In this study, glassy carbon electrode modified by silver nanoparticles/carbon nanotube/reduced graphene oxide(AgNPs/CNT/rGO) composite has been utilized as a platform to immobilize cis-dioxomolybdenum(VI)–salicylald...In this study, glassy carbon electrode modified by silver nanoparticles/carbon nanotube/reduced graphene oxide(AgNPs/CNT/rGO) composite has been utilized as a platform to immobilize cis-dioxomolybdenum(VI)–salicylaldehydehistidine(MoO_2/Sal-His). The modified electrode shows two reversible redox couples for MoO_2/Sal-His. Electrocatalytic oxidation of cysteine(CySH) and electrocatalytic reduction of iodate on the surface of the modified electrode were investigated with cyclic voltammetry and electrochemical impedance spectroscopy methods. The presence of MoO_2/SalHis on AgNPs/CNT/rGO shifted the catalytic current of iodate reduction to a more positive potential and the catalytic current of cysteine oxidation to a more negative potential. The change of interfacial charge transfer resistance(R_(ct))recorded by the modified electrode was monitored for sensitive quantitative detection of CySH and iodate. Moreover, the sensor has a good stability, and it can be renewed easily and repeatedly through a mechanical or electrochemical process.展开更多
基金the Khorramabad Branch, Islamic Azad University, for financial support
文摘In this study, glassy carbon electrode modified by silver nanoparticles/carbon nanotube/reduced graphene oxide(AgNPs/CNT/rGO) composite has been utilized as a platform to immobilize cis-dioxomolybdenum(VI)–salicylaldehydehistidine(MoO_2/Sal-His). The modified electrode shows two reversible redox couples for MoO_2/Sal-His. Electrocatalytic oxidation of cysteine(CySH) and electrocatalytic reduction of iodate on the surface of the modified electrode were investigated with cyclic voltammetry and electrochemical impedance spectroscopy methods. The presence of MoO_2/SalHis on AgNPs/CNT/rGO shifted the catalytic current of iodate reduction to a more positive potential and the catalytic current of cysteine oxidation to a more negative potential. The change of interfacial charge transfer resistance(R_(ct))recorded by the modified electrode was monitored for sensitive quantitative detection of CySH and iodate. Moreover, the sensor has a good stability, and it can be renewed easily and repeatedly through a mechanical or electrochemical process.
