The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experim...The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.展开更多
An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the...An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.展开更多
Tin-lead(Sn-Pb)mixed perovskites are extensively investigated in near-infrared(NIR)photodetectors(PDs)owing to their excellent photoelectric performance.However,achieving high-performance Sn-Pb mixed PDs remains chall...Tin-lead(Sn-Pb)mixed perovskites are extensively investigated in near-infrared(NIR)photodetectors(PDs)owing to their excellent photoelectric performance.However,achieving high-performance Sn-Pb mixed PDs remains challenging,primarily because of the rapid crystallization and the susceptibility of Sn^(2+) to oxidation.To ad⁃dress these issues,this study introduces the multifunctional molecules 2,3-difluorobenzenamine(DBM)to modulate the crystallization of Sn-Pb mixed perovskites and retard the oxidation of Sn^(2+),thereby significantly enhancing film quality.Compared with the pristine film,Sn-Pb mixed perovskite films modulated by DBM molecules exhibit a high⁃ly homogeneous morphology,reduced roughness and defect density.The self-powered NIR PDs fabricated with the improved films have a spectral response range from 300 nm to 1100 nm,a peak responsivity of 0.51 A·W^(-1),a spe⁃cific detectivity as high as 2.46×10^(11)Jones within the NIR region(780 nm to 1100 nm),a linear dynamic range ex⁃ceeding 152 dB,and ultrafast rise/fall time of 123/464 ns.Thanks to the outstanding performance of PDs,the fabri⁃cated 5×5 PDs array demonstrates superior imaging ability in the NIR region up to 980 nm.This work advances the development of Sn-Pb mixed perovskites for NIR detection and paves the way for their commercialization.展开更多
Sodium cocoyl glycinate(SCG),an environmentally friendly anionic amino acid surfactant,is widely used in daily chemical products as an upgraded alternative to traditional surfactants.In this study,crude Camellia oleif...Sodium cocoyl glycinate(SCG),an environmentally friendly anionic amino acid surfactant,is widely used in daily chemical products as an upgraded alternative to traditional surfactants.In this study,crude Camellia oleifera saponin(COS)was purified using AB-8 macroporous adsorption resin,and its composition and structure were analyzed.The effects of different mole fractions of COS(αCOS)on surface tension(γ),oil-water interfacial tension(IFT),emulsification,and foam properties of COS-SCG binary mixed systems were investigated in mixtures of SCG with purified COS.The stability ofγand foamability under diverse environmental conditions were also discussed.The results indicated that the COS-SCG system exhibited remarkable surface-active synergism.The minimum critical micelle concentration(cmc)of the mixed system was lower than that of SCG,and adding a small mole fraction of COS(1%-2%)induced a synergistic reduction ofγ.Specifically,the cmc andγwere 2.50×10-4 mol/L and 23.1 mN/m forαCOS=1%,respectively.The system exhibited exceptional IFT reduction capacity,achieving a minimum value of 1.42 mN/m atαCOS=10%.The mixed system reached a foaming volume(atαCOS=50%)and foam stability(atαCOS=75%)were 51.0 mL and 97.37%,respectively.Microscopic analysis further confirmed these outstanding foam properties.Moreover,the COS-SCG system displayed reducedγwith enhanced foaming volume under elevated temperatures(35-75℃)and salinity(0-20 g/L).However,acidic conditions and hard water compromised bothγstability and foamability.展开更多
The evaluation of the mixing effect of gas-liquid two-phase flow during the top-blown gas agitation mixing is one of the difficulties in the testing field, especially in the process of using the model method to study ...The evaluation of the mixing effect of gas-liquid two-phase flow during the top-blown gas agitation mixing is one of the difficulties in the testing field, especially in the process of using the model method to study the metallurgical top-blowing process. In order to evaluate the effect of gas-liquid two-phase flow mixing, a gas chromatography simulation based on capacitance tomography was used to visualize the flow pattern and analyze the mixed characteristics. A gas top-blown agitation test rig was set up, the gas phase was air-selected, and the liquid phase was selected from synthetic heat-conducting oil. The top-blown stirring test process was measured and imaged by electrical capacitance tomography (ECT) equipment from ECT Instruments Ltd (UK). The MATLAB program was used to identify the mixing areas of the images to obtain the distribution of gas-liquid two-phase. The flow pattern of the gas-liquid mixing region was obtained. The chaotic detection of the gas-liquid mixing process was performed by the three-state test method;the images were processed by the counting box dimension-corrosion method to obtain the mixing uniformity time of gas-liquid flow. Results show that it is feasible to use the capacitance tomography technique to visualize the gas-liquid two-phase distribution. The uniformity time quantification of the gas-liquid mixing process is also achieved.展开更多
Chaotic mixing is regarded as an effective method to improve the mixing effect in the laminar stirred tank.To generate chaos in flow field in stirred tank,many efforts including aperiodic movement,asystematic installa...Chaotic mixing is regarded as an effective method to improve the mixing effect in the laminar stirred tank.To generate chaos in flow field in stirred tank,many efforts including aperiodic movement,asystematic installation impeller,etc.,were made to save mixing time and energy consumption.The computational fluid dynamics of chaotic flow field and the hyperchaotic controlling method as well as macro-instability were reviewed.Multiple flow field coupling is important in the turbulent mixing region of stirred tank.The development trends of flow field coupling and hyperchaotic controlling in chaotic mixing were prospected in energy saving operation.展开更多
Signals from multi-sensor systems are often mixtures of （statistically） independent sources by unknown mixing method. Blind source separation（BSS） and independent component analysis（ICA） are the methods to ident...Signals from multi-sensor systems are often mixtures of （statistically） independent sources by unknown mixing method. Blind source separation（BSS） and independent component analysis（ICA） are the methods to identify/recover the channels and the sources. BSS/ICA of nonlinear mixing models are difficult problems. For instance, the post-nonlinear model has been studied by several authors. It is noticed that in most cases, the proposed models are always with an invertible mixing. According to this fact there is an interesting question, how about the situation of the non-invertible non-linear mixing in BSS or ICA？ A new simple non-linear mixing model is proposed with a kind of non-invertible mixing, the folding mixing, and method to identify its channel, blindly.展开更多
In order to obtain high-quality spherical RDX crystal particles,the RDX crystals were suspended in a mixed solvent of cyclohexanone and cyclohexane,subsequently a solvent etching study was carried out under the action...In order to obtain high-quality spherical RDX crystal particles,the RDX crystals were suspended in a mixed solvent of cyclohexanone and cyclohexane,subsequently a solvent etching study was carried out under the action of vibration/acoustic flow coupled flow field,which generated by resonance acoustic mixing.The effects of solvent ratio,temperature,acceleration and experiment time on morphology as well as particle size of RDX crystals were studied.Not only were the morphology,particle size distribution and crystal form of RDX crystals determined,but also the thermal decomposition performance and mechanical sensitivity of spherical RDX were examined and discussed.Results indicated that under the process of solvent/non-solvent volume ratio at 1:2,temperature of 40℃,acceleration of 40 g and experiment time of 4 h,α-type RDX crystal with sphericity of 0.92 can be obtained.Furthermore,the median particle size(D_(50))of spherical RDX crystals is 215.8 μm with a unimodal particle size distribution(size span 1.34).For one thing,the thermal decomposition peak temperature of spherical RDX is about 2.5℃ higher than that of raw RDX,and apparent activation energy reaches 444.68 kJ/mol.For another thing,impact sensitivity and friction sensitivity of spherical RDX are 18.18% and 33.33% lower than that of raw RDX,respectively.It demonstrates that safety of spherical RDX under thermal,impact and friction stimuli has been improved.展开更多
The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of ma...The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.展开更多
In order to correctly predict tube cross section time-smoothed velocity distribution, friction factor and mass transfer behavior, two models for turbulent flow in circular tubes based on classical Prandtl mixing lengt...In order to correctly predict tube cross section time-smoothed velocity distribution, friction factor and mass transfer behavior, two models for turbulent flow in circular tubes based on classical Prandtl mixing length theory and a modified mixing length were established. The results show that the modified mixing length includes the introduction of a damping function for the viscous sublayer and the second-order derivative to approximate eddy velocity. The calculated dimensionless time-smoothed velocity from the model based on Prandtl mixing length is much better than the result from the concept of eddy viscosity. The calculated eddy viscosity from the model based on modified mixing length is much better than the result from the model based on the classical Prandtl mixing length theory. And the friction factor calculated from the model based on the modified mixing length agrees well with the reported empirical relationships.展开更多
Recent eruption in 1991-1995 years of Unzen Volcano(Kyushu Island,Japan)has caught attention of many volcanologists because of dramatical consequences of the previos eruption in 1792,when more than 15000 people were p...Recent eruption in 1991-1995 years of Unzen Volcano(Kyushu Island,Japan)has caught attention of many volcanologists because of dramatical consequences of the previos eruption in 1792,when more than 15000 people were perished.So it is important to study this volcano and try to predict future eruptions and their possible damage.It is proved now,that magma hybridization processes展开更多
The main structure and working principle of the single-shaft horizontal total mixed ration mixer was discussed. For studying the mixing principle, the analysis of force and motion of the material on the paddle were ma...The main structure and working principle of the single-shaft horizontal total mixed ration mixer was discussed. For studying the mixing principle, the analysis of force and motion of the material on the paddle were made, and paddle angle and rotational speed of the rotor were determined by the experiment, the main mixing ways were explained.展开更多
In this paper,adiabatic density surface,neutral density surface and potential density surface are compared.The adiabatic density surface is defined as the surface on which a water parcel can move adiabatically,without...In this paper,adiabatic density surface,neutral density surface and potential density surface are compared.The adiabatic density surface is defined as the surface on which a water parcel can move adiabatically,without changing its potential temperature and salinity.For a water parcel taken at a given station and pressure level,the corresponding adiabatic density surface can be determined through simple calculations.This family of surface is neutrally buoyant in the world ocean,and different from other surfaces that are not truly neutrally buoyant.In order to explore mixing path in the ocean,a mixing ratio m is introduced,which is defined as the portion of potential temperature and salinity of a water parcel that has exchanged with the environment during a segment of migration in the ocean.Two extreme situations of mixing path in the ocean are m=0(no mixing),which is represented by the adiabatic density curve,and m=1,where the original information is completely lost through mixing.The latter is represented by the neutral density curve.The reality lies in between,namely,0<m<1.In the turbulent ocean,there are potentially infinite mixing paths,some of which may be identified by using different tracers(or their combinations)and different mixing criteria.Searching for mixing paths in the real ocean presents a great challenge for further research.展开更多
We have been observed the frequency difference signal between higher order harmonic of 4 mm microwave oscillating source and CH2F2 FIR laser.In three experiments,the frequencies of Gunn oscillators are 93.16 GHz,73.54...We have been observed the frequency difference signal between higher order harmonic of 4 mm microwave oscillating source and CH2F2 FIR laser.In three experiments,the frequencies of Gunn oscillators are 93.16 GHz,73.54 GHz and 73.9 GHz,and their harmonic orders are 15th,19th amd 22th,the laser frequency are 1.397 THz(former twin)and 1.626 THz(latter one),and frequency difference signal-noise ratio are better than 20dB.展开更多
The occurrence of liquid condensation in natural gas accounts for new challenges during the interoperability between transmission networks,where condensation would lead to higher pressure drops,lower line capacity and...The occurrence of liquid condensation in natural gas accounts for new challenges during the interoperability between transmission networks,where condensation would lead to higher pressure drops,lower line capacity and may cause safety problem.A successful case of hydrocarbon dew point(HCDP)analysis is demonstrated during the mixing of natural gases in the transmission pipeline.Methods used to predict the HCDP are combined with equations of state(EOS)and characterization of C6+heavy components.Predictions are compared with measured HCDP with different concentrations of mixed gases at a wide range of pressure and temperature scopes.Software named"PipeGasAnalysis"is developed and helps to systematic analyze the condensation problem,which will provide the guidance for the design and operation of the network.展开更多
A spatial color-mixing model based on tricolor angular frequencies is proposed in consideration that the design theory falls behind the application of digital camouflage pattern.The model is based on Fourier transform...A spatial color-mixing model based on tricolor angular frequencies is proposed in consideration that the design theory falls behind the application of digital camouflage pattern.The model is based on Fourier transform and Gaussian low-pass filter(LPF).In the model,the tricolor angular frequencies are introduced to the spatial frequency response function of human color vision,and the effects of atmospheric attenuation and air screen brightness on color mixture are considered.The field test shows that the model can simulate the color-mixing process in the aspects of color-mixing order,and shape and position of color-mixing spot.But the color-mixing spot color is not perfect,which can be improved by optimizing the atmospheric parameters and tricolor cut-off angular frequencies.The model provides a tool for the research on digital camouflage pattern.展开更多
基金financially supported by the Fundamental Research Funds for the Central Universities(Grant No.30923011018)。
文摘The present study introduces a screw-pressing charging method to tackle deficiencies in automation and charge uniformity during the melt-casting of polymer-based energetic materials.To ensure the safety of the experiments,this study used inert materials with similar physical properties to partially substitute for the actual energetic components in the preparation of simulant materials.By thoroughly analyzing slurry physical properties,a simulation framework and an extensive performance evaluation method were developed.Such tools guide the design of the structure and configuration of process parameters.Results demonstrate that employing the Pin element significantly enhances radial mixing within the screw,minimizes temperature variations in the slurry,and improves both efficiency and safety in the mixing process.Further,adjustments such as widening the cone angle of the barrel,modifying the solid content of the slurry,and varying the speed of the screw can optimize the mechanical and thermal coupling in the flow field.These adjustments promote higher-quality slurry and create a safer production environment for the extrusion process.
文摘An aluminoborate,Na_(2.5)Rb[Al{B_(5)O_(10)}{B_(3)O_(5)}]·0.5NO_(3)·H_(2)O(1),was synthesized under hydrothermal condition,which was built by mixed oxoboron clusters and AlO_(4)tetrahedra.In the structure,the[B_(5)O_(10)]^(5-)and[B_(3)O_(7)]^(5-)clusters are alternately connected to form 1D[B_(8)O_(15)]_(n)^(6n-)chains,which are further linked by AlO_(4)units to form a 2D monolayer with 7‑membered ring and 10‑membered ring windows.Two adjacent monolayers with opposite orientations further form a porous‑layered structure with six channels through B—O—Al bonds.Compound 1 was characterized by single crystal X‑ray diffraction,powder X‑ray diffraction(PXRD),IR spectroscopy,UV‑Vis diffuse reflection spectroscopy,and thermogravimetric analysis(TGA),respectively.UV‑Vis diffuse reflectance analysis indicates that compound 1 shows a wide transparency range with a short cutoff edge of 201 nm,suggesting it may have potential application in UV regions.CCDC:2383923.
基金Supported by National Key Research and Development Program of China(2022YFA1404201)National Natural Science Foundation of China(62205187,U23A20380,U22A2091,62222509,62127817,62075120)+3 种基金Changjiang Scholars and Innovative Research Team in University of Ministry of Education of China(IRT_17R70)Fundamental Research Program of Shanxi Province(202103021223032,202303021222031)Project Funded by China Postdoctoral Science Foundation(2022M722006)Fund for Shanxi“1331 Project”Key Subjects Construction。
文摘Tin-lead(Sn-Pb)mixed perovskites are extensively investigated in near-infrared(NIR)photodetectors(PDs)owing to their excellent photoelectric performance.However,achieving high-performance Sn-Pb mixed PDs remains challenging,primarily because of the rapid crystallization and the susceptibility of Sn^(2+) to oxidation.To ad⁃dress these issues,this study introduces the multifunctional molecules 2,3-difluorobenzenamine(DBM)to modulate the crystallization of Sn-Pb mixed perovskites and retard the oxidation of Sn^(2+),thereby significantly enhancing film quality.Compared with the pristine film,Sn-Pb mixed perovskite films modulated by DBM molecules exhibit a high⁃ly homogeneous morphology,reduced roughness and defect density.The self-powered NIR PDs fabricated with the improved films have a spectral response range from 300 nm to 1100 nm,a peak responsivity of 0.51 A·W^(-1),a spe⁃cific detectivity as high as 2.46×10^(11)Jones within the NIR region(780 nm to 1100 nm),a linear dynamic range ex⁃ceeding 152 dB,and ultrafast rise/fall time of 123/464 ns.Thanks to the outstanding performance of PDs,the fabri⁃cated 5×5 PDs array demonstrates superior imaging ability in the NIR region up to 980 nm.This work advances the development of Sn-Pb mixed perovskites for NIR detection and paves the way for their commercialization.
文摘Sodium cocoyl glycinate(SCG),an environmentally friendly anionic amino acid surfactant,is widely used in daily chemical products as an upgraded alternative to traditional surfactants.In this study,crude Camellia oleifera saponin(COS)was purified using AB-8 macroporous adsorption resin,and its composition and structure were analyzed.The effects of different mole fractions of COS(αCOS)on surface tension(γ),oil-water interfacial tension(IFT),emulsification,and foam properties of COS-SCG binary mixed systems were investigated in mixtures of SCG with purified COS.The stability ofγand foamability under diverse environmental conditions were also discussed.The results indicated that the COS-SCG system exhibited remarkable surface-active synergism.The minimum critical micelle concentration(cmc)of the mixed system was lower than that of SCG,and adding a small mole fraction of COS(1%-2%)induced a synergistic reduction ofγ.Specifically,the cmc andγwere 2.50×10-4 mol/L and 23.1 mN/m forαCOS=1%,respectively.The system exhibited exceptional IFT reduction capacity,achieving a minimum value of 1.42 mN/m atαCOS=10%.The mixed system reached a foaming volume(atαCOS=50%)and foam stability(atαCOS=75%)were 51.0 mL and 97.37%,respectively.Microscopic analysis further confirmed these outstanding foam properties.Moreover,the COS-SCG system displayed reducedγwith enhanced foaming volume under elevated temperatures(35-75℃)and salinity(0-20 g/L).However,acidic conditions and hard water compromised bothγstability and foamability.
基金Project(51666006) supported by the National Natural Science Foundation of ChinaProject(U1602272) supported by the Joint Funds of the National Natural Science Foundation of ChinaProject(2015HA019) supported by the Scientific and Technological Leading Talent Projects in Yunnan Province,China
文摘The evaluation of the mixing effect of gas-liquid two-phase flow during the top-blown gas agitation mixing is one of the difficulties in the testing field, especially in the process of using the model method to study the metallurgical top-blowing process. In order to evaluate the effect of gas-liquid two-phase flow mixing, a gas chromatography simulation based on capacitance tomography was used to visualize the flow pattern and analyze the mixed characteristics. A gas top-blown agitation test rig was set up, the gas phase was air-selected, and the liquid phase was selected from synthetic heat-conducting oil. The top-blown stirring test process was measured and imaged by electrical capacitance tomography (ECT) equipment from ECT Instruments Ltd (UK). The MATLAB program was used to identify the mixing areas of the images to obtain the distribution of gas-liquid two-phase. The flow pattern of the gas-liquid mixing region was obtained. The chaotic detection of the gas-liquid mixing process was performed by the three-state test method;the images were processed by the counting box dimension-corrosion method to obtain the mixing uniformity time of gas-liquid flow. Results show that it is feasible to use the capacitance tomography technique to visualize the gas-liquid two-phase distribution. The uniformity time quantification of the gas-liquid mixing process is also achieved.
基金supported by Natural Science Foundation of China(20806095)ScientificResearch Foundation for the Returned Overseas Chinese Scholars,State Education Ministry(教外司留20091341-2)+1 种基金China Postdoctoral Science Foundation(20080430747)National High Technology Research and Development Program of China(2008AA0312)
文摘Chaotic mixing is regarded as an effective method to improve the mixing effect in the laminar stirred tank.To generate chaos in flow field in stirred tank,many efforts including aperiodic movement,asystematic installation impeller,etc.,were made to save mixing time and energy consumption.The computational fluid dynamics of chaotic flow field and the hyperchaotic controlling method as well as macro-instability were reviewed.Multiple flow field coupling is important in the turbulent mixing region of stirred tank.The development trends of flow field coupling and hyperchaotic controlling in chaotic mixing were prospected in energy saving operation.
基金This project was supported by the Talent Foundation of Anhui Province(2004Z025)
文摘Signals from multi-sensor systems are often mixtures of （statistically） independent sources by unknown mixing method. Blind source separation（BSS） and independent component analysis（ICA） are the methods to identify/recover the channels and the sources. BSS/ICA of nonlinear mixing models are difficult problems. For instance, the post-nonlinear model has been studied by several authors. It is noticed that in most cases, the proposed models are always with an invertible mixing. According to this fact there is an interesting question, how about the situation of the non-invertible non-linear mixing in BSS or ICA？ A new simple non-linear mixing model is proposed with a kind of non-invertible mixing, the folding mixing, and method to identify its channel, blindly.
文摘In order to obtain high-quality spherical RDX crystal particles,the RDX crystals were suspended in a mixed solvent of cyclohexanone and cyclohexane,subsequently a solvent etching study was carried out under the action of vibration/acoustic flow coupled flow field,which generated by resonance acoustic mixing.The effects of solvent ratio,temperature,acceleration and experiment time on morphology as well as particle size of RDX crystals were studied.Not only were the morphology,particle size distribution and crystal form of RDX crystals determined,but also the thermal decomposition performance and mechanical sensitivity of spherical RDX were examined and discussed.Results indicated that under the process of solvent/non-solvent volume ratio at 1:2,temperature of 40℃,acceleration of 40 g and experiment time of 4 h,α-type RDX crystal with sphericity of 0.92 can be obtained.Furthermore,the median particle size(D_(50))of spherical RDX crystals is 215.8 μm with a unimodal particle size distribution(size span 1.34).For one thing,the thermal decomposition peak temperature of spherical RDX is about 2.5℃ higher than that of raw RDX,and apparent activation energy reaches 444.68 kJ/mol.For another thing,impact sensitivity and friction sensitivity of spherical RDX are 18.18% and 33.33% lower than that of raw RDX,respectively.It demonstrates that safety of spherical RDX under thermal,impact and friction stimuli has been improved.
基金Project(51276131)supported by the National Natural Science Foundation of ChinaProject(ZRZ0316)supported by the Natural Science Foundation of Hubei Province,ChinaProject(2013070104010025)supported by the Morning Glory Project of Wuhan Science and Technology Bureau,China
文摘The mixing time of impact zone in liquid-continuous impinging streams reactor(LISR) is theoretically calculated by empirical model and modern micromixing model of the fluid mixing process, and the variation laws of macromixing time and micromixing time are quantitatively discussed. The results show that under a continuous and stable operating condition, as the paddle speed increases, the macromixing time and micromixing time calculated by the two models both decrease, even in a linkage equilibrium state. Simultaneously, as the paddle speed increases, the results figured by the two models tend to be consistent. It indicates that two models both are more suitable for calculation of mixing time in high paddle speed. Compared with the existing experimental results of this type of reactor, the mixing time computed in the speed of 1500 r/min is closer to it. These conclusions can provide an important reference for systematically studying the strengthening mechanism of LISR under continuous mixing conditions.
基金Project(20736009) supported by the National Natural Science Foundation of ChinaProject(07JJ6017) supported by the Natural Science Foundation of Hunan Province, China
文摘In order to correctly predict tube cross section time-smoothed velocity distribution, friction factor and mass transfer behavior, two models for turbulent flow in circular tubes based on classical Prandtl mixing length theory and a modified mixing length were established. The results show that the modified mixing length includes the introduction of a damping function for the viscous sublayer and the second-order derivative to approximate eddy velocity. The calculated dimensionless time-smoothed velocity from the model based on Prandtl mixing length is much better than the result from the concept of eddy viscosity. The calculated eddy viscosity from the model based on modified mixing length is much better than the result from the model based on the classical Prandtl mixing length theory. And the friction factor calculated from the model based on the modified mixing length agrees well with the reported empirical relationships.
文摘Recent eruption in 1991-1995 years of Unzen Volcano(Kyushu Island,Japan)has caught attention of many volcanologists because of dramatical consequences of the previos eruption in 1792,when more than 15000 people were perished.So it is important to study this volcano and try to predict future eruptions and their possible damage.It is proved now,that magma hybridization processes
基金Innovative Talent Research Fund of Harbin City(2006RFQXN011)
文摘The main structure and working principle of the single-shaft horizontal total mixed ration mixer was discussed. For studying the mixing principle, the analysis of force and motion of the material on the paddle were made, and paddle angle and rotational speed of the rotor were determined by the experiment, the main mixing ways were explained.
文摘In this paper,adiabatic density surface,neutral density surface and potential density surface are compared.The adiabatic density surface is defined as the surface on which a water parcel can move adiabatically,without changing its potential temperature and salinity.For a water parcel taken at a given station and pressure level,the corresponding adiabatic density surface can be determined through simple calculations.This family of surface is neutrally buoyant in the world ocean,and different from other surfaces that are not truly neutrally buoyant.In order to explore mixing path in the ocean,a mixing ratio m is introduced,which is defined as the portion of potential temperature and salinity of a water parcel that has exchanged with the environment during a segment of migration in the ocean.Two extreme situations of mixing path in the ocean are m=0(no mixing),which is represented by the adiabatic density curve,and m=1,where the original information is completely lost through mixing.The latter is represented by the neutral density curve.The reality lies in between,namely,0<m<1.In the turbulent ocean,there are potentially infinite mixing paths,some of which may be identified by using different tracers(or their combinations)and different mixing criteria.Searching for mixing paths in the real ocean presents a great challenge for further research.
文摘We have been observed the frequency difference signal between higher order harmonic of 4 mm microwave oscillating source and CH2F2 FIR laser.In three experiments,the frequencies of Gunn oscillators are 93.16 GHz,73.54 GHz and 73.9 GHz,and their harmonic orders are 15th,19th amd 22th,the laser frequency are 1.397 THz(former twin)and 1.626 THz(latter one),and frequency difference signal-noise ratio are better than 20dB.
基金Project(2011ZX05026-004-03)supported by the Key National Science and Technology Specific Program,ChinaProject(NCET-12-0969)supported by the Program for New Century Excellent Talents in University,China+1 种基金Project(51104167)supported by the National Natural Science Foundation of ChinaProject(BJ-2011-02)supported by the Research Funds of China University of Petroleum-Beijing
文摘The occurrence of liquid condensation in natural gas accounts for new challenges during the interoperability between transmission networks,where condensation would lead to higher pressure drops,lower line capacity and may cause safety problem.A successful case of hydrocarbon dew point(HCDP)analysis is demonstrated during the mixing of natural gases in the transmission pipeline.Methods used to predict the HCDP are combined with equations of state(EOS)and characterization of C6+heavy components.Predictions are compared with measured HCDP with different concentrations of mixed gases at a wide range of pressure and temperature scopes.Software named"PipeGasAnalysis"is developed and helps to systematic analyze the condensation problem,which will provide the guidance for the design and operation of the network.
文摘A spatial color-mixing model based on tricolor angular frequencies is proposed in consideration that the design theory falls behind the application of digital camouflage pattern.The model is based on Fourier transform and Gaussian low-pass filter(LPF).In the model,the tricolor angular frequencies are introduced to the spatial frequency response function of human color vision,and the effects of atmospheric attenuation and air screen brightness on color mixture are considered.The field test shows that the model can simulate the color-mixing process in the aspects of color-mixing order,and shape and position of color-mixing spot.But the color-mixing spot color is not perfect,which can be improved by optimizing the atmospheric parameters and tricolor cut-off angular frequencies.The model provides a tool for the research on digital camouflage pattern.
