This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only b...This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only be obtained by some USVs.In order to achieve semi-encirclement tracking of noncooperative targets under maritime security conditions,a fixed-time tracking control method based on dynamic surface control(DSC)is proposed in this paper.Firstly,a novel TACC architecture with decoupled kinematic control law and decoupled kinetic control law was designed to reduce the complexity of control system design.Secondly,the proposed DSC-based target-guided kinematic control law including tracking points pre-allocation strategy and sigmoid artificial potential functions(SigAPFs)can avoid collisions during tracking process and optimize kinematic control output.Finally,a fixed-time TACC system was proposed to achieve fast convergence of kinematic and kinetics errors.The effectiveness of the proposed TACC approach in improving target tracking safety and reducing control output chattering was verified by simulation comparison results.展开更多
This paper proposed a new libration decoupling analytical speed function(LD-ASF)in lieu of the classic analytical speed function to control the climber's speed along a partial space elevator to improve libration s...This paper proposed a new libration decoupling analytical speed function(LD-ASF)in lieu of the classic analytical speed function to control the climber's speed along a partial space elevator to improve libration stability in cargo transportation.The LD-ASF is further optimized for payload transportation efficiency by a novel coordinate game theory to balance competing control objectives among payload transport speed,stable end body's libration,and overall control input via model predictive control.The transfer period is divided into several sections to reduce computational burden.The validity and efficacy of the proposed LD-ASF and coordinate game-based model predictive control are demonstrated by computer simulation.Numerical results reveal that the optimized LD-ASF results in higher transportation speed,stable end body's libration,lower thrust fuel consumption,and more flexible optimization space than the classic analytical speed function.展开更多
New adaptive preprocessing algorithms based on the polar coordinate system were put forward to get high-precision corneal topography calculation results. Adaptive locating algorithms of concentric circle center were c...New adaptive preprocessing algorithms based on the polar coordinate system were put forward to get high-precision corneal topography calculation results. Adaptive locating algorithms of concentric circle center were created to accurately capture the circle center of original Placido-based image, expand the image into matrix centered around the circle center, and convert the matrix into the polar coordinate system with the circle center as pole. Adaptive image smoothing treatment was followed and the characteristics of useful circles were extracted via horizontal edge detection, based on useful circles presenting approximate horizontal lines while noise signals presenting vertical lines or different angles. Effective combination of different operators of morphology were designed to remedy data loss caused by noise disturbances, get complete image about circle edge detection to satisfy the requests of precise calculation on follow-up parameters. The experimental data show that the algorithms meet the requirements of practical detection with characteristics of less data loss, higher data accuracy and easier availability.展开更多
To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The ...To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The thermal properties of pristine RDX and its modified variants(RDX@PDA-Fe,RDX@PDA-Cu,RDX@PDA-Pb)were characterized using differential scanning calorimetry(DSC)and accelerating rate calorimetry(ARC).The impact sensitivity of these materials was evaluated via the characteristic drop-height method.The results demonstrate that PDA-metal metal coatings—formed through coordination between PDA and single metal ions(Fe^(3+),Cu^(2+),or Pb^(2+))—significantly enhance RDX′s thermal stability while attenuating its mechanical sensitivity.These coatings act as energy-absorbing barriers against external stimuli,effectively mitigating RDX′s sensitivity.Furthermore,they elevate RDX′s thermal stability by increasing its decomposition onset temperature and accelerating its decomposition kinetics.The monometallic coatings also catalyze RDX′s thermal decomposition and combustion,with Cu and Pb exhibiting particularly distinct catalytic effects.展开更多
Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions an...Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-(3',4'-dicarboxylphenoxy)-1,2,4-benzenetricarboxylic acid(H_(5)L)in the presence of N-auxiliary ligands 1,10-phenanthroline(phen)and1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib).The structures of coordination polymers 1 and 2 were characterized by infrared spectroscopy,single-crystal X-ray diffraction,thermogravimetric analysis,and powder X-ray diffraction.Single-crystal X-ray diffraction reveals that 1 has a 1D chain structure based on binuclear Mn(Ⅱ)units,while 2 features a(3,8)-connected 3D network structure based on tetranuclear Mn(Ⅱ)units.Magnetic studies show that 1 and 2exhibit antiferromagnetic interactions between manganese ions.2 shows stronger antiferromagnetic interactions due to the shorter Mn…Mn distances within the tetranuclear manganese units.CCDC:2357601,1;2357602,2.展开更多
One Yb(Ⅲ)-based coordination polymer,{[Yb(H_(2)dhtp)1.5(H_(2)O)_(4)]·3H_(2)O}n(1)(H_(4)dhtp=2,5-dihydroxytere-phthalic acid),was fabricated and structurally characterized by single-crystal X-ray diffraction,IR,p...One Yb(Ⅲ)-based coordination polymer,{[Yb(H_(2)dhtp)1.5(H_(2)O)_(4)]·3H_(2)O}n(1)(H_(4)dhtp=2,5-dihydroxytere-phthalic acid),was fabricated and structurally characterized by single-crystal X-ray diffraction,IR,powder X-ray diffraction,X-ray diffraction,and elemental analysis.Complex 1 displays a 1D chain structure,and belongs to P1 group.The solid-state luminescent spectrum of 1 showed an emission band with the maximum at 508 nm(λex=408 nm).It exhibited the emission characteristic of the H_(4)dhtp ligand.The fluorescence of 1 in water displayed the stron-gest intensity.In detecting various metal ions,adding Zr^(4+)led to a blue shift in fluorescence,accompanied by an increase in intensity,whereas the presence of Fe^(3+)resulted in a decrease in luminescence.The changes observed in the IR spectrum indicate an interaction between Fe^(3+)/Zr^(4+)and complex 1,resulting in the variation of luminescence properties.展开更多
The thermal power boiler-turbine system is a complex system with high nonlinearity,time-delay and strong coupling.It is difi cult to obtain an excellent dynamic response by means of traditional PI/PID control when the...The thermal power boiler-turbine system is a complex system with high nonlinearity,time-delay and strong coupling.It is difi cult to obtain an excellent dynamic response by means of traditional PI/PID control when the power system load changes in a wide range.So far many advanced control strategies have been presented to solve the above problem,but most of these strategies are dependent on an accurate object model.展开更多
A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been d...A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been designed and synthesized through solvothermal reaction.Structural analysis shows that Cd(Ⅱ)is connected by H4L and 1,4-bimb to form a 2D network,and 1,4-bimb further expands the 2D network into a 3D framework.CP 1 can be used as an excellent fluorescence sensor for Fe^(3+)and 4-nitrophenol(4-NP),with low detection limits and good anti-interference.The detection limits of Fe^(3+)and 4-NP were 0.034 and 0.031μmol·L^(-1),respectively.In addition,the fluorescence quenching mechanism was studied.1 was successfully applied to determine Fe^(3+)and 4-NP content in the Yanhe River water sample.CCDC:2351092.展开更多
Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfull...Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfully synthesized under hydrothermal conditions and characterized structurally by IR spectroscopy,elemental analyses,single-crystal X-ray diffraction,powder X-ray diffraction,and thermogravimetric analysis.The results of single-crystal X-ray diffraction show that complex 1 presents a 1D zigzag chain structure and further extends to a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.Meanwhile,complex 2 has a zero-dimensional structure and also extends to form a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.In addition,both 1and 2 exhibited luminescent properties in the solid state.Furthermore,quantum chemical calculations were carried out on the"molecular fragments"extracted from the crystal structures of 1 and 2 using the PBE0/LANL2DZ method constructed by the Gaussian 16 program.The calculated values signify a significant covalent interaction between the coordination atoms and the Cd(Ⅱ)ions.CCDC:2332173,1;2332176,2.展开更多
Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have re...Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have received increasing attention.In contrast to the conventional tube furnace method,the high-temperature shock(HTS)method enables ultra-fast thermal processing,superior atomic efficiency,and a streamlined synthesis protocol,offering a simplified method for the preparation of high-performance single-atom catalysts(SACs).The reports have shown that nickel-based SACs can be synthesized quickly and conveniently using the HTS method,making their application in CO_(2)reduction reactions(CO_(2)RR)a viable and promising avenue for further exploration.In this study,the effect of heating temperature,metal loading and different nitrogen(N)sources on the catalyst morphology,coordination environment and electrocatalytic performance were investigated.Under optimal conditions,0.05Ni-DCD-C-1050 showed excellent performance in reducing CO_(2)to CO,with CO selectivity close to 100%(−0.7 to−1.0 V vs RHE)and current density as high as 130 mA/cm^(2)(−1.1 V vs RHE)in a flow cell under alkaline environment.展开更多
A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_...A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)O.The structure was characterized by single-crystal X-ray diffraction,powder X-ray diffraction,elemental analysis,and infrared spectroscopy.Cd-CP belongs to the monoclinic crystal system with the P2_1/c space group and performs in a 1D double-chain structure.The adjacent double chains further form a 3D supramolecular network structure through hydrogen bonding.Thermogravimetric analysis shows that Cd-CP has good thermal stability.Fluorescence analysis showed that Cd-CP had good choosing selectively and was sensitive to metal ions(Fe^(3+)and Zn^(2+)),2,4,6-trinitrophenylhydrazine(TRI),and pyrimethanil(Pth).Interestingly,when Cd-CP was used for fluorescence detection of metal ions,it was found to have a fluorescence quenching effect on Fe^(3+)but had an obvious enhancement effect on Zn^(2+).Therefore,we designed an“on-off-on”logic gate.In addition,the mechanism of fluorescence sensing has been deeply explored.CCDC:2258625.展开更多
With the increasing of electric vehicles(EVs)penetration in power grids,the charging of EVs will have significant impacts on power system planning and operation.It is necessary to note that the majority of EVs are not...With the increasing of electric vehicles(EVs)penetration in power grids,the charging of EVs will have significant impacts on power system planning and operation.It is necessary to note that the majority of EVs are not in use in most ofthe time in a day.Therefore,the onboard batteries can be utilized as energy storage devices.This article reviews and discusses the current related research in the following areas.展开更多
To improve the performance of the supply chain with one supplier and multiple retailers under deterministic price-sensitive customer demand, an optimal strategy is proposed based on knowledge discovery. First the dece...To improve the performance of the supply chain with one supplier and multiple retailers under deterministic price-sensitive customer demand, an optimal strategy is proposed based on knowledge discovery. First the decentralized system in which the supplier and the retailers are independent, profit-maximizing participants with the supplier acting as a Stackelberg game leader is studied. Numerical examples illustrate the importance of the coordination. The conventional quantity discount mechanism needs to be modified to coordinate the supply chain, so a revenue-sharing contract is proposed to coordinate such supply chain. Lastly, a special decision under certain demand rates is studied. The pricing and replenishment policies can be decided sequentially, which yields much less loss comparing with optimal decision when the demand rates are sufficiently large.展开更多
One-way roads have potential for improving vehicle speed and reducing traffic delay.Suffering from dense road network,most of adjacent intersections’distance on one-way roads becomes relatively close,which makes isol...One-way roads have potential for improving vehicle speed and reducing traffic delay.Suffering from dense road network,most of adjacent intersections’distance on one-way roads becomes relatively close,which makes isolated control of intersections inefficient in this scene.Thus,it is significant to develop coordinated control of multiple intersection signals on the one-way roads.This paper proposes a signal coordination control method that is suitable for one-way arterial roads.This method uses the cooperation technology of the vehicle infrastructure to collect intersection traffic information and share information among the intersections.Adaptive signal control system is adopted for each intersection in the coordination system,and the green light time is adjusted in real time based on the number of vehicles in queue.The offset and clearance time can be calculated according to the real-time traffic volume.The proposed method was verified with simulation results by VISSIM traffic simulation software.The results compared with other methods show that the coordinated control method proposed in this paper can effectively reduce the average delay of vehicles on the arterial roads and improve the traffic efficiency.展开更多
Considering the influence of reagent adjustment in different flotation bank on the final production index and the difficulty of establishing an effective mathematical model,a coordinated optimization method for dosage...Considering the influence of reagent adjustment in different flotation bank on the final production index and the difficulty of establishing an effective mathematical model,a coordinated optimization method for dosage reagent based on key characteristics variation tendency and case-based reasoning is proposed.On the basis of the expert reagent regulation method in antimony flotation process,the reagent dosage pre-setting model of the roughing–scavenging bank is constructed based on case-based reasoning.Then,the sensitivity index is used to calculate the key features of reagent dosage.The reagent dosage compensation model is constructed based on the variation tendency of the key features in the roughing and scavenging process.At last,the prediction model is used to finish the classification and discriminant analysis.The simulation results and industrial experiment in antimony flotation process show that the proposed method reduces fluctuation of the tailings indicators and the cost of reagent dosage.It can lay a foundation for optimizing the whole process of flotation.展开更多
Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) w...Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) was designed followed the end-effector principle, and an active partial body weight support(PBWS) system was introduced to facilitate successful gait training. For successful establishment of a walking gait on the GTR with PBWS, the motion laws of the GTR were planned to enable the phase distribution relationships of the cycle step, and the center of gravity(COG) trajectory of the human body during gait training on the GTR was measured. A coordinated control strategy was proposed based on the impedance control principle. A robotic prototype was developed as a platform for evaluating the design concepts and control strategies. Preliminary gait training with a healthy subject was implemented by the robotic-assisted gait training system and the experimental results are encouraging.展开更多
A novel iterative technique, the phase descent search detection was proposed. This technique constrained the solution （PDS） algorithm, for M-ary phase shift keying （M-PSK） symbols to have a unit magnitude and it w...A novel iterative technique, the phase descent search detection was proposed. This technique constrained the solution （PDS） algorithm, for M-ary phase shift keying （M-PSK） symbols to have a unit magnitude and it was based on coordinate descent iterations where coordinates were the unknown symbol phases. The PDS algorithm, together with a descent local search （also implemented as a version of the PDS algorithm）, was used multiple times with different initializations in a proposed multiple phase detector; the solution with the minimum cost was then chosen as the final solution. The simulation results show that for highly loaded multiuser scenarios, the proposed technique has a detection performance that is close to the single-user bound. The results also show that the multiple phase detector allows detection in highly overloaded scenarios and it exhibits near-far resistance. In particular, the detector has a performance that is significantly better, and complexity that is significantly lower, than that of the detector based on semi-definite relaxation.展开更多
A nonlinear visual mapping model is presented to replace the image Jacobian relation for uncalibrated hand/eye coordination. A new visual tracking controller based on artificial neural network is designed. Simulation ...A nonlinear visual mapping model is presented to replace the image Jacobian relation for uncalibrated hand/eye coordination. A new visual tracking controller based on artificial neural network is designed. Simulation results show that this method can drive the static tracking error to zero quickly and keep good robustness and adaptability at the same time. In addition, the algorithm is very easy to be implemented with low computational complexity.展开更多
In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. W...In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. While neural networks can model highly complex nonlinear dynamical systems, they produce black box models. This has led to significant interest in neuro-fuzzy networks (NFNs) to represent a nonlinear dynamical process by a set of locally valid and simpler submodels. Two alternative methods of exploiting the NFNs within a generalised predictive control (GPC) framework for nonlinear model predictive control are described. Coordinated control of steam-boiler generation using the two nonlinear GPC methods show excellent tracking and disturbance rejection results and improved performance compared with conventional linear GPC.展开更多
An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i. e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-tur...An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i. e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-turbine unit in the power plant leads to changes in operating points which result in nonlinear variations of the plant variables and parameters. For the variation of operating condition and slowly varying dynamics, an intelligent control scheme has been developed by combining fuzzy self-tuning with adaptive control and auto-tuning techniques. As there exist strong couplings between control loops of main steam pressure and power output in the unit, a new design for static decoupler aimed at decoupling for setpoints and unmeasured pulverized coal disturbance of the system at the same time is presented. Satisfactory industrial application results show that such a control system has enhanced adaptability and robustness to the complex process, and better control performance and high economic benefit have been obtained.展开更多
文摘This paper presents an investigation on the target-guided coordinated control(TACC)of unmanned surface vehicles(USVs).In the scenario of tracking non-cooperative targets,the status information of the target can only be obtained by some USVs.In order to achieve semi-encirclement tracking of noncooperative targets under maritime security conditions,a fixed-time tracking control method based on dynamic surface control(DSC)is proposed in this paper.Firstly,a novel TACC architecture with decoupled kinematic control law and decoupled kinetic control law was designed to reduce the complexity of control system design.Secondly,the proposed DSC-based target-guided kinematic control law including tracking points pre-allocation strategy and sigmoid artificial potential functions(SigAPFs)can avoid collisions during tracking process and optimize kinematic control output.Finally,a fixed-time TACC system was proposed to achieve fast convergence of kinematic and kinetics errors.The effectiveness of the proposed TACC approach in improving target tracking safety and reducing control output chattering was verified by simulation comparison results.
基金funded by the National Natural Science Foundation of China(12102487)Basic and Applied Basic Research Foundation of Guangdong Province,China(2023A1515012339)+1 种基金Shenzhen Science and Technology Program(ZDSYS20210623091808026)the Discovery Grant(RGPIN-2024-06290)of the Natural Sciences and Engineering Research Council of Canada。
文摘This paper proposed a new libration decoupling analytical speed function(LD-ASF)in lieu of the classic analytical speed function to control the climber's speed along a partial space elevator to improve libration stability in cargo transportation.The LD-ASF is further optimized for payload transportation efficiency by a novel coordinate game theory to balance competing control objectives among payload transport speed,stable end body's libration,and overall control input via model predictive control.The transfer period is divided into several sections to reduce computational burden.The validity and efficacy of the proposed LD-ASF and coordinate game-based model predictive control are demonstrated by computer simulation.Numerical results reveal that the optimized LD-ASF results in higher transportation speed,stable end body's libration,lower thrust fuel consumption,and more flexible optimization space than the classic analytical speed function.
基金Project(20120321028-01)supported by Scientific and Technological Key Project of Shanxi Province,ChinaProject(20113101)supported by Postgraduate Innovative Key Project of Shanxi Province,China
文摘New adaptive preprocessing algorithms based on the polar coordinate system were put forward to get high-precision corneal topography calculation results. Adaptive locating algorithms of concentric circle center were created to accurately capture the circle center of original Placido-based image, expand the image into matrix centered around the circle center, and convert the matrix into the polar coordinate system with the circle center as pole. Adaptive image smoothing treatment was followed and the characteristics of useful circles were extracted via horizontal edge detection, based on useful circles presenting approximate horizontal lines while noise signals presenting vertical lines or different angles. Effective combination of different operators of morphology were designed to remedy data loss caused by noise disturbances, get complete image about circle edge detection to satisfy the requests of precise calculation on follow-up parameters. The experimental data show that the algorithms meet the requirements of practical detection with characteristics of less data loss, higher data accuracy and easier availability.
基金National Natural Science Foundation of China(No.22405249)Open Project of Key Laboratory of Rubber Research Institute,Chinese Academy of Tropical Agricultural Science in 2025(No.RRI-KLOF202402)。
文摘To enhance the overall performance of cyclotrimethylenetrinitramine(RDX),a modification strategy for RDX via in situ coordination with monometallic polydopamine(PDA)coatings(PDA-Fe,PDA-Cu,and PDA-Pb)was developed.The thermal properties of pristine RDX and its modified variants(RDX@PDA-Fe,RDX@PDA-Cu,RDX@PDA-Pb)were characterized using differential scanning calorimetry(DSC)and accelerating rate calorimetry(ARC).The impact sensitivity of these materials was evaluated via the characteristic drop-height method.The results demonstrate that PDA-metal metal coatings—formed through coordination between PDA and single metal ions(Fe^(3+),Cu^(2+),or Pb^(2+))—significantly enhance RDX′s thermal stability while attenuating its mechanical sensitivity.These coatings act as energy-absorbing barriers against external stimuli,effectively mitigating RDX′s sensitivity.Furthermore,they elevate RDX′s thermal stability by increasing its decomposition onset temperature and accelerating its decomposition kinetics.The monometallic coatings also catalyze RDX′s thermal decomposition and combustion,with Cu and Pb exhibiting particularly distinct catalytic effects.
文摘Two new Mn(Ⅱ)coordination polymers,namely{[Mn_(2)(HL)(phen)_(3)(H_(2)O)_(2)]·7.5H_(2)O}_n(1)and[Mn_(4)(HL)_(2)(1,4-bib)_(3)(H_(2)O)_(2)]_n(2),were synthesized under hydrothermal conditions by using Mn(Ⅱ)ions and 6-(3',4'-dicarboxylphenoxy)-1,2,4-benzenetricarboxylic acid(H_(5)L)in the presence of N-auxiliary ligands 1,10-phenanthroline(phen)and1,4-bis(1H-imidazol-1-yl)benzene(1,4-bib).The structures of coordination polymers 1 and 2 were characterized by infrared spectroscopy,single-crystal X-ray diffraction,thermogravimetric analysis,and powder X-ray diffraction.Single-crystal X-ray diffraction reveals that 1 has a 1D chain structure based on binuclear Mn(Ⅱ)units,while 2 features a(3,8)-connected 3D network structure based on tetranuclear Mn(Ⅱ)units.Magnetic studies show that 1 and 2exhibit antiferromagnetic interactions between manganese ions.2 shows stronger antiferromagnetic interactions due to the shorter Mn…Mn distances within the tetranuclear manganese units.CCDC:2357601,1;2357602,2.
文摘One Yb(Ⅲ)-based coordination polymer,{[Yb(H_(2)dhtp)1.5(H_(2)O)_(4)]·3H_(2)O}n(1)(H_(4)dhtp=2,5-dihydroxytere-phthalic acid),was fabricated and structurally characterized by single-crystal X-ray diffraction,IR,powder X-ray diffraction,X-ray diffraction,and elemental analysis.Complex 1 displays a 1D chain structure,and belongs to P1 group.The solid-state luminescent spectrum of 1 showed an emission band with the maximum at 508 nm(λex=408 nm).It exhibited the emission characteristic of the H_(4)dhtp ligand.The fluorescence of 1 in water displayed the stron-gest intensity.In detecting various metal ions,adding Zr^(4+)led to a blue shift in fluorescence,accompanied by an increase in intensity,whereas the presence of Fe^(3+)resulted in a decrease in luminescence.The changes observed in the IR spectrum indicate an interaction between Fe^(3+)/Zr^(4+)and complex 1,resulting in the variation of luminescence properties.
文摘The thermal power boiler-turbine system is a complex system with high nonlinearity,time-delay and strong coupling.It is difi cult to obtain an excellent dynamic response by means of traditional PI/PID control when the power system load changes in a wide range.So far many advanced control strategies have been presented to solve the above problem,but most of these strategies are dependent on an accurate object model.
文摘A novel coordination polymer(CP){[Cd_(2)(L)(1,4-bimb)_(1.5)(DMF)_(2)]·DMF}n(1)(H_(4)L=5,5'-[1,1'-biphenyl-4,4'-diylbis(oxy)]diisophthalic acid,1,4-bimb=1,4-bis(imidazole-1-ylmethyl)-benzene)has been designed and synthesized through solvothermal reaction.Structural analysis shows that Cd(Ⅱ)is connected by H4L and 1,4-bimb to form a 2D network,and 1,4-bimb further expands the 2D network into a 3D framework.CP 1 can be used as an excellent fluorescence sensor for Fe^(3+)and 4-nitrophenol(4-NP),with low detection limits and good anti-interference.The detection limits of Fe^(3+)and 4-NP were 0.034 and 0.031μmol·L^(-1),respectively.In addition,the fluorescence quenching mechanism was studied.1 was successfully applied to determine Fe^(3+)and 4-NP content in the Yanhe River water sample.CCDC:2351092.
文摘Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfully synthesized under hydrothermal conditions and characterized structurally by IR spectroscopy,elemental analyses,single-crystal X-ray diffraction,powder X-ray diffraction,and thermogravimetric analysis.The results of single-crystal X-ray diffraction show that complex 1 presents a 1D zigzag chain structure and further extends to a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.Meanwhile,complex 2 has a zero-dimensional structure and also extends to form a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.In addition,both 1and 2 exhibited luminescent properties in the solid state.Furthermore,quantum chemical calculations were carried out on the"molecular fragments"extracted from the crystal structures of 1 and 2 using the PBE0/LANL2DZ method constructed by the Gaussian 16 program.The calculated values signify a significant covalent interaction between the coordination atoms and the Cd(Ⅱ)ions.CCDC:2332173,1;2332176,2.
基金supported by the National Key R&D Program of China(2024YFB4106400)National Natural Science Foundation of China(22209200,52302331)。
文摘Electrocatalytic reduction of carbon dioxide(CO_(2))to carbon monoxide(CO)is an effective strategy to achieve carbon neutrality.High selective and low-cost catalysts for the electrocatalytic reduction of CO_(2)have received increasing attention.In contrast to the conventional tube furnace method,the high-temperature shock(HTS)method enables ultra-fast thermal processing,superior atomic efficiency,and a streamlined synthesis protocol,offering a simplified method for the preparation of high-performance single-atom catalysts(SACs).The reports have shown that nickel-based SACs can be synthesized quickly and conveniently using the HTS method,making their application in CO_(2)reduction reactions(CO_(2)RR)a viable and promising avenue for further exploration.In this study,the effect of heating temperature,metal loading and different nitrogen(N)sources on the catalyst morphology,coordination environment and electrocatalytic performance were investigated.Under optimal conditions,0.05Ni-DCD-C-1050 showed excellent performance in reducing CO_(2)to CO,with CO selectivity close to 100%(−0.7 to−1.0 V vs RHE)and current density as high as 130 mA/cm^(2)(−1.1 V vs RHE)in a flow cell under alkaline environment.
文摘A coordination polymer{[Cd(H_(2)dpa)(bpy)]·3H_(2)O}_(n)(Cd-CP)was designed and hydrothermal synthesized based on 4-(2,4-dicarboxyphenoxy)phthalic acid(H_(4)dpa),2,2'-bipyridine(bpy)and Cd(NO_(3))_(2)·4H_(2)O.The structure was characterized by single-crystal X-ray diffraction,powder X-ray diffraction,elemental analysis,and infrared spectroscopy.Cd-CP belongs to the monoclinic crystal system with the P2_1/c space group and performs in a 1D double-chain structure.The adjacent double chains further form a 3D supramolecular network structure through hydrogen bonding.Thermogravimetric analysis shows that Cd-CP has good thermal stability.Fluorescence analysis showed that Cd-CP had good choosing selectively and was sensitive to metal ions(Fe^(3+)and Zn^(2+)),2,4,6-trinitrophenylhydrazine(TRI),and pyrimethanil(Pth).Interestingly,when Cd-CP was used for fluorescence detection of metal ions,it was found to have a fluorescence quenching effect on Fe^(3+)but had an obvious enhancement effect on Zn^(2+).Therefore,we designed an“on-off-on”logic gate.In addition,the mechanism of fluorescence sensing has been deeply explored.CCDC:2258625.
文摘With the increasing of electric vehicles(EVs)penetration in power grids,the charging of EVs will have significant impacts on power system planning and operation.It is necessary to note that the majority of EVs are not in use in most ofthe time in a day.Therefore,the onboard batteries can be utilized as energy storage devices.This article reviews and discusses the current related research in the following areas.
基金the National Natural Science Foundation of China (70471034)the Talent Foundation of Nanjing University of Aeronautics and Astronautics (s0670-082).
文摘To improve the performance of the supply chain with one supplier and multiple retailers under deterministic price-sensitive customer demand, an optimal strategy is proposed based on knowledge discovery. First the decentralized system in which the supplier and the retailers are independent, profit-maximizing participants with the supplier acting as a Stackelberg game leader is studied. Numerical examples illustrate the importance of the coordination. The conventional quantity discount mechanism needs to be modified to coordinate the supply chain, so a revenue-sharing contract is proposed to coordinate such supply chain. Lastly, a special decision under certain demand rates is studied. The pricing and replenishment policies can be decided sequentially, which yields much less loss comparing with optimal decision when the demand rates are sufficiently large.
基金Project(61503048)supported by the National Natural Science Foundation of ChinaProjects(16C0050,16C0062)supported by Scientific Research Project of Hunan Provincial Department of Education,China
文摘One-way roads have potential for improving vehicle speed and reducing traffic delay.Suffering from dense road network,most of adjacent intersections’distance on one-way roads becomes relatively close,which makes isolated control of intersections inefficient in this scene.Thus,it is significant to develop coordinated control of multiple intersection signals on the one-way roads.This paper proposes a signal coordination control method that is suitable for one-way arterial roads.This method uses the cooperation technology of the vehicle infrastructure to collect intersection traffic information and share information among the intersections.Adaptive signal control system is adopted for each intersection in the coordination system,and the green light time is adjusted in real time based on the number of vehicles in queue.The offset and clearance time can be calculated according to the real-time traffic volume.The proposed method was verified with simulation results by VISSIM traffic simulation software.The results compared with other methods show that the coordinated control method proposed in this paper can effectively reduce the average delay of vehicles on the arterial roads and improve the traffic efficiency.
基金Project(61725306)supported by the National Science Foundation for Distinguished Young Scholars of ChinaProjects(61473318,61403136,61703157,61751312)supported by the National Natural Science Foundation of ChinaProject(16C0940)supported by Foundation of Hunan Educational Committee,China
文摘Considering the influence of reagent adjustment in different flotation bank on the final production index and the difficulty of establishing an effective mathematical model,a coordinated optimization method for dosage reagent based on key characteristics variation tendency and case-based reasoning is proposed.On the basis of the expert reagent regulation method in antimony flotation process,the reagent dosage pre-setting model of the roughing–scavenging bank is constructed based on case-based reasoning.Then,the sensitivity index is used to calculate the key features of reagent dosage.The reagent dosage compensation model is constructed based on the variation tendency of the key features in the roughing and scavenging process.At last,the prediction model is used to finish the classification and discriminant analysis.The simulation results and industrial experiment in antimony flotation process show that the proposed method reduces fluctuation of the tailings indicators and the cost of reagent dosage.It can lay a foundation for optimizing the whole process of flotation.
基金Project(61175128) supported by the National Natural Science Foundation of ChinaProject(2008AA040203) supported by the National High Technology Research and Development Program of China
文摘Walking is the most basic and essential part of the activities of daily living. To enable the elderly and non-ambulatory gait-impaired patients, the repetitive practice of this task, a novel gait training robot(GTR) was designed followed the end-effector principle, and an active partial body weight support(PBWS) system was introduced to facilitate successful gait training. For successful establishment of a walking gait on the GTR with PBWS, the motion laws of the GTR were planned to enable the phase distribution relationships of the cycle step, and the center of gravity(COG) trajectory of the human body during gait training on the GTR was measured. A coordinated control strategy was proposed based on the impedance control principle. A robotic prototype was developed as a platform for evaluating the design concepts and control strategies. Preliminary gait training with a healthy subject was implemented by the robotic-assisted gait training system and the experimental results are encouraging.
文摘A novel iterative technique, the phase descent search detection was proposed. This technique constrained the solution （PDS） algorithm, for M-ary phase shift keying （M-PSK） symbols to have a unit magnitude and it was based on coordinate descent iterations where coordinates were the unknown symbol phases. The PDS algorithm, together with a descent local search （also implemented as a version of the PDS algorithm）, was used multiple times with different initializations in a proposed multiple phase detector; the solution with the minimum cost was then chosen as the final solution. The simulation results show that for highly loaded multiuser scenarios, the proposed technique has a detection performance that is close to the single-user bound. The results also show that the multiple phase detector allows detection in highly overloaded scenarios and it exhibits near-far resistance. In particular, the detector has a performance that is significantly better, and complexity that is significantly lower, than that of the detector based on semi-definite relaxation.
基金This project was supported by the National Natural Science Foundation (No. 69875010).
文摘A nonlinear visual mapping model is presented to replace the image Jacobian relation for uncalibrated hand/eye coordination. A new visual tracking controller based on artificial neural network is designed. Simulation results show that this method can drive the static tracking error to zero quickly and keep good robustness and adaptability at the same time. In addition, the algorithm is very easy to be implemented with low computational complexity.
基金Supported by National Natural Science Foundation of P. R. China (69804003, 50576022)the Natural Science Foundation of Beijing (4062030)
文摘In unit steam-boiler generation, a coordinated control strategy is required to ensure a higher rate of load change without violating thermal constraints. The process is characterized by nonlinearity and uncertainty. While neural networks can model highly complex nonlinear dynamical systems, they produce black box models. This has led to significant interest in neuro-fuzzy networks (NFNs) to represent a nonlinear dynamical process by a set of locally valid and simpler submodels. Two alternative methods of exploiting the NFNs within a generalised predictive control (GPC) framework for nonlinear model predictive control are described. Coordinated control of steam-boiler generation using the two nonlinear GPC methods show excellent tracking and disturbance rejection results and improved performance compared with conventional linear GPC.
基金This project was supported by the National Nature Science Foundation of China( 60074004).
文摘An intelligent coordinated control strategy has been proposed and successfully applied to a 300MW boiler-turbine unit i. e. Unit 1 of Yuanbaoshan power plant in China. Load following operation of coal-fired boiler-turbine unit in the power plant leads to changes in operating points which result in nonlinear variations of the plant variables and parameters. For the variation of operating condition and slowly varying dynamics, an intelligent control scheme has been developed by combining fuzzy self-tuning with adaptive control and auto-tuning techniques. As there exist strong couplings between control loops of main steam pressure and power output in the unit, a new design for static decoupler aimed at decoupling for setpoints and unmeasured pulverized coal disturbance of the system at the same time is presented. Satisfactory industrial application results show that such a control system has enhanced adaptability and robustness to the complex process, and better control performance and high economic benefit have been obtained.
