This study focuses on using a green reagent scheme of methanesulfonic acid (MSA) and citric acid (CA) to extract valuable metals from the cathodes, aiming to minimize environmental impact during the recycling process....This study focuses on using a green reagent scheme of methanesulfonic acid (MSA) and citric acid (CA) to extract valuable metals from the cathodes, aiming to minimize environmental impact during the recycling process. Leaching studies on LiCoO_(2) identified optimal conditions as follows: 2.4 mol/L MSA, 1.6 mol/L CA, S/L ratio of 80 g/L, leaching temperature of 90oC and leaching time of 6 h. The maximum Co and Li extraction achieved was 92% and 85%, respectively. LiCoO_(2) dissolution in MSA-CA leaching solution is highly impacted by temperature;Avrami equation showed a good fitting for the leaching data. The experimental activation energy of Co and Li was 50.98 kJ/mol and 50.55 kJ/mol, respectively, indicating that it is a chemical reaction-controlled process. Furthermore, cobalt was efficiently recovered from the leachate using oxalic acid, achieving a precipitation efficiency of 99.91% and a high-purity cobalt oxalate product (99.85 wt.%). In the MSA-CA leaching solution, MSA served as a lixiviant, while CA played a key role in reducing Co in LiCoO_(2). The overall organic acid leaching methodology presents an attractive option due to its reduced environmental impact.展开更多
It is still challenging for exploring high-active photocatalysts to efficiently remove levofloxacin(LFX)by activating peroxymonosulfate(PMS).Herein,we constructed a novel Z scheme ZnFe_(2)O_(4)/g-C_(3)N_(4)/CQDs(ZCC)h...It is still challenging for exploring high-active photocatalysts to efficiently remove levofloxacin(LFX)by activating peroxymonosulfate(PMS).Herein,we constructed a novel Z scheme ZnFe_(2)O_(4)/g-C_(3)N_(4)/CQDs(ZCC)heterojunction by anchoring ZnFe_(2)O_(4)on tubular-like g-C_(3)N_(4)induced by CQDs(denoted as CNC)using microwave-assisted thermal methods.The ZCC exhibits the highest photocatalytic activity in activating PMS for LFX degradation,endowing a removal rate~95.3%,which is 4.8 and 7.3 times that of pure ZnFe_(2)O_(4)(19.8%)and g-C_(3)N_(4)(13.1%),separately.The enhanced photocatalytic activity of ZCC can be attributed to the distinctive morphology of CNC,enhanced light response,increased specific surface area and abundant pore structure.Besides,the formed Z scheme heterojunction and CQDs acting as a transmission bridge of the photogenerated charges(e−and h+)can accelerate transfer and inhibit recombination of e−and h+.Radical capture experiments and electron spin resonance(ESR)measurements revealed that SO4•-and O2•-play a predominant role in degradation process of LFX.Liquid chromatography-mass spectrometry(LC-MS)was applied to identify intermediates and propose feasible degradation pathways of LFX.In conclusion,this study presents a promising strategy for regulating the photocatalytic activity of g-C_(3)N_(4)by simultaneously integrating CQDs induction and Z scheme heterojunction construction.展开更多
Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the e...Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the earth. And it will be the most important energy for the 21st century. The energy balance and numerical simulation are applied to study the schemes of the natural gas hydrates production in this paper,and it is considered that both depressurization and thermal stimulation are effective methods for exploiting natural gas hydrates, and that the gas production of the thermal stimulation is higher than that of the depressurization. But thermal stimulation is non-economic because it requires large amounts of energy.Therefore the combination of the two methods is a preferable method for the current development of the natural gas hydrates. The main factors which influence the production of natural gas hydrates are: the temperature of injected water, the injection rate, the initial saturation of the hydrates and the initial temperature of the reservoir which is the most important factor.展开更多
A concept of secret sharing scheme with the function of assignment is proposed. It provides great capabilities for many practical applications. In this scheme, the dealer can randomly assign one or more than one parti...A concept of secret sharing scheme with the function of assignment is proposed. It provides great capabilities for many practical applications. In this scheme, the dealer can randomly assign one or more than one participant to get the secret at any time, but these participants can get nothing about the secret before that moment. At the same time, the other participants cannot get anything about the secret by stealing the secret value when it is transferred. However, if the dealer is lost, a certain number or more partidtmnts of them can reoonstruct the secret by ccoperating. In order to clear this concept, an illustrating scheme with geometry method and a practical scheme with algebra method is given.展开更多
The Arbitrary accuracy Derivatives Riemann problem method(ADER) scheme is a new high order numerical scheme based on the concept of finite volume integration,and it is very easy to be extended up to any order of space...The Arbitrary accuracy Derivatives Riemann problem method(ADER) scheme is a new high order numerical scheme based on the concept of finite volume integration,and it is very easy to be extended up to any order of space and time accuracy by using a Taylor time expansion at the cell interface position.So far the approach has been applied successfully to flow mechanics problems.Our objective here is to carry out the extension of multidimensional ADER schemes to multidimensional MHD systems of conservation laws by calculating several MHD problems in one and two dimensions: (ⅰ) Brio-Wu shock tube problem,(ⅱ) Dai-Woodward shock tube problem,(ⅲ) Orszag-Tang MHD vortex problem.The numerical results prove that the ADER scheme possesses the ability to solve MHD problem,remains high order accuracy both in space and time,keeps precise in capturing the shock.Meanwhile,the compared tests show that the ADER scheme can restrain the oscillation and obtain the high order non-oscillatory result.展开更多
In view of that existing opening technologies of front cover for rocket launch canister have disadvantages such as causing damage on the ground equipment,not being reused and easily broken.A novel reusable non-separat...In view of that existing opening technologies of front cover for rocket launch canister have disadvantages such as causing damage on the ground equipment,not being reused and easily broken.A novel reusable non-separation spring-driven opening scheme is proposed to achieve rapid and reliable opening of the front cover.The mathematical model of the opening process of the front cover is established by the rigid body dynamics theory.To establish a response surface model to optimize the opening scheme,three main influencing factors of the opening process are obtained through the designed experiments,including the pre-compression,the stiffness of the thrust spring,and the thrust spring force arm length.In addition,the prescribed kinematic law was taken as constraint,and the smaller thrust spring preliminary pressure and angular velocity was taken as optimization expectations.The results show that the opening scheme meets the design requirements on opening process well.It also shows that the optimized scheme can reduce the kinetic energy of the front cover,and the impact on the canister effectively,achieving a reliable and rapid opening of the front cover.展开更多
The internal turbulent flow in conical diffuser is a very complicated adverse pressure gradient flow.DLR k-ε turbulence model was adopted to study it.The every terms of the Laplace operator in DLR k-ε turbulence mod...The internal turbulent flow in conical diffuser is a very complicated adverse pressure gradient flow.DLR k-ε turbulence model was adopted to study it.The every terms of the Laplace operator in DLR k-ε turbulence model and pressure Poisson equation were discretized by upwind difference scheme.A new full implicit difference scheme of 5-point was constructed by using finite volume method and finite difference method.A large sparse matrix with five diagonals was formed and was stored by three arrays of one dimension in a compressed mode.General iterative methods do not work wel1 with large sparse matrix.With algebraic multigrid method(AMG),linear algebraic system of equations was solved and the precision was set at 10-6.The computation results were compared with the experimental results.The results show that the computation results have a good agreement with the experiment data.The precision of computational results and numerical simulation efficiency are greatly improved.展开更多
A new hybrid numerical scheme of combining an E-CUSP(Energy-Convective Upwind and Split Pressure) method for the fluid part and the Constrained Transport(CT) for the magnetic induction part is proposed.In order to avo...A new hybrid numerical scheme of combining an E-CUSP(Energy-Convective Upwind and Split Pressure) method for the fluid part and the Constrained Transport(CT) for the magnetic induction part is proposed.In order to avoid the occurrence of negative pressure in the reconstructed profiles and its updated value,a positivity preserving method is provided.Furthermore,the MHD equations are solved at each physical time step by advancing in pseudo time.The use of dual time stepping is beneficial in the computation since the use of dual time stepping allows the physical time step not to be limited by the corresponding values in the smallest cell and to be selected based on the numerical accuracy criterion.This newly established hybrid scheme combined with positivity preserving method and dual time technique has demonstrated the accurateness and robustness through numerical experiments of benchmark problems such as the 2D Orszag-Tang vortex problem and the3 D shock-cloud interaction problem.展开更多
To improve the accuracy of strapdown inertial navigation system(SINS) for long term applications,the rotation technique is employed to modulate the errors of the inertial sensors into periodically varied signals,and,a...To improve the accuracy of strapdown inertial navigation system(SINS) for long term applications,the rotation technique is employed to modulate the errors of the inertial sensors into periodically varied signals,and,as a result,to suppress the divergence of SINS errors.However,the errors of rotation platform will be introduced into SINS and might affect the final navigation accuracy.Considering the disadvantages of the conventional navigation computation scheme,an improved computation scheme of the SINS using rotation technique is proposed which can reduce the effects of the rotation platform errors.And,the error characteristics of the SINS with this navigation computation scheme are analyzed.Theoretical analysis,simulations and real test results show that the proposed navigation computation scheme outperforms the conventional navigation computation scheme,meanwhile reduces the requirement to the measurement accuracy of rotation angles.展开更多
To assure the shareholders can look for their ＂legal＂ attorneys to renew the secret, once the secret sharing scheme is initialized, a secret sharing scheme with inherited characteristic is constructed. In this schem...To assure the shareholders can look for their ＂legal＂ attorneys to renew the secret, once the secret sharing scheme is initialized, a secret sharing scheme with inherited characteristic is constructed. In this scheme, each shareholder can produce a new share by his algorithm, which is equivalent to the primary one. Together with other shares, the primary secret can be renewed. Since this scheme is constructed not by replacing the primary share with a new share produced by the dealer in his primitive secret sharing scheme, so no matter how much shares the shareholder produces, these shares can not be gathered together to renew the secret in this scheme. Compared with the existing secret sharing schemes, this scheme provides more agility for the shareholders by investing each of them a function but not affect its security.展开更多
In the application of periodic data-gathering in sensor networks,sensor nodes located near the sink have to forward the data received from all other nodes to the sink,which depletes their energy very quickly.A moving ...In the application of periodic data-gathering in sensor networks,sensor nodes located near the sink have to forward the data received from all other nodes to the sink,which depletes their energy very quickly.A moving scheme for the sink based on local residual energy was proposed.In the scheme,the sink periodically moves to a new location with the highest stay-value defined by the average residual energy and the number of neighbors.The scheme can balance energy consumption and prevent nodes around sink from draining their energy very quickly in the networks.The simulation results show that the scheme can prolong the network lifetime by 26%-65%compared with the earlier schemes where the sink is static or moves randomly.展开更多
文摘This study focuses on using a green reagent scheme of methanesulfonic acid (MSA) and citric acid (CA) to extract valuable metals from the cathodes, aiming to minimize environmental impact during the recycling process. Leaching studies on LiCoO_(2) identified optimal conditions as follows: 2.4 mol/L MSA, 1.6 mol/L CA, S/L ratio of 80 g/L, leaching temperature of 90oC and leaching time of 6 h. The maximum Co and Li extraction achieved was 92% and 85%, respectively. LiCoO_(2) dissolution in MSA-CA leaching solution is highly impacted by temperature;Avrami equation showed a good fitting for the leaching data. The experimental activation energy of Co and Li was 50.98 kJ/mol and 50.55 kJ/mol, respectively, indicating that it is a chemical reaction-controlled process. Furthermore, cobalt was efficiently recovered from the leachate using oxalic acid, achieving a precipitation efficiency of 99.91% and a high-purity cobalt oxalate product (99.85 wt.%). In the MSA-CA leaching solution, MSA served as a lixiviant, while CA played a key role in reducing Co in LiCoO_(2). The overall organic acid leaching methodology presents an attractive option due to its reduced environmental impact.
基金Project(32272823) supported by the National Natural Science Foundation of ChinaProject(145309315) supported by the Research Foundation of Education Bureau of Heilongjiang Province of ChinaProject(YSTSXK202309) supported by the Plant Food Processing Technology Advantages Characteristic Discipline “Science and Technology Research” Special Project in Heilongjiang Province,China。
文摘It is still challenging for exploring high-active photocatalysts to efficiently remove levofloxacin(LFX)by activating peroxymonosulfate(PMS).Herein,we constructed a novel Z scheme ZnFe_(2)O_(4)/g-C_(3)N_(4)/CQDs(ZCC)heterojunction by anchoring ZnFe_(2)O_(4)on tubular-like g-C_(3)N_(4)induced by CQDs(denoted as CNC)using microwave-assisted thermal methods.The ZCC exhibits the highest photocatalytic activity in activating PMS for LFX degradation,endowing a removal rate~95.3%,which is 4.8 and 7.3 times that of pure ZnFe_(2)O_(4)(19.8%)and g-C_(3)N_(4)(13.1%),separately.The enhanced photocatalytic activity of ZCC can be attributed to the distinctive morphology of CNC,enhanced light response,increased specific surface area and abundant pore structure.Besides,the formed Z scheme heterojunction and CQDs acting as a transmission bridge of the photogenerated charges(e−and h+)can accelerate transfer and inhibit recombination of e−and h+.Radical capture experiments and electron spin resonance(ESR)measurements revealed that SO4•-and O2•-play a predominant role in degradation process of LFX.Liquid chromatography-mass spectrometry(LC-MS)was applied to identify intermediates and propose feasible degradation pathways of LFX.In conclusion,this study presents a promising strategy for regulating the photocatalytic activity of g-C_(3)N_(4)by simultaneously integrating CQDs induction and Z scheme heterojunction construction.
文摘Natural gas hydrates are a kind of nonpolluting and high quality energy resources for future, the reserves of which are about twice of the carbon of the current fossil energy (petroleum, natural gas and coal) on the earth. And it will be the most important energy for the 21st century. The energy balance and numerical simulation are applied to study the schemes of the natural gas hydrates production in this paper,and it is considered that both depressurization and thermal stimulation are effective methods for exploiting natural gas hydrates, and that the gas production of the thermal stimulation is higher than that of the depressurization. But thermal stimulation is non-economic because it requires large amounts of energy.Therefore the combination of the two methods is a preferable method for the current development of the natural gas hydrates. The main factors which influence the production of natural gas hydrates are: the temperature of injected water, the injection rate, the initial saturation of the hydrates and the initial temperature of the reservoir which is the most important factor.
基金This project was supported by Liuhui Applied Mathematics Center of Nankai University .
文摘A concept of secret sharing scheme with the function of assignment is proposed. It provides great capabilities for many practical applications. In this scheme, the dealer can randomly assign one or more than one participant to get the secret at any time, but these participants can get nothing about the secret before that moment. At the same time, the other participants cannot get anything about the secret by stealing the secret value when it is transferred. However, if the dealer is lost, a certain number or more partidtmnts of them can reoonstruct the secret by ccoperating. In order to clear this concept, an illustrating scheme with geometry method and a practical scheme with algebra method is given.
基金Supported by the National Natural Science Foundation of China(40904050,40874077)the Specialized Research Fund for State Key Laboratories
文摘The Arbitrary accuracy Derivatives Riemann problem method(ADER) scheme is a new high order numerical scheme based on the concept of finite volume integration,and it is very easy to be extended up to any order of space and time accuracy by using a Taylor time expansion at the cell interface position.So far the approach has been applied successfully to flow mechanics problems.Our objective here is to carry out the extension of multidimensional ADER schemes to multidimensional MHD systems of conservation laws by calculating several MHD problems in one and two dimensions: (ⅰ) Brio-Wu shock tube problem,(ⅱ) Dai-Woodward shock tube problem,(ⅲ) Orszag-Tang MHD vortex problem.The numerical results prove that the ADER scheme possesses the ability to solve MHD problem,remains high order accuracy both in space and time,keeps precise in capturing the shock.Meanwhile,the compared tests show that the ADER scheme can restrain the oscillation and obtain the high order non-oscillatory result.
文摘In view of that existing opening technologies of front cover for rocket launch canister have disadvantages such as causing damage on the ground equipment,not being reused and easily broken.A novel reusable non-separation spring-driven opening scheme is proposed to achieve rapid and reliable opening of the front cover.The mathematical model of the opening process of the front cover is established by the rigid body dynamics theory.To establish a response surface model to optimize the opening scheme,three main influencing factors of the opening process are obtained through the designed experiments,including the pre-compression,the stiffness of the thrust spring,and the thrust spring force arm length.In addition,the prescribed kinematic law was taken as constraint,and the smaller thrust spring preliminary pressure and angular velocity was taken as optimization expectations.The results show that the opening scheme meets the design requirements on opening process well.It also shows that the optimized scheme can reduce the kinetic energy of the front cover,and the impact on the canister effectively,achieving a reliable and rapid opening of the front cover.
基金Projects(59375211,10771178,10676031) supported by the National Natural Science Foundation of ChinaProject(07A068) supported by the Key Project of Hunan Education CommissionProject(2005CB321702) supported by the National Key Basic Research Program of China
文摘The internal turbulent flow in conical diffuser is a very complicated adverse pressure gradient flow.DLR k-ε turbulence model was adopted to study it.The every terms of the Laplace operator in DLR k-ε turbulence model and pressure Poisson equation were discretized by upwind difference scheme.A new full implicit difference scheme of 5-point was constructed by using finite volume method and finite difference method.A large sparse matrix with five diagonals was formed and was stored by three arrays of one dimension in a compressed mode.General iterative methods do not work wel1 with large sparse matrix.With algebraic multigrid method(AMG),linear algebraic system of equations was solved and the precision was set at 10-6.The computation results were compared with the experimental results.The results show that the computation results have a good agreement with the experiment data.The precision of computational results and numerical simulation efficiency are greatly improved.
基金Supported by the National Basic Research Program of China(2012CB825601)the National Natural Science Foundationof China(41031066,41231068,41274192,41074121,41204127)+1 种基金the Knowledge Innovation Program of the ChineseAcademy of Sciences(KZZD-EW-01-4)the Specialized Research Fund for State Key Laboratories
文摘A new hybrid numerical scheme of combining an E-CUSP(Energy-Convective Upwind and Split Pressure) method for the fluid part and the Constrained Transport(CT) for the magnetic induction part is proposed.In order to avoid the occurrence of negative pressure in the reconstructed profiles and its updated value,a positivity preserving method is provided.Furthermore,the MHD equations are solved at each physical time step by advancing in pseudo time.The use of dual time stepping is beneficial in the computation since the use of dual time stepping allows the physical time step not to be limited by the corresponding values in the smallest cell and to be selected based on the numerical accuracy criterion.This newly established hybrid scheme combined with positivity preserving method and dual time technique has demonstrated the accurateness and robustness through numerical experiments of benchmark problems such as the 2D Orszag-Tang vortex problem and the3 D shock-cloud interaction problem.
基金Project(60604011) supported by the National Natural Science Foundation of China
文摘To improve the accuracy of strapdown inertial navigation system(SINS) for long term applications,the rotation technique is employed to modulate the errors of the inertial sensors into periodically varied signals,and,as a result,to suppress the divergence of SINS errors.However,the errors of rotation platform will be introduced into SINS and might affect the final navigation accuracy.Considering the disadvantages of the conventional navigation computation scheme,an improved computation scheme of the SINS using rotation technique is proposed which can reduce the effects of the rotation platform errors.And,the error characteristics of the SINS with this navigation computation scheme are analyzed.Theoretical analysis,simulations and real test results show that the proposed navigation computation scheme outperforms the conventional navigation computation scheme,meanwhile reduces the requirement to the measurement accuracy of rotation angles.
基金This project was supported by Young Teacher Foundation of North China Elec. Power Univ.(200521001)
文摘To assure the shareholders can look for their ＂legal＂ attorneys to renew the secret, once the secret sharing scheme is initialized, a secret sharing scheme with inherited characteristic is constructed. In this scheme, each shareholder can produce a new share by his algorithm, which is equivalent to the primary one. Together with other shares, the primary secret can be renewed. Since this scheme is constructed not by replacing the primary share with a new share produced by the dealer in his primitive secret sharing scheme, so no matter how much shares the shareholder produces, these shares can not be gathered together to renew the secret in this scheme. Compared with the existing secret sharing schemes, this scheme provides more agility for the shareholders by investing each of them a function but not affect its security.
基金Project(60673164)supported by the National Natural Science Foundation of ChinaProject(20060533057)supported by the Specialized Research Foundation for the Doctoral Program of Higher Education of China
文摘In the application of periodic data-gathering in sensor networks,sensor nodes located near the sink have to forward the data received from all other nodes to the sink,which depletes their energy very quickly.A moving scheme for the sink based on local residual energy was proposed.In the scheme,the sink periodically moves to a new location with the highest stay-value defined by the average residual energy and the number of neighbors.The scheme can balance energy consumption and prevent nodes around sink from draining their energy very quickly in the networks.The simulation results show that the scheme can prolong the network lifetime by 26%-65%compared with the earlier schemes where the sink is static or moves randomly.
