Grafting dodecyl in EDTA,A ligand-N,N′-di ( dodecyl ) disodium ethylenediamine di-acetic acid was synthesized and its complex C 30 H 58 O 4N 2Cu ( Ⅱ ) was obtained in chloroformme∶thanol=1∶1( V/V ).The products we...Grafting dodecyl in EDTA,A ligand-N,N′-di ( dodecyl ) disodium ethylenediamine di-acetic acid was synthesized and its complex C 30 H 58 O 4N 2Cu ( Ⅱ ) was obtained in chloroformme∶thanol=1∶1( V/V ).The products were characterized by IR?EA? 1HNMR and UV spectra.展开更多
Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure ...Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1\^821 6(4) nm, β=128.16(3) °, V=6.329(2) nm 3, Z=2 , D c=20.200 Mg/m 3, M r= 1 314.744, μ=10.274 mm -1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.展开更多
The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a=...The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a= 1.41999(2)nm, b=1.43467(2)nm, c=1.694610(10)nm, α=95.7250(10)°, β=92.2110(10)°, γ=92.6060(10)°, V=3.42829(7)nm3, Z=2, Dc=2.388g·cm-3, Mr=2465.10g·mol-1, μ=2.489mm-1, F(000)=2388, R1=0.0584, wR2=0.1461, S=1.164. The heteropolyanion is a bi capped pseudo Keggin complex. CCDC: 186645.展开更多
A novel coordination polymer [(C10H16N)2(Pb2I6)·2DMF·H2O]n (C10H16N=N-butyl-2-Methy-Pyridinium) was synthesized by the reaction of Pb(NO3)2 with C6H10NI at room temperature in DMF solvent and structurally ch...A novel coordination polymer [(C10H16N)2(Pb2I6)·2DMF·H2O]n (C10H16N=N-butyl-2-Methy-Pyridinium) was synthesized by the reaction of Pb(NO3)2 with C6H10NI at room temperature in DMF solvent and structurally characterized by means of X-ray single diffraction. The title compound crystallizes in triclinic system, space group P1 with a=1.123 7(2) nm, b=1.253 30(16) nm, c=0.808 00(12) nm, 穖-3, F(000)=738, chemical formula C26H48N4O3Pb2I6 and Mr=1 640.46, ombined by static attracting forces in the crystal. DMF and H2O locate between the organic and inorganic moiety. CCDC: 210812.展开更多
文摘Grafting dodecyl in EDTA,A ligand-N,N′-di ( dodecyl ) disodium ethylenediamine di-acetic acid was synthesized and its complex C 30 H 58 O 4N 2Cu ( Ⅱ ) was obtained in chloroformme∶thanol=1∶1( V/V ).The products were characterized by IR?EA? 1HNMR and UV spectra.
文摘Compound [Co 3(BTC)(HBTC)(H 2BTC)(C 2H 4O 2) 3]·3(DMF)·6(H 3O) was synthesized under mild conditions and its crystal structure was determined by using single crystal X-ray diffraction. The crystal structure was solved by direct method and refined by full-matrix least-square method. The crystal is monoclinic and belongs to space group Cc with a=2.645 3(5) nm, b= 1.670 4(3) nm, c=1\^821 6(4) nm, β=128.16(3) °, V=6.329(2) nm 3, Z=2 , D c=20.200 Mg/m 3, M r= 1 314.744, μ=10.274 mm -1, F(000) =38 226, GOF=0.99, R=0.094 1, ωR=0.257 3.
文摘The novel polyoxometalate, 32[Mo8ⅣMo4ⅤV2ⅣO38(PO4)], was synthesized and characterized by elementary analysis, EPR, IR spectra and X ray diffraction. The compoundcrystallizes in triclinic system, space group with a= 1.41999(2)nm, b=1.43467(2)nm, c=1.694610(10)nm, α=95.7250(10)°, β=92.2110(10)°, γ=92.6060(10)°, V=3.42829(7)nm3, Z=2, Dc=2.388g·cm-3, Mr=2465.10g·mol-1, μ=2.489mm-1, F(000)=2388, R1=0.0584, wR2=0.1461, S=1.164. The heteropolyanion is a bi capped pseudo Keggin complex. CCDC: 186645.
文摘A novel coordination polymer [(C10H16N)2(Pb2I6)·2DMF·H2O]n (C10H16N=N-butyl-2-Methy-Pyridinium) was synthesized by the reaction of Pb(NO3)2 with C6H10NI at room temperature in DMF solvent and structurally characterized by means of X-ray single diffraction. The title compound crystallizes in triclinic system, space group P1 with a=1.123 7(2) nm, b=1.253 30(16) nm, c=0.808 00(12) nm, 穖-3, F(000)=738, chemical formula C26H48N4O3Pb2I6 and Mr=1 640.46, ombined by static attracting forces in the crystal. DMF and H2O locate between the organic and inorganic moiety. CCDC: 210812.
