Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle li...Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle life caused by volume expansion and low electrical conductivity of phosphides in SIBs remain still unsolved.To address these issues,GeP_(3) was first prepared by high-energy ball milling,and then Ketjen black(KB)was introduced to synthesize composite GeP_(3)/KB anode materials under controlled milling speed and time by a secondary ball milling process.During the ball milling process,GeP_(3) and KB form strong chemical bonds,resulting in a closely bonded composite.Consequently,the GeP_(3)/KB anodes was demonstrated excellent sodium storage performance,achieving a high reversible capacity of 933.41 mAh·g^(–1) at a current density of 0.05 A·g^(–1) for a special formula of GeP_(3)/KB-600-40 sample prepared at ball milling speed of 600 r/min for 40 h.Even at a high current density of 2 A·g^(–1) over 200 cycles,the capacity remains 314.52 mAh·g^(–1) with a retention rate of 66.6%.In conclusion,this work successfully prepares GeP_(3)/KB anode-carbon composite for electrodes by high-energy ball milling,which can restrict electrode volume expansion,enhance capacity,and improve cycle stability of SIBs.展开更多
As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation ...As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation and fragmentation.This ultimately leads to a decrease in cell capacity.The trends of volume expansion and capacity change of the SiO/graphite(SiO/C)composite electrode during cycling were investigated via in situ expansion monitoring.First,a series of expansion test schemes were designed,and the linear relationship between negative electrode expansion and cell capacity degradation was quantitatively analyzed.Then,the effects of different initial pressures on the long-term cycling performance of the cell were evaluated.Finally,the mechanism of their effects was analyzed by scanning electron microscope.The results show that after 50 cycles,the cell capacity decreases from 2.556 mAh to 1.689 mAh,with a capacity retention ratio(CRR)of only 66.08%.A linear relationship between the capacity retention ratio and thickness expansion was found.Electrochemical measurements and scanning electron microscope images demonstrate that intense stress inhibits the lithiation of the negative electrode and that the electrode is more susceptible to irreversible damage during cycling.Overall,these results reveal the relationship between the cycling performance of SiO and the internal pressure of the electrode from a macroscopic point of view,which provides some reference for the application of SiO/C composite electrodes in lithium-ion batteries.展开更多
The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditiona...The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.展开更多
The densification rate of C/C composites fabricated by directional flow thermal gradient chemical vapor infiltration process from C 3H 6, C 3H 6 N 2 and C 3H 6 H 2 was investigated respectively. The mechanism on the r...The densification rate of C/C composites fabricated by directional flow thermal gradient chemical vapor infiltration process from C 3H 6, C 3H 6 N 2 and C 3H 6 H 2 was investigated respectively. The mechanism on the role of carrier gas in chemical vapor infiltration was also discussed. The results shows that whether or not adding N 2 as carrier gas has little influences on the densification behavior of C/C composites with the controlled temperature, the partial pressure of hydrocarbon and the effective residence time of the gas phase remain constant. When the controlled temperature is not less than 1 173 K,using N 2 or H 2 as carrier gas makes pronounced differences in densifying of C/C composites. The average bulk density of C/C composites from C 3H 6 H 2 is eight to ten percent higher than that from C 3H 6 N 2. However, when the controlled temperature is not higher than 1 123 K,the densification rate of C/C composites from C 3H 6 H 2 is much lower than that from C 3H 6 N 2, which implies that effects of carrier gas on densification of C/C composites are closely related to the type of carrier gas and infiltration temperature. At higher temperature, using H 2 as carrier gas is favorable to the densification of C/C composites, while at lower temperature, hydrogen, acting as reactive gas, can inhibit the formation of pyrolytic carbon.展开更多
Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical micro...Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical microscope and polarizing light microscope were used to characterize the microstructure of 3D C/C.The microscopy results show that large number of pores and cracks exist at both bundle/matrix interface and pitch carbon matrix.These defects have important effect on the mechanical behavior of 3D C/C.The in situ properties for components of 3D C/C were acquired by nanoindentation technique.Relative to the matrix sample,the fiber samples have more larger values for modulus,stiffness and hardness.However,there is no significant difference of modulus and stiffness among fiber samples with different directions.展开更多
The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0&#...The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up, were quantitatively evaluated by performing the ablation tests with an engine torch. And their ablation discrepancies were analyzed according to the surface characteristic, porosity and thermal diffusivity. The results show that the 0°/45° weftless composite has a fiat eroded surface with no obvious macroscopic pits. Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%, 25.0% and 27.5%, and 17.5% and 19.4% compared with those of the mat, the 0°/90° weftless and the 0°/45° twill composites, respectively. The ablation properties are mainly controlled by the thermo-chemical effect （oxidation）, and a little by the thermo-mechanical effect （mechanical denudation）. The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.展开更多
C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, silico...C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, siliconizing, liquid phase impregnation and carbonization. The wear and friction properties were tested by an MM-1000 wet friction machine. The results show that SiC phases are mainly distributed between carbon fibers and pyrocarbons as well as among the pryoearbons. The dynamic friction coefficient of the composites decreases gradually from 0.126 to 0.088 with the increase of the surface pressure from 0.5 to 2.5 MPa at the same rotary speed. Furthermore, under the constant surface pressure, the dynamic friction coefficient increases from 0.114 to 0.126 with the increase of the rotary speed from 1 500 to 2 500 r/min. However, the coefficient decreases to 0.104 when the rotary speed exceeds 4 500 r/min. During the friction process, the friction coefficient of C/C-SiC composite is between 0.088 and 0.126, and the wear value is zero after 300 times brake testing.展开更多
In the present study,the unique three-dimensional graphene coated nickel(Ni/C)foam reinforced silicon carbide(Ni/C@SiC)composites were first obtained via the precursor impregnation and pyrolysis(PIP)processes.The micr...In the present study,the unique three-dimensional graphene coated nickel(Ni/C)foam reinforced silicon carbide(Ni/C@SiC)composites were first obtained via the precursor impregnation and pyrolysis(PIP)processes.The microstructure images indicated that the SiC fillers were successfully prepared in the skeleton pores of the Ni/C foam.The influence of the PIP cycles on the microwave absorption performances was researched,and the results indicated that after the primary PIP process,Ni/C@SiC-I possessed the optimal microwave absorbing performance with a minimum reflection loss(RL)of-25.87 d B at 5.28 GHz and 5.00 mm.Besides,the RL values could be below-10.00 dB from 5.88 GHz to 7.74 GHz when the corresponding matching thickness was 3.85 mm.However,the microwave absorption properties of Ni/C@SiC-II and Ni/C@SiC-Ⅲwere tremendously degraded as the PIP times increased.At last,the electromagnetic parameter,dielectric loss,attenuation constant as well as impedance matching coefficient were further investigated to analyze the absorbing mechanism,which opened a new path for the certain scientific evaluation of the absorbing materials and had extremely important to the defence technology.展开更多
B4C/6061Al composites reinforced with nano-to micrometer-sized B4C particles were fabricated via powder metallurgy route consisting of spark plasma sintering(SPS)and hot extrusion and rolling(HER),followed by T6 treat...B4C/6061Al composites reinforced with nano-to micrometer-sized B4C particles were fabricated via powder metallurgy route consisting of spark plasma sintering(SPS)and hot extrusion and rolling(HER),followed by T6 treatment.The microstructural evolution and mechanical properties were investigated.Results showed that the status of B4C particles changed from a network after SPS to a dispersion distribution after HER.The substructured grains reached 66.5%owing to the pinning effect of nano-sized B4C,and the grain size was refined from 3.12μm to 1.56μm after HER.After T6 treatment,dispersed Mg_(2)Si precipitated phases formed,and the grain size increased to 1.87μm.Fine recrystallized grains around micro-sized B4C were smaller than those in the areas with uniform distribution of nano-sized B4C and Mg_(2)Si.The stress distributions of as-rolled and heated composites were similar,considering that the T6 heat treatment was only effective in eliminating the first internal stress.The Vickers,microhardness,and tensile strength of as-SPSed composites were greatly improved from HV 55.45,0.86 GPa,and 180 MPa to HV 77.51,1.08 GPa,and 310 MPa,respectively.Despite the precipitation strengthening,the corresponding values of as-heated composites decreased to HV 70.82,0.85 GPa,and 230 MPa owing to grain coarsening.展开更多
In order to improve the friction-wear properties of the C/C composites for aircraft brake pairs, the fric-tion behavior of samples with infiltrating Si was investigated. The influence of Si smearing thickness on frict...In order to improve the friction-wear properties of the C/C composites for aircraft brake pairs, the fric-tion behavior of samples with infiltrating Si was investigated. The influence of Si smearing thickness on frictionproperties was studied in detail. The results show that with the increase of Si smearing thickness and β-SiC content,the friction coefficient reduces from 0.40 to 0.30; the linear wear of stators increases from 2.0 μm to 18.9 μm percycle, and that of rotors increases from 1.4 μm to 22.6 μm per cycle; mass wear of stators increases from 20.6 mgto 126.9 mg per cycle, and that of rotors increases from 13.7 mg to 166.2 mg per cycle. On the other hand, whena large number of inhomogeneous β-SiC particulates are performed, friction surfaces of the samples flake off layer bylayer and many nicks are observed.展开更多
The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar （RL） pyrocarbon and a smooth laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy....The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar （RL） pyrocarbon and a smooth laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy. The full width at half maximum （FWHM） of the D-band indicates the amount of defects in the in-plane lattice, while the G-to-D band intensity （peak area） ratios （lC/ID） is used to evaluate the degree of graphitization. The results show that the FWHM of D-band of sample with RL pyrocarbon changes greatly from 36 cm-1 to 168 cm 1 after braking tests, which indicates that a large number of lattice defects are produced on its wear surface. However, the graphitization degree of resin-derived carbon sample rises significantly, because the IC/1D increases from 0.427 to 0.928. Braking tests under normal loading conditions, involving high temperature and high pressure, produce a lot of lattice defects on the wear surface, and induce the graphitization of the surface. Sample with RL pyrocarbon having a low hardness is easy to deform, and has the most lattice defects on the wear surface after braking. While raw materials with resin-derived carbon have the lowest graphitization degree which rises greatly during braking.展开更多
The effects of Ti-Mo-V composite addition on the evolution of precipitates in marine 10Ni5CrMoV steel andthe corresponding strength and toughness mechanisms were systematically investigated.Ti-Mo-V composite addition ...The effects of Ti-Mo-V composite addition on the evolution of precipitates in marine 10Ni5CrMoV steel andthe corresponding strength and toughness mechanisms were systematically investigated.Ti-Mo-V composite addition canform the Ti_(x)Mo_(y)V_(z)C carbide with TiC as core and Mo-V as shell in the order of Ti(C)→V→Mo.The yield strength of thespecimens is increased from 815 MPa to 876 MPa due to the nanoscale precipitates enhancing the pinning effect on grainboundaries and dislocations,and the contribution of precipitation and dislocation strengthening is increased.The decrease of ductile-brittle transition temperature from−103 to−116℃is attributed to the decrease in equivalent grainsize and the increase of high-angle grain boundary misorientation,which hinders the initiation and propagation of cracks.When the mass fraction of Ti is 0.05%,the strength and cryogenic toughness can be improved synergistically,which alsoprovides a theoretical basis and experimental reference for exploring the more excellent combination of strength andcryogenic toughness of marine 10Ni5CrMoV steel.展开更多
基金National Natural Science Foundation of China Young Scientist Fund(22105120)Shaanxi Province Qin Chuangyuan“Scientist+Engineer”Team Construction Project(2024QCY-KXJ-127)。
文摘Metal phosphides have been studied as prospective anode materials for sodium-ion batteries(SIBs)due to their higher specific capacity compared to other anode materials.However,rapid capacity decay and limited cycle life caused by volume expansion and low electrical conductivity of phosphides in SIBs remain still unsolved.To address these issues,GeP_(3) was first prepared by high-energy ball milling,and then Ketjen black(KB)was introduced to synthesize composite GeP_(3)/KB anode materials under controlled milling speed and time by a secondary ball milling process.During the ball milling process,GeP_(3) and KB form strong chemical bonds,resulting in a closely bonded composite.Consequently,the GeP_(3)/KB anodes was demonstrated excellent sodium storage performance,achieving a high reversible capacity of 933.41 mAh·g^(–1) at a current density of 0.05 A·g^(–1) for a special formula of GeP_(3)/KB-600-40 sample prepared at ball milling speed of 600 r/min for 40 h.Even at a high current density of 2 A·g^(–1) over 200 cycles,the capacity remains 314.52 mAh·g^(–1) with a retention rate of 66.6%.In conclusion,this work successfully prepares GeP_(3)/KB anode-carbon composite for electrodes by high-energy ball milling,which can restrict electrode volume expansion,enhance capacity,and improve cycle stability of SIBs.
基金supported by the Fundamental Research Funds for the Central Universities(WK2090000055)Anhui Provincial Natural Science Foundation of China(2308085QG231).
文摘As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation and fragmentation.This ultimately leads to a decrease in cell capacity.The trends of volume expansion and capacity change of the SiO/graphite(SiO/C)composite electrode during cycling were investigated via in situ expansion monitoring.First,a series of expansion test schemes were designed,and the linear relationship between negative electrode expansion and cell capacity degradation was quantitatively analyzed.Then,the effects of different initial pressures on the long-term cycling performance of the cell were evaluated.Finally,the mechanism of their effects was analyzed by scanning electron microscope.The results show that after 50 cycles,the cell capacity decreases from 2.556 mAh to 1.689 mAh,with a capacity retention ratio(CRR)of only 66.08%.A linear relationship between the capacity retention ratio and thickness expansion was found.Electrochemical measurements and scanning electron microscope images demonstrate that intense stress inhibits the lithiation of the negative electrode and that the electrode is more susceptible to irreversible damage during cycling.Overall,these results reveal the relationship between the cycling performance of SiO and the internal pressure of the electrode from a macroscopic point of view,which provides some reference for the application of SiO/C composite electrodes in lithium-ion batteries.
文摘The development of advanced aircraft relies on high performance thermal-structural materials,and carbon/carbon com-posites(C/C)composited with ultrahigh-temperature ceramics are ideal candidates.However,the traditional routes of compositing are either inefficient and expensive or lead to a non-uniform distribution of ceramics in the matrix.Compared with the traditional C/C-ZrC-SiC composites prepared by the reactive melt infiltration of ZrSi_(2),C/C-ZrB_(2)-ZrC-SiC composites prepared by the vacuum infiltration of ZrB_(2) combined with reactive melt infiltration have the higher content and more uniform distribution of the introduced ceramic phases.The mass and linear ablation rates of the C/C-ZrB_(2)-ZrC-SiC composites were respectively 68.9%and 29.7%lower than those of C/C-ZrC-SiC composites prepared by reactive melt infiltration.The ablation performance was improved because the volatilization of B_(2)O_(3),removes some of the heat,and the more uniformly distributed ZrO_(2),that helps produce a ZrO2-SiO2 continu-ous protective layer,hinders oxygen infiltration and decreases ablation.
文摘The densification rate of C/C composites fabricated by directional flow thermal gradient chemical vapor infiltration process from C 3H 6, C 3H 6 N 2 and C 3H 6 H 2 was investigated respectively. The mechanism on the role of carrier gas in chemical vapor infiltration was also discussed. The results shows that whether or not adding N 2 as carrier gas has little influences on the densification behavior of C/C composites with the controlled temperature, the partial pressure of hydrocarbon and the effective residence time of the gas phase remain constant. When the controlled temperature is not less than 1 173 K,using N 2 or H 2 as carrier gas makes pronounced differences in densifying of C/C composites. The average bulk density of C/C composites from C 3H 6 H 2 is eight to ten percent higher than that from C 3H 6 N 2. However, when the controlled temperature is not higher than 1 123 K,the densification rate of C/C composites from C 3H 6 H 2 is much lower than that from C 3H 6 N 2, which implies that effects of carrier gas on densification of C/C composites are closely related to the type of carrier gas and infiltration temperature. At higher temperature, using H 2 as carrier gas is favorable to the densification of C/C composites, while at lower temperature, hydrogen, acting as reactive gas, can inhibit the formation of pyrolytic carbon.
基金Project(61391) supported by the National Security Basic Research Program of ChinaProject (91016029) supported by the National Natural Science Foundation of China
文摘Nanoindentation tests were conducted to investigate the near-surface mechanical properties of the individual components(fiber and matrix) for three-dimensional reinforced carbon/carbon composites(3D C/C).Optical microscope and polarizing light microscope were used to characterize the microstructure of 3D C/C.The microscopy results show that large number of pores and cracks exist at both bundle/matrix interface and pitch carbon matrix.These defects have important effect on the mechanical behavior of 3D C/C.The in situ properties for components of 3D C/C were acquired by nanoindentation technique.Relative to the matrix sample,the fiber samples have more larger values for modulus,stiffness and hardness.However,there is no significant difference of modulus and stiffness among fiber samples with different directions.
基金Project(200202AA305207) supported by the National High Technology Research and Development Program of China
文摘The ablation properties of C/C composites with four different needled preforms prepared by isothermal chemical vapor infiltration （ICVI）, which are super-thin mat lay-up, 0°/90° weftless fabric lay-up, 0°/45° weftless fabric lay-up and 0°/45° twill fabric lay-up, were quantitatively evaluated by performing the ablation tests with an engine torch. And their ablation discrepancies were analyzed according to the surface characteristic, porosity and thermal diffusivity. The results show that the 0°/45° weftless composite has a fiat eroded surface with no obvious macroscopic pits. Its thickness and mass erosion rates are decreased by about 46.8% and 34.8%, 25.0% and 27.5%, and 17.5% and 19.4% compared with those of the mat, the 0°/90° weftless and the 0°/45° twill composites, respectively. The ablation properties are mainly controlled by the thermo-chemical effect （oxidation）, and a little by the thermo-mechanical effect （mechanical denudation）. The needling fiber bundles play an important role in accelerating the ablation process and resulting in the heterogeneous ablation.
基金Project(2006CB600901) supported by the Major State Basic Research and Development Program of ChinaProject(0991015) supported by Guangxi Science Found, ChinaProject(200808MS083) supported by Guangxi Education Department Found
文摘C/C-SiC composites with SiC island distribution Were prepared via a new processing route. The fabrication process mainly included silicon infiltration by ultrasonic vibration, chemical vapor deposition （CVD）, siliconizing, liquid phase impregnation and carbonization. The wear and friction properties were tested by an MM-1000 wet friction machine. The results show that SiC phases are mainly distributed between carbon fibers and pyrocarbons as well as among the pryoearbons. The dynamic friction coefficient of the composites decreases gradually from 0.126 to 0.088 with the increase of the surface pressure from 0.5 to 2.5 MPa at the same rotary speed. Furthermore, under the constant surface pressure, the dynamic friction coefficient increases from 0.114 to 0.126 with the increase of the rotary speed from 1 500 to 2 500 r/min. However, the coefficient decreases to 0.104 when the rotary speed exceeds 4 500 r/min. During the friction process, the friction coefficient of C/C-SiC composite is between 0.088 and 0.126, and the wear value is zero after 300 times brake testing.
基金supported by the Fundamental Research Funds for the Central Universities (Grant No. D5000210522 and D5000200408)Jiangsu Planned Projects for Postdoctoral Research Funds, National Natural Science Foundation of China [grant number 51772151]+2 种基金Natural Science Foundation of Shaanxi Province (Grant No. 2021JQ-117)Basic Research Programs of Taicang (Grant No.TC2020JC10)Natural Science Foundation of Shandong Province (Grant No. ZR2020QE180)
文摘In the present study,the unique three-dimensional graphene coated nickel(Ni/C)foam reinforced silicon carbide(Ni/C@SiC)composites were first obtained via the precursor impregnation and pyrolysis(PIP)processes.The microstructure images indicated that the SiC fillers were successfully prepared in the skeleton pores of the Ni/C foam.The influence of the PIP cycles on the microwave absorption performances was researched,and the results indicated that after the primary PIP process,Ni/C@SiC-I possessed the optimal microwave absorbing performance with a minimum reflection loss(RL)of-25.87 d B at 5.28 GHz and 5.00 mm.Besides,the RL values could be below-10.00 dB from 5.88 GHz to 7.74 GHz when the corresponding matching thickness was 3.85 mm.However,the microwave absorption properties of Ni/C@SiC-II and Ni/C@SiC-Ⅲwere tremendously degraded as the PIP times increased.At last,the electromagnetic parameter,dielectric loss,attenuation constant as well as impedance matching coefficient were further investigated to analyze the absorbing mechanism,which opened a new path for the certain scientific evaluation of the absorbing materials and had extremely important to the defence technology.
基金Projects(51775366,51805358)supported by the National Natural Science Foundation of ChinaProject(20130321024)supported by the Key Science and Technology Program of Shanxi Province,China。
文摘B4C/6061Al composites reinforced with nano-to micrometer-sized B4C particles were fabricated via powder metallurgy route consisting of spark plasma sintering(SPS)and hot extrusion and rolling(HER),followed by T6 treatment.The microstructural evolution and mechanical properties were investigated.Results showed that the status of B4C particles changed from a network after SPS to a dispersion distribution after HER.The substructured grains reached 66.5%owing to the pinning effect of nano-sized B4C,and the grain size was refined from 3.12μm to 1.56μm after HER.After T6 treatment,dispersed Mg_(2)Si precipitated phases formed,and the grain size increased to 1.87μm.Fine recrystallized grains around micro-sized B4C were smaller than those in the areas with uniform distribution of nano-sized B4C and Mg_(2)Si.The stress distributions of as-rolled and heated composites were similar,considering that the T6 heat treatment was only effective in eliminating the first internal stress.The Vickers,microhardness,and tensile strength of as-SPSed composites were greatly improved from HV 55.45,0.86 GPa,and 180 MPa to HV 77.51,1.08 GPa,and 310 MPa,respectively.Despite the precipitation strengthening,the corresponding values of as-heated composites decreased to HV 70.82,0.85 GPa,and 230 MPa owing to grain coarsening.
基金Project [1998(1817)] supported by the National High-Technology for Industrial Development of China
文摘In order to improve the friction-wear properties of the C/C composites for aircraft brake pairs, the fric-tion behavior of samples with infiltrating Si was investigated. The influence of Si smearing thickness on frictionproperties was studied in detail. The results show that with the increase of Si smearing thickness and β-SiC content,the friction coefficient reduces from 0.40 to 0.30; the linear wear of stators increases from 2.0 μm to 18.9 μm percycle, and that of rotors increases from 1.4 μm to 22.6 μm per cycle; mass wear of stators increases from 20.6 mgto 126.9 mg per cycle, and that of rotors increases from 13.7 mg to 166.2 mg per cycle. On the other hand, whena large number of inhomogeneous β-SiC particulates are performed, friction surfaces of the samples flake off layer bylayer and many nicks are observed.
基金Project(2006CB600906) supported by the National Basic Research Program of China
文摘The microstructure and texture of C/C composites with a resin-derived carbon, a rough laminar （RL） pyrocarbon and a smooth laminar pyrocarbon, before and after braking tests, were investigated by Raman spectroscopy. The full width at half maximum （FWHM） of the D-band indicates the amount of defects in the in-plane lattice, while the G-to-D band intensity （peak area） ratios （lC/ID） is used to evaluate the degree of graphitization. The results show that the FWHM of D-band of sample with RL pyrocarbon changes greatly from 36 cm-1 to 168 cm 1 after braking tests, which indicates that a large number of lattice defects are produced on its wear surface. However, the graphitization degree of resin-derived carbon sample rises significantly, because the IC/1D increases from 0.427 to 0.928. Braking tests under normal loading conditions, involving high temperature and high pressure, produce a lot of lattice defects on the wear surface, and induce the graphitization of the surface. Sample with RL pyrocarbon having a low hardness is easy to deform, and has the most lattice defects on the wear surface after braking. While raw materials with resin-derived carbon have the lowest graphitization degree which rises greatly during braking.
基金Project(2023YFE0200300)supported by the National Key K&D Program of ChinaProject(52174303,51874084)supported by the National Natural Science Foundation of ChinaProject(B21001)supported by the Introducing Talents of Discipline to Universities,China。
文摘The effects of Ti-Mo-V composite addition on the evolution of precipitates in marine 10Ni5CrMoV steel andthe corresponding strength and toughness mechanisms were systematically investigated.Ti-Mo-V composite addition canform the Ti_(x)Mo_(y)V_(z)C carbide with TiC as core and Mo-V as shell in the order of Ti(C)→V→Mo.The yield strength of thespecimens is increased from 815 MPa to 876 MPa due to the nanoscale precipitates enhancing the pinning effect on grainboundaries and dislocations,and the contribution of precipitation and dislocation strengthening is increased.The decrease of ductile-brittle transition temperature from−103 to−116℃is attributed to the decrease in equivalent grainsize and the increase of high-angle grain boundary misorientation,which hinders the initiation and propagation of cracks.When the mass fraction of Ti is 0.05%,the strength and cryogenic toughness can be improved synergistically,which alsoprovides a theoretical basis and experimental reference for exploring the more excellent combination of strength andcryogenic toughness of marine 10Ni5CrMoV steel.
