The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle dif...The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle diffraction method.The crystal belongs to triclinic,space group Pi,crystal cell parameters:a=9 009(2),b=10 437(2),c=18 858(4)?,α=80 99(3),β=88 55(3),γ=82 01(3)°,V=1734 3(6)? 3,Z=2,Mr=698 7,Dc=1 338g·cm -3 ,μ=1 022mm -1 ,F(000)=732,R=0 0342,Rw=0 0812.The structural analysis showed that six sulfur atoms from three ligands 〔S 2P(O- i -C 3H 7) 2〕 coordinate with a cobalt atom,CoS 6 framework in molecular stucture approximately octahedral.The complex was also characterized by IR? 1H NMR? 31 P NMR and MS.展开更多
Using over 3 500 first P arrival times recorded by nine digital seismic stations from Hainan Digital Seismic Net-work during 1999～2005,a 3-D P-wave velocity model of the crust under Hainan Island and adjacent regions...Using over 3 500 first P arrival times recorded by nine digital seismic stations from Hainan Digital Seismic Net-work during 1999～2005,a 3-D P-wave velocity model of the crust under Hainan Island and adjacent regions has been determined. The results show that the pattern of velocity anomalies in the shallower upper crust is somewhat associated with the surface geological tectonics in the region. A relative low-velocity anomaly appears north of the Wangwu-Wenjiao fault zone and a relative high-velocity anomaly appears south of the Wangwu-Wenjiao fault zone,corresponding to the depressed areas in north Hainan Island,where many volcanoes are frequently active and geothermal values are relatively higher,and the uplifted and stable regions in central and south of the Hainan Is-land. In the middle and lower crust velocities are relatively lower in east Hainan than those in west Hainan,possi-bly suggesting the existence of the upwelling of hot materials from the mantle in east Hainan. The pattern of veloc-ity anomalies also indicates that NW faults,i.e.,the Puqian-Qinglan fault,may be shallower,while the E-W Wangwu-Wenjiao fault may be deeper,which perhaps extends down to Moho depth or deeper.展开更多
文摘The Complex Co〔S 2P(O- i -C 3H 7) 2〕 3 was synthesized through the reaction of Co 2(CO) 8 with the ligand (C 3H 7- i -O) 2P(S)S-SP(S)(O- i -C 3H 7) 2,and its crystal structure was determined by X-ray four -cycle diffraction method.The crystal belongs to triclinic,space group Pi,crystal cell parameters:a=9 009(2),b=10 437(2),c=18 858(4)?,α=80 99(3),β=88 55(3),γ=82 01(3)°,V=1734 3(6)? 3,Z=2,Mr=698 7,Dc=1 338g·cm -3 ,μ=1 022mm -1 ,F(000)=732,R=0 0342,Rw=0 0812.The structural analysis showed that six sulfur atoms from three ligands 〔S 2P(O- i -C 3H 7) 2〕 coordinate with a cobalt atom,CoS 6 framework in molecular stucture approximately octahedral.The complex was also characterized by IR? 1H NMR? 31 P NMR and MS.
基金The special project of Detection of Haikou City Earthquake Active Faults from the Tenth Five-year Plan of China Earthquake Administration (0106512)Joint Seismological Science Foundation of China (105086)CAS Key Laboratory of Marginal Sea Geology (MSGL0503).
文摘Using over 3 500 first P arrival times recorded by nine digital seismic stations from Hainan Digital Seismic Net-work during 1999～2005,a 3-D P-wave velocity model of the crust under Hainan Island and adjacent regions has been determined. The results show that the pattern of velocity anomalies in the shallower upper crust is somewhat associated with the surface geological tectonics in the region. A relative low-velocity anomaly appears north of the Wangwu-Wenjiao fault zone and a relative high-velocity anomaly appears south of the Wangwu-Wenjiao fault zone,corresponding to the depressed areas in north Hainan Island,where many volcanoes are frequently active and geothermal values are relatively higher,and the uplifted and stable regions in central and south of the Hainan Is-land. In the middle and lower crust velocities are relatively lower in east Hainan than those in west Hainan,possi-bly suggesting the existence of the upwelling of hot materials from the mantle in east Hainan. The pattern of veloc-ity anomalies also indicates that NW faults,i.e.,the Puqian-Qinglan fault,may be shallower,while the E-W Wangwu-Wenjiao fault may be deeper,which perhaps extends down to Moho depth or deeper.
