This study presents the deep removal of copper (Ⅱ) from the simulated cobalt electrolyte using fabricated polystyrene-supported 2-aminomethylpyridine chelating resin (PS-AMP) in a fixed-bed.The effects of bed height ...This study presents the deep removal of copper (Ⅱ) from the simulated cobalt electrolyte using fabricated polystyrene-supported 2-aminomethylpyridine chelating resin (PS-AMP) in a fixed-bed.The effects of bed height (7.0–14.0 cm),feed flow rate (4.5–9.0 mL/min),initial copper (Ⅱ) concentration of the feed (250–1000 mg/L),feed temperature (25–40 ℃) and the value of pH (2.0–4.0) on the adsorption process of the PS-AMP resin were investigated.The experimental data showed that the PS-AMP resin can deeply eliminate copper (Ⅱ) from the simulated cobalt electrolyte.The bed height,feed flow rate,initial copper (Ⅱ) concentration of the feed,feed temperature and feed pH value which corresponded to the highest removal of copper (Ⅱ) were 7.0 cm with 35 mm of the column diameter,4.5 mL/min,40℃,1000 mg/L and 4.0,respectively.The breakthrough capacity,the saturated capacity of the column and the mass ratio of Cu/Co (g/g) in the saturated resin were correspondingly 16.51 mg/g dry resin,61.72 mg/g dry resin and 37.67 under the optimal experimental conditions.The copper (Ⅱ) breakthrough curves were fitted by the empirical models of Thomas,Yoon-Nelson and Adam-Bohart,respectively.The Thomas model was found to be the most suitable one for predicting how the concentration of copper (Ⅱ) in the effluent changes with the adsorption time.展开更多
In this work,the efficiency of an adsorption process,in which Moroccan diatomite(ND)is used as a low-cost adsorbent to remove Congo red(CR)dye from contaminated waters in batch and column system,was examined.The influ...In this work,the efficiency of an adsorption process,in which Moroccan diatomite(ND)is used as a low-cost adsorbent to remove Congo red(CR)dye from contaminated waters in batch and column system,was examined.The influence of experimental conditions(pH,adsorbent dose and temperature)on the adsorption of CR onto the ND adsorbent was studied.A study of the adsorption kinetics for CR revealed that a pseudo-second-order model provided the best fit to the experimental kinetic data,and the equilibrium data were well described by the Langmuir isotherm model with an adsorption capacity of 6.07 mg/g using 15 g/L of ND,pH=6,contact time 3 h and 25℃.On the other hand,the ND regeneration tests were investigated and showed that the desorption reaches at least 50%when using ethanol as eluent.In addition,the adsorption process in a continuous mode was studied.Breakthrough curves were properly represented by the Yoon—Nelson model.Hence,the adsorption capacity of 5.71 mg/g was reached using 0.114 g of adsorbent,CR concentration of 6 mg/L and a flow of 1 mL/min under 25℃.展开更多
基金Project(2014CB643401)supported by the National Basic Research Program of ChinaProjects(51134007,51474256)supported by the National Natural Science Foundation of ChinaProject(2017TP1001)supported by the Hunan Provincial Science and Technology Plan Project,China
文摘This study presents the deep removal of copper (Ⅱ) from the simulated cobalt electrolyte using fabricated polystyrene-supported 2-aminomethylpyridine chelating resin (PS-AMP) in a fixed-bed.The effects of bed height (7.0–14.0 cm),feed flow rate (4.5–9.0 mL/min),initial copper (Ⅱ) concentration of the feed (250–1000 mg/L),feed temperature (25–40 ℃) and the value of pH (2.0–4.0) on the adsorption process of the PS-AMP resin were investigated.The experimental data showed that the PS-AMP resin can deeply eliminate copper (Ⅱ) from the simulated cobalt electrolyte.The bed height,feed flow rate,initial copper (Ⅱ) concentration of the feed,feed temperature and feed pH value which corresponded to the highest removal of copper (Ⅱ) were 7.0 cm with 35 mm of the column diameter,4.5 mL/min,40℃,1000 mg/L and 4.0,respectively.The breakthrough capacity,the saturated capacity of the column and the mass ratio of Cu/Co (g/g) in the saturated resin were correspondingly 16.51 mg/g dry resin,61.72 mg/g dry resin and 37.67 under the optimal experimental conditions.The copper (Ⅱ) breakthrough curves were fitted by the empirical models of Thomas,Yoon-Nelson and Adam-Bohart,respectively.The Thomas model was found to be the most suitable one for predicting how the concentration of copper (Ⅱ) in the effluent changes with the adsorption time.
文摘In this work,the efficiency of an adsorption process,in which Moroccan diatomite(ND)is used as a low-cost adsorbent to remove Congo red(CR)dye from contaminated waters in batch and column system,was examined.The influence of experimental conditions(pH,adsorbent dose and temperature)on the adsorption of CR onto the ND adsorbent was studied.A study of the adsorption kinetics for CR revealed that a pseudo-second-order model provided the best fit to the experimental kinetic data,and the equilibrium data were well described by the Langmuir isotherm model with an adsorption capacity of 6.07 mg/g using 15 g/L of ND,pH=6,contact time 3 h and 25℃.On the other hand,the ND regeneration tests were investigated and showed that the desorption reaches at least 50%when using ethanol as eluent.In addition,the adsorption process in a continuous mode was studied.Breakthrough curves were properly represented by the Yoon—Nelson model.Hence,the adsorption capacity of 5.71 mg/g was reached using 0.114 g of adsorbent,CR concentration of 6 mg/L and a flow of 1 mL/min under 25℃.
