A method of spectrophotometric determination of micro amounts of platinum with MPT was proposed.Beers law is obeyed in the range of 0~3.7mg·L1Pt(Ⅳ),an apparent molar absorptivity of ε682.0=5.46×104L...A method of spectrophotometric determination of micro amounts of platinum with MPT was proposed.Beers law is obeyed in the range of 0~3.7mg·L1Pt(Ⅳ),an apparent molar absorptivity of ε682.0=5.46×104L·mol-1·cm-1.The method has been applied to the determination of platinum in minerals and catalysts with satisfactory results.展开更多
Aroyl isothiocyanate is synthesized by the reaction of aroyl chloride with ammoniurrthiocyanate under the condition of solid1iquid phase transfer catalysis using PEG-400 as the catalyst.The tater needs not to be isola...Aroyl isothiocyanate is synthesized by the reaction of aroyl chloride with ammoniurrthiocyanate under the condition of solid1iquid phase transfer catalysis using PEG-400 as the catalyst.The tater needs not to be isolated and is reacted with aromatic amine immediately to give N-aroy 1-N′-aryl thiourea derivatives in high yield.The promoting effects of the title compounds on wheat growth are tested preliminily.展开更多
文摘A method of spectrophotometric determination of micro amounts of platinum with MPT was proposed.Beers law is obeyed in the range of 0~3.7mg·L1Pt(Ⅳ),an apparent molar absorptivity of ε682.0=5.46×104L·mol-1·cm-1.The method has been applied to the determination of platinum in minerals and catalysts with satisfactory results.
文摘Aroyl isothiocyanate is synthesized by the reaction of aroyl chloride with ammoniurrthiocyanate under the condition of solid1iquid phase transfer catalysis using PEG-400 as the catalyst.The tater needs not to be isolated and is reacted with aromatic amine immediately to give N-aroy 1-N′-aryl thiourea derivatives in high yield.The promoting effects of the title compounds on wheat growth are tested preliminily.