The insensitive munitions compound nitroguanidine(NQ)is used by the U.S.Army to avoid unintended explosions.However,NQ also represents an emerging contaminant whose environmental emissions can cause toxicity toward aq...The insensitive munitions compound nitroguanidine(NQ)is used by the U.S.Army to avoid unintended explosions.However,NQ also represents an emerging contaminant whose environmental emissions can cause toxicity toward aquatic organisms,indicating the need for effective remediation strategies.Thus,we investigated the feasibility of treating water contaminated with NQ in continuous-flow columns packed with zero-valent iron(ZVI)or iron sulfide(FeS).Initially,the impact of pH on NQ transformation by ZVI or FeS was evaluated in batch experiments.The pseudo first-order rate constant for NQ transformation(k_(1,NQ))by ZVI was 8-10 times higher at pH 3.0 compared to pH 5.5 and 7.0,whereas similar k_(1,NQ)values were obtained for FeS at pH 5.5-10.0.Based on these findings,the influent p H fed to the ZVIand Fe S-packed columns was adjusted to 3.0 and 5.5,respectively.Both reactors transformed NQ into nitrosoguanidine(Nso Q).Further transformation of Nso Q by ZVI produced aminoguanidine,guanidine,and cyanamide,whereas Nso Q transformation by Fe S produced guanidine,ammonium,and traces of urea.ZVI outperformed Fe S as a reactive material to remove NQ.The ZVI-packed column effectively removed NQ below detection even after 45 d of operation(490 pore volumes,PV).In contrast,NQ breakthrough(removal efficiency<85%)was observed after 18 d(180 PV)in the Fe S-packed column.The high NQ removal efficiency and long service life of the ZVI-packed column(>490 PV)suggest that the technology is a promising approach for NQ treatment in packed-bed reactors and in situ remediation.展开更多
High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pos...High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pose more stringent challenges to its protective structure. In this study, the kinetic response model of the protective structure under single-pulse and continuous double-pulse impact is established,and a continuous double-pulse high overload impact test impact platform based on the sleeve-type bullet is constructed, and the protective performance of the multi-layer structure under multi-pulse is analyzed based on the acceleration decay ratio, and the results show that the protective performance of the structure has a positive correlation with its thickness, and it is not sensitive to the change of the load of the first impact;the first impact under double-pulse impact will cause damage to the microstructure through the superposition of the second impact. The first impact under double-pulse impact will cause an increase in the overload amplitude of the second impact through superposition;compared with the single-layer structure, the acceleration attenuation ratio of the double-layer structure can be increased by up to 26.13%, among which the epoxy-polyurethane combination has the best protection performance, with an acceleration attenuation ratio of up to 44.68%. This work provides a robust theoretical foundation and experimental basis for the reliable operation of MEMS devices, as well as for the design of protective structures in extreme environments.展开更多
Considering arch rib, lateral brace, suspender, girder, pier and track position, the model for the interaction between long-span tied arch continuous bridge and multiple tracks was established by using steel-concrete ...Considering arch rib, lateral brace, suspender, girder, pier and track position, the model for the interaction between long-span tied arch continuous bridge and multiple tracks was established by using steel-concrete composite section beam element to simulate concrete-filled steel tube(CFST) arch rib, using the beam element with rigid arm to simulate the prestressed concrete girder and using nonlinear bar element to simulate longitudinal constraint between track and bridge. Taking a(77+3×156.8+77) m tied arch continuous bridge with four tracks on the Harbin-Qiqihar Passenger Dedicated Line as an example, the arrangement of continuously welded rail(CWR) was explored. The longitudinal force in CWR on the tied arch continuous bridge, the pier top horizontal force and torque due to the unbalance load case, were analyzed under the action of temperature, vertical live load, train braking and wind load.Studies show that, it can significantly reduce track displacement to set the track expansion devices at main span arch springing on both sides; the track stress due to arch temperature variation can reach 40.8 MPa; the track stress, pier top horizontal force and torque are related to the number of loaded tracks and train running direction, and the bending force applied to unloaded track is close to the loaded track, while the braking force applied to unloaded track is 1/4 to 1/2 of the loaded track; the longitudinal force of track due to the wind load is up to 12.4 MPa, which should be considered.展开更多
The 2024/3003 aluminum gradient alloys are prepared by semi continuous casting. The influences of throttle bore diameter of embedded nozzle and temperature of internal melt on composition distribution, macrostructure,...The 2024/3003 aluminum gradient alloys are prepared by semi continuous casting. The influences of throttle bore diameter of embedded nozzle and temperature of internal melt on composition distribution, macrostructure, hardness are analyzed, and the stability of gradient distribution of composition, macrostructure and hardness along the axial direction of the ingot is also studied. The results show that diffe rent composition profiles can be achieved by adjusting the processing parameters; the volume fraction of inner alloy in the ingot can be increased by enlarging the throttle bore diameter and elevating the temperature of inner melt; quasi steady solidification can be realized within 20 s during cast processing, and consistent quality ingot is obtained by controlling the casting speed and liquid height of inner melt.展开更多
A proven beam-track contact model was used to analyze the track-structure interaction of CWR (continuously welded track) on bridge. Considering the impact of adjacent bridges, the tower-cable-track-beam-pier-pile fini...A proven beam-track contact model was used to analyze the track-structure interaction of CWR (continuously welded track) on bridge. Considering the impact of adjacent bridges, the tower-cable-track-beam-pier-pile finite element model of the cable-stayed bridge was established. Taking a bridge group including 40-32m simply-supported beam and (32+80+112)m single-tower cable-stayed bridge and 17-32m simply-supported beam on the Kunming-Shanghai high-speed railway as an example, the characteristics of CWR longitudinal force on the cable-stayed bridge were studied. It is shown that adjacent bridges must be considered in the calculation of the track expansion force and bending force on cable-stayed bridge. When the span amount of adjacent bridges is too numerous, it can be simplified as six spans; the fixed bearing of adjacent simply-supported beams should be placed on the side near the cable-stayed bridge; the track expansion device should be set at the bridge tower to reduce the track force near the bridge abutment.展开更多
Reports the effects of selenium on lipid peroxidation of soybean under continuous cropping stress.Results of pot culture and plot experiment showed that appropriate amount of Se addition increased the activity of glut...Reports the effects of selenium on lipid peroxidation of soybean under continuous cropping stress.Results of pot culture and plot experiment showed that appropriate amount of Se addition increased the activity of glutathione peroxidase (GSH-Px) significantly,and cleared away the excessive free radicals existing in soybean plant under continuous cropping stress,decreased the concentration of malonaldehyde(MDA),which is the end product of lipid peroxidation,maintained the perfection of chloroplast and mitochondrion structure,enhanced the resistance of continuous cropped soybean,and therefore increased the dry weight of seedlong and yield.展开更多
基金financially supported by the Strategic Environmental Research and Development Program(Grant No.ER19-1075)。
文摘The insensitive munitions compound nitroguanidine(NQ)is used by the U.S.Army to avoid unintended explosions.However,NQ also represents an emerging contaminant whose environmental emissions can cause toxicity toward aquatic organisms,indicating the need for effective remediation strategies.Thus,we investigated the feasibility of treating water contaminated with NQ in continuous-flow columns packed with zero-valent iron(ZVI)or iron sulfide(FeS).Initially,the impact of pH on NQ transformation by ZVI or FeS was evaluated in batch experiments.The pseudo first-order rate constant for NQ transformation(k_(1,NQ))by ZVI was 8-10 times higher at pH 3.0 compared to pH 5.5 and 7.0,whereas similar k_(1,NQ)values were obtained for FeS at pH 5.5-10.0.Based on these findings,the influent p H fed to the ZVIand Fe S-packed columns was adjusted to 3.0 and 5.5,respectively.Both reactors transformed NQ into nitrosoguanidine(Nso Q).Further transformation of Nso Q by ZVI produced aminoguanidine,guanidine,and cyanamide,whereas Nso Q transformation by Fe S produced guanidine,ammonium,and traces of urea.ZVI outperformed Fe S as a reactive material to remove NQ.The ZVI-packed column effectively removed NQ below detection even after 45 d of operation(490 pore volumes,PV).In contrast,NQ breakthrough(removal efficiency<85%)was observed after 18 d(180 PV)in the Fe S-packed column.The high NQ removal efficiency and long service life of the ZVI-packed column(>490 PV)suggest that the technology is a promising approach for NQ treatment in packed-bed reactors and in situ remediation.
基金supported by Fund of the National Natural Science Foundation of China (Grant No. 52375553)。
文摘High-overload shocks are very likely to cause damage to the microstructure of MEMS devices, especially the continuous multiple high-overload shocks generated by the penetration of the multilayer target environment pose more stringent challenges to its protective structure. In this study, the kinetic response model of the protective structure under single-pulse and continuous double-pulse impact is established,and a continuous double-pulse high overload impact test impact platform based on the sleeve-type bullet is constructed, and the protective performance of the multi-layer structure under multi-pulse is analyzed based on the acceleration decay ratio, and the results show that the protective performance of the structure has a positive correlation with its thickness, and it is not sensitive to the change of the load of the first impact;the first impact under double-pulse impact will cause damage to the microstructure through the superposition of the second impact. The first impact under double-pulse impact will cause an increase in the overload amplitude of the second impact through superposition;compared with the single-layer structure, the acceleration attenuation ratio of the double-layer structure can be increased by up to 26.13%, among which the epoxy-polyurethane combination has the best protection performance, with an acceleration attenuation ratio of up to 44.68%. This work provides a robust theoretical foundation and experimental basis for the reliable operation of MEMS devices, as well as for the design of protective structures in extreme environments.
基金Project(51378503)supported by the National Natural Science Foundation of ChinaProject(2014M552158)supported by China Postdoctoral Science Foundation
文摘Considering arch rib, lateral brace, suspender, girder, pier and track position, the model for the interaction between long-span tied arch continuous bridge and multiple tracks was established by using steel-concrete composite section beam element to simulate concrete-filled steel tube(CFST) arch rib, using the beam element with rigid arm to simulate the prestressed concrete girder and using nonlinear bar element to simulate longitudinal constraint between track and bridge. Taking a(77+3×156.8+77) m tied arch continuous bridge with four tracks on the Harbin-Qiqihar Passenger Dedicated Line as an example, the arrangement of continuously welded rail(CWR) was explored. The longitudinal force in CWR on the tied arch continuous bridge, the pier top horizontal force and torque due to the unbalance load case, were analyzed under the action of temperature, vertical live load, train braking and wind load.Studies show that, it can significantly reduce track displacement to set the track expansion devices at main span arch springing on both sides; the track stress due to arch temperature variation can reach 40.8 MPa; the track stress, pier top horizontal force and torque are related to the number of loaded tracks and train running direction, and the bending force applied to unloaded track is close to the loaded track, while the braking force applied to unloaded track is 1/4 to 1/2 of the loaded track; the longitudinal force of track due to the wind load is up to 12.4 MPa, which should be considered.
文摘The 2024/3003 aluminum gradient alloys are prepared by semi continuous casting. The influences of throttle bore diameter of embedded nozzle and temperature of internal melt on composition distribution, macrostructure, hardness are analyzed, and the stability of gradient distribution of composition, macrostructure and hardness along the axial direction of the ingot is also studied. The results show that diffe rent composition profiles can be achieved by adjusting the processing parameters; the volume fraction of inner alloy in the ingot can be increased by enlarging the throttle bore diameter and elevating the temperature of inner melt; quasi steady solidification can be realized within 20 s during cast processing, and consistent quality ingot is obtained by controlling the casting speed and liquid height of inner melt.
基金Project(51178469) supported by the National Natural Science Foundation of China
文摘A proven beam-track contact model was used to analyze the track-structure interaction of CWR (continuously welded track) on bridge. Considering the impact of adjacent bridges, the tower-cable-track-beam-pier-pile finite element model of the cable-stayed bridge was established. Taking a bridge group including 40-32m simply-supported beam and (32+80+112)m single-tower cable-stayed bridge and 17-32m simply-supported beam on the Kunming-Shanghai high-speed railway as an example, the characteristics of CWR longitudinal force on the cable-stayed bridge were studied. It is shown that adjacent bridges must be considered in the calculation of the track expansion force and bending force on cable-stayed bridge. When the span amount of adjacent bridges is too numerous, it can be simplified as six spans; the fixed bearing of adjacent simply-supported beams should be placed on the side near the cable-stayed bridge; the track expansion device should be set at the bridge tower to reduce the track force near the bridge abutment.
基金National Nature Science Foundation projectgrant No:39870 4 70 Natural Scieuce Foundation of Heilongjiang Province
文摘Reports the effects of selenium on lipid peroxidation of soybean under continuous cropping stress.Results of pot culture and plot experiment showed that appropriate amount of Se addition increased the activity of glutathione peroxidase (GSH-Px) significantly,and cleared away the excessive free radicals existing in soybean plant under continuous cropping stress,decreased the concentration of malonaldehyde(MDA),which is the end product of lipid peroxidation,maintained the perfection of chloroplast and mitochondrion structure,enhanced the resistance of continuous cropped soybean,and therefore increased the dry weight of seedlong and yield.
