Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometri...Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.展开更多
首次利用CiteSpace文献计量分析软件对Web of Science中2003—2023年高温结构材料用Laves相研究文献的关键词、文献共被引、作者和期刊共被引进行了定量和可视化网络图谱分析。关键词聚类时间线图反映了检索区间内Laves相研究的基本发...首次利用CiteSpace文献计量分析软件对Web of Science中2003—2023年高温结构材料用Laves相研究文献的关键词、文献共被引、作者和期刊共被引进行了定量和可视化网络图谱分析。关键词聚类时间线图反映了检索区间内Laves相研究的基本发展状况,揭示两大热点前沿主题分别是Laves相增强的多相高熵合金的室温脆性改善或强度-塑性协同提升问题,以及Laves相析出物对600~650℃蠕变服役条件下P92、12Cr和G115等新型耐热合金钢组织与性能的影响。关键词聚类时间线图与文献、作者共被引网络图具备一致性,共同反映Laves相研究的活跃性。未来,应关注可视化图谱挖掘的高质量成果产出的关键作者和期刊。展开更多
基金supported by the National Natural Science Foundation(22279036)the Innovation and Talent Recruitment Base of New Energy Chemistry and Device(B21003).
文摘Alloying transition metals with Pt is an effective strategy for optimizing Pt-based catalysts toward the oxygen reduction reaction(ORR).Atomic ordered intermetallic compounds(IMC)provide unique electronic and geometrical effects as well as stronger intermetallic interactions due to the ordered arrangement of metal atoms,thus exhibiting superior electrocata-lytic activity and durability.However,quantitatively analyzing the ordering degree of IMC and exploring the correlation between the ordering degree and ORR activity remains extremely challenging.Herein,a series of ternary Pt_(2)NiCo interme-tallic catalysts(o-Pt_(2)NiCo)with different ordering degree were synthesized by annealing temperature modulation.Among them,the o-Pt_(2)NiCo which annealed at 800℃for two hours exhibits the highest ordering degree and the optimal ORR ac-tivity,which the mass activity of o-Pt_(2)NiCo is 1.8 times and 2.8 times higher than that of disordered Pt_(2)NiCo alloy and Pt/C.Furthermore,the o-Pt_(2)NiCo still maintains 70.8%mass activity after 30,000 potential cycles.Additionally,the ORR activity test results for Pt_(2)NiCo IMC with different ordering degree also provide a positive correlation between the ordering degree and ORR activity.This work provides a prospective design direction for ternary Pt-based electrocatalysts.
文摘首次利用CiteSpace文献计量分析软件对Web of Science中2003—2023年高温结构材料用Laves相研究文献的关键词、文献共被引、作者和期刊共被引进行了定量和可视化网络图谱分析。关键词聚类时间线图反映了检索区间内Laves相研究的基本发展状况,揭示两大热点前沿主题分别是Laves相增强的多相高熵合金的室温脆性改善或强度-塑性协同提升问题,以及Laves相析出物对600~650℃蠕变服役条件下P92、12Cr和G115等新型耐热合金钢组织与性能的影响。关键词聚类时间线图与文献、作者共被引网络图具备一致性,共同反映Laves相研究的活跃性。未来,应关注可视化图谱挖掘的高质量成果产出的关键作者和期刊。
