The selective reduction of carbon dioxide(CO_(2))into high-value-added chemicals is one of the most effective means to solve the current energy and environmental problems,which could realize the utilization of CO_(2) ...The selective reduction of carbon dioxide(CO_(2))into high-value-added chemicals is one of the most effective means to solve the current energy and environmental problems,which could realize the utilization of CO_(2) and promote the balance of the carbon cycle.Formate is one of the most economical and practical products of all the electrochemical CO_(2) reduction products.Among the many metal-based electrocatalysts that can convert CO_(2) into formate,Sn-based catalysts have received a lot of attention because of their low-cost,non-toxic characteristics and high selectivity for formate.In this article,the most recent development of Sn-based electrocatalysts is comprehensively summarized by giving examples,which are mainly divided into monometallic Sn,alloyed Sn,Sn-based compounds and Sn composite catalysts.Finally,the current performance enhancement strategies and future directions of the field are summarized.展开更多
Deep geothermal extraction processes expose rock masses to frequent and significant temperature fluctuations. Developing a comprehensive understanding of the shear fracture mechanisms and crack propagation behaviors i...Deep geothermal extraction processes expose rock masses to frequent and significant temperature fluctuations. Developing a comprehensive understanding of the shear fracture mechanisms and crack propagation behaviors in rocks under the influence of cyclic heating is imperative for optimizing geothermal energy extraction. This study encompasses several critical aspects under cyclic heating conditions, including the assessment of stress distribution states, the characterization of two-dimensional fracture paths, the quantitative analysis of three-dimensional damage characteristics on fracture surfaces, and the determination of the fractal dimension of debris generated after the failure of granite. The test results demonstrate that cyclic heating has a pronounced adverse effect on the physical and mechanical properties of granite. Consequently, stress tends to develop and propagate in a direction perpendicular to the two-dimensional fracture path. This leads to an increase in the extent of tensile damage on the fracture surface and accelerates the overall rock failure process. This increases the number of small-sized debris, raises the fractal dimension, and enhances the rock’s rupture degree. In practical enhanced geothermal energy extraction, the real-time monitoring of fracture propagation within the reservoir rock mass is achieved through the analysis of rock debris generated during the staged fracturing process.展开更多
基金Project(52204378)supported by the National Natural Science Foundation of China。
文摘The selective reduction of carbon dioxide(CO_(2))into high-value-added chemicals is one of the most effective means to solve the current energy and environmental problems,which could realize the utilization of CO_(2) and promote the balance of the carbon cycle.Formate is one of the most economical and practical products of all the electrochemical CO_(2) reduction products.Among the many metal-based electrocatalysts that can convert CO_(2) into formate,Sn-based catalysts have received a lot of attention because of their low-cost,non-toxic characteristics and high selectivity for formate.In this article,the most recent development of Sn-based electrocatalysts is comprehensively summarized by giving examples,which are mainly divided into monometallic Sn,alloyed Sn,Sn-based compounds and Sn composite catalysts.Finally,the current performance enhancement strategies and future directions of the field are summarized.
基金Project(52409132) supported by the National Natural Science Foundation of ChinaProject(ZR2024QE018) supported by the Natural Science Foundation of Shandong Province,China+2 种基金Project(BK20240431) supported by Basic Research Program of Jiangsu,ChinaProject(SNKJ2023A07-R14) supported by the Major Key Technical Research Projects of Shandong Energy Group,ChinaProject(2024M751813) supported by China Postdoctoral Science Foundation。
文摘Deep geothermal extraction processes expose rock masses to frequent and significant temperature fluctuations. Developing a comprehensive understanding of the shear fracture mechanisms and crack propagation behaviors in rocks under the influence of cyclic heating is imperative for optimizing geothermal energy extraction. This study encompasses several critical aspects under cyclic heating conditions, including the assessment of stress distribution states, the characterization of two-dimensional fracture paths, the quantitative analysis of three-dimensional damage characteristics on fracture surfaces, and the determination of the fractal dimension of debris generated after the failure of granite. The test results demonstrate that cyclic heating has a pronounced adverse effect on the physical and mechanical properties of granite. Consequently, stress tends to develop and propagate in a direction perpendicular to the two-dimensional fracture path. This leads to an increase in the extent of tensile damage on the fracture surface and accelerates the overall rock failure process. This increases the number of small-sized debris, raises the fractal dimension, and enhances the rock’s rupture degree. In practical enhanced geothermal energy extraction, the real-time monitoring of fracture propagation within the reservoir rock mass is achieved through the analysis of rock debris generated during the staged fracturing process.
基金现代农业产业技术体系建设专项资金项目(nycytx-49-18)农业行业专项资金项目(200803013)+3 种基金科技部农业科技成果转化资金项目(2008GB23260402)中央级公益性科研院所基本科研专项资金项目(2007JBFB11)International Foundation for ScienceIFS(A/4396)
