Two new coordination polymers, [M（phen）（e, a-cis-1, 4-chdc） （H2O）]n （M = Mn^（1）; M = Cu^（2）; chdc = cyclohexanedicarboxylic acid; phen = 1, 10-phenanthroline）, were prepared under hydrothermal conditions a...Two new coordination polymers, [M（phen）（e, a-cis-1, 4-chdc） （H2O）]n （M = Mn^（1）; M = Cu^（2）; chdc = cyclohexanedicarboxylic acid; phen = 1, 10-phenanthroline）, were prepared under hydrothermal conditions and characterized by IR spectra and single crystal X-ray diffraction analysis. X-ray crystal structural analyses reveal that polymer 1 and 2 are isomorphic and belong to the monoclinic system. C20H20MnN2O5, P2 （1） / c, a=1.0235（2） nm, b=0.89134（19） nm, c=2.0466（4） mm,β=99.820（3）, Z=4 for 1; and C20H20CuN2O5, P2（1）/c, a=1.0002（3）nm, b=0.8949（2）nm, c=2.0270（5）nm, β=99.694（3）＇, Z = 4 for 2. In the structures of 1 and 2, the 1, 4-chdc ligand only possesses e, a-cis conformation although there are both cis- and trans-conformations in the raw material.展开更多
According to the equilibrium constant of copper-1,10-phenanthroline,[Cu（phen）]2+solution（aq） was prepared and the surface of the graphite electrode was modified by adsorbed [Cu（phen）]2+ solution,the electrochemi...According to the equilibrium constant of copper-1,10-phenanthroline,[Cu（phen）]2+solution（aq） was prepared and the surface of the graphite electrode was modified by adsorbed [Cu（phen）]2+ solution,the electrochemical properties of [Cu（phen）]2+were investigated by cyclic voltammetry.The results show that the redox process of the complex is a reversible,one-elextron reaction and is controlled by the diffusion.展开更多
Homogeneous solution of poor soluble aza bridged bis phenanthroline macrocyclic compound(H 2HAPP) was obtained by adding K 2CO 3 to its trifluoroacetate in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)= 1∶1] solution. C...Homogeneous solution of poor soluble aza bridged bis phenanthroline macrocyclic compound(H 2HAPP) was obtained by adding K 2CO 3 to its trifluoroacetate in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)= 1∶1] solution. Coordination reaction between H 2HAPP and metal ion Zn(Ⅱ) in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)=1∶1] solvent was studied by UV Vis spectroscopic method, which indicated 1∶1 complexing between H 2HAPP and Zn(II) ion occurred easily in such a homogeneous system at room temperature. And the formation of ZnHAPP complex was further confirmed by FAB MS and 1H NMR spectra.展开更多
文摘Two new coordination polymers, [M（phen）（e, a-cis-1, 4-chdc） （H2O）]n （M = Mn^（1）; M = Cu^（2）; chdc = cyclohexanedicarboxylic acid; phen = 1, 10-phenanthroline）, were prepared under hydrothermal conditions and characterized by IR spectra and single crystal X-ray diffraction analysis. X-ray crystal structural analyses reveal that polymer 1 and 2 are isomorphic and belong to the monoclinic system. C20H20MnN2O5, P2 （1） / c, a=1.0235（2） nm, b=0.89134（19） nm, c=2.0466（4） mm,β=99.820（3）, Z=4 for 1; and C20H20CuN2O5, P2（1）/c, a=1.0002（3）nm, b=0.8949（2）nm, c=2.0270（5）nm, β=99.694（3）＇, Z = 4 for 2. In the structures of 1 and 2, the 1, 4-chdc ligand only possesses e, a-cis conformation although there are both cis- and trans-conformations in the raw material.
文摘According to the equilibrium constant of copper-1,10-phenanthroline,[Cu（phen）]2+solution（aq） was prepared and the surface of the graphite electrode was modified by adsorbed [Cu（phen）]2+ solution,the electrochemical properties of [Cu（phen）]2+were investigated by cyclic voltammetry.The results show that the redox process of the complex is a reversible,one-elextron reaction and is controlled by the diffusion.
文摘Homogeneous solution of poor soluble aza bridged bis phenanthroline macrocyclic compound(H 2HAPP) was obtained by adding K 2CO 3 to its trifluoroacetate in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)= 1∶1] solution. Coordination reaction between H 2HAPP and metal ion Zn(Ⅱ) in CH 3OH CH 2Cl 2[ V (CH 3OH)∶ V (CH 2Cl 2)=1∶1] solvent was studied by UV Vis spectroscopic method, which indicated 1∶1 complexing between H 2HAPP and Zn(II) ion occurred easily in such a homogeneous system at room temperature. And the formation of ZnHAPP complex was further confirmed by FAB MS and 1H NMR spectra.
