Cu/ZnO-based catalysts are widely employed for methanol synthesis via CO_(2) hydrogenation.The preparation procedure is sensitive to the particle size and interfacial structure,which are considered as potential active...Cu/ZnO-based catalysts are widely employed for methanol synthesis via CO_(2) hydrogenation.The preparation procedure is sensitive to the particle size and interfacial structure,which are considered as potential active centers influencing the rate of both methanol and CO formation.The particle size and the interaction between Cu and the support materials are influenced by the coprecipitation conditions,let alone that the mechanistic divergence remains unclear.In this work,a series of Cu/ZnO/ZrO_(2) catalysts were prepared via co-precipitation at different pH value and systematically characterized.The structure has been correlated with kinetic results to establish the structure-performance relationship.Kinetic analysis demonstrates that methanol synthesis follows a single-site Langmuir-Hinshelwood(L-H)mechanism,i.e.,Cu serves as the active site where CO_(2) and H_(2) competitively adsorb and react to form methanol.In contrast,CO formation proceeds via a dual-site L-H mechanism,where CO_(2) adsorbs onto ZnO and H_(2) onto Cu,with the reaction occurring at the Cu/ZnO interface.Therefore,for the direct formation of methanol,solely reducing the particle size of Cu would not be beneficial.展开更多
In recent years,numer-ous single-atom catalysts(SACs)have been synthesized to activate persulfate(PS)by a non-radical pathway because of its high se-lectivity,and activity for the cata-lyst.Metal-nitrogen-carbon(M-N_(...In recent years,numer-ous single-atom catalysts(SACs)have been synthesized to activate persulfate(PS)by a non-radical pathway because of its high se-lectivity,and activity for the cata-lyst.Metal-nitrogen-carbon(M-N_(x)-C)has been identified as the key active site in SACs.Although methods for preparing SACs have been extensively reported,a systematic summary of the direct construction of M-N_(x)-C,espe-cially unconventional metal-nitrogen-carbon(UM-N_(x)-C,x≠4),on SACs for PS non-radical activation has still not been reported.The role of the M-N_(x)-C active sites on PS non-radical activation is discussed and methods for the formation of M-N_(x)-C and UM-N_(x)-C active sites in SACs and the effect of catalyst carriers such as carbon nitride(g-C_(3)N_(4)),MOFs,COFs,and other car-bon materials are reviewed.Direct and indirect methods,especially for UM-N_(x)-C active site formation,are also elaborated.Factors affecting the formation of a M-N_(x)-C active site on SACs are also discussed.Prospects for the use of M-N_(x)-C active sites for the non-radical activation of PS by SACs to remove organic contaminants from wastewater are evaluated.展开更多
Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
为弥补现有开采沉陷预测程序在可视化表达中的缺陷,采用VB和SURFER的Active X Automation技术开发了基于概率积分法的开采沉陷预测分析系统。通过VB语言操纵SURFER内核程序实现开采沉陷的各种移动变形等值线、三维表面图及剖面图制作和...为弥补现有开采沉陷预测程序在可视化表达中的缺陷,采用VB和SURFER的Active X Automation技术开发了基于概率积分法的开采沉陷预测分析系统。通过VB语言操纵SURFER内核程序实现开采沉陷的各种移动变形等值线、三维表面图及剖面图制作和数据分析的自动化。以山东某煤矿多工作面、多煤层开采沉陷预计对所建立分析系统进行验证。结果表明,采用VB与SURFER结合用于开采沉陷的预测分析,能够满足工程需要,并且能极大地提高工作效率,减少程序开发的工作量,实现开采沉陷预测分析图件制作的专业化、自动化。展开更多
分数阶Active Demons(fractional active demons,FAD)算法是图像非刚性配准的有效方法,并且能解决灰度均匀和弱纹理图像配准精度低,优化易陷入局部极小而导致的配准速度缓慢问题,但是该算法中分数阶最佳阶次的寻找需要通过多次实验人工...分数阶Active Demons(fractional active demons,FAD)算法是图像非刚性配准的有效方法,并且能解决灰度均匀和弱纹理图像配准精度低,优化易陷入局部极小而导致的配准速度缓慢问题,但是该算法中分数阶最佳阶次的寻找需要通过多次实验人工选取,缺乏阶次自适应性.针对该问题,提出了基于多分辨率和自适应分数阶的Active Demons算法,该算法首先根据图像梯度模值和信息熵,构建了自适应分数阶阶次的数学模型,基于该模型自动计算出分数阶的最佳阶次和微分动态模板;然后将多分辨率策略加入到自适应分数阶Active Demons算法中,进一步提高了图像配准效率.理论分析和实验结果均表明:提出的算法可用于灰度均匀、弱边缘和弱纹理图像的配准,能根据图像的局部特征自适应计算最佳分数阶阶次,并避免了算法陷入局部最优,从而提高了图像配准的精度和效率.展开更多
Deterministic, probabilistic and composite-grading methods are used to get the possible locations of strong earth-quakes in the future in Norwest Beijing and its vicinity based on the quantitative data and their accur...Deterministic, probabilistic and composite-grading methods are used to get the possible locations of strong earth-quakes in the future in Norwest Beijing and its vicinity based on the quantitative data and their accuracy about active tectonics in the research area and by ordering, some questions in the results are also discussed. It shows that the most dangerous fault segments for strong earthquakes in the future include: segments B and A of the southern boundary fault of the Yangyuan basin, the southern boundary fault of the Xuanhua basin, the east segment of the southern Huaian fault and the east segment of the northern YanggaoTianzhen fault. The most dangerous area is YangyuanShenjing basin, the second one is TianzhenHuaianXuanhua basin and the third dangerous areas are WanquanZhangjiakou and northeast of Yuxian to southwest of Fanshan.展开更多
基金supported by Research Grant from China Petroleum and Chemical Corp。
文摘Cu/ZnO-based catalysts are widely employed for methanol synthesis via CO_(2) hydrogenation.The preparation procedure is sensitive to the particle size and interfacial structure,which are considered as potential active centers influencing the rate of both methanol and CO formation.The particle size and the interaction between Cu and the support materials are influenced by the coprecipitation conditions,let alone that the mechanistic divergence remains unclear.In this work,a series of Cu/ZnO/ZrO_(2) catalysts were prepared via co-precipitation at different pH value and systematically characterized.The structure has been correlated with kinetic results to establish the structure-performance relationship.Kinetic analysis demonstrates that methanol synthesis follows a single-site Langmuir-Hinshelwood(L-H)mechanism,i.e.,Cu serves as the active site where CO_(2) and H_(2) competitively adsorb and react to form methanol.In contrast,CO formation proceeds via a dual-site L-H mechanism,where CO_(2) adsorbs onto ZnO and H_(2) onto Cu,with the reaction occurring at the Cu/ZnO interface.Therefore,for the direct formation of methanol,solely reducing the particle size of Cu would not be beneficial.
文摘In recent years,numer-ous single-atom catalysts(SACs)have been synthesized to activate persulfate(PS)by a non-radical pathway because of its high se-lectivity,and activity for the cata-lyst.Metal-nitrogen-carbon(M-N_(x)-C)has been identified as the key active site in SACs.Although methods for preparing SACs have been extensively reported,a systematic summary of the direct construction of M-N_(x)-C,espe-cially unconventional metal-nitrogen-carbon(UM-N_(x)-C,x≠4),on SACs for PS non-radical activation has still not been reported.The role of the M-N_(x)-C active sites on PS non-radical activation is discussed and methods for the formation of M-N_(x)-C and UM-N_(x)-C active sites in SACs and the effect of catalyst carriers such as carbon nitride(g-C_(3)N_(4)),MOFs,COFs,and other car-bon materials are reviewed.Direct and indirect methods,especially for UM-N_(x)-C active site formation,are also elaborated.Factors affecting the formation of a M-N_(x)-C active site on SACs are also discussed.Prospects for the use of M-N_(x)-C active sites for the non-radical activation of PS by SACs to remove organic contaminants from wastewater are evaluated.
文摘Because of an unfortunate mistake by authors,the Project(5227010679)of Foundation item was wrong.The corrected Project is shown as follows:Project(52271073).
文摘为弥补现有开采沉陷预测程序在可视化表达中的缺陷,采用VB和SURFER的Active X Automation技术开发了基于概率积分法的开采沉陷预测分析系统。通过VB语言操纵SURFER内核程序实现开采沉陷的各种移动变形等值线、三维表面图及剖面图制作和数据分析的自动化。以山东某煤矿多工作面、多煤层开采沉陷预计对所建立分析系统进行验证。结果表明,采用VB与SURFER结合用于开采沉陷的预测分析,能够满足工程需要,并且能极大地提高工作效率,减少程序开发的工作量,实现开采沉陷预测分析图件制作的专业化、自动化。
基金National major basic-theory planning project Mechanism and Prediction of Strong Earthquake (95130105) and the Key Project from China Seismological Bureau (95040803).
文摘Deterministic, probabilistic and composite-grading methods are used to get the possible locations of strong earth-quakes in the future in Norwest Beijing and its vicinity based on the quantitative data and their accuracy about active tectonics in the research area and by ordering, some questions in the results are also discussed. It shows that the most dangerous fault segments for strong earthquakes in the future include: segments B and A of the southern boundary fault of the Yangyuan basin, the southern boundary fault of the Xuanhua basin, the east segment of the southern Huaian fault and the east segment of the northern YanggaoTianzhen fault. The most dangerous area is YangyuanShenjing basin, the second one is TianzhenHuaianXuanhua basin and the third dangerous areas are WanquanZhangjiakou and northeast of Yuxian to southwest of Fanshan.
