The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,inte...The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.展开更多
In order to improve the through-thickness homogeneity and properties of aviation aluminum alloy thick plate.The effect of heating-cooling retrogression and re-ageing on the performance of Al-8Zn-2Mg-2Cu alloy thick pl...In order to improve the through-thickness homogeneity and properties of aviation aluminum alloy thick plate.The effect of heating-cooling retrogression and re-ageing on the performance of Al-8Zn-2Mg-2Cu alloy thick plate was investigated by hardness tests, electrical conductivity tests and transmission electron microscopy(TEM) observation.Results revealed that, during retrogression heating, the fine pre-precipitates in surface layer dissolve more and the undissolved η′ or η phases are more coarsened than that of center layer. During slow cooling after retrogression,precipitates continue coarsening but with a lower rate and the secondary precipitation occurs in both layers. Finer precipitates resulting from the secondary precipitation are more in surface. However, the coarsening and secondary precipitation behaviors are restrained in both layers under quick cooling condition. The electrical conductivity and through-thickness homogeneity of precipitates increases while the hardness decreases with cooling rate decreasing. After the optimized non-isothermal retrogression and re-ageing(NRRA) including air-cooling retrogression, the throughthickness homogeneity which is evaluated by integrated retrogression effects has been improved to 94%. The tensile strength, fracture toughness and exfoliation corrosion grade of Al-8Zn-2Mg-2Cu alloy plate is 619 MPa, 24.7 MPa·m^(1/2)and EB, respectively, which indicates that the non-isothermal retrogression and re-aging(NRRA) could improve the mechanical properties and corrosion resistance with higher through-thickness homogeneity.展开更多
The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimet...The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.展开更多
The failure of AA3003 aluminum alloy sheet metal was predicted for non-isothermal viscous pressure bulging (VPB). Utilizing the coupled thermo-mechanical finite element method combined with ductile fracture criterion,...The failure of AA3003 aluminum alloy sheet metal was predicted for non-isothermal viscous pressure bulging (VPB). Utilizing the coupled thermo-mechanical finite element method combined with ductile fracture criterion, the calculations were carried out for non-isotherm VPB at various temperatures and the influences of the initial temperature of viscous medium on failure mode of bulge specimens were investigated. The results show that the failure modes are different for the non-isothermal VPB with different initial temperatures of viscous medium. For the non-isothermal VPB of AA3003 aluminum alloy sheet with initial temperature of 250 ℃, when the initial temperature of viscous medium ranges from 150 to 180 ℃, the formability of sheet metal can be improved to a full extent. The validity of the predictions is examined by comparing with experimental results.展开更多
The thermal decompositions of Ca-bentonites (CaB) from Santai ,Shichuan Province, China over the temperature rage of 30-1100℃ were investigated by simultaneous thermal analyzer. Non-isothermal Kinetic analysis were e...The thermal decompositions of Ca-bentonites (CaB) from Santai ,Shichuan Province, China over the temperature rage of 30-1100℃ were investigated by simultaneous thermal analyzer. Non-isothermal Kinetic analysis were employed to study the thermal decomposition mechanism by using Netzsch Thermokinetics software. The dependence of the activation energy on conversion degree were evaluated by isoconversional methods. The probably mechanism and the corresponding kinetic parameters were determined by multivariate non-linear regression program.展开更多
In this work,we have reported the synthesis and spectroscopic characterization of captopril(Cap)coordination compounds:Cu(Cap)·2H 2O,Cr(Cap)·H 2O,Zn(Cap)·3H 2O and Mg(Cap)4.Herein,it is worthily mention...In this work,we have reported the synthesis and spectroscopic characterization of captopril(Cap)coordination compounds:Cu(Cap)·2H 2O,Cr(Cap)·H 2O,Zn(Cap)·3H 2O and Mg(Cap)4.Herein,it is worthily mentioned that the FTIR spectroscopic technique was employed to recognized the nature of coordination between captopril ligand and copper,chromium,zinc and magnesium(Ⅱ)metal ions.In view of the infrared spectroscopic tool,the copper(Ⅱ)metal ion coordinated toward captopril drug ligand through sulfur atom of SH group dependent on the absent of stretching vibration band of—SH.Based on this result,the stretching motion ofνa(COO)shifts clearly indicates that Cu 2+,Cr 2+,Zn 2+and Mg 2+the carboxylic group is employed as coordinative site for all compounds as a metal-ligand coordinative bond.As a general behavior,it is verified that the coordination compound thermal stability(considering the release of captopril molecules,not the release of water molecules)is affected by the metal cation radius:minor radius is associated with higher thermal stability,probably due to a higher metal-captopril bond dissociation enthalpy.展开更多
基金Project(202302AB080024)supported by the Department of Science and Technology of Yunnan Province,China。
文摘The evolution of mechanical properties,localized corrosion resistance of a high purity Al-Zn-Mg-Cu alloy during non-isothermal aging(NIA)was investigated by hardness test,electrical conductivity test,tensile test,intergranular corrosion test,exfoliation corrosion test,slow strain rate tensile test and electrochemical test,and the mechanism has been discussed based on microstructure examination by optical microscopy,electron back scattered diffraction,scanning electron microscopy and scanning transmission electron microscopy.The NIA treatment includes a heating stage from 40℃to 180℃with a rate of 20℃/h and a cooling stage from 180℃to 40℃with a rate of 10℃/h.The results show that the hardness and strength increase rapidly during the heating stage of NIA since the increasing temperature favors the nucleation and the growth of strengthening precipitates and promotes the transformation of Guinier-Preston(GPI)zones toη'phase.During the cooling stage,the sizes ofη'phase increase with a little change in the number density,leading to a further slight increase of the hardness and strength.As NIA proceeds,the corroded morphology in the alloy changes from a layering feature to a wavy feature,the maximum corrosion depth decreases,and the reason has been analyzed based on the microstructural and microchemical feature of precipitates at grain boundaries and subgrain boundaries.
基金Project(51801082) supported by National Natural Science Foundation of ChinaProjects(GY2021003, GY2021020)supported by the Key Research and Development Program of Zhenjiang City,China+1 种基金Project(KYCX21_3453) supported by Graduate Research and Innovation Projects in Jiangsu Province,ChinaProject(202110289002Z) supported by Undergraduate Innovation and Entrepreneurship Training Program of Jiangsu Province,China。
文摘In order to improve the through-thickness homogeneity and properties of aviation aluminum alloy thick plate.The effect of heating-cooling retrogression and re-ageing on the performance of Al-8Zn-2Mg-2Cu alloy thick plate was investigated by hardness tests, electrical conductivity tests and transmission electron microscopy(TEM) observation.Results revealed that, during retrogression heating, the fine pre-precipitates in surface layer dissolve more and the undissolved η′ or η phases are more coarsened than that of center layer. During slow cooling after retrogression,precipitates continue coarsening but with a lower rate and the secondary precipitation occurs in both layers. Finer precipitates resulting from the secondary precipitation are more in surface. However, the coarsening and secondary precipitation behaviors are restrained in both layers under quick cooling condition. The electrical conductivity and through-thickness homogeneity of precipitates increases while the hardness decreases with cooling rate decreasing. After the optimized non-isothermal retrogression and re-ageing(NRRA) including air-cooling retrogression, the throughthickness homogeneity which is evaluated by integrated retrogression effects has been improved to 94%. The tensile strength, fracture toughness and exfoliation corrosion grade of Al-8Zn-2Mg-2Cu alloy plate is 619 MPa, 24.7 MPa·m^(1/2)and EB, respectively, which indicates that the non-isothermal retrogression and re-aging(NRRA) could improve the mechanical properties and corrosion resistance with higher through-thickness homogeneity.
基金the research committee of Malek-ashtar University of Technology(MUT)
文摘The kintic and activation energy of mass loss of two grades of melted TNT explosive, grade A and grade B, with freezing points of 80.57 and 78.15 ℃, respectively, were studied by isothermal and nonisothermal gravimetric methods. In isothermal method, the mass loss of samples in containers of glass and aluminum was followed in temperatures of 80, 90 and 100 ℃. The kinetic of the mass loss of the samples in the aluminum container was higher than the kinetic of it in the glass container that can be related to the effects of heat transfer and catalytic of aluminm metal. Also, the presence of impurities in grade B was due to increasing of kinetic of mass loss of it versus grade A. The non-isothermal curves were obtained in range of 30-330 ℃ at heating rates of 10,15 and 20 ℃·min^(-1).The TG/DTG data were used for determination of activation energy(E_a) of mass loss of TNT samples upon degradation by using Ozawa, Kissinger, Ozawa-Flynn-Wall(OFW) and Kissinger-Akahira-Sunose(KAS) methods as model free methods. The activation energies of grades of A and B of TNT was obtained 99-120 and 66-70 kJ mol^(-1)respectively. The lower values of activation energy of the degradation reaction of grade B confirm the effect of impurities in the kinetics of mass loss of this grade.
基金Projects(50805034, 50275035) supported by the National Natural Science Foundation of China
文摘The failure of AA3003 aluminum alloy sheet metal was predicted for non-isothermal viscous pressure bulging (VPB). Utilizing the coupled thermo-mechanical finite element method combined with ductile fracture criterion, the calculations were carried out for non-isotherm VPB at various temperatures and the influences of the initial temperature of viscous medium on failure mode of bulge specimens were investigated. The results show that the failure modes are different for the non-isothermal VPB with different initial temperatures of viscous medium. For the non-isothermal VPB of AA3003 aluminum alloy sheet with initial temperature of 250 ℃, when the initial temperature of viscous medium ranges from 150 to 180 ℃, the formability of sheet metal can be improved to a full extent. The validity of the predictions is examined by comparing with experimental results.
文摘The thermal decompositions of Ca-bentonites (CaB) from Santai ,Shichuan Province, China over the temperature rage of 30-1100℃ were investigated by simultaneous thermal analyzer. Non-isothermal Kinetic analysis were employed to study the thermal decomposition mechanism by using Netzsch Thermokinetics software. The dependence of the activation energy on conversion degree were evaluated by isoconversional methods. The probably mechanism and the corresponding kinetic parameters were determined by multivariate non-linear regression program.
基金The Deanship of Scientific Research at Princess Nourah bint Abdulrahman University,through the Research Groups Program Grant no.(RGP-1440-0003)
文摘In this work,we have reported the synthesis and spectroscopic characterization of captopril(Cap)coordination compounds:Cu(Cap)·2H 2O,Cr(Cap)·H 2O,Zn(Cap)·3H 2O and Mg(Cap)4.Herein,it is worthily mentioned that the FTIR spectroscopic technique was employed to recognized the nature of coordination between captopril ligand and copper,chromium,zinc and magnesium(Ⅱ)metal ions.In view of the infrared spectroscopic tool,the copper(Ⅱ)metal ion coordinated toward captopril drug ligand through sulfur atom of SH group dependent on the absent of stretching vibration band of—SH.Based on this result,the stretching motion ofνa(COO)shifts clearly indicates that Cu 2+,Cr 2+,Zn 2+and Mg 2+the carboxylic group is employed as coordinative site for all compounds as a metal-ligand coordinative bond.As a general behavior,it is verified that the coordination compound thermal stability(considering the release of captopril molecules,not the release of water molecules)is affected by the metal cation radius:minor radius is associated with higher thermal stability,probably due to a higher metal-captopril bond dissociation enthalpy.
