Dear Editor,Timely and effective hemostasis is of great significance for reducing body damage and mortality of patients [1]. Alginate is generally considered to be an excellent hemostatic polymer-based biomaterial and...Dear Editor,Timely and effective hemostasis is of great significance for reducing body damage and mortality of patients [1]. Alginate is generally considered to be an excellent hemostatic polymer-based biomaterial and has been approved by the Food and Drug Administration as Generally Recognized as Safe [2]. However, the violent crosslinking reaction and unstable structure at the wound site limit its clinical applications. Hence, we report a biocompatible and injectable composite hydrogel methacrylate alginate (Alg-AEMA)-based Eosin Y/N-phenylglycine (NPG)-initiated composite hydrogel (AEC) composed of photocrosslinkable alginate, viscosity modifiers and novel white light photoinitiator, namely Eosin Y/NPG system, for instant hemorrhage control.展开更多
A new polyvinylalcohol-based photopolymeric holographic recording material has been developed. The recording is obtained by the copolymerization of acrylamide and N-hydroxymethyl acrylamide. Diffraction efficiencies n...A new polyvinylalcohol-based photopolymeric holographic recording material has been developed. The recording is obtained by the copolymerization of acrylamide and N-hydroxymethyl acrylamide. Diffraction efficiencies near 50% are obtained with energetic exposure of 80mJ/cm^2. N-hydroxymethyl acrylamide can improve the optical quality of the film. With the increase of the concentration of N-hydroxymethyl acrylamide, the flatness of the film increases, scattering reduces and the straight image is clearer with a small distortion. The postexposure effect on the grating is also studied. The diffraction efficiency of grating increases further during postexposure, gradient of monomer exists after exposure.展开更多
In this paper, we experimentally investigate the dark diffusional enhancement of the optimized multiplexed grating in the phenanthrenequinone doped poly （methyl methacrylate） （PQ-PMMA） photopolymer. The possibilit...In this paper, we experimentally investigate the dark diffusional enhancement of the optimized multiplexed grating in the phenanthrenequinone doped poly （methyl methacrylate） （PQ-PMMA） photopolymer. The possibility of improving the holographic characteristics of the material through the dark enhancement is demonstrated. The optimal preillumination exposure and the optimal time interval between exposures are extracted to obtain the optimized diffraction efficiency, and their values are 3.4×103 mJ/cm2 and 2 min, respectively. The dark enhancement of the multiplexed grating is presented as an effective method to improve the response region and the dynamic range and to prevent saturation of the material. The dependence of the phenanthrenequinone concentration on the increment of the refractive index modulation is quantitatively studied, which provides a significant basis for improving the homogeneity in the multiplexed gratings using a quantitative strategy. Finally, a simple experimental procedure using the dark enhancement is introduced to improve the homogeneity of the diffraction efficiency and to avoid the complex schedule exposure.展开更多
We present holographic storage of three-dimensional（3D） images and data in a photopolymer film without any applied electric field.Its absorption and diffraction efficiency are measured,and reflective analog hologram...We present holographic storage of three-dimensional（3D） images and data in a photopolymer film without any applied electric field.Its absorption and diffraction efficiency are measured,and reflective analog hologram of real object and image of digital information are recorded in the films.The photopolymer is compared with polymer dispersed liquid crystals as holographic materials.Besides holographic diffraction efficiency of the former is little lower than that of the latter,this work demonstrates that the photopolymer is more suitable for analog hologram and big data permanent storage because of its high definition and no need of high voltage electric field.Therefore,our study proposes a potential holographic storage material to apply in large size static 3D holographic displays,including analog hologram displays,digital hologram prints,and holographic disks.展开更多
In this work, a dual-side parabolic structural(DSPS) multimode interference(MMI) thermo–optic(TO) waveguide switch is designed and fabricated by using novel low-loss fluorinated photopolymer materials. Comparing with...In this work, a dual-side parabolic structural(DSPS) multimode interference(MMI) thermo–optic(TO) waveguide switch is designed and fabricated by using novel low-loss fluorinated photopolymer materials. Comparing with the traditional dual-side linear structural(DSLS) MMI device, the effective length of the MMI coupling region proposed can be effectively reduced by 40%. The thermal stability of the waveguide material is analyzed, and the optical characteristics of the switching chip are simulated. The actual performances of the entire MMI switch are measured with an insertion loss of7 dB, switching power of 15 m W and an extinction ratio of 28 dB. In contrast to the traditional MMI optical switch, the new type of parabolic structural MMI TO waveguide switch exhibits lower power consumption and larger extinction ratio. The compact fluorinated polymer MMI TO switches are suitable well for realizing miniaturization, high-properties, and lower cost of photonic integrated circuits.展开更多
A dynamic theoretical model of photochemistry and hologram formation in holographic photopolymer is established, and the dynamic development process of holographic gratings in the photopolymer is discussed with the mo...A dynamic theoretical model of photochemistry and hologram formation in holographic photopolymer is established, and the dynamic development process of holographic gratings in the photopolymer is discussed with the model. A novel multi-wavelength visible light sensitive photopolymer for holographic storage is prepared. The influence of exposure wavelength on holographic storage characteristics is analysed. By fitting the experimental data of transmittance and diffraction efficiency to a function of time with different exposure intensities and wavelengths, the variations of dynamic parameters of photochemistry and photopolymerization diffusion are presented.展开更多
Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield...Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence： Triethanolamine （TEA）〉 Diethanolamine （DEA）〉 Ethanolamine （EA）〉 Triethylamine （TETN）〉 Diethylamine （DETN）. The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26／%, sensitivity is 1.72／times 10^{ - 3}~cm^{2}/mJ, and the maximum refractive modulation index is 4.64／times 10^{ - 4}.展开更多
基金National Key Research and Development Program(2022YFA1104604,2017YFC1103303)Science Fund for National Defense Distinguished Young Scholars(2022-JCJQ-ZQ-016)+2 种基金National Nature Science Foundation of China(32000969,82002056,92268206)Military Medical Research Projects(145AKJ260015000X,2022-JCJQ-ZD-096-00)Key Support Program for Growth Factor Research(SZYZ-TR-03).
文摘Dear Editor,Timely and effective hemostasis is of great significance for reducing body damage and mortality of patients [1]. Alginate is generally considered to be an excellent hemostatic polymer-based biomaterial and has been approved by the Food and Drug Administration as Generally Recognized as Safe [2]. However, the violent crosslinking reaction and unstable structure at the wound site limit its clinical applications. Hence, we report a biocompatible and injectable composite hydrogel methacrylate alginate (Alg-AEMA)-based Eosin Y/N-phenylglycine (NPG)-initiated composite hydrogel (AEC) composed of photocrosslinkable alginate, viscosity modifiers and novel white light photoinitiator, namely Eosin Y/NPG system, for instant hemorrhage control.
文摘A new polyvinylalcohol-based photopolymeric holographic recording material has been developed. The recording is obtained by the copolymerization of acrylamide and N-hydroxymethyl acrylamide. Diffraction efficiencies near 50% are obtained with energetic exposure of 80mJ/cm^2. N-hydroxymethyl acrylamide can improve the optical quality of the film. With the increase of the concentration of N-hydroxymethyl acrylamide, the flatness of the film increases, scattering reduces and the straight image is clearer with a small distortion. The postexposure effect on the grating is also studied. The diffraction efficiency of grating increases further during postexposure, gradient of monomer exists after exposure.
基金supported by the National Basic Research Program of China(Grant No.2007CB3070001)the Fundamental Research Funds for the Central Universities,China(Grant No.HIT.NSRIF.2010009)+1 种基金the Program of Excellent Team in Harbin Institute of Technology,Chinathe Research Startup Foundation of Civil Aviation University of China(Grant No.2010QN03X)
文摘In this paper, we experimentally investigate the dark diffusional enhancement of the optimized multiplexed grating in the phenanthrenequinone doped poly （methyl methacrylate） （PQ-PMMA） photopolymer. The possibility of improving the holographic characteristics of the material through the dark enhancement is demonstrated. The optimal preillumination exposure and the optimal time interval between exposures are extracted to obtain the optimized diffraction efficiency, and their values are 3.4×103 mJ/cm2 and 2 min, respectively. The dark enhancement of the multiplexed grating is presented as an effective method to improve the response region and the dynamic range and to prevent saturation of the material. The dependence of the phenanthrenequinone concentration on the increment of the refractive index modulation is quantitatively studied, which provides a significant basis for improving the homogeneity in the multiplexed gratings using a quantitative strategy. Finally, a simple experimental procedure using the dark enhancement is introduced to improve the homogeneity of the diffraction efficiency and to avoid the complex schedule exposure.
基金Project supported by the National Natural Science Foundation of China(Grant Nos.11474194,11004037,and 61101176)the Natural Science Foundation of Shanghai,China(Grant No.14ZR1415500)
文摘We present holographic storage of three-dimensional（3D） images and data in a photopolymer film without any applied electric field.Its absorption and diffraction efficiency are measured,and reflective analog hologram of real object and image of digital information are recorded in the films.The photopolymer is compared with polymer dispersed liquid crystals as holographic materials.Besides holographic diffraction efficiency of the former is little lower than that of the latter,this work demonstrates that the photopolymer is more suitable for analog hologram and big data permanent storage because of its high definition and no need of high voltage electric field.Therefore,our study proposes a potential holographic storage material to apply in large size static 3D holographic displays,including analog hologram displays,digital hologram prints,and holographic disks.
基金Project supported by the National Key Research and Development Program of China(Grant No.2016YFB0402502)the National Natural Science Foundation of China(Grant Nos.61575076,61475061,61605057,and 61675087)the Jilin Provincial Industrial Innovation Special Fund Project,China(Grant No.2016C019)
文摘In this work, a dual-side parabolic structural(DSPS) multimode interference(MMI) thermo–optic(TO) waveguide switch is designed and fabricated by using novel low-loss fluorinated photopolymer materials. Comparing with the traditional dual-side linear structural(DSLS) MMI device, the effective length of the MMI coupling region proposed can be effectively reduced by 40%. The thermal stability of the waveguide material is analyzed, and the optical characteristics of the switching chip are simulated. The actual performances of the entire MMI switch are measured with an insertion loss of7 dB, switching power of 15 m W and an extinction ratio of 28 dB. In contrast to the traditional MMI optical switch, the new type of parabolic structural MMI TO waveguide switch exhibits lower power consumption and larger extinction ratio. The compact fluorinated polymer MMI TO switches are suitable well for realizing miniaturization, high-properties, and lower cost of photonic integrated circuits.
基金Project supported by the Natural Science Foundation of Henan University, China (Grant No. 06ZDZR002)
文摘A dynamic theoretical model of photochemistry and hologram formation in holographic photopolymer is established, and the dynamic development process of holographic gratings in the photopolymer is discussed with the model. A novel multi-wavelength visible light sensitive photopolymer for holographic storage is prepared. The influence of exposure wavelength on holographic storage characteristics is analysed. By fitting the experimental data of transmittance and diffraction efficiency to a function of time with different exposure intensities and wavelengths, the variations of dynamic parameters of photochemistry and photopolymerization diffusion are presented.
基金supported by the Natural Science Foundation of Henan University, China (Grant No. 06ZDZR002)
文摘Holographic parameters and photobleaching kinetics of the photopolymers with five different amine photoinitiators are studied. The maximum values of diffraction efficiency, photobleaching coefficient and quantum yield follow the sequence： Triethanolamine （TEA）〉 Diethanolamine （DEA）〉 Ethanolamine （EA）〉 Triethylamine （TETN）〉 Diethylamine （DETN）. The holographic capabilities of photopolymer performances are determined by the number of functional groups in the amine molecular structure. There is an optimum proportion of the photoinitiator, the photosensitizer and the monomer in the test of holographic parameters with different amine concentrations. The maximum diffraction efficiency is 59.26／%, sensitivity is 1.72／times 10^{ - 3}~cm^{2}/mJ, and the maximum refractive modulation index is 4.64／times 10^{ - 4}.
