The aging process of pure copper precursors and copper-zinc binary precursorswere studied by XRD, TG-DTG and TPR techniques. The catalytic activity and stability of CuO/ZnOwere tested using fixed-bed flow reactor, and...The aging process of pure copper precursors and copper-zinc binary precursorswere studied by XRD, TG-DTG and TPR techniques. The catalytic activity and stability of CuO/ZnOwere tested using fixed-bed flow reactor, and the physical properties of the catalysts and Cuspecies were characterized with N_2 adsorption and N_2O passivation method, respectively. For theCu-Zn binary system prepared at the precipitating condition of pH=8.0 and temperature=80℃, theinitial phase was a mixture of copper nitrate hydroxide Cu_2(NO_3)(OH)_3, georgeite and hydrozinciteZn_5(CO_3)_2(OH)_6. By increasing the duration of its aging time, the phase of Cu_2(NO_3)(OH)_2first transited to georgeite, and then interdiffused into Zn_5(CO_3)_2(OH)_6 and resulted in two newphases: rosasite (Cu,Zn)_2CO_3(OH)_2 and au-richalcite (Zn,Cu)_5(CO_3)_2(OH)_6. The former phasewas much easier to be formed than the latter one, while the latter phase was more responsible forthe activity of methanol synthesis than the former one. It is found that the composition andstructure of the precursors altered obviously after the colour transition point. The experimentalresults showed that methanol synthesis is a structure-sensitive catalytic reaction.展开更多
The Fenghua River Bridge is a major structure on the highway between Hengzhang and Guojiachi, which is to be built with a four-span prestress concrete (PC) box girder and symmetrical cantilever castings. In this paper...The Fenghua River Bridge is a major structure on the highway between Hengzhang and Guojiachi, which is to be built with a four-span prestress concrete (PC) box girder and symmetrical cantilever castings. In this paper, a finite element method (FEM) model is set up to study the effects of concrete differential aging time on the construction phases of the Fenghua River Bridge by calculating the vertical displacement of the folding segment of the middle span and the longitudinal bending moment of Pier 12#. In the model, the girders are classified into 150 changing sections based on the desgn scheme, and their construction is to be carried in 16 phases respectively to build 12 blocks connected by a side folding segment and a middle folding segment, covered with a second dead load and in completion for 20 years. It is found that the internal forces and deformations of the concrete structures at the aging time of 60 d are quite different from those of 0 d aging time while the behaviors of the structures of 120 d aging time is nearly the same as those of 60 d aging time― the differences are so small that can be neglected, suggesting that the creep develops obviously about one month after the cement is hardened and the development fades later on.展开更多
Well-crystallized high-silica NaY zeolites （Si/Al〉2.5） were prepared from a reaction mixture consisting of metakaolin, sodium silicate solution and seed solution via optimization of the mixture composition and reac...Well-crystallized high-silica NaY zeolites （Si/Al〉2.5） were prepared from a reaction mixture consisting of metakaolin, sodium silicate solution and seed solution via optimization of the mixture composition and reaction conditions. The transformation from kaolin to high-silica NaY zeolite was confirmed by XRD, SEM and IR techniques. Subsequently, the influence of synthesis parameters, i.e. initial SIO2/Al2O3, initial Na2O/SiO2, initial H2O/SiO2, aging time of the seed solution, crystallization temperature and crystallization time, on the NaY growth was investigated in terms of crystallinity and Si/Al ratio. The results showed that the effects of initial SiO2/Al2O3, initial Na2O/SiO2 and initial H2O/ SiO2 on the crystaIlinity and Si/Al ratio of NaY zeolite are similar to those observed in the conventional syntheses of NaY zeolites only using sodium silicate solution as silicon source. However, due to the use of metakaolin as the main silicon and aluminum sources in the present study, a long crystallization induction period of 20 h was achieved, which can be attributed to the dissolution of metakaolin. In addition, different from the conventional syntheses of zeolite NaY, pure NaY zeolites （i.e. without NaP zeolite impurity） were still obtained even at 120℃ because of the use of a large quantity of seed solution （23 wt%） in the reaction mixture. As the aging time of the seed solution increased from 3.5 h to 22 h, the relative crystallinity of the NaY zeolite first increased sharply and then reached a plateau, while the Si/Al ratio first increased rapidly up to a maximum value of 2.75 corresponding to an aging time of 6.5 h, and then decreased sharply with the aging time.展开更多
文摘The aging process of pure copper precursors and copper-zinc binary precursorswere studied by XRD, TG-DTG and TPR techniques. The catalytic activity and stability of CuO/ZnOwere tested using fixed-bed flow reactor, and the physical properties of the catalysts and Cuspecies were characterized with N_2 adsorption and N_2O passivation method, respectively. For theCu-Zn binary system prepared at the precipitating condition of pH=8.0 and temperature=80℃, theinitial phase was a mixture of copper nitrate hydroxide Cu_2(NO_3)(OH)_3, georgeite and hydrozinciteZn_5(CO_3)_2(OH)_6. By increasing the duration of its aging time, the phase of Cu_2(NO_3)(OH)_2first transited to georgeite, and then interdiffused into Zn_5(CO_3)_2(OH)_6 and resulted in two newphases: rosasite (Cu,Zn)_2CO_3(OH)_2 and au-richalcite (Zn,Cu)_5(CO_3)_2(OH)_6. The former phasewas much easier to be formed than the latter one, while the latter phase was more responsible forthe activity of methanol synthesis than the former one. It is found that the composition andstructure of the precursors altered obviously after the colour transition point. The experimentalresults showed that methanol synthesis is a structure-sensitive catalytic reaction.
文摘The Fenghua River Bridge is a major structure on the highway between Hengzhang and Guojiachi, which is to be built with a four-span prestress concrete (PC) box girder and symmetrical cantilever castings. In this paper, a finite element method (FEM) model is set up to study the effects of concrete differential aging time on the construction phases of the Fenghua River Bridge by calculating the vertical displacement of the folding segment of the middle span and the longitudinal bending moment of Pier 12#. In the model, the girders are classified into 150 changing sections based on the desgn scheme, and their construction is to be carried in 16 phases respectively to build 12 blocks connected by a side folding segment and a middle folding segment, covered with a second dead load and in completion for 20 years. It is found that the internal forces and deformations of the concrete structures at the aging time of 60 d are quite different from those of 0 d aging time while the behaviors of the structures of 120 d aging time is nearly the same as those of 60 d aging time― the differences are so small that can be neglected, suggesting that the creep develops obviously about one month after the cement is hardened and the development fades later on.
基金supported by Beijing Natural Science Foundation (Grant No.2093043)the National Natural Science Foundation of China (Grant No.20606038)
文摘Well-crystallized high-silica NaY zeolites （Si/Al〉2.5） were prepared from a reaction mixture consisting of metakaolin, sodium silicate solution and seed solution via optimization of the mixture composition and reaction conditions. The transformation from kaolin to high-silica NaY zeolite was confirmed by XRD, SEM and IR techniques. Subsequently, the influence of synthesis parameters, i.e. initial SIO2/Al2O3, initial Na2O/SiO2, initial H2O/SiO2, aging time of the seed solution, crystallization temperature and crystallization time, on the NaY growth was investigated in terms of crystallinity and Si/Al ratio. The results showed that the effects of initial SiO2/Al2O3, initial Na2O/SiO2 and initial H2O/ SiO2 on the crystaIlinity and Si/Al ratio of NaY zeolite are similar to those observed in the conventional syntheses of NaY zeolites only using sodium silicate solution as silicon source. However, due to the use of metakaolin as the main silicon and aluminum sources in the present study, a long crystallization induction period of 20 h was achieved, which can be attributed to the dissolution of metakaolin. In addition, different from the conventional syntheses of zeolite NaY, pure NaY zeolites （i.e. without NaP zeolite impurity） were still obtained even at 120℃ because of the use of a large quantity of seed solution （23 wt%） in the reaction mixture. As the aging time of the seed solution increased from 3.5 h to 22 h, the relative crystallinity of the NaY zeolite first increased sharply and then reached a plateau, while the Si/Al ratio first increased rapidly up to a maximum value of 2.75 corresponding to an aging time of 6.5 h, and then decreased sharply with the aging time.
