Magnesium hydroxide(Mg(OH)2)has been considered as a potential solvent for CO2 removal of coal-fired power plant and biomass gas.The chemistry action and mass to transfer mechanism of CO2-H2O-Mg(OH)2 system in a slurr...Magnesium hydroxide(Mg(OH)2)has been considered as a potential solvent for CO2 removal of coal-fired power plant and biomass gas.The chemistry action and mass to transfer mechanism of CO2-H2O-Mg(OH)2 system in a slurry bubble column reactor was described,and a reliable computational model was developed.The overall mass transfer coefficient and surface area per unit volume were obtained using experimental approach and simulation with software assistance.The results show that the mass transfer process of CO2 absorbed by Mg(OH)2 slurry is mainly liquid-controlled,and slurry concentration and temperature are main contributory factors of volumetric mass transfer coefficient and liquid side mass transfer coefficient.High concentration of CO2 has an adverse effect on its absorption because it leads to the fast deposition of MgCO3·3H2O crystals on the surfaces of unreacted Mg(OH)2 particles,reducing the utilization ratio of magnesium hydroxide.Meanwhile,high CO3^2– ion concentration limits the dissolution of MgCO3 to absorb CO2 continually.Concentration of 0.05 mol/L Mg(OH)2,15%vol CO2 gas and operation temperature at 35℃are recommended for this CO2 capture system.展开更多
Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface ...Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface with interaction high speed wire electrode discharge machining (HS-WEDM). The other was the ramification of MCAS, named micro-column-array and sintered-copper compound structure (MSCS), which was fabricated with sintered method on micro-column array structure. Considering the wall superheat and critical heat flux (CHF), comparisons were made between them. The results show that both MCAS and MSCS can enhance the boiling heat transfer. It is also found that the enhanced boiling heat transfer ability of MSCS is changed obviously while the porosity of the sintered copper layer is changed.展开更多
Bubble dispersion greatly relies on spargers. Single or ifice and porous spargers were tested inside a bubble column under a low gas thr oughput to study their influences on gas dispersion and gas-liquid interface ar ...Bubble dispersion greatly relies on spargers. Single or ifice and porous spargers were tested inside a bubble column under a low gas thr oughput to study their influences on gas dispersion and gas-liquid interface ar ea. A PBE model without considering the effect of bubble coalescence was develo ped to describe axial bubble distribution. Both simulation and experimental res ults showed that bubbles broke up much faster than coalesced under low gas veloc ity. For a single orifice sparger, breakage was a dominant feature for bubbles after they left the orifice. Initial bubbles formed over the orifice were mostl y larger than the largest stable bubble. They broke up quickly and their sizes were reduced below the maximum diameter d_s of stable bubbles. In contrast , a porous sparger produced a large amount of initial bubbles smaller than the l argest stable bubble. The bubbles possessed smaller size and narrower distribut ion compared with the bubbles obtained by single orifice spargers. With the por ous sparger, gas-liquid surface area was increased by 5—6 times even though th e gas holdup changed insignificantly. High mass transfer area could be obtained by injecting more small initial bubbles with diameters under d_s.展开更多
基金Project(21878338)supported by the National Natural Science Foundation of ChinaProject(2015BAL04B02)supported by the National key Technology R&D Program of China+1 种基金Project(2018K2038)supported by the key Research and Development Project of Hunan Province,ChinaProject supported by Hunan Collaborative Innovation Center of Building Energy Conservation&Environmental Control,China
文摘Magnesium hydroxide(Mg(OH)2)has been considered as a potential solvent for CO2 removal of coal-fired power plant and biomass gas.The chemistry action and mass to transfer mechanism of CO2-H2O-Mg(OH)2 system in a slurry bubble column reactor was described,and a reliable computational model was developed.The overall mass transfer coefficient and surface area per unit volume were obtained using experimental approach and simulation with software assistance.The results show that the mass transfer process of CO2 absorbed by Mg(OH)2 slurry is mainly liquid-controlled,and slurry concentration and temperature are main contributory factors of volumetric mass transfer coefficient and liquid side mass transfer coefficient.High concentration of CO2 has an adverse effect on its absorption because it leads to the fast deposition of MgCO3·3H2O crystals on the surfaces of unreacted Mg(OH)2 particles,reducing the utilization ratio of magnesium hydroxide.Meanwhile,high CO3^2– ion concentration limits the dissolution of MgCO3 to absorb CO2 continually.Concentration of 0.05 mol/L Mg(OH)2,15%vol CO2 gas and operation temperature at 35℃are recommended for this CO2 capture system.
基金Projects(50605023 50436010) supported by the National Natural Science Foundation of China
文摘Enhanced boiling experiments of two different enhanced structures were carried out in a thermosyphon loop evaporator chamber. One was micro-columns array structure (MCAS), which was fabricated on copper plate surface with interaction high speed wire electrode discharge machining (HS-WEDM). The other was the ramification of MCAS, named micro-column-array and sintered-copper compound structure (MSCS), which was fabricated with sintered method on micro-column array structure. Considering the wall superheat and critical heat flux (CHF), comparisons were made between them. The results show that both MCAS and MSCS can enhance the boiling heat transfer. It is also found that the enhanced boiling heat transfer ability of MSCS is changed obviously while the porosity of the sintered copper layer is changed.
文摘Bubble dispersion greatly relies on spargers. Single or ifice and porous spargers were tested inside a bubble column under a low gas thr oughput to study their influences on gas dispersion and gas-liquid interface ar ea. A PBE model without considering the effect of bubble coalescence was develo ped to describe axial bubble distribution. Both simulation and experimental res ults showed that bubbles broke up much faster than coalesced under low gas veloc ity. For a single orifice sparger, breakage was a dominant feature for bubbles after they left the orifice. Initial bubbles formed over the orifice were mostl y larger than the largest stable bubble. They broke up quickly and their sizes were reduced below the maximum diameter d_s of stable bubbles. In contrast , a porous sparger produced a large amount of initial bubbles smaller than the l argest stable bubble. The bubbles possessed smaller size and narrower distribut ion compared with the bubbles obtained by single orifice spargers. With the por ous sparger, gas-liquid surface area was increased by 5—6 times even though th e gas holdup changed insignificantly. High mass transfer area could be obtained by injecting more small initial bubbles with diameters under d_s.
