Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfull...Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfully synthesized under hydrothermal conditions and characterized structurally by IR spectroscopy,elemental analyses,single-crystal X-ray diffraction,powder X-ray diffraction,and thermogravimetric analysis.The results of single-crystal X-ray diffraction show that complex 1 presents a 1D zigzag chain structure and further extends to a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.Meanwhile,complex 2 has a zero-dimensional structure and also extends to form a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.In addition,both 1and 2 exhibited luminescent properties in the solid state.Furthermore,quantum chemical calculations were carried out on the"molecular fragments"extracted from the crystal structures of 1 and 2 using the PBE0/LANL2DZ method constructed by the Gaussian 16 program.The calculated values signify a significant covalent interaction between the coordination atoms and the Cd(Ⅱ)ions.CCDC:2332173,1;2332176,2.展开更多
横波可控震源振动器平板作为页岩气勘探中的关键部件,其疲劳寿命直接影响可控震源的使用寿命和勘探精度。然而,传统的振动器平板疲劳寿命优化方法未考虑平板与平板齿间焊接残余应力的影响,导致平板结构在抗疲劳优化设计方面效果不佳。为...横波可控震源振动器平板作为页岩气勘探中的关键部件,其疲劳寿命直接影响可控震源的使用寿命和勘探精度。然而,传统的振动器平板疲劳寿命优化方法未考虑平板与平板齿间焊接残余应力的影响,导致平板结构在抗疲劳优化设计方面效果不佳。为此,使用局部灵敏度法对平板疲劳寿命进行敏感性分析,确定了焊接残余应力为影响疲劳寿命的关键因素。随后,建立了平板的各向最大焊接残余应力与焊接速度和焊接层间温度之间的数学模型,并以各向最大焊接残余应力为约束,以疲劳寿命为优化目标,建立相应的优化模型。最后,利用NSGA-Ⅱ(nondominated sorting genetic algorithm-Ⅱ,非支配排序遗传算法-Ⅱ)获取Pareto解集,并结合熵权法和TOPSIS(technique for order preference by similarity to ideal solution,逼近理想解排序)法确定最佳优化方案:焊接速度为10.23 mm/s,焊接层间温度为105℃。结果表明,优化后平板的疲劳寿命为10.23年,相比优化前提高了17.72%。研究结果可为横波可控震源振动器平板的疲劳寿命优化提供科学有效的理论方法和工程指导。展开更多
文摘Two new transition-metal coordination polymers,{[Cd(oba)(L)_(2)]·H_(2)O}_n(1)and[Cd(4-nph)(L)_(2)]_n(2)(H_(2)oba=4,4'-oxydibenzoic acid,4-H_(2)nph=4-nitrophthalic acid,L=2,2'-biimidazole),were successfully synthesized under hydrothermal conditions and characterized structurally by IR spectroscopy,elemental analyses,single-crystal X-ray diffraction,powder X-ray diffraction,and thermogravimetric analysis.The results of single-crystal X-ray diffraction show that complex 1 presents a 1D zigzag chain structure and further extends to a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.Meanwhile,complex 2 has a zero-dimensional structure and also extends to form a 2D network through N—H…O hydrogen bonds andπ-πstacking interactions.In addition,both 1and 2 exhibited luminescent properties in the solid state.Furthermore,quantum chemical calculations were carried out on the"molecular fragments"extracted from the crystal structures of 1 and 2 using the PBE0/LANL2DZ method constructed by the Gaussian 16 program.The calculated values signify a significant covalent interaction between the coordination atoms and the Cd(Ⅱ)ions.CCDC:2332173,1;2332176,2.
文摘横波可控震源振动器平板作为页岩气勘探中的关键部件,其疲劳寿命直接影响可控震源的使用寿命和勘探精度。然而,传统的振动器平板疲劳寿命优化方法未考虑平板与平板齿间焊接残余应力的影响,导致平板结构在抗疲劳优化设计方面效果不佳。为此,使用局部灵敏度法对平板疲劳寿命进行敏感性分析,确定了焊接残余应力为影响疲劳寿命的关键因素。随后,建立了平板的各向最大焊接残余应力与焊接速度和焊接层间温度之间的数学模型,并以各向最大焊接残余应力为约束,以疲劳寿命为优化目标,建立相应的优化模型。最后,利用NSGA-Ⅱ(nondominated sorting genetic algorithm-Ⅱ,非支配排序遗传算法-Ⅱ)获取Pareto解集,并结合熵权法和TOPSIS(technique for order preference by similarity to ideal solution,逼近理想解排序)法确定最佳优化方案:焊接速度为10.23 mm/s,焊接层间温度为105℃。结果表明,优化后平板的疲劳寿命为10.23年,相比优化前提高了17.72%。研究结果可为横波可控震源振动器平板的疲劳寿命优化提供科学有效的理论方法和工程指导。
