Boehmite was prepared under heat treatment in water vapour, and the phase transformation of gibbsite heat-treated at various temperatures was investigated. The sample was characterized by scanning electron microscopy(...Boehmite was prepared under heat treatment in water vapour, and the phase transformation of gibbsite heat-treated at various temperatures was investigated. The sample was characterized by scanning electron microscopy(SEM), X-ray diffraction (XRD), thermogravimetry and differential thermalanalysis (TG-DTA), fourier transform infrared (FTIR),and BET surface area.Effect of temperature on preparation was studied in the range of 155°–195°.With the increase in temperature, transformation of gibbsite into crystalline boehmites took place as indicated by the X-ray diffraction (XRD). The shape of the grains in the prepared sample was cube-like morphology.In water vapour gibbsite transform into boehmite by a dissolution - precipitation mechanism.展开更多
The conventional solar heating floor system contains a big water tank to store energy in the day time for heating at night,which takes much building space and is very heavy.In order to reduce the water tank volume eve...The conventional solar heating floor system contains a big water tank to store energy in the day time for heating at night,which takes much building space and is very heavy.In order to reduce the water tank volume even to cancel the tank,a novel structure of integrated water pipe floor heating system using shape-stabilized phase change materials(SSPCM)for thermal energy storage was developed.A numerical model was developed to analyze the performance of SSPCM floor heating system under the intermittent heating condition,which was verified by our experimental data.The thermal performance of the heating system and the effects of various factors on it were analyzed numerically.The factors including phase transition temperature,heat of fusion,thermal conductivity of SSPCM and thermal conductivity of the decoration material were analyzed.The results show that tm and kd are the most import influencing factors on the thermal performance of SSPCM floor heating system,since they determine the heat source temperature and thermal resistance between SSPCM plates and indoor air,respectively.Hm should be large to store enough thermal energy in the day time for nighttimes heating.The effects of kp can be ignored in this system.The SSPCM floor heating system has potential of making use of the daytime solar energy for heating at night efficiently in various climates when its structure is properly designed.展开更多
文摘Boehmite was prepared under heat treatment in water vapour, and the phase transformation of gibbsite heat-treated at various temperatures was investigated. The sample was characterized by scanning electron microscopy(SEM), X-ray diffraction (XRD), thermogravimetry and differential thermalanalysis (TG-DTA), fourier transform infrared (FTIR),and BET surface area.Effect of temperature on preparation was studied in the range of 155°–195°.With the increase in temperature, transformation of gibbsite into crystalline boehmites took place as indicated by the X-ray diffraction (XRD). The shape of the grains in the prepared sample was cube-like morphology.In water vapour gibbsite transform into boehmite by a dissolution - precipitation mechanism.
基金Supported by National 11th Five-Year Plan of Dept.of Science,China(2006BAA04B02,2006BAJ02A09)
文摘The conventional solar heating floor system contains a big water tank to store energy in the day time for heating at night,which takes much building space and is very heavy.In order to reduce the water tank volume even to cancel the tank,a novel structure of integrated water pipe floor heating system using shape-stabilized phase change materials(SSPCM)for thermal energy storage was developed.A numerical model was developed to analyze the performance of SSPCM floor heating system under the intermittent heating condition,which was verified by our experimental data.The thermal performance of the heating system and the effects of various factors on it were analyzed numerically.The factors including phase transition temperature,heat of fusion,thermal conductivity of SSPCM and thermal conductivity of the decoration material were analyzed.The results show that tm and kd are the most import influencing factors on the thermal performance of SSPCM floor heating system,since they determine the heat source temperature and thermal resistance between SSPCM plates and indoor air,respectively.Hm should be large to store enough thermal energy in the day time for nighttimes heating.The effects of kp can be ignored in this system.The SSPCM floor heating system has potential of making use of the daytime solar energy for heating at night efficiently in various climates when its structure is properly designed.
