A new Schiff base derived from tyrosine and salicylidene and its copper(Ⅱ ) complex have been synthesized and characterized by elemental analyses,molar conductances,thermal analyses,infrared spectra,electronic spectr...A new Schiff base derived from tyrosine and salicylidene and its copper(Ⅱ ) complex have been synthesized and characterized by elemental analyses,molar conductances,thermal analyses,infrared spectra,electronic spectra and EPR spectra.The composition of the complex is K[CuL(Ac)]· H2O, where L=H13C16NO4. EPR spectra of the copper(Ⅱ ) complex were investigated in various solvents at different temperatures.It is found that the linewidth of four hyperfine lines on solution spectra at room temperature is unequal and changes with mⅠ ,this could be satisfactorily explained by the relaxation effect.The relaxation time and the relaxation rate were calculated.By using spectral parameters from solution spectra at low temperature,the bonding parameters of Cu(Ⅱ ) complex were calculated.The bonding characterization and stability of the complex were disscussed.The results show that the in-planeσ-bond and the in-planeπ-bond in the complex all play an important role.展开更多
基金National Science and Technology Support Program(2012BAD21B04)The National Natural Science Fund(31170627)+1 种基金The priority academic program development of Jiangsu higher education institutions(PAPD)Scientific Research Foundation of Nanjing Jinguiyuan Agricultural Development Co.Ltd
文摘A new Schiff base derived from tyrosine and salicylidene and its copper(Ⅱ ) complex have been synthesized and characterized by elemental analyses,molar conductances,thermal analyses,infrared spectra,electronic spectra and EPR spectra.The composition of the complex is K[CuL(Ac)]· H2O, where L=H13C16NO4. EPR spectra of the copper(Ⅱ ) complex were investigated in various solvents at different temperatures.It is found that the linewidth of four hyperfine lines on solution spectra at room temperature is unequal and changes with mⅠ ,this could be satisfactorily explained by the relaxation effect.The relaxation time and the relaxation rate were calculated.By using spectral parameters from solution spectra at low temperature,the bonding parameters of Cu(Ⅱ ) complex were calculated.The bonding characterization and stability of the complex were disscussed.The results show that the in-planeσ-bond and the in-planeπ-bond in the complex all play an important role.
