The dynamic behaviors of water contained in calcium-silicate-hydrate(C-S-H) gel with different water content values from 10%to 30%(by weight),are studied by using an empirical diffusion model(EDM) to analyze the...The dynamic behaviors of water contained in calcium-silicate-hydrate(C-S-H) gel with different water content values from 10%to 30%(by weight),are studied by using an empirical diffusion model(EDM) to analyze the experimental data of quasi-elastic neutron scattering(QENS) spectra at measured temperatures ranging from 230 K to 280 K.In the study,the experimental QENS spectra with the whole Q-range are considered.Several important parameters including the bound/immobile water elastic coefficient A,the bound water index BWI,the Lorentzian with a half-width at half-maximum(HWHM) Γ;(Q) and Γ;(Q),the self-diffusion coefficients D;and D;of water molecules,the average residence times τ;and τ;,and the proton mean squared displacement(MSD)(u;) are obtained.The results show that the QENS spectra can be fitted very well not only for small Q(≤1 A;) but also for large Q.The bound/immobile water fraction in a C-S-H gel sample can be shown by the fitted BWI.The distinction between bound/immobile and mobile water,which includes confined water and ultra-confined water,can be seen by the fitted MSD.All the MSD tend to be the smallest value below 0.25 A;(the MSD of bound/immobile water) as the Q increases to 1.9 A;no matter what the temperature and water content are.Furthermore,by the abrupt changes of the fitted values of D;,τ;,and Γ;(Q),a crossover temperature at 250 K,namely the liquid-to-crystal-like transition temperature,can be identified for confined water in large gel pores(LGPs) and/or small gel pores(SGPs) contained in the C-S-H gel sample with 30% water content.展开更多
This paper is concerned with the inverse problem of scattering of time-harmonic acoustic waves by an inhomogeneous penetrable obstacle in a piecewise homogeneous medium. The well-posedness of the direct problem is fir...This paper is concerned with the inverse problem of scattering of time-harmonic acoustic waves by an inhomogeneous penetrable obstacle in a piecewise homogeneous medium. The well-posedness of the direct problem is first established by using the integral equation method. We then proceed to establish two tools that play important roles for the inverse problem: one is a mixed reciprocity relation and the other is a priori estimates of the solution on some part of the interfaces between the layered media. For the inverse problem, we prove in this paper that both the penetrable interfaces and the possible inside inhomogeneity can be uniquely determined from a knowledge of the far field pattern for incident plane waves.展开更多
The scattering of oblique incident surface waves by the edge of a small cylindrical deformation on a porous bed in an ocean of finite depth, is investigated here within the framework of linearized water wave theory. U...The scattering of oblique incident surface waves by the edge of a small cylindrical deformation on a porous bed in an ocean of finite depth, is investigated here within the framework of linearized water wave theory. Using perturbation analysis, the corresponding problem governed by modified Helmholtz equation is reduced to a boundary value problem for the first-order correction of the potential function. The first-order potential and, hence, the reflection and transmission coefficients are obtained by a method based on Green's integral theorem with the introduction of appropriate Green's function. Consideration of a patch of sinusoidal ripples shows that when the quotient of twice the component of the incident field wave number along x-direction and the ripple wave number approaches one, the theory predicts a resonant interaction between the bed and the free-surface, and the reflection coefficient becomes a multiple of the number of ripples. Again, for small angles of incidence, the reflected energy is more as compared to the other angles of incidence. It is also observed that the reflected energy is somewhat sensitive to the changes in the porosity of the ocean bed. From the derived results, the solutions for problems with impermeable ocean bed can be obtained as particular cases.展开更多
The present study deals with the scattering of oblique surface water waves by small undulation on the bottom in the presence of a thin vertical barrier. Here, three different configurations of vertical barriers are in...The present study deals with the scattering of oblique surface water waves by small undulation on the bottom in the presence of a thin vertical barrier. Here, three different configurations of vertical barriers are investigated. Perturbation analysis is employed to determine the physical quantities, namely, the reflection and transmission coefficients. In this analysis, many different Boundary Value Problems (BVPs) are obtained out of which the first two bvps are considered. The zeroth order bvp is solved with the aid of eigenfunction expansion method. The first order reflection and transmission coefficients are derived in terms of the integrals by the method of the Green's integral theorem. The variation of these coefficients is plotted and analyzed for different physical parameters. Furthermore, the energy balance relation, an important relation in the study of water wave scattering, is derived and checked for assuring the correctness of the numerical results for the present problem.展开更多
The scattering characteristics of the periodic surface of infinite and finite media are investigated in detail.The Fourier expression of the scattering field of the periodic surface is obtained in terms of Huygens’ s...The scattering characteristics of the periodic surface of infinite and finite media are investigated in detail.The Fourier expression of the scattering field of the periodic surface is obtained in terms of Huygens’ s principle and Floquet’s theorem.Using the extended boundary condition method(EBCM) and T-matrix method, the scattering amplitude factor is solved,and the correctness of the algorithm is verified by use of the law of conservation of energy.The scattering cross section of the periodic surface in the infinitely long region is derived by improving the scattering cross section of the finite period surface.Furthermore, the effects of the incident wave parameters and the geometric structure parameters on the scattering of the periodic surface are analyzed and discussed.By reasonable approximation, the scattering calculation methods of infinite and finite long surfaces are unified.Besides, numerical results show that the dielectric constant of the periodic dielectric surface has a significant effect on the scattering rate and transmittance.The period and amplitude of the surface determine the number of scattering intensity peaks, and, together with the incident angle, influence the scattering intensity distribution.展开更多
The elastic scattering properties in a mixture of sodium and cesium atoms are investigated at cold and ultracold temperatures. Based on the accurate interatomic potential for the NaCs mixture, the interspecies s-wave ...The elastic scattering properties in a mixture of sodium and cesium atoms are investigated at cold and ultracold temperatures. Based on the accurate interatomic potential for the NaCs mixture, the interspecies s-wave scattering lengths, the effective ranges and the p-wave scattering lengths are calculated by the quantal method and the semiclassical method, respectively. The s-wave scattering lengths are 512.7a0 for the singlet state and 33.4a0 for the triplet state. In addition, the spin-change and elastic cross sections are also calculated, and the g-wave shape resonance is found in the total elastic cross sections.展开更多
The solution of water wave scattering problem involving small deformation on a porous bed in a channel, where the upper surface is bounded above by an infinitely extent rigid horizontal surface, is studied here within...The solution of water wave scattering problem involving small deformation on a porous bed in a channel, where the upper surface is bounded above by an infinitely extent rigid horizontal surface, is studied here within the framework of linearized water wave theory. In such a situation, there exists only one mode of waves propagating on the porous surface. A simplified perturbation analysis, involving a small parameter ε (≤1) , which measures the smallness of the deformation, is employed to reduce the governing Boundary Value Problem (BVP) to a simpler BVP for the first-order correction of the potential function. The first-order potential function and, hence, the first-order reflection and transmission coefficients are obtained by the method based on Fourier transform technique as well as Green's integral theorem with the introduction of appropriate Green's function. Two special examples of bottom deformation: the exponentially damped deformation and the sinusoidal ripple bed, are considered to validate the results. For the particular example of a patch of sinusoidal ripples, the resonant interaction between the bed and the upper surface of the fluid is attained in the neighborhood of a singularity, when the ripples wavenumbers of the bottom deformation become approximately twice the components of the incident field wavenumber along the positive x -direction. Also, the main advantage of the present study is that the results for the values of reflection and transmission coefficients are found to satisfy the energy-balance relation almost accurately.展开更多
文摘The dynamic behaviors of water contained in calcium-silicate-hydrate(C-S-H) gel with different water content values from 10%to 30%(by weight),are studied by using an empirical diffusion model(EDM) to analyze the experimental data of quasi-elastic neutron scattering(QENS) spectra at measured temperatures ranging from 230 K to 280 K.In the study,the experimental QENS spectra with the whole Q-range are considered.Several important parameters including the bound/immobile water elastic coefficient A,the bound water index BWI,the Lorentzian with a half-width at half-maximum(HWHM) Γ;(Q) and Γ;(Q),the self-diffusion coefficients D;and D;of water molecules,the average residence times τ;and τ;,and the proton mean squared displacement(MSD)(u;) are obtained.The results show that the QENS spectra can be fitted very well not only for small Q(≤1 A;) but also for large Q.The bound/immobile water fraction in a C-S-H gel sample can be shown by the fitted BWI.The distinction between bound/immobile and mobile water,which includes confined water and ultra-confined water,can be seen by the fitted MSD.All the MSD tend to be the smallest value below 0.25 A;(the MSD of bound/immobile water) as the Q increases to 1.9 A;no matter what the temperature and water content are.Furthermore,by the abrupt changes of the fitted values of D;,τ;,and Γ;(Q),a crossover temperature at 250 K,namely the liquid-to-crystal-like transition temperature,can be identified for confined water in large gel pores(LGPs) and/or small gel pores(SGPs) contained in the C-S-H gel sample with 30% water content.
基金the first author (XL) was supported by the China Postdoctoral Science Foundation (20100480494)the NSF of China (11101412)+1 种基金K.C. Wong Education Foundation, Hong Kongthe second author (BZ) was supported by the NSF of China (11071244,11161130002)
文摘This paper is concerned with the inverse problem of scattering of time-harmonic acoustic waves by an inhomogeneous penetrable obstacle in a piecewise homogeneous medium. The well-posedness of the direct problem is first established by using the integral equation method. We then proceed to establish two tools that play important roles for the inverse problem: one is a mixed reciprocity relation and the other is a priori estimates of the solution on some part of the interfaces between the layered media. For the inverse problem, we prove in this paper that both the penetrable interfaces and the possible inside inhomogeneity can be uniquely determined from a knowledge of the far field pattern for incident plane waves.
基金partially supported by a research grant from Department of Science and Technology(DST),India(No.SB/FTP/MS-003/2013)
文摘The scattering of oblique incident surface waves by the edge of a small cylindrical deformation on a porous bed in an ocean of finite depth, is investigated here within the framework of linearized water wave theory. Using perturbation analysis, the corresponding problem governed by modified Helmholtz equation is reduced to a boundary value problem for the first-order correction of the potential function. The first-order potential and, hence, the reflection and transmission coefficients are obtained by a method based on Green's integral theorem with the introduction of appropriate Green's function. Consideration of a patch of sinusoidal ripples shows that when the quotient of twice the component of the incident field wave number along x-direction and the ripple wave number approaches one, the theory predicts a resonant interaction between the bed and the free-surface, and the reflection coefficient becomes a multiple of the number of ripples. Again, for small angles of incidence, the reflected energy is more as compared to the other angles of incidence. It is also observed that the reflected energy is somewhat sensitive to the changes in the porosity of the ocean bed. From the derived results, the solutions for problems with impermeable ocean bed can be obtained as particular cases.
基金Supported by SERB-DST Grant(No.SB/FTP/MS-034/2013)
文摘The present study deals with the scattering of oblique surface water waves by small undulation on the bottom in the presence of a thin vertical barrier. Here, three different configurations of vertical barriers are investigated. Perturbation analysis is employed to determine the physical quantities, namely, the reflection and transmission coefficients. In this analysis, many different Boundary Value Problems (BVPs) are obtained out of which the first two bvps are considered. The zeroth order bvp is solved with the aid of eigenfunction expansion method. The first order reflection and transmission coefficients are derived in terms of the integrals by the method of the Green's integral theorem. The variation of these coefficients is plotted and analyzed for different physical parameters. Furthermore, the energy balance relation, an important relation in the study of water wave scattering, is derived and checked for assuring the correctness of the numerical results for the present problem.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.61571355,61801349,and 61601355)
文摘The scattering characteristics of the periodic surface of infinite and finite media are investigated in detail.The Fourier expression of the scattering field of the periodic surface is obtained in terms of Huygens’ s principle and Floquet’s theorem.Using the extended boundary condition method(EBCM) and T-matrix method, the scattering amplitude factor is solved,and the correctness of the algorithm is verified by use of the law of conservation of energy.The scattering cross section of the periodic surface in the infinitely long region is derived by improving the scattering cross section of the finite period surface.Furthermore, the effects of the incident wave parameters and the geometric structure parameters on the scattering of the periodic surface are analyzed and discussed.By reasonable approximation, the scattering calculation methods of infinite and finite long surfaces are unified.Besides, numerical results show that the dielectric constant of the periodic dielectric surface has a significant effect on the scattering rate and transmittance.The period and amplitude of the surface determine the number of scattering intensity peaks, and, together with the incident angle, influence the scattering intensity distribution.
基金Project supported by the National Natural Science Foundation of China (Grant No.10874064)the National Science Foundation of Henan Province,China (Grant No.2011A140017)the Youth Foundation of Henan Normal University,China (Grant No.2010qk03)
文摘The elastic scattering properties in a mixture of sodium and cesium atoms are investigated at cold and ultracold temperatures. Based on the accurate interatomic potential for the NaCs mixture, the interspecies s-wave scattering lengths, the effective ranges and the p-wave scattering lengths are calculated by the quantal method and the semiclassical method, respectively. The s-wave scattering lengths are 512.7a0 for the singlet state and 33.4a0 for the triplet state. In addition, the spin-change and elastic cross sections are also calculated, and the g-wave shape resonance is found in the total elastic cross sections.
基金Partially supported by a research grant from Department of Science and Technology(DST),India(No.SB/FTP/MS-003/2013)
文摘The solution of water wave scattering problem involving small deformation on a porous bed in a channel, where the upper surface is bounded above by an infinitely extent rigid horizontal surface, is studied here within the framework of linearized water wave theory. In such a situation, there exists only one mode of waves propagating on the porous surface. A simplified perturbation analysis, involving a small parameter ε (≤1) , which measures the smallness of the deformation, is employed to reduce the governing Boundary Value Problem (BVP) to a simpler BVP for the first-order correction of the potential function. The first-order potential function and, hence, the first-order reflection and transmission coefficients are obtained by the method based on Fourier transform technique as well as Green's integral theorem with the introduction of appropriate Green's function. Two special examples of bottom deformation: the exponentially damped deformation and the sinusoidal ripple bed, are considered to validate the results. For the particular example of a patch of sinusoidal ripples, the resonant interaction between the bed and the upper surface of the fluid is attained in the neighborhood of a singularity, when the ripples wavenumbers of the bottom deformation become approximately twice the components of the incident field wavenumber along the positive x -direction. Also, the main advantage of the present study is that the results for the values of reflection and transmission coefficients are found to satisfy the energy-balance relation almost accurately.