Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable p...Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m（PEG）/m（RF） and the （relative） molecular mass of PEG on the pore structure and electric double layer capacitance（EDLC） performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach （755 m2/g） and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels.展开更多
This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double...This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.展开更多
A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-di...A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-dibromobutane and pyrrolidine, and subsequent ion exchange pathway with KOH followed by neutralization reaction via HBF4 in the system of ethanol solution. 1H NMR, 13 C NMR, FI-IR and XPS analyses showed the structure of SBP-BF4. The as-obtained SBP-BF4 was dissolved in AN and used as the electrolyte for supercapacitor. Electrochemical measurements demonstrate that, compared with commercial electrolyte TEMA-BF4/AN, SBP-BF4/AN exhibits high ionic conductivity, lower resistance and improved cycling performance, which is due to its smaller ion size and stable symmetry structure.展开更多
Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti...Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.展开更多
Based on non-Darcian flow law described by exponent and threshold gradient within a double-layered soil, the classic theory of one-dimensional consolidation of double-layered soil was modified to consider the change o...Based on non-Darcian flow law described by exponent and threshold gradient within a double-layered soil, the classic theory of one-dimensional consolidation of double-layered soil was modified to consider the change of vertical total stress with depth and time together. Because of the complexity of governing equations, the numerical solutions were obtained in detail by finite difference method. Then, the numerical solutions were compared with the analytical solutions in condition that non-Darcian flow law was degenerated to Dary's law, and the comparison results show that numerical solutions are reliable. Finally, consolidation behavior of double-layered soil with different parameters was analyzed, and the results show that the consolidation rate of double-layered soil decreases with increasing the value of exponent and threshold of non-Darcian flow, and the exponent and threshold gradient of the first soil layer greatly influence the consolidation rate of double-layered soil. The larger the ratio of the equivalent water head of external load to the total thickness of double-layered soil, the larger the rate of the consolidation, and the similitude relationship in classical consolidation theory of double-layered soil is not satisfied. The other consolidation behavior of double-layered soil with non-Darcian flow is the same as that with Darcy's law.展开更多
To further investigate the one-dimensional(1D)rheological consolidation mechanism of double-layered soil,the fractional derivative Merchant model(FDMM)and the non-Darcian flow model with the non-Newtonian index are re...To further investigate the one-dimensional(1D)rheological consolidation mechanism of double-layered soil,the fractional derivative Merchant model(FDMM)and the non-Darcian flow model with the non-Newtonian index are respectively introduced to describe the deformation of viscoelastic soil and the flow of pore water in the process of consolidation.Accordingly,an 1D rheological consolidation equation of double-layered soil is obtained,and its numerical analysis is performed by the implicit finite difference method.In order to verify its validity,the numerical solutions by the present method for some simplified cases are compared with the results in the related literature.Then,the influence of the revelent parameters on the rheological consolidation of double-layered soil are investigated.Numerical results indicate that the parameters of non-Darcian flow and FDMM of the first soil layer greatly influence the consolidation rate of double-layered soil.As the decrease of relative compressibility or the increase of relative permeability between the lower soil and the upper soil,the dissipation rate of excess pore water pressure and the settlement rate of the ground will be accelerated.Increasing the relative thickness of soil layer with high permeability or low compressibility will also accelerate the consolidation rate of double-layered soil.展开更多
The time-sequenced damage behavior of the reactive projectile impacting double-layer plates is discussed.The analytical model considering the combined effect of kinetic and chemical energy is developed to reveal the d...The time-sequenced damage behavior of the reactive projectile impacting double-layer plates is discussed.The analytical model considering the combined effect of kinetic and chemical energy is developed to reveal the damage mechanism.The influences of impact velocity and reactive projectile chemical characteristics on the damage effect are decoupled analyzed based on this model.These analyses indicate that the high energy releasing efficiency and fast reaction propagation velocity of the reactive projectile are conducive to enhancing the damage effect.The experiments with various reactive projectiles impact velocity increasing from 702 to 1385 m/s were conducted to verify this model.The experimental results presented that,the damage hole radius of the rear-plate increases with the increase of impact velocity.At the impact velocity of 1350 m/s,the radius of damage hole formed by PTFE/Al/Bi_(2)O_(3),PTFE/Al/MoO_(3),PTFE/Al/Fe_(2)O_(3)projectile on the rear-plate become smaller in sequence.These results are consistent with the analytical model prediction,demonstrating that this model can predict the damage effect quantitatively.This work is of constructive significance to the application of reactive projectiles.展开更多
Double-layered pellet （DLP） roasting is a novel pretreatment method for sulfur and arsenic-bearing gold concentrates. In this process, preparation of DLPs is a fundamental step which is required to produce DLPs with...Double-layered pellet （DLP） roasting is a novel pretreatment method for sulfur and arsenic-bearing gold concentrates. In this process, preparation of DLPs is a fundamental step which is required to produce DLPs with favorable mechanical strength and thermal stability. Studies were carried out to investigate the affecting factors and conditions on the preparation and properties of DLPs. The results show that moisture content has significant influence on DLPs preparation. With the increase of moisture content in the range of no more than 9.8%, drop resistance and compressive strength of green DLPs are raised and the pelletizing dynamics is improved accordingly. The optimum conditions are determined as moisture content of 9.8%, coating time of 14-16 min, drying temperature 〈80 ℃and drying gas velocity 〈1.2 m/s. When DLPs prepared under these conditions are roasted at 600 ℃ for 1 h, favorable removal and solidifying rates can be obtained, in which the removal rates of arsenic and sulfur are 94.38% and 82.55%, and the solidifying rates of arsenic and sulfur reach 99.62% and 99.79%, respectively. These results promise industrial application of DLP roasting.展开更多
The microstructure and electrical properties of ZnO-Bi2O3-Yb2O3 based varistor ceramics were investigated with various temperature effects from 900°C to 1050°C.From the results,it was observed that the incre...The microstructure and electrical properties of ZnO-Bi2O3-Yb2O3 based varistor ceramics were investigated with various temperature effects from 900°C to 1050°C.From the results,it was observed that the increase of sintering temperature offers a reduced capacitive effect from 0.460 nF to 0.321 nF.Furthermore,the grain sizes of varistors were varied from 6.8μm to 9.8μm.The consequence of such smaller grain sizes provided a better voltage gradient of about 895 V/mm for the disc sintered at 900°C and fallen drastically to 410 V/mm for the sample sintered at 1050°C.In addition,there was an increase of non-linearity index to a maximum value of 36.0 and reduced leakage current of 0.026 mA/cm2.However,the density of the varistor decreased with an increase of temperature from 5.41 g/cm3 to 5.24 g/cm3.With this base,the influence of varistor capacitance and high voltage gradient were scrutinized and it led an improved transition speed of the varistor assembly from non-conduction to conduction mode during intruding nanosecond transients.展开更多
In the framework of upper bound theorem of limit analysis, the progressive collapse of shallow rectangular tunnels with double-layer rock mass has been theoretically analyzed based on the three-dimensional (3D) veloci...In the framework of upper bound theorem of limit analysis, the progressive collapse of shallow rectangular tunnels with double-layer rock mass has been theoretically analyzed based on the three-dimensional (3D) velocity discontinuity surfaces. According to the virtual work principle, the difference theorem and the variation method, the collapse surface of double-layer rock mass is determined based on the Hoek-Brown failure criterion. The formula can be degenerated to a single-layer rock collapsing problem when the rock mass is homogeneous. To estimate the validity of the result, the numerical simulation software PLAXIS 3D is used to simulate the collapse of shallow tunnels with double-layer rock mass, and the comparative analysis shows that numerical results are in good agreement with upper-bound solutions. According to the results of parametric analysis, the potential range of collapse of a double-layer rock mass above a shallow cavity decreases with a decrease in A1/A2,σci1/σci2 and σtm1/σtm2 and an increase in B1/B2,γ1/γ2. The range will decrease with a decrease in support pressure q and increase with a decrease in surface overload σs. Therefore, reinforced supporting is beneficial to improve the stability of the cavity during actual construction.展开更多
Introduction Blood flow provides a mechanical condition for blood cells and vessels,especially for endothelial cells.It is important to understand the mechanical characteristics of
Mn/Ni composite oxides as active electrode materials for supercapacitors were prepared by solid-state reaction through the reduction of KMnO4 with manganese acetate and nickel acetate at low temperature. The products ...Mn/Ni composite oxides as active electrode materials for supercapacitors were prepared by solid-state reaction through the reduction of KMnO4 with manganese acetate and nickel acetate at low temperature. The products were characterized by X-ray diffractometry(XRD) and transmission electron microscopy(TEM). The electrochemical characterizations were performed by cyclic voltammetry (CV) and constant current charge-discharge in a three-electrode system. The effects of different potential windows, scan rates, and cycle numbers on the capacitance behavior of Mn0.8Ni0.2Ox composite oxide were also investigated. The results show that the composite oxides are of nano-size and amorphous structure. With increasing the molar ratio of Ni, the specific capacitance goes through a maximum at molar fraction of Ni of 20%. The specific capacitance of Mn0.8Ni0.2Ox composite oxide is 194.5 F/g at constant current discharge of 5 mA.展开更多
In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance...In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance tomography(ECT)is a technique for visualizing two-phase flow in a pipe or closed container.In this paper,a visual detection method was proposed by image reconstruction of core,laminar,bubble and annular flow based on ECT technology,which reflects distribution of slurry in deep filling pipeline and measures the degree of blockage.There is an error between the measured and the real two-phase flow distribution due to two factors,which are immature image reconstruction algorithm of ECT and difference of flow patterns leading to degrees of error.In this paper,convolutional neural networks(CNN)is used to recognize flow patterns,and then the optimal image is calculated by the improved particle swarm optimization(PSO)algorithm with weights using simulated annealing strategy,and the fitness function is improved based on the results of the shallow neural network.Finally,the reconstructed binary image is further processed to obtain the position,size and direction of the blocked pipe.The realization of this method provides technical support for pipeline detection technology.展开更多
Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is ...Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is first application of the method to visualization of water flow in soil.We describe the principles behind the method,and then demonstrate its use with a simple laboratory infiltration experiment.32 ECVT sensors were installed on the sides of an empty PVC column.Water was poured into the column at a constant rate,and ECVT data were collected every second.The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second.Data were analyzed to give bulk average water contents,which proved consistent with the water supply rates.Data were also analyzed to give 3D images(216 voxels) allowing visualization of the water distribution during the experiments.Result of this work shows that water infiltration into the soil,wall flow,progress of the unstable wetting front and the final water distribution are clearly visible.展开更多
The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can...The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can not be implemented and the data from this sensor may be unreliable due to the sensor pipe interior wall abrasion during pneumatic transport,so the solids concentration calculated from the reconstructed image based on these data will be highly inaccurate.The simulations show that, the inter-electrode relative capacitance variation of electrode pair spacing 1 is the most sensitive to the abrasion of sensor pipe interior wall, so this relative capacitance variation when the sensor is filled with air can be used as an indicator demanding offline system recalibration when the wall abrasion goes significant.Furthermore, while the pipe interior wall abrasion is not very serious, online correcting measured inter-electrode capacitance with wall capacitance variation can improve the accuracy of concentration calculation.展开更多
It presents a method which can equivalently arrange the capacitance distribution along with the winding of the generator on the terminal and neutral respectively in a reasonable partition,particularly for a type of hi...It presents a method which can equivalently arrange the capacitance distribution along with the winding of the generator on the terminal and neutral respectively in a reasonable partition,particularly for a type of high-voltage graded insulated cable wound generator,Powerformer.The winding of the Powerformer adopts graded insulation,which leads to the various cable thicknesses in different portion of the winding,and thus,the uneven capacitance distribution.The large capacitive currents and large transient outrush currents resulting from the cable consisting of the stator winding of Powerformer may cause problems to the generator differential protection.Most of literatures available in the field of compensated differential protection focus on the charging current compensation for long transmission line,instead of for generator.The authors give a method which can be used to compensate the capacitive current wholly to improve the reliability of the differential protection of Powerformer.It is proved that the distributed capacitance can be equivalent as the lump circuit with a capacitance partition coefficient ρ,and ρ is proved as a constant no matter whether the generator experiences the normal operation,external phase(s) fault or internal phase(s) fault.The formula of the partition coefficient is provided and the corresponding equivalent circuit of the Powerformer cable to calculate capacitance currents is given.An analysis programming resolving the minimum value of the coefficient ρ is written in MATLAB 7.0/m according to this formula,using the function fmincon() which can work in any type of constraint condition.The program always gets the same global minimum points under the different initial values condition which proves our point by mathematical test.With this new approach to winding capacitance dividing method,the protection scheme used for Powerformer can be validated and improved accordingly.展开更多
The capacitive performance of carbon materials as supercapacitor electrode is synergistically influenced by the surface porous structure,graphitization structure,and surface atomic doping.However,simple realization of...The capacitive performance of carbon materials as supercapacitor electrode is synergistically influenced by the surface porous structure,graphitization structure,and surface atomic doping.However,simple realization of their synergistic regulation still faces significant challenges.Based on the biological porous structure,heteroatom-rich content and low cost of chestnut,this work adopt chestnut as precursor to prepare carbon electrode,of which the pores,graphitization,and surface atomic doping are synergistically regulated by simply changing the activation temperature.The optimized carbon electrode possesses a hierarchical porous structure with partial graphitization and O and N co doping.Benefited from these merits,the chestnut-derived porous carbon as a supercapacitor electrode,can achieve a high specific capacitance of 328.6 F/g at 1 A/g,which still retains 80.8%when the current density enlarging to 20 A/g.By packaging the symmetric electric double-layer capacitor,the device exhibits a specific capacitance of 63.6 F/g at 1 A/g,delivering an energy density of 12.7 W·h/kg at a power density of 600 W/kg.The stability of the device is tested at a current density of 20 A/g,which shows a capacitance retention rate of up to 90%after 10000 charge-discharge cycles.展开更多
文摘Mesoporous polyethylene glycol-resorcinol and formaldehyde（PEG-RF） carbon xerogels were prepared by a new polymer blend method in which PEG-RF mixed organic xerogels were synthesized by blending thermally unstable polyethylene glycol with organic monomers, resorcinol and formaldehyde and then subjected to pyrolization at 1 000 ℃. The influences of mass ratio of PEG to the theoretical yield of RF xerogel, m（PEG）/m（RF） and the （relative） molecular mass of PEG on the pore structure and electric double layer capacitance（EDLC） performance of PEG-RF carbon xerogels were investigated. The results show that PEG under different conditions leads to the difference of phase separation structure of the polymer blend and thus the change of pore structure of PEG-RF carbon xerogels. Specific surface area and capacity of PEG-RF carbon xerogels in 30% H2SO4 solution can reach （755 m2/g） and 150 F/g, respectively. Their surface can be fully utilized to form electric double layer. However, the pore structure differences of PEG-RF carbon xerogels result in their different EDLC performances. The distributed capacitance effect increases with decreasing the pore size of PEG-RF carbon xerogels.
基金funded by the China Postdoctoral Science Foundation(Grant No.2022M721614)the opening project of State Key Laboratory of Explosion Science and Technology,Beijing Institute of Technology(Grant No.KFJJ23-07M)。
文摘This paper proposes a type of double-layer charge liner fabricated using chemical vapor deposition(CVD)that has tungsten as its inner liner.The feasibility of this design was evaluated through penetration tests.Double-layer charge liners were fabricated by using CVD to deposit tungsten layers on the inner surfaces of pure T2 copper liners.The microstructures of the tungsten layers were analyzed using a scanning electron microscope(SEM).The feasibility analysis was carried out by pulsed X-rays,slug-retrieval test and static penetration tests.The shaped charge jet forming and penetration law of inner tungsten-coated double-layer liner were studied by numerical simulation method.The results showed that the double-layer liners could form well-shaped jets.The errors between the X-ray test results and the numerical results were within 11.07%.A slug-retrieval test was found that the retrieved slug was similar to a numerically simulated slug.Compared with the traditional pure copper shaped charge jet,the penetration depth of the double-layer shaped charge liner increased by 11.4% and>10.8% respectively.In summary,the test results are good,and the numerical simulation is in good agreement with the test,which verified the feasibility of using the CVD method to fabricate double-layer charge liners with a high-density and high-strength refractory metal as the inner liner.
基金Project(51371198)supported by the National Natural Science Foundation of China
文摘A spiro-type quaternary ammonium salt, spiro-(1,1′)-bipyrrolidinium tetrafluoroborate(SBP-BF4) was successfully prepared by an economical and efficient three-step process comprising the cyclization reaction of 1,4-dibromobutane and pyrrolidine, and subsequent ion exchange pathway with KOH followed by neutralization reaction via HBF4 in the system of ethanol solution. 1H NMR, 13 C NMR, FI-IR and XPS analyses showed the structure of SBP-BF4. The as-obtained SBP-BF4 was dissolved in AN and used as the electrolyte for supercapacitor. Electrochemical measurements demonstrate that, compared with commercial electrolyte TEMA-BF4/AN, SBP-BF4/AN exhibits high ionic conductivity, lower resistance and improved cycling performance, which is due to its smaller ion size and stable symmetry structure.
文摘Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.
基金Projects(50878191,51109092)supported by the National Natural Science Foundation of China
文摘Based on non-Darcian flow law described by exponent and threshold gradient within a double-layered soil, the classic theory of one-dimensional consolidation of double-layered soil was modified to consider the change of vertical total stress with depth and time together. Because of the complexity of governing equations, the numerical solutions were obtained in detail by finite difference method. Then, the numerical solutions were compared with the analytical solutions in condition that non-Darcian flow law was degenerated to Dary's law, and the comparison results show that numerical solutions are reliable. Finally, consolidation behavior of double-layered soil with different parameters was analyzed, and the results show that the consolidation rate of double-layered soil decreases with increasing the value of exponent and threshold of non-Darcian flow, and the exponent and threshold gradient of the first soil layer greatly influence the consolidation rate of double-layered soil. The larger the ratio of the equivalent water head of external load to the total thickness of double-layered soil, the larger the rate of the consolidation, and the similitude relationship in classical consolidation theory of double-layered soil is not satisfied. The other consolidation behavior of double-layered soil with non-Darcian flow is the same as that with Darcy's law.
基金Project(51578511)supported by the National Natural Science Foundation of China。
文摘To further investigate the one-dimensional(1D)rheological consolidation mechanism of double-layered soil,the fractional derivative Merchant model(FDMM)and the non-Darcian flow model with the non-Newtonian index are respectively introduced to describe the deformation of viscoelastic soil and the flow of pore water in the process of consolidation.Accordingly,an 1D rheological consolidation equation of double-layered soil is obtained,and its numerical analysis is performed by the implicit finite difference method.In order to verify its validity,the numerical solutions by the present method for some simplified cases are compared with the results in the related literature.Then,the influence of the revelent parameters on the rheological consolidation of double-layered soil are investigated.Numerical results indicate that the parameters of non-Darcian flow and FDMM of the first soil layer greatly influence the consolidation rate of double-layered soil.As the decrease of relative compressibility or the increase of relative permeability between the lower soil and the upper soil,the dissipation rate of excess pore water pressure and the settlement rate of the ground will be accelerated.Increasing the relative thickness of soil layer with high permeability or low compressibility will also accelerate the consolidation rate of double-layered soil.
基金supported by the State Key Program of National Natural Science Foundation of China(Grant No.12132003)State Key Laboratory of Explosion Science and Technology(Grant No.QNKT20-07)。
文摘The time-sequenced damage behavior of the reactive projectile impacting double-layer plates is discussed.The analytical model considering the combined effect of kinetic and chemical energy is developed to reveal the damage mechanism.The influences of impact velocity and reactive projectile chemical characteristics on the damage effect are decoupled analyzed based on this model.These analyses indicate that the high energy releasing efficiency and fast reaction propagation velocity of the reactive projectile are conducive to enhancing the damage effect.The experiments with various reactive projectiles impact velocity increasing from 702 to 1385 m/s were conducted to verify this model.The experimental results presented that,the damage hole radius of the rear-plate increases with the increase of impact velocity.At the impact velocity of 1350 m/s,the radius of damage hole formed by PTFE/Al/Bi_(2)O_(3),PTFE/Al/MoO_(3),PTFE/Al/Fe_(2)O_(3)projectile on the rear-plate become smaller in sequence.These results are consistent with the analytical model prediction,demonstrating that this model can predict the damage effect quantitatively.This work is of constructive significance to the application of reactive projectiles.
基金Project(51074182)supported by the National Natural Science Foundation of ChinaProject(201012200032)supported by the Fundamental Research Funds for the Central Universities,China
文摘Double-layered pellet （DLP） roasting is a novel pretreatment method for sulfur and arsenic-bearing gold concentrates. In this process, preparation of DLPs is a fundamental step which is required to produce DLPs with favorable mechanical strength and thermal stability. Studies were carried out to investigate the affecting factors and conditions on the preparation and properties of DLPs. The results show that moisture content has significant influence on DLPs preparation. With the increase of moisture content in the range of no more than 9.8%, drop resistance and compressive strength of green DLPs are raised and the pelletizing dynamics is improved accordingly. The optimum conditions are determined as moisture content of 9.8%, coating time of 14-16 min, drying temperature 〈80 ℃and drying gas velocity 〈1.2 m/s. When DLPs prepared under these conditions are roasted at 600 ℃ for 1 h, favorable removal and solidifying rates can be obtained, in which the removal rates of arsenic and sulfur are 94.38% and 82.55%, and the solidifying rates of arsenic and sulfur reach 99.62% and 99.79%, respectively. These results promise industrial application of DLP roasting.
文摘The microstructure and electrical properties of ZnO-Bi2O3-Yb2O3 based varistor ceramics were investigated with various temperature effects from 900°C to 1050°C.From the results,it was observed that the increase of sintering temperature offers a reduced capacitive effect from 0.460 nF to 0.321 nF.Furthermore,the grain sizes of varistors were varied from 6.8μm to 9.8μm.The consequence of such smaller grain sizes provided a better voltage gradient of about 895 V/mm for the disc sintered at 900°C and fallen drastically to 410 V/mm for the sample sintered at 1050°C.In addition,there was an increase of non-linearity index to a maximum value of 36.0 and reduced leakage current of 0.026 mA/cm2.However,the density of the varistor decreased with an increase of temperature from 5.41 g/cm3 to 5.24 g/cm3.With this base,the influence of varistor capacitance and high voltage gradient were scrutinized and it led an improved transition speed of the varistor assembly from non-conduction to conduction mode during intruding nanosecond transients.
基金Projects(51478477,51878074)supported by the National Natural Science Foundation of ChinaProject(2017-123-033)supported by the Guizhou Provincial Department of Transportation Foundation,ChinaProjects(2018zzts663,2018zzts656)supported by the Fundamental Research Funds for the Central Universities,China
文摘In the framework of upper bound theorem of limit analysis, the progressive collapse of shallow rectangular tunnels with double-layer rock mass has been theoretically analyzed based on the three-dimensional (3D) velocity discontinuity surfaces. According to the virtual work principle, the difference theorem and the variation method, the collapse surface of double-layer rock mass is determined based on the Hoek-Brown failure criterion. The formula can be degenerated to a single-layer rock collapsing problem when the rock mass is homogeneous. To estimate the validity of the result, the numerical simulation software PLAXIS 3D is used to simulate the collapse of shallow tunnels with double-layer rock mass, and the comparative analysis shows that numerical results are in good agreement with upper-bound solutions. According to the results of parametric analysis, the potential range of collapse of a double-layer rock mass above a shallow cavity decreases with a decrease in A1/A2,σci1/σci2 and σtm1/σtm2 and an increase in B1/B2,γ1/γ2. The range will decrease with a decrease in support pressure q and increase with a decrease in surface overload σs. Therefore, reinforced supporting is beneficial to improve the stability of the cavity during actual construction.
基金supported by grant from National Natural Science Foundation of China No10772127,30570450Program for New Century Excellent Talents in University NCET-06-0789Sichaun Youth Science and Technology Foundation 06ZQ026-009
文摘Introduction Blood flow provides a mechanical condition for blood cells and vessels,especially for endothelial cells.It is important to understand the mechanical characteristics of
基金Project(20060390889) supported by China Postdoctoral Science FoundationProject (2006FJ4236) supported by Hunan Postdoctoral Scientific Program
文摘Mn/Ni composite oxides as active electrode materials for supercapacitors were prepared by solid-state reaction through the reduction of KMnO4 with manganese acetate and nickel acetate at low temperature. The products were characterized by X-ray diffractometry(XRD) and transmission electron microscopy(TEM). The electrochemical characterizations were performed by cyclic voltammetry (CV) and constant current charge-discharge in a three-electrode system. The effects of different potential windows, scan rates, and cycle numbers on the capacitance behavior of Mn0.8Ni0.2Ox composite oxide were also investigated. The results show that the composite oxides are of nano-size and amorphous structure. With increasing the molar ratio of Ni, the specific capacitance goes through a maximum at molar fraction of Ni of 20%. The specific capacitance of Mn0.8Ni0.2Ox composite oxide is 194.5 F/g at constant current discharge of 5 mA.
基金Project(51704229)supported by the National Natural Science Foundation of ChinaProject(2018YQ2-01)supported by the Outstanding Youth Science Fund of Xi’an University of Science and Technology,China。
文摘In the long distance transportation of slurry filled for mining filling,there exist complex variation rules of pressure and flow velocity,pipe distribution location and other influencing factors.Electrical capacitance tomography(ECT)is a technique for visualizing two-phase flow in a pipe or closed container.In this paper,a visual detection method was proposed by image reconstruction of core,laminar,bubble and annular flow based on ECT technology,which reflects distribution of slurry in deep filling pipeline and measures the degree of blockage.There is an error between the measured and the real two-phase flow distribution due to two factors,which are immature image reconstruction algorithm of ECT and difference of flow patterns leading to degrees of error.In this paper,convolutional neural networks(CNN)is used to recognize flow patterns,and then the optimal image is calculated by the improved particle swarm optimization(PSO)algorithm with weights using simulated annealing strategy,and the fitness function is improved based on the results of the shallow neural network.Finally,the reconstructed binary image is further processed to obtain the position,size and direction of the blocked pipe.The realization of this method provides technical support for pipeline detection technology.
文摘Electrical capacitance volume tomography(ECVT) is a recently-developed technique for real-time,non-invasive 3D monitoring of processes involving materials with strong contrasts in dielectric permittivity.This work is first application of the method to visualization of water flow in soil.We describe the principles behind the method,and then demonstrate its use with a simple laboratory infiltration experiment.32 ECVT sensors were installed on the sides of an empty PVC column.Water was poured into the column at a constant rate,and ECVT data were collected every second.The column was then packed with dry sand and again supplied with water at a constant rate with data collected every second.Data were analyzed to give bulk average water contents,which proved consistent with the water supply rates.Data were also analyzed to give 3D images(216 voxels) allowing visualization of the water distribution during the experiments.Result of this work shows that water infiltration into the soil,wall flow,progress of the unstable wetting front and the final water distribution are clearly visible.
文摘The recalibration of electrical capacitance tomography (ECT) system is one of the key problems in keeping the system running steadily.However, for engineering application in solids/gas transport,online calibration can not be implemented and the data from this sensor may be unreliable due to the sensor pipe interior wall abrasion during pneumatic transport,so the solids concentration calculated from the reconstructed image based on these data will be highly inaccurate.The simulations show that, the inter-electrode relative capacitance variation of electrode pair spacing 1 is the most sensitive to the abrasion of sensor pipe interior wall, so this relative capacitance variation when the sensor is filled with air can be used as an indicator demanding offline system recalibration when the wall abrasion goes significant.Furthermore, while the pipe interior wall abrasion is not very serious, online correcting measured inter-electrode capacitance with wall capacitance variation can improve the accuracy of concentration calculation.
基金Project Supported by National Natural Science Foundation of China(50407010)
文摘It presents a method which can equivalently arrange the capacitance distribution along with the winding of the generator on the terminal and neutral respectively in a reasonable partition,particularly for a type of high-voltage graded insulated cable wound generator,Powerformer.The winding of the Powerformer adopts graded insulation,which leads to the various cable thicknesses in different portion of the winding,and thus,the uneven capacitance distribution.The large capacitive currents and large transient outrush currents resulting from the cable consisting of the stator winding of Powerformer may cause problems to the generator differential protection.Most of literatures available in the field of compensated differential protection focus on the charging current compensation for long transmission line,instead of for generator.The authors give a method which can be used to compensate the capacitive current wholly to improve the reliability of the differential protection of Powerformer.It is proved that the distributed capacitance can be equivalent as the lump circuit with a capacitance partition coefficient ρ,and ρ is proved as a constant no matter whether the generator experiences the normal operation,external phase(s) fault or internal phase(s) fault.The formula of the partition coefficient is provided and the corresponding equivalent circuit of the Powerformer cable to calculate capacitance currents is given.An analysis programming resolving the minimum value of the coefficient ρ is written in MATLAB 7.0/m according to this formula,using the function fmincon() which can work in any type of constraint condition.The program always gets the same global minimum points under the different initial values condition which proves our point by mathematical test.With this new approach to winding capacitance dividing method,the protection scheme used for Powerformer can be validated and improved accordingly.
基金Project(2023JJ40040)supported by the Natural Science Foundation of Hunan Province,ChinaProject(502221904)supported by the Project of Innovation-Driven Plan in Central South University,ChinaProject(24C0140)supported by the Scientific Research Fund of Hunan Provincial Education Department,China。
文摘The capacitive performance of carbon materials as supercapacitor electrode is synergistically influenced by the surface porous structure,graphitization structure,and surface atomic doping.However,simple realization of their synergistic regulation still faces significant challenges.Based on the biological porous structure,heteroatom-rich content and low cost of chestnut,this work adopt chestnut as precursor to prepare carbon electrode,of which the pores,graphitization,and surface atomic doping are synergistically regulated by simply changing the activation temperature.The optimized carbon electrode possesses a hierarchical porous structure with partial graphitization and O and N co doping.Benefited from these merits,the chestnut-derived porous carbon as a supercapacitor electrode,can achieve a high specific capacitance of 328.6 F/g at 1 A/g,which still retains 80.8%when the current density enlarging to 20 A/g.By packaging the symmetric electric double-layer capacitor,the device exhibits a specific capacitance of 63.6 F/g at 1 A/g,delivering an energy density of 12.7 W·h/kg at a power density of 600 W/kg.The stability of the device is tested at a current density of 20 A/g,which shows a capacitance retention rate of up to 90%after 10000 charge-discharge cycles.
