The P-branch emission spectra of (4,1) and (3,1) bands of the A^1П-X^1∑^+ system of IrN molecule are studied using an analytical formula which is derived from elementary expression of molecular total energy by...The P-branch emission spectra of (4,1) and (3,1) bands of the A^1П-X^1∑^+ system of IrN molecule are studied using an analytical formula which is derived from elementary expression of molecular total energy by taking multiple spectral differences. It not only reproduces the known experimental transition lines, but also predicts the unknown spectral lines up to J = 80 for each band by using a group of fifteen known experimental transition lines.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.11074204)the Science Foundation of the Ministry of Education of China (Grant No.20100181110085)+1 种基金the Research Fund of Key Disciplines of Atomic and Molecular Physicsthe Fund of Key Laboratory of Advanced Scientific Computation,Xihua University,China
文摘The P-branch emission spectra of (4,1) and (3,1) bands of the A^1П-X^1∑^+ system of IrN molecule are studied using an analytical formula which is derived from elementary expression of molecular total energy by taking multiple spectral differences. It not only reproduces the known experimental transition lines, but also predicts the unknown spectral lines up to J = 80 for each band by using a group of fifteen known experimental transition lines.