed tissues is in decreasing order: firous root > rhizome > stem. All are smaller in the level of phosphorous than that in rhizosphere sediments (0-2 cm).展开更多
The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate expl...The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate exploitation efficiency,a significant understanding of the effective thermal conductivity(ETC)of the hydrate-bearing sediment has become essential,since it directly controls the heat and mass transfer behaviors,and thereby determines the stability of hydrate reservoir and production rate.In this study,the effective thermal conductivities of various hydrate-bearing sediments were in-situ measured and studied.The impacts of temperature,particle size and type of sediment were investigated.The effective thermal conductivities of the quartz sand sediments before and after hydrate formation were in-situ measured.The results show the weak negative correlation of effective thermal conductivity of the quartz sand sediment on the temperature before and after the hydrate formation.The effective thermal conductivity of the hydrate-bearing sediment decreases with the increase of particle size of the sediment.The dominant effect of the type of porous medium on the characteristics of the effective thermal conductivity of hydrate-bearing sediment was highlighted.The results indicate that both the effective thermal conductivities of hydrate-bearing quartz sand sediment and hydrate-bearing silicon carbide sediment are weakly negatively correlated with temperature,but the effective thermal conductivity of hydrate-bearing clay sediment is weakly positively dependent on the temperature.In addition,the values of the effective thermal conductivities of various hydrate-bearing sediments are in the order of hydrate-bearing silicon carbide sediment>hydrate-bearing quartz sand sediment>hydrate-bearing clay sediment.These findings could suggest that the intrinsic thermal conductivity of porous medium could control the characteristics of effective thermal conductivity of hydrate-bearing sediment.展开更多
Pollution of heavy metals Cu,Pb and Hg is assessed using geo-accumulation index in this paper. The result shows that the bottom sediments of surface water in Xuzhou is polluted by these heavy metals to deferent degree...Pollution of heavy metals Cu,Pb and Hg is assessed using geo-accumulation index in this paper. The result shows that the bottom sediments of surface water in Xuzhou is polluted by these heavy metals to deferent degrees, of which the Jinma River is the most serious, and then the Kuihe River, the abandoned Yellow River, and the Jinghang Canal. The Yunlong Lake has also been polluted by Hg. The three kinds of heavy metals in the order of concentration is Hg>Cu>Pb. The pollution degree and the type of element is closely related with industrial structure in Xuzhou.展开更多
A new method of NAA for sediment movement study is presented in this paper. Through analyzing the natural sediment, the information about natural tracing agents has been obtained, which can show the direction of sedim...A new method of NAA for sediment movement study is presented in this paper. Through analyzing the natural sediment, the information about natural tracing agents has been obtained, which can show the direction of sediment movement and relative discharge of sediment transportation. Test results in some areas, such as Shantou Harbour and Hangzhou Bay, are in good agreement with those from normal hydrologic measurements and some results are not obtainable with the latter. The NAA is economical, practical and reliable, and should be widely used in engineering practice.展开更多
In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes ...In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade).展开更多
Solar-driven interfacial evaporation from seawater is considered an effective way to alleviate the emerging freshwater crisis because of its green and environmentally friendly characteristics.However,developing an eva...Solar-driven interfacial evaporation from seawater is considered an effective way to alleviate the emerging freshwater crisis because of its green and environmentally friendly characteristics.However,developing an evaporator with high efficiency,stability,and salt resistance remains a key challenge.MXene,with an internal photothermal conversion efficiency of 100%,has received tremendous research interest as a photothermal material.However,the process to prepare the MXene with monolayer is inefficient and generates a large amount of“waste”MXene sediments(MS).Here,MXene sediments is selected as the photothermal material,and a three-dimensional MXene sediments/poly(vinyl alcohol)/sodium alginate aerogel evaporator with vertically aligned pores by directional freezing method is innovatively designed.The vertical porous structure enables the evaporator to improve water transport,light capture,and high evaporation rate.Cotton swabs and polypropylene are used as the water channel and support,respectively,thus fabricating a self-floating evaporator.The evaporator exhibits an evaporation rate of 3.6 kg m^(-2)h^(-1)under one-sun illumination,and 18.37 kg m^(-2)of freshwater is collected in the condensation collection device after 7 h of outdoor sun irradiation.The evaporator also displays excellent oil and salt resistance.This research fully utilizes“waste”MS,enabling a self-floating evaporation device for freshwater collection.展开更多
Aragonite is a metastable mineral,which is easily transformed into calcite,and generally difficult to preserve in the stratum.However,large amounts of aragonites were found in the Paleogene shale of the Jiyang Depress...Aragonite is a metastable mineral,which is easily transformed into calcite,and generally difficult to preserve in the stratum.However,large amounts of aragonites were found in the Paleogene shale of the Jiyang Depression.The characteristics and preservation mechanisms of these aragonites were analyzed through a series of analytical methods,including cathodoluminescence,field-emission scanning electron microscopy(FESEM),laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS),microarea carbon and oxygen isotopes,Sr isotopes,and dissolution simulation experiments under high temperature and high pressure.The research results show that:(1)Aragonite in the Paleogene shale of the Jiyang Depression is related to algal microbial fossils,primarily composed of coccoliths and characterized by two emission peaks at 420 nm and 480 nm in cathodoluminescence;(2)The primary factor allowing biological aragonite to be preserved is the immaturity of the organic matter and the deficiency of abundant organic acids necessary for its dissolution or transformation,which is confirmed by the evidence of organic matter maturity and simulation experiments of organic acid dissolution on aragonite under high-temperature and high-pressure conditions.Additional factors that may aid in the preservation of aragonite are the ideal sedimentation conditions,the defense of organic coating,and the enclosed environment with tiny pores,low porosity,and low permeability;(3)These aragonite-rich shales,characterized by coccolithophores,provide a solid evidence for seawater intrusion into terrestrial lake basin,and have a significant implication for the source and storage of shale oil.展开更多
Deep-sea sediment disturbance may occur when collecting polymetallic nodules,resulting in the creation of plumes that could have a negative impact on the ecological environment.This study aims to investigate the poten...Deep-sea sediment disturbance may occur when collecting polymetallic nodules,resulting in the creation of plumes that could have a negative impact on the ecological environment.This study aims to investigate the potential solution of using polyaluminum chloride(PAC)in the water jet.The effects of PAC are examined through a self-designed simulation system for deep-sea polymetallic nodule collection and sediment samples from a potential deep-sea mining area.The experimental results showed that the optimal PAC dose was found to be 0.75 g/L.Compared with the test conditions without the addition of PAC,the presence of PAC leads to a reduction in volume,lower characteristic turbidity,smaller diffusion velocity,and shorter settling time of the plume.This indicates that PAC inhibits the entire development process of the plume.The addition of PAC leads to the flocculation of mm-sized particles,resulting in the formation of cm-sized flocs.The flocculation of particles decreases the rate of erosion on the seabed by around 30%.This reduction in erosion helps to decrease the formation of plumes.Additionally,when the size of suspended particles increases,it reduces the scale at which they diffuse.Furthermore,the settling velocity of flocs(around 10^(-2) m/s)is much higher that of compared to sediment particles(around 10^(-5) m/s),which effectively reduces the amount of time the plume remains in suspension.展开更多
Monitoring the ecology and physiology of corals,sediments,planktons,and microplastic at a suitable spatial resolution is of great importance in oceanic scientific research.To meet this requirement,an underwater micros...Monitoring the ecology and physiology of corals,sediments,planktons,and microplastic at a suitable spatial resolution is of great importance in oceanic scientific research.To meet this requirement,an underwater microscope with an electrically controlled variable lens was designed and tested.The captured microscopic images of corals,sediments,planktons,and microplastic revealed their physical,biological,and morphological characteristics.Further studies of the images also revealed the growth,degradation,and bleaching patterns of corals;the presence of plankton communities;and the types of microplastics.The imaging performance is majorly influenced by the choice of lenses,camera selection,and lighting method.Image dehazing,global saturation masks,and image histograms were used to extract the image features.Fundamental experimental proof was obtained with micro-scale images of corals,sediments,planktons,and microplastic at different magnifications.The designed underwater microscope can provide relevant new insights into the observation and detection of the future conditions of aquatic ecosystems.展开更多
The study of internal-wave and internal-tide deposits is a new research field on sedimentology during the last ten years. Deep-water traction currents induced by internal waves and internal tides are developed on the ...The study of internal-wave and internal-tide deposits is a new research field on sedimentology during the last ten years. Deep-water traction currents induced by internal waves and internal tides are developed on the modern sea floor, which can form not only all kinds of small scale and dispersal deepwater traction currents deposits, but also large-scale sediment wave in km-size scale. In this paper, the concepts and features of internal waves and internal tides in oceanography are introduced, and the characteristics, sedimentary sequences, sedimentary microfacies and sedimentation models of internalwave and internal-tide deposits found and the origin of large scale sediment waves in deep sea bottom are summarized. The relationship between internal-wave and internal-tide deposits and petroleum is discussed, and finally internal-wave and internal-tide deposits are shown to be a new potential field for petroleum exploration.展开更多
基金financially supported by the National Science & Technology Specific Project (Grant No. 2011ZX05023-006)
文摘The characteristics and formation mechanisms of the mixed siliciclastic-carbonate reservoirs of the Paleogene Shahejie Formation in the central Bohai Sea were examined based on polarized light microscopy and scanning electron microscopy observations, X-ray diffrac- tometry, carbon and oxygen stable isotope geochemistry, and integrated fluid inclusion analysis. High-quality reservoirs are mainly distributed in Type I and Type II mixed siliciclastic-carbonate sediments, and the dominant pore types include residual primary intergranular pores and intrafossil pores, feldspar dissolution pores mainly devel- oped in Type II sediments. Type I mixed sediments are characterized by precipitation of early pore-lining dolo- mite, relatively weak mechanical compaction during deep burial, and the occurrence of abundant oil inclusions in high-quality reservoirs. Microfacies played a critical role in the formation of the mixed reservoirs, and high-quality reservoirs are commonly found in high-energy environ- ments, such as fan delta underwater distributary channels, mouth bars, and submarine uplift beach bars. Abundant intrafossil pores were formed by bioclastic decay, and secondary pores due to feldspar dissolution further enhance reservoir porosity. Mechanical compaction was inhibited by the precipitation of pore-lining dolomite formed during early stage, and oil emplacement has further led to the preservation of good reservoir quality.
基金supported by the Science Foundation for Distinguished Young Scholars of China University of Petroleum,Beijing(No.2462020QNXZ004)the National Natural Science and Technology Major Project(No.2016ZX05034-001 and 2017ZX05035-002)。
文摘Achieving a thorough understanding of how primary sedimentary granularity drives considerable heterogeneity in internal reservoir attributes of terrigenous fine-grained deposits is of great significance.We investigated the quantitative differentiation and its corresponding driving forces of physical reservoir properties and pore-structure characteristics of silty-mud sediments in the Upper Triassic Xujiahe Formation(SW China)using a multi-method approach.The results show that the micro-mesopore volume and surface area of mudstones/shales are apparently higher than those of silty mudstones and a remarkable threefold rise in average permeability also presents.Extensively distributed bitumen pores occurring mostly along brittle mineral grains or forming clay-organic complexes make considerable contributions to shrinking microcracks.Furthermore,an evidently higher concentration of clay minerals in mudstone/shale reservoirs is primarily responsible for development of the two types of clay intercrystalline pores distributed along grain aggregates and between well-oriented platelets.These two major causes facilitate the formation of micro-bedding fractures/non-bedding micro fractures and connected fracture and pore-fracture networks,and also high-quality argillaceous reservoirs by strongly enhancing storage spaces and seepage capacities.Finally,a conceptual model is established for interpreting a differential reservoir-forming mechanism and corresponding two-sided effects on petrophysical and reservoir quality properties for continental silty-mud sediments.
文摘This paper deals with the recovery of ilmenite mineral from red sediments of badlands topography and suggested flowsheet with material balance.The results of these investigations reveal that the red sediment samples contain 33.2%total heavy mineral,in which ilmenite mineral concentrate is 28.71%(by weight).The ilmenite concentrate recovered from red sediment sample by physical benefciation process,which included scrubbing,desliming,gravity concentration,magnetic and electrostatic separation,contains 99.41%grade with 97.3%recovery.The ilmenite mineral concentrate recovered from red sediments is also suitable for industrial applications.The characterization studies on ilmenite reveal that the TiO2percentage is marginally increasing from 46.69%to 47.86%with increasing magnetic intensity from0.46 to 1.55 T.
基金Project 2003kj294 supported by natural science foundation of bureau education Anhui province
文摘The chemical and physical properties of nitrogen and phosphorus as well as their concentrations in the over- lying water, pore-water and sediments in Huainan segment of the Huaihe river were analyzed. The chemical forms of phosphorus in sediments were differentiated by a sequential fraction method. The results revealed that the NH+4 -N content in pore-water of 6 surface sediments is obviously higher than that in overlying water, indicating that there is a dynamic tendency of releasing NH+4 -N from sediment into overlying water. Chemical compound of nitrogen differs among segments of the river, while phosphorus has no such difference. Calcium bound phosphate (Ca-P) and iron bound phosphate (Fe-P) accounts for 60 % of the total phosphorus, and occluded-P (O-P) accounts for less than 20 %. Our findings indicate that 1) industrial waste water and domestic sewage have contributed to the excessive nu- trient salts in Huaihe river, 2) decreased water flow during low water periods, and the interaction between sediments and overlying water disturbed by transport ships accelerate nutrient salt releasing into overlying water, which results in eutrophication of the river.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11974018 and 11734017)the Strategic Pilot and Technology Special Fund of the Chinese Academy of Sciences,China(Grant No.XDA14020303)。
文摘Based on Carcione-Leclaire model,the time-splitting high-order staggered-grid finite-difference algorithm is proposed and constructed for understanding wave propagation mechanisms in gas hydrate-bearing sediments.Three compressional waves and two shear waves,as well as their energy distributions are investigated in detail.In particular,the influences of the friction coefficient between solid grains and gas hydrate and the viscosity of pore fluid on wave propagation are analyzed.The results show that our proposed numerical simulation algorithm proposed in this paper can effectively solve the problem of stiffness in the velocity-stress equations and suppress the grid dispersion,resulting in higher accuracy compared with the result of the Fourier pseudospectral method used by Carcione.The excitation mechanisms of the five wave modes are clearly revealed by the results of simulations.Besides,it is pointed that,the wave diffusion of the second kind of compressional and shear waves is influenced by the friction coefficient between solid grains and gas hydrate,while the diffusion of the third compressional wave is controlled by the fluid viscosity.Finally,two fluid-solid(gas-hydrate formation)models are constructed to study the mode conversion of various waves.The results show that the reflection,transmission,and transformation of various waves occur on the interface,forming a very complicated wave field,and the energy distribution of various converted waves in different phases is different.It is demonstrated from our studies that,the unconventional waves,such as the second and third kinds of compressional waves may be converted into conventional waves on an interface.These propagation mechanisms provide a concrete wave attenuation explanation in inhomogeneous media.
基金supported by the National Natural Science Foundation of China(No.31470543)
文摘This study investigated the occurrence and distribution of 15 phthalate esters (PAEs) in sediments collected from Qixinghe wetlands, northeast China. Total concentration of PAEs in all sediments ranged from 128.41 to 502.79 mu g kg(-1), with the mean value of 284.61 mu g kg(-1). PAEs significantly differed among wetland types; the average PAEs concentration of surface sediments were as follows: Phragmites australis wetland (PAW, 419.87 +/- 73.61 mu g kg(-1)) > Carex lasiocarpa wetland (CLW, 304.18 +/- 56.47 mu g kg(-1)) > Deyeuxia angustifolia wetland (DAW, 129.78 +/- 18.24 mu g kg(-1)). Dimethyl phthalate (DMP), diisobutyl phthalate, di-n-butyl phthalate, and di-(2-ethylhexyl) phthalate (DEHP) were found in all sediments, DEHP was the most abundant PAEs congeners with concentrations varying from 37.62 to 294.9 mu g kg(-1). DMP and DEHP exhibited relatively higher concentrations in CLW and PAW wetlands than in DAW, indicating that the different deoxidization and biodegradation conditions could have important implications for the distribution patterns of PAEs in wetland sediments. The variation of PAEs concentrations in horizontal and vertical sediments with wetland types could be attributed to the migration of contaminants by surface water, groundwater and atmospheric deposition. The occurrence and distribution of PAEs in wetlands also suggests that contamination in natural ecosystems should not be overlooked.
基金Supported by the China National Science and Technology Major Project(2016ZX05004002-001)the National Natural Science Foundation of China(41602147)
文摘Taking the Cambrian Yuertus Formation outcrop profiles in the Aksu-Keping-Wushi areas of northwestern Tarim Basin as examples, the depositional environments of organic rich fine sediment were analyzed by examining the outcrop profiles macroscopically and microscopically. The study reveals that:(1) The lower part of the Yuertus Formation consists of organic-rich fine sediment or thin rhythmic interbeds of organic-rich fine sediment and siliceous sediment, the formation transforms to terrigenous diamictic grain shoal and inverse grading carbonate rocks upward.(2) The thin limestone interbedded with dark shale rhythmically has inverse grading.(3) The thin-bedded siliceous rock has metasomatic residual granular texture, stromatolithic structure and cementation fabric in vugs.(4) There are iron crust layers at the top of the shallowing diamictic grain shoal, beneath which exposed karst signs, such as karrens, dissolved fissures, sack-like vugs, near surface karst(plastic) breccia, breccia inside the karst system and terrigenous clastic fillings, can be seen.(5) Both the outcrops and seismic profiles show that organic-rich fine sediments above the unconformities or exposed surfaces are characterized by overlapping. The organic-rich fine sediment of the Cambrian Yuertus Formation was deposited in the anoxic-suboxidized restricted gulf lagoon environment, and its formation was controlled by high paleoproductivity and poor oxygen exchange jointly, then a shallow-water overlapping sedimentary model has been established. The results will help enrich and improve the sedimentary theory of organic-rich fine sediments.
文摘We have collected 18 samples corresponding to 18 locations in the middle and lower reaches of the Huaihe River. The sediment samples were tested for their pH level,percentage of solids,organic matter and five heavy metals (Cr,Cu,Zn,Cd and Pb). The average concentrations of Cr,Cu,Zn,Cd and Pb of the 18 sampling locations were re-spectively 56.1,22.2,70.0,0.17 and 20.4 μg/g. Compared with their background values,the average concentrations of Zn and Cu in sediment samples from the Huaihe River were slightly higher,while the average concentrations of Cr and Pb were slightly lower. The concentration of Cd in all sediment samples was higher than its background value,while the average concentration of Cd in all sediment samples was about twice the amount of the background value. The concen-tration of the five heavy metals was lower than that of the Yangtze River. A correlation analysis revealed that heavy metals have similar geochemical feautures. The geo-accumulation index (Igeo) was used to evaluate the degree of pollu-tion of the Huaihe River sediments. The index reveals that the sediment samples are largely ranked from zero pollution to no to medium pollution.
基金Projects KZCX1-SW-12 supported by the Chinese Academy of Sciences Knowledge Innovation Program2002AA60101 by the National High Technol- ogy Research and Development Program of China
文摘To reveal additional effects of aquatic macrophytes on biogeochemical properties of onshore lake phosphorus and to investigate the ecological response of reed communities to this phosphorus,sediments from the Meiliangwan onshore reed area of Lake Taihu were sampled by using a columnar sampler (D=8 cm) on September 18,October 17 and December 3,2003. The samples were compared with those from macrophyte-free areas. The collected samples were dried naturally at room temperature,ground and screened with a 100 mesh sieve. The HClO4-H2SO4 digesting and H2SO4-H2O2 heating digesting methods were used to analyze the total amount of phosphorus (TP) contained in sedi-ments of the reed area and in tissues of reed roots and stems. The result shows: 1) the level of TP,from both the reed area sediment and the reference samples,is highest during the vigorous growing stage and lowest during the slow growing stage. The difference between the two levels is statistically significant (p<0.01); 2) the top layer (0-2 cm) of the sediment from the area without higher aquatic macrophytes and the sediment (4-7 cm) in the central reed area show peak values of phosphorus enrichment; 3) the phosphorus enrichment of different parts of reed tissues is in decreasing order: firous root > rhizome > stem. All are smaller in the level of phosphorous than that in rhizosphere sediments (0-2 cm).
基金This work was supported by the National Natural Science Foundation of China(U19B2005,21808238,U20B6005,22127812)the National Key Research and Development Program of China(2021YFC2800902).
文摘The natural gas hydrate has been regarded as an important future green energy.Significant progress on the hydrate exploitation has been made,but some challenges are still remaining.In order to enhance the hydrate exploitation efficiency,a significant understanding of the effective thermal conductivity(ETC)of the hydrate-bearing sediment has become essential,since it directly controls the heat and mass transfer behaviors,and thereby determines the stability of hydrate reservoir and production rate.In this study,the effective thermal conductivities of various hydrate-bearing sediments were in-situ measured and studied.The impacts of temperature,particle size and type of sediment were investigated.The effective thermal conductivities of the quartz sand sediments before and after hydrate formation were in-situ measured.The results show the weak negative correlation of effective thermal conductivity of the quartz sand sediment on the temperature before and after the hydrate formation.The effective thermal conductivity of the hydrate-bearing sediment decreases with the increase of particle size of the sediment.The dominant effect of the type of porous medium on the characteristics of the effective thermal conductivity of hydrate-bearing sediment was highlighted.The results indicate that both the effective thermal conductivities of hydrate-bearing quartz sand sediment and hydrate-bearing silicon carbide sediment are weakly negatively correlated with temperature,but the effective thermal conductivity of hydrate-bearing clay sediment is weakly positively dependent on the temperature.In addition,the values of the effective thermal conductivities of various hydrate-bearing sediments are in the order of hydrate-bearing silicon carbide sediment>hydrate-bearing quartz sand sediment>hydrate-bearing clay sediment.These findings could suggest that the intrinsic thermal conductivity of porous medium could control the characteristics of effective thermal conductivity of hydrate-bearing sediment.
文摘Pollution of heavy metals Cu,Pb and Hg is assessed using geo-accumulation index in this paper. The result shows that the bottom sediments of surface water in Xuzhou is polluted by these heavy metals to deferent degrees, of which the Jinma River is the most serious, and then the Kuihe River, the abandoned Yellow River, and the Jinghang Canal. The Yunlong Lake has also been polluted by Hg. The three kinds of heavy metals in the order of concentration is Hg>Cu>Pb. The pollution degree and the type of element is closely related with industrial structure in Xuzhou.
文摘A new method of NAA for sediment movement study is presented in this paper. Through analyzing the natural sediment, the information about natural tracing agents has been obtained, which can show the direction of sediment movement and relative discharge of sediment transportation. Test results in some areas, such as Shantou Harbour and Hangzhou Bay, are in good agreement with those from normal hydrologic measurements and some results are not obtainable with the latter. The NAA is economical, practical and reliable, and should be widely used in engineering practice.
文摘In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade).
基金supported by the National Natural Science Foundation of China(No.52003131)China Postdoctoral Science Foundation(No.2023M731838)Taishan Scholar Program of Shandong Province in China(tsqn202211116).
文摘Solar-driven interfacial evaporation from seawater is considered an effective way to alleviate the emerging freshwater crisis because of its green and environmentally friendly characteristics.However,developing an evaporator with high efficiency,stability,and salt resistance remains a key challenge.MXene,with an internal photothermal conversion efficiency of 100%,has received tremendous research interest as a photothermal material.However,the process to prepare the MXene with monolayer is inefficient and generates a large amount of“waste”MXene sediments(MS).Here,MXene sediments is selected as the photothermal material,and a three-dimensional MXene sediments/poly(vinyl alcohol)/sodium alginate aerogel evaporator with vertically aligned pores by directional freezing method is innovatively designed.The vertical porous structure enables the evaporator to improve water transport,light capture,and high evaporation rate.Cotton swabs and polypropylene are used as the water channel and support,respectively,thus fabricating a self-floating evaporator.The evaporator exhibits an evaporation rate of 3.6 kg m^(-2)h^(-1)under one-sun illumination,and 18.37 kg m^(-2)of freshwater is collected in the condensation collection device after 7 h of outdoor sun irradiation.The evaporator also displays excellent oil and salt resistance.This research fully utilizes“waste”MS,enabling a self-floating evaporation device for freshwater collection.
基金supported by the National Natural Science Foundation of China(Nos.42302152,42072164,41821002,and 42272119)the Natural Science Foundation of Shandong Province(No.ZR2023QD076)+3 种基金the Shandong Provincial Key research and Development Program(No.2020ZLYS08)the Taishan Scholars Program(No.TSQN201812030)the Fundamental Research Funds for the Central Universities(No.22CX06010A)Qingdao Postdoctoral Application Research Project(No.QDBSH20220202075)。
文摘Aragonite is a metastable mineral,which is easily transformed into calcite,and generally difficult to preserve in the stratum.However,large amounts of aragonites were found in the Paleogene shale of the Jiyang Depression.The characteristics and preservation mechanisms of these aragonites were analyzed through a series of analytical methods,including cathodoluminescence,field-emission scanning electron microscopy(FESEM),laser ablation inductively coupled plasma mass spectrometry(LA-ICP-MS),microarea carbon and oxygen isotopes,Sr isotopes,and dissolution simulation experiments under high temperature and high pressure.The research results show that:(1)Aragonite in the Paleogene shale of the Jiyang Depression is related to algal microbial fossils,primarily composed of coccoliths and characterized by two emission peaks at 420 nm and 480 nm in cathodoluminescence;(2)The primary factor allowing biological aragonite to be preserved is the immaturity of the organic matter and the deficiency of abundant organic acids necessary for its dissolution or transformation,which is confirmed by the evidence of organic matter maturity and simulation experiments of organic acid dissolution on aragonite under high-temperature and high-pressure conditions.Additional factors that may aid in the preservation of aragonite are the ideal sedimentation conditions,the defense of organic coating,and the enclosed environment with tiny pores,low porosity,and low permeability;(3)These aragonite-rich shales,characterized by coccolithophores,provide a solid evidence for seawater intrusion into terrestrial lake basin,and have a significant implication for the source and storage of shale oil.
基金supported by the National Natural Science Foundation of China(Nos.52225107,U2106224,U1906234,51822904,and U1706223)the Fundamental Research Funds for the Central Universities(No.202041004)
文摘Deep-sea sediment disturbance may occur when collecting polymetallic nodules,resulting in the creation of plumes that could have a negative impact on the ecological environment.This study aims to investigate the potential solution of using polyaluminum chloride(PAC)in the water jet.The effects of PAC are examined through a self-designed simulation system for deep-sea polymetallic nodule collection and sediment samples from a potential deep-sea mining area.The experimental results showed that the optimal PAC dose was found to be 0.75 g/L.Compared with the test conditions without the addition of PAC,the presence of PAC leads to a reduction in volume,lower characteristic turbidity,smaller diffusion velocity,and shorter settling time of the plume.This indicates that PAC inhibits the entire development process of the plume.The addition of PAC leads to the flocculation of mm-sized particles,resulting in the formation of cm-sized flocs.The flocculation of particles decreases the rate of erosion on the seabed by around 30%.This reduction in erosion helps to decrease the formation of plumes.Additionally,when the size of suspended particles increases,it reduces the scale at which they diffuse.Furthermore,the settling velocity of flocs(around 10^(-2) m/s)is much higher that of compared to sediment particles(around 10^(-5) m/s),which effectively reduces the amount of time the plume remains in suspension.
基金This study is supported by the Key Research and Development Plan of Zhejiang Province,China(Grant number:2020C03012).
文摘Monitoring the ecology and physiology of corals,sediments,planktons,and microplastic at a suitable spatial resolution is of great importance in oceanic scientific research.To meet this requirement,an underwater microscope with an electrically controlled variable lens was designed and tested.The captured microscopic images of corals,sediments,planktons,and microplastic revealed their physical,biological,and morphological characteristics.Further studies of the images also revealed the growth,degradation,and bleaching patterns of corals;the presence of plankton communities;and the types of microplastics.The imaging performance is majorly influenced by the choice of lenses,camera selection,and lighting method.Image dehazing,global saturation masks,and image histograms were used to extract the image features.Fundamental experimental proof was obtained with micro-scale images of corals,sediments,planktons,and microplastic at different magnifications.The designed underwater microscope can provide relevant new insights into the observation and detection of the future conditions of aquatic ecosystems.
文摘The study of internal-wave and internal-tide deposits is a new research field on sedimentology during the last ten years. Deep-water traction currents induced by internal waves and internal tides are developed on the modern sea floor, which can form not only all kinds of small scale and dispersal deepwater traction currents deposits, but also large-scale sediment wave in km-size scale. In this paper, the concepts and features of internal waves and internal tides in oceanography are introduced, and the characteristics, sedimentary sequences, sedimentary microfacies and sedimentation models of internalwave and internal-tide deposits found and the origin of large scale sediment waves in deep sea bottom are summarized. The relationship between internal-wave and internal-tide deposits and petroleum is discussed, and finally internal-wave and internal-tide deposits are shown to be a new potential field for petroleum exploration.
