Eu^(2+)-doped Na_(3)Sc_(2)(PO_(4))_(3)ionic conductor possesses superior thermal quenching(TQ)resistance,which is considered as a promising phosphor for high-power lighting applications.Yet the underlying mechanism of...Eu^(2+)-doped Na_(3)Sc_(2)(PO_(4))_(3)ionic conductor possesses superior thermal quenching(TQ)resistance,which is considered as a promising phosphor for high-power lighting applications.Yet the underlying mechanism of negative thermal quenching(NTQ)is not fully understood.In this study,we focus on upconversion(UC)and downshifting(DS)luminescence of Yb^(3+)/Er^(3+)with f-f transition rather than susceptible d-f transition of Eu^(2+)in Na_(3)Sc_(2)(PO_(4))_(3),aiming to get a more insightful view.The results show that thermally accelerated dynamic defects/ions contributes to the significant negative thermal quenching(NTQ)of UC luminescence and thermally stabilized DS luminescence by promoting the radiative transition and suppressing the non-radiative transition.The UC process with slow population rate is more susceptible to perturbation of Na+migration process with time scale equivalent to that of the former,resulting in evident NTQ of UC luminescence.This research opens an avenue for understanding the NTQ mechanism of luminescence via dynamic defects/ions.展开更多
制备了NaYF_4∶Er^(3+),Yb^(3+)纳米晶,表征了纳米晶的形貌,通过物理掺杂的方式将纳米粒子掺杂到SU-8中作为光波导放大器的芯层材料,优化了波导放大器的尺寸,利用旋涂、刻蚀等工艺,在二氧化硅衬底上制备了光波导放大器。实验中用光漂白...制备了NaYF_4∶Er^(3+),Yb^(3+)纳米晶,表征了纳米晶的形貌,通过物理掺杂的方式将纳米粒子掺杂到SU-8中作为光波导放大器的芯层材料,优化了波导放大器的尺寸,利用旋涂、刻蚀等工艺,在二氧化硅衬底上制备了光波导放大器。实验中用光漂白法和湿法刻蚀两种方法制备光波导放大器,分别给出了两种方法制备的器件的结构、工艺流程、光场模拟结果,并对两种方法制备的器件的放大特性进行了测试。测试结果表明,当980 nm波长的泵浦光功率为241 m W且1 550 nm波长的信号光功率为0.1 m W时,使用湿法刻蚀法制备的放大器得到2.7 d B的相对增益。当980 nm波长的泵浦光功率为235 m W且1 550 nm波长的信号光功率为0.1 m W时,使用光漂白法制备的放大器得到4.5 d B的相对增益。根据以上测试结果,分析了两种工艺对器件性能的影响。展开更多
文摘Eu^(2+)-doped Na_(3)Sc_(2)(PO_(4))_(3)ionic conductor possesses superior thermal quenching(TQ)resistance,which is considered as a promising phosphor for high-power lighting applications.Yet the underlying mechanism of negative thermal quenching(NTQ)is not fully understood.In this study,we focus on upconversion(UC)and downshifting(DS)luminescence of Yb^(3+)/Er^(3+)with f-f transition rather than susceptible d-f transition of Eu^(2+)in Na_(3)Sc_(2)(PO_(4))_(3),aiming to get a more insightful view.The results show that thermally accelerated dynamic defects/ions contributes to the significant negative thermal quenching(NTQ)of UC luminescence and thermally stabilized DS luminescence by promoting the radiative transition and suppressing the non-radiative transition.The UC process with slow population rate is more susceptible to perturbation of Na+migration process with time scale equivalent to that of the former,resulting in evident NTQ of UC luminescence.This research opens an avenue for understanding the NTQ mechanism of luminescence via dynamic defects/ions.
文摘制备了NaYF_4∶Er^(3+),Yb^(3+)纳米晶,表征了纳米晶的形貌,通过物理掺杂的方式将纳米粒子掺杂到SU-8中作为光波导放大器的芯层材料,优化了波导放大器的尺寸,利用旋涂、刻蚀等工艺,在二氧化硅衬底上制备了光波导放大器。实验中用光漂白法和湿法刻蚀两种方法制备光波导放大器,分别给出了两种方法制备的器件的结构、工艺流程、光场模拟结果,并对两种方法制备的器件的放大特性进行了测试。测试结果表明,当980 nm波长的泵浦光功率为241 m W且1 550 nm波长的信号光功率为0.1 m W时,使用湿法刻蚀法制备的放大器得到2.7 d B的相对增益。当980 nm波长的泵浦光功率为235 m W且1 550 nm波长的信号光功率为0.1 m W时,使用光漂白法制备的放大器得到4.5 d B的相对增益。根据以上测试结果,分析了两种工艺对器件性能的影响。
