The low temperature phase transformation in the Cu_2ZnSnS_4（CZTS） films was investigated by laser annealing and low temperature thermal annealing.The Raman measurements show that a-high-power laser annealing could c...The low temperature phase transformation in the Cu_2ZnSnS_4（CZTS） films was investigated by laser annealing and low temperature thermal annealing.The Raman measurements show that a-high-power laser annealing could cause a red shift of the Raman scattering peaks of the kesterite（KS） structure and promotes the formation of the partially disordered kesterite（PD-KS） structure in the CZTS films,and the low-temperature thermal annealing only shifts the Raman scattering peak of KS phase by several wavenumber to low frequency and the broads Raman peaks in the low frequency region.Moreover,the above two processes were reversible.The Raman analyses of the CZTS samples prepared under different process show that the PD-KS structure tends to be found at low temperatures and low sulfur vapor pressures.Our results reveal that the control of the phase structure in CZTS films is feasible by adjusting the preparation process of the films.展开更多
The transient radial shearing interferometry technique based on fast Fourier transform(FFT)provides a means for the measurement of the wavefront phase of transient light field.However,which factors affect the spatial ...The transient radial shearing interferometry technique based on fast Fourier transform(FFT)provides a means for the measurement of the wavefront phase of transient light field.However,which factors affect the spatial bandwidth of the wavefront phase measurement of this technology and how to achieve high-precision measurement of the broad-band transient wavefront phase are problems that need to be studied further.To this end,a theoretical model of phase-retrieved bandwidth of radial shearing interferometry is established in this paper.The influence of the spatial carrier frequency and the calculation window on phase-retrieved bandwidth is analyzed,and the optimal carrier frequency and calculation window are obtained.On this basis,a broad-band transient radial shearing interference phase-retrieval method based on chirp Z transform(CZT)is proposed,and the corresponding algorithm is given.Through theoretical simulation,a known phase is used to generate the interferogram and it is retrieved by the traditional method and the proposed method respectively.The residual wavefront RMS of the traditional method is 0.146λ,and it is 0.037λfor the proposed method,which manifests an improvement of accuracy by an order of magnitude.At the same time,different levels of signal-to-noise ratios(SNRs)from 50 dB to 10 dB of the interferogram are simulated,and the RMS of the residual wavefront is from 0.040λto 0.066λ.In terms of experiments,an experimental verification device based on a phase-only spatial light modulator is built,and the known phase on the modulator is retrieved from the actual interferogram.The RMS of the residual wavefront retrieved through FFT is 0.112λ,and it decreases to 0.035λthrough CZT.The experimental results verify the effectiveness of the method proposed in this paper.Furthermore,the method can be used in other types of spatial carrier frequency interference,such as lateral shearing interference,rotational shearing interference,flipping shearing interference,and four-wave shearing interference.展开更多
基金Project supported by the Natural Science Foundation for Youth Fund of Hebei Province,China(Grant No.A2016201087)the Specialized Research Fund for the Doctoral Program of Higher Education of China(Grant No.20131301120003)the National Natural Science Foundation of China(Grant Nos.11504078and 61504054)
文摘The low temperature phase transformation in the Cu_2ZnSnS_4（CZTS） films was investigated by laser annealing and low temperature thermal annealing.The Raman measurements show that a-high-power laser annealing could cause a red shift of the Raman scattering peaks of the kesterite（KS） structure and promotes the formation of the partially disordered kesterite（PD-KS） structure in the CZTS films,and the low-temperature thermal annealing only shifts the Raman scattering peak of KS phase by several wavenumber to low frequency and the broads Raman peaks in the low frequency region.Moreover,the above two processes were reversible.The Raman analyses of the CZTS samples prepared under different process show that the PD-KS structure tends to be found at low temperatures and low sulfur vapor pressures.Our results reveal that the control of the phase structure in CZTS films is feasible by adjusting the preparation process of the films.
基金Project supported by the National Natural Science Foundation of China(Grant No.61705254)the Key Research and Development Program of Shaanxi Province of China(Grant No.2020GY-114).
文摘The transient radial shearing interferometry technique based on fast Fourier transform(FFT)provides a means for the measurement of the wavefront phase of transient light field.However,which factors affect the spatial bandwidth of the wavefront phase measurement of this technology and how to achieve high-precision measurement of the broad-band transient wavefront phase are problems that need to be studied further.To this end,a theoretical model of phase-retrieved bandwidth of radial shearing interferometry is established in this paper.The influence of the spatial carrier frequency and the calculation window on phase-retrieved bandwidth is analyzed,and the optimal carrier frequency and calculation window are obtained.On this basis,a broad-band transient radial shearing interference phase-retrieval method based on chirp Z transform(CZT)is proposed,and the corresponding algorithm is given.Through theoretical simulation,a known phase is used to generate the interferogram and it is retrieved by the traditional method and the proposed method respectively.The residual wavefront RMS of the traditional method is 0.146λ,and it is 0.037λfor the proposed method,which manifests an improvement of accuracy by an order of magnitude.At the same time,different levels of signal-to-noise ratios(SNRs)from 50 dB to 10 dB of the interferogram are simulated,and the RMS of the residual wavefront is from 0.040λto 0.066λ.In terms of experiments,an experimental verification device based on a phase-only spatial light modulator is built,and the known phase on the modulator is retrieved from the actual interferogram.The RMS of the residual wavefront retrieved through FFT is 0.112λ,and it decreases to 0.035λthrough CZT.The experimental results verify the effectiveness of the method proposed in this paper.Furthermore,the method can be used in other types of spatial carrier frequency interference,such as lateral shearing interference,rotational shearing interference,flipping shearing interference,and four-wave shearing interference.
