With the rise of the electric vehicle industry,as the power source of electric vehicles,lithium battery has become a research hotspot.The state of charge(SOC)estimation and modelling of lithium battery are studied in ...With the rise of the electric vehicle industry,as the power source of electric vehicles,lithium battery has become a research hotspot.The state of charge(SOC)estimation and modelling of lithium battery are studied in this paper.The ampere-hour(Ah)integration method based on external characteristics is analyzed,and the open-circuit voltage(OCV)method is studied.The two methods are combined to estimate SOC.Considering the accuracy and complexity of the model,the second-order RC equivalent circuit model of lithium battery is selected.Pulse discharge and exponential fitting of lithium battery are used to obtain corresponding parameters.The simulation is carried out by using fixed resistance capacitance and variable resistance capacitor respectively.The accuracy of variable resistance and capacitance model is 2.9%,which verifies the validity of the proposed model.展开更多
This paper analyzes lightning surge on the stator windings of wind turbine generators.The path of lightning in the wind turbines was analyzed.An equivalent circuit model for megawatt direct-driven wind turbine system ...This paper analyzes lightning surge on the stator windings of wind turbine generators.The path of lightning in the wind turbines was analyzed.An equivalent circuit model for megawatt direct-driven wind turbine system was developed,in which high-frequency distributed parameters of the blade conducts,tower,power cables and stator windings of generator were calculated based on finite element method,and the models of converter,grounding,loads, surge protection devices and power grid were established.The voltage distribution along stator windings,when struck by lightning with 10/350μs wave form and different amplitude current between 50 kA and 200 kA,was simulated using electro-magnetic transient analysis method.The simulated results show that the highest coil-to-core voltage peak appears on the last coil or near the neutral of stator windings,and the voltage distribution along the windings is nonuniform initially.The voltage drops of each coil fall from first to last coil,and the highest voltage drop appears on the first coil.The insulation damage may occur on the windings under lightning overvoltage.The surge arresters can restrain the lightning surge in effect and protect the insulation.The coil-to-core voltage in the end of windings is nearly 19.5 kV under the 200 kA lightning current without surge arresters on the terminal of generator,but is only 2.7 kV with arresters.展开更多
The transmission upper limit of a double-layer frequency selective surface （FSS） with two infinitely thin metal arrays is pre- sented based on the study of the general equivalent transmission line model of a double-...The transmission upper limit of a double-layer frequency selective surface （FSS） with two infinitely thin metal arrays is pre- sented based on the study of the general equivalent transmission line model of a double-layer FSS. Results of theoretical analyses, numerical simulations and experiments show that this transmis- sion upper limit is independent of the array and the element, which indicates that it is impossible to achieve a transmission upper limit higher than this one under a given incident and dielectric- supporting condition by the design of the periodic array. Both the applicable condition and the possible application of the transmis- sion upper limit are discussed. The results show that the transmis- sion upper limit not only has a good reachability, but also provides a key to effectively improve the transmission performance of a double-layer FSS or more complex frequency selective structures.展开更多
Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide...Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.展开更多
Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capabilit...Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.展开更多
基金Project(51507073)supported by the National Natural Science Foundation of China。
文摘With the rise of the electric vehicle industry,as the power source of electric vehicles,lithium battery has become a research hotspot.The state of charge(SOC)estimation and modelling of lithium battery are studied in this paper.The ampere-hour(Ah)integration method based on external characteristics is analyzed,and the open-circuit voltage(OCV)method is studied.The two methods are combined to estimate SOC.Considering the accuracy and complexity of the model,the second-order RC equivalent circuit model of lithium battery is selected.Pulse discharge and exponential fitting of lithium battery are used to obtain corresponding parameters.The simulation is carried out by using fixed resistance capacitance and variable resistance capacitor respectively.The accuracy of variable resistance and capacitance model is 2.9%,which verifies the validity of the proposed model.
基金Supported by National Natural Science Foundation of China(50877063)
文摘This paper analyzes lightning surge on the stator windings of wind turbine generators.The path of lightning in the wind turbines was analyzed.An equivalent circuit model for megawatt direct-driven wind turbine system was developed,in which high-frequency distributed parameters of the blade conducts,tower,power cables and stator windings of generator were calculated based on finite element method,and the models of converter,grounding,loads, surge protection devices and power grid were established.The voltage distribution along stator windings,when struck by lightning with 10/350μs wave form and different amplitude current between 50 kA and 200 kA,was simulated using electro-magnetic transient analysis method.The simulated results show that the highest coil-to-core voltage peak appears on the last coil or near the neutral of stator windings,and the voltage distribution along the windings is nonuniform initially.The voltage drops of each coil fall from first to last coil,and the highest voltage drop appears on the first coil.The insulation damage may occur on the windings under lightning overvoltage.The surge arresters can restrain the lightning surge in effect and protect the insulation.The coil-to-core voltage in the end of windings is nearly 19.5 kV under the 200 kA lightning current without surge arresters on the terminal of generator,but is only 2.7 kV with arresters.
文摘The transmission upper limit of a double-layer frequency selective surface （FSS） with two infinitely thin metal arrays is pre- sented based on the study of the general equivalent transmission line model of a double-layer FSS. Results of theoretical analyses, numerical simulations and experiments show that this transmis- sion upper limit is independent of the array and the element, which indicates that it is impossible to achieve a transmission upper limit higher than this one under a given incident and dielectric- supporting condition by the design of the periodic array. Both the applicable condition and the possible application of the transmis- sion upper limit are discussed. The results show that the transmis- sion upper limit not only has a good reachability, but also provides a key to effectively improve the transmission performance of a double-layer FSS or more complex frequency selective structures.
文摘Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.
基金Project(2010ZC051)supported by the Natural Science Foundation of Yunnan Province,ChinaProject(20140439)supported by Analysis and Testing Foundation from Kunming University of Science and Technology,ChinaProject(14118245)supported by Starting Research Fund from Kunming University of Science and Technology,China
文摘Li Fe PO4/C was prepared via solid state reaction and characterized with X-ray powder diffraction and charge–discharge test. As-prepared Li Fe PO4/C has a triphylite structure and exhibits an excellent rate capability and capacity retention. Electrochemical impedance spectroscopy(EIS) was applied to investigate LixFe PO4/C(0<x<1) electrode on temperature variation. The valid equivalent circuit for EIS fitting was determined which contains an intercalation capacitance for Li+ ion accumulation and consumption in the electrode reaction. The surface layer impedance needs to be included in the equivalent circuit when Li Fe PO4/C is deeply delithiated at a relatively high temperature. EIS examination indicates that a temperature rise leads to a better reversibility, lower charge transfer resistance, higher exchange current density J0 and greater Li+ ion diffusion coefficient for the LixFe PO4/C electrode process. The Li+ ion concentration in LixFe PO4/C is potential to impact the Li+ ion diffusion coefficient, and a decrease in the former results in an increase in the latter.
