Five-valued Boolean functions play an important role in the design of symmetric cryptography.While the design and properties of single-output almost optimal five-valued spectra Boolean functions have been extensively ...Five-valued Boolean functions play an important role in the design of symmetric cryptography.While the design and properties of single-output almost optimal five-valued spectra Boolean functions have been extensively studied over the past few decades,there has been limited research on the construction of almost optimal five-valued spectra vectorial Boolean functions.In this paper,we present a construction method for even-variable 2-output almost optimal five-valued spectra balanced Boolean functions,whose Walsh spectra values belong to the set{0,±2^(n/2),±2^(n/2+1)},at the same time,we discuss the existence of sufficient conditions in the construction.Additionally,this paper presents a novel construction method for balanced single-output Boolean functions with even variables featuring a special five-valued spectral structure,whose Walsh spectra values are constrained to the set{0,±2^(n/2),±3·2^(n/2)}.These functions provide new canonical examples for the study of Boolean function spectral theory.展开更多
The seismic damage to ancillary facilities on high-speed railway(HSR)bridges can affect the normal movement of trains.To propose the bridge deck acceleration response spectra of the typical HSR simply-supported girder...The seismic damage to ancillary facilities on high-speed railway(HSR)bridges can affect the normal movement of trains.To propose the bridge deck acceleration response spectra of the typical HSR simply-supported girder bridge for simplifying the seismic responses analysis of the facilities on bridges,the finite element models of the HSR multi-span simply-supported girder bridges with CRTSII track were established,and the numerical model was validated by tests.Besides,the effects of the span number,peak ground acceleration(PGA),pier height on the seismic acceleration and response spectra of the bridge deck were investigated.Afterward,the bridge acceleration amplification factor curves and bridge deck response spectra with different PGAs and pier heights were obtained.The formula for bridge deck acceleration amplification factor,with a 95%guarantee rate,was fitted.Moreover,the finite element models of the overhead contact lines(OCL)mounted on rigid base and bridges were established to validate the fitted formula.The results indicated that the maximum seismic acceleration response is in the midspan of the beam.The proposed formula for the bridge deck acceleration response spectra can be used to analyze the earthquake response of the OCL and other ancillary facilities on HSR simply-supported girder bridges.The bridge deck acceleration response spectra are conservative in terms of structural safety and can significantly improving the analysis efficiency.展开更多
The photo absorbing, photo transmitting and photoluminescence performances of WiO2 photocatalysts compounded with V2O5 or WO3 were investigated by UV-Vis spectra, transmitting spectra, and PL spectra, respectively. Th...The photo absorbing, photo transmitting and photoluminescence performances of WiO2 photocatalysts compounded with V2O5 or WO3 were investigated by UV-Vis spectra, transmitting spectra, and PL spectra, respectively. The energy band structures of TiO2 photocatalysts were analyzed. The photocatalytic activities of the TiO2 photocatalysts were investigated by splitting of water for 02 evolution. The results indicate that the band gaps of WO3 and V205 are about 2.8 and 2.14 eV, respectively, and the band gap of rutile TiO2 is about 3.08 eV. Speeds of water splitting for 2%WO3-TiO2 and 8%V2O5-TiO2 photocatalysts are 420 and 110 μmol/（L.h）, respectively, under UV light irradiation. V2O5 and WO3 compounded with suitable concentration can improve the photocatalytic activity of TiO2 with Fe3＋ as electron acceptor.展开更多
Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide...Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.展开更多
Aim of the study is to evaluate the environmental impact of geothermic activities by the use of in site spectral analyses of different environmental com- ponents.These activities can cause the heavy metal （Hg,Sb,S,B,...Aim of the study is to evaluate the environmental impact of geothermic activities by the use of in site spectral analyses of different environmental com- ponents.These activities can cause the heavy metal （Hg,Sb,S,B,As,H<sub>2</sub>S）drifting from power plants to around areas.Different analytical techniques展开更多
The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to ...The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to shorter wavelength when polyaniline was doped with CSAH in N methyl 2 pyrrolidione (NMP) solvent, while the red shift of polaron band was observed when it was in N, N dimethylformamide (DMF). It indicates that the influence of different processing solvents on the doping property of polyaniline is greatly different. N methyl 2 pyrrolidione is a good solvent for polyaniline, polyaniline chain is unfolded in it. The interaction of NMP with CSAH is so strong that the resulting product is apt to dedoping, while the solubility of polyaniline in DMF is relatively low and polyaniline chain is in partly folded state. Thus the doping reaction is kinetically disadvantageous but thermodynamically advantageous.展开更多
Dye-sensitized solar cells(DSSCs) are one of the most promising renewable energy technologies. Charge transfer and charge transport are pivotal processes in DSSCs, which govern solar energy capture and conversion. The...Dye-sensitized solar cells(DSSCs) are one of the most promising renewable energy technologies. Charge transfer and charge transport are pivotal processes in DSSCs, which govern solar energy capture and conversion. These processes can be probed using modern electronic structure methods. Because of the heterogeneity and complexity of the local environment of a chromophore in DSSCs(such as solvatochromism and chromophore aggregation), a part of the solvation environment should be treated explicitly during the calculation. However, because of the high computational cost and unfavorable scaling with the number of electrons of high-level quantum mechanical methods, approaches to explicitly treat the local environment need careful consideration. Two problems must be tackled to reduce computational cost. First, the number of configurations representing the solvent distribution should be limited as much as possible. Second, the size of the explicit region should be kept relatively small. The purpose of this study is to develop efficient computational approaches to select representative configurations and to limit the explicit solvent region to reduce the computational cost for later(higher-level) quantum mechanical calculations. For this purpose, an ensemble of solvent configurations around a 1-methyl-8-oxyquinolinium betaine(QB) dye molecule was generated using Monte Carlo simulations and molecular mechanics force fields. Then, a fitness function was developed using data from inexpensive electronic structure calculations to reduce the number of configurations. Specific solvent molecules were also selected for explicit treatment based on a distance criterion, and those not selected were treated as background charges. The configurations and solvent molecules selected proved to be good representatives of the entire ensemble; thus, expensive electronic structure calculations need to be performed only on this subset of the system, which significantly reduces the computational cost.展开更多
Nine 5 (β substituted stylryl) salicyladehyde derivatives were prepared by PTC Witting reactions in the paper . The stereochemistry of the Witting reactions and the substituted effect on the UV spectra of salicylad...Nine 5 (β substituted stylryl) salicyladehyde derivatives were prepared by PTC Witting reactions in the paper . The stereochemistry of the Witting reactions and the substituted effect on the UV spectra of salicyladehyde derivaties have been reported . It was observed that the spectra undergo a red shift as the conjugative effect of substituted becomes stronger . A good linear relationship between the shift of UV of p substituted compounds and conjugation effect was obtained.It showed that the Hammett equation may be applied to the UV frequencies of the title compounds.展开更多
The Fourier Transform Infrared(FTIR)and Fourier transform Raman(FT-Raman)spectra of 1,3-Diphenyl Propenone were recorded in the regions 4000~400 and 4000~100 cm^-1,respectively,in the solid phase.Molecular electronic ...The Fourier Transform Infrared(FTIR)and Fourier transform Raman(FT-Raman)spectra of 1,3-Diphenyl Propenone were recorded in the regions 4000~400 and 4000~100 cm^-1,respectively,in the solid phase.Molecular electronic energy,geometrical structure,harmonic vibrational spectra was computed at the DFT/6-31G(d,p)and three parameter hybrid functional Lee-Yang-Parr/6-31G(d,p)levels of theory.The vibrational studies were interpreted in terms of potential energy distribution(PED).The results were compared with experimental values with the help of scaling procedures.Most of the modes have wave numbers in the expected range and are in good agreement with computed values and also the molecular properties of Mulliken population analysis have been calculated.Besides,thermodynamic properties were performed.展开更多
The second-order small slope approximation （SSA2） method is introduced to study the Doppler characteristics from time-evolving sea surfaces. Simulation results show better agreement between the SSA2 model and the nu...The second-order small slope approximation （SSA2） method is introduced to study the Doppler characteristics from time-evolving sea surfaces. Simulation results show better agreement between the SSA2 model and the numerical method for both vertical and horizontal polarizations, meaning that SSA2 gives a satisfactory prediction of the spectral difference between two po- larizations; while such discrepancy cannot be captured using the lowest-order SSA （SSA1） model. In particular, the Doppler shifts and spectral widths for different incident angles, wind directions and polarizations are analyzed, demonstrating correct variations with respect to such parameters. Those observations prove that the SSA2 provides an efficient and relatively fast tool for sea surface Doppler spectral analysis.展开更多
Based upon our previous work [Commun. Theor. Phys.. 40,702 (2003)], we developed the closed orbit theory from two degrees of freedom to three non-separable degrees of freedom and calculated the recurrence spectra of L...Based upon our previous work [Commun. Theor. Phys.. 40,702 (2003)], we developed the closed orbit theory from two degrees of freedom to three non-separable degrees of freedom and calculated the recurrence spectra of Li Rydberg atom in strong perpendicular electric and magnetic fields. The Fourier transformed spectra of Li atom has allowed direct comparison between the resonance peaks and the scaled action values of closed orbits, whereas the nonhydrogenic resonance can be explained in terms of the new orbits created by the core scattering. The semiclassical result is in good agreement with the quantum one, which suggests that our calculation is correct.展开更多
For atmospheric pressure plasma jets(APPJ),the gas temperature is essential for their applications.A spectral diagnosis of APPJ’s gas temperature is conducted in this work.The optical emission spectra of helium APPJ ...For atmospheric pressure plasma jets(APPJ),the gas temperature is essential for their applications.A spectral diagnosis of APPJ’s gas temperature is conducted in this work.The optical emission spectra of helium APPJ are captured by using an optical spectrometer system.Then,the grating secondary spectrum of OH(A2∑+(ν=0)→X2П(ν=0))are used to diagnose the gas temperature of plasmas because the spectrum has excellent resolution.Meanwhile,the vibrational temperatures are estimated by using the vibration sequence of N2band(SPS,the second positive system).On the basis of the method,some important conclusions were obtained.First,the spectral identifying indicates that the grating primary spectrum covers a whole wavelength range from 200 nm to 900 nm,and that the grating secondary spectrum overlaps with the primary spectrum from 400 nm to 900 nm.Second,the gas temperature(about 320 K)is close to the room temperature,while the vibrational temperature of the N2(SPS)is about 5 000 K.The trend of the two temperatures changing with the applied voltage is discussed in the end.展开更多
Development of a prototype of a portable optical sensing system is presented for fast detecting of samples’fluorescence spectra.A compact configuration is achieved by integrating a small spectrometer,a microcontrolle...Development of a prototype of a portable optical sensing system is presented for fast detecting of samples’fluorescence spectra.A compact configuration is achieved by integrating a small spectrometer,a microcontroller,a Universal Serial Bus(USB)Host Shield,a network module,and a web server.The fluorescence spectra of a tested sample can be obtained.Then the test data are sent through network communication to our Cloud Server which can store the data for further analyses.With this configuration,test results can be revealed in a short time and downloaded by users to their laptops,tablets or cellphones anytime and anywhere.展开更多
AIM: To provide a basis for nuclear magnetic resonance (NMR) characterization of polypeptide compounds. METHODS: The 1 H, 13 C NMR and 2D NMR spectra were used to characterize Thymopentin. By using infrared(IR), ultra...AIM: To provide a basis for nuclear magnetic resonance (NMR) characterization of polypeptide compounds. METHODS: The 1 H, 13 C NMR and 2D NMR spectra were used to characterize Thymopentin. By using infrared(IR), ultraviolet(UV), mass spectrometry(MS) techniques, along with 1 H-1 H correlation spectrometry (COSY) and distorsionless enhancement by polarization transfer (DEPT), the proton and carbon-13 spectra were assigned completely. RESULTS: The Thymopentin was characterized based on the methods described above. CONCLUSION: The target molecule is confirmed and the structure is identified.展开更多
基金National Natural Science Foundation of China(62272360)。
文摘Five-valued Boolean functions play an important role in the design of symmetric cryptography.While the design and properties of single-output almost optimal five-valued spectra Boolean functions have been extensively studied over the past few decades,there has been limited research on the construction of almost optimal five-valued spectra vectorial Boolean functions.In this paper,we present a construction method for even-variable 2-output almost optimal five-valued spectra balanced Boolean functions,whose Walsh spectra values belong to the set{0,±2^(n/2),±2^(n/2+1)},at the same time,we discuss the existence of sufficient conditions in the construction.Additionally,this paper presents a novel construction method for balanced single-output Boolean functions with even variables featuring a special five-valued spectral structure,whose Walsh spectra values are constrained to the set{0,±2^(n/2),±3·2^(n/2)}.These functions provide new canonical examples for the study of Boolean function spectral theory.
基金Project(HNTY2022K03)supported by the Hunan Tieyuan Civil Engineering Testing Co.,Ltd.,ChinaProject(52478573)supported by the National Natural Science Foundation of China。
文摘The seismic damage to ancillary facilities on high-speed railway(HSR)bridges can affect the normal movement of trains.To propose the bridge deck acceleration response spectra of the typical HSR simply-supported girder bridge for simplifying the seismic responses analysis of the facilities on bridges,the finite element models of the HSR multi-span simply-supported girder bridges with CRTSII track were established,and the numerical model was validated by tests.Besides,the effects of the span number,peak ground acceleration(PGA),pier height on the seismic acceleration and response spectra of the bridge deck were investigated.Afterward,the bridge acceleration amplification factor curves and bridge deck response spectra with different PGAs and pier heights were obtained.The formula for bridge deck acceleration amplification factor,with a 95%guarantee rate,was fitted.Moreover,the finite element models of the overhead contact lines(OCL)mounted on rigid base and bridges were established to validate the fitted formula.The results indicated that the maximum seismic acceleration response is in the midspan of the beam.The proposed formula for the bridge deck acceleration response spectra can be used to analyze the earthquake response of the OCL and other ancillary facilities on HSR simply-supported girder bridges.The bridge deck acceleration response spectra are conservative in terms of structural safety and can significantly improving the analysis efficiency.
基金Project(11JJ5010) supported by the Natural Science Foundation of Hunan Province, ChinaProject(2011RS4069) supported by the Planned Science and Technology Program of Hunan Province, ChinaProject supported by the Postdoctoral Science Foundation of Central South University,China
文摘The photo absorbing, photo transmitting and photoluminescence performances of WiO2 photocatalysts compounded with V2O5 or WO3 were investigated by UV-Vis spectra, transmitting spectra, and PL spectra, respectively. The energy band structures of TiO2 photocatalysts were analyzed. The photocatalytic activities of the TiO2 photocatalysts were investigated by splitting of water for 02 evolution. The results indicate that the band gaps of WO3 and V205 are about 2.8 and 2.14 eV, respectively, and the band gap of rutile TiO2 is about 3.08 eV. Speeds of water splitting for 2%WO3-TiO2 and 8%V2O5-TiO2 photocatalysts are 420 and 110 μmol/（L.h）, respectively, under UV light irradiation. V2O5 and WO3 compounded with suitable concentration can improve the photocatalytic activity of TiO2 with Fe3＋ as electron acceptor.
文摘Vanadium pentoxide xerogel films used for lithium rechargeable batteries were prepared from crystalline c-V2O5 by melt quenching method,then the electrochemical process of lithium intercalation into vanadium pentoxide xerogel films was simulated with an equivalent circuit model, which was derived from the mechanism of electrode reactions. Measured electrochemical impedance spectra at various electrode potentials were analyzed by using the complex non-linear least-squares fitting method. The results show that impedance spectra consist of 2 high-to- medium frequency depressed arcs and a low frequency straight line. The high frequency arc is attributed to the absorption reaction of lithium ions into the oxide film, the medium frequency arc is attributed to the charge transfer reaction at the vanadium oxide/electrolyte interface and the low frequency is characterized by a straight line with a phase angle of 45° corresponding to the diffusion of lithium ion through vanadium oxide phase. The experimental and calculated results are compared and discussed focusing on the electrochemical performance and the state of charge of the electrode. Moreover, the high consistence of the fitted values of the model to the experimental data indicates that this mathematical model does give a satisfying description of the intercalation process of vanadium pentoxide xerogel films.
文摘Aim of the study is to evaluate the environmental impact of geothermic activities by the use of in site spectral analyses of different environmental com- ponents.These activities can cause the heavy metal （Hg,Sb,S,B,As,H<sub>2</sub>S）drifting from power plants to around areas.Different analytical techniques
文摘The doping reaction of polyaniline with camphor sulfonic acid (CSAH) in different organic solvents was studied by UV Vis spectroscopy. The experimental results show that the polaron band of the species was shifted to shorter wavelength when polyaniline was doped with CSAH in N methyl 2 pyrrolidione (NMP) solvent, while the red shift of polaron band was observed when it was in N, N dimethylformamide (DMF). It indicates that the influence of different processing solvents on the doping property of polyaniline is greatly different. N methyl 2 pyrrolidione is a good solvent for polyaniline, polyaniline chain is unfolded in it. The interaction of NMP with CSAH is so strong that the resulting product is apt to dedoping, while the solubility of polyaniline in DMF is relatively low and polyaniline chain is in partly folded state. Thus the doping reaction is kinetically disadvantageous but thermodynamically advantageous.
基金This material is based upon work supported by the U.S.Department of Energy,Office of Science,Office of Advanced Scientific Computing Research,Scientific Discovery through Advanced Computing(SciDAC)program,under Award No.DE-SC0008666.
文摘Dye-sensitized solar cells(DSSCs) are one of the most promising renewable energy technologies. Charge transfer and charge transport are pivotal processes in DSSCs, which govern solar energy capture and conversion. These processes can be probed using modern electronic structure methods. Because of the heterogeneity and complexity of the local environment of a chromophore in DSSCs(such as solvatochromism and chromophore aggregation), a part of the solvation environment should be treated explicitly during the calculation. However, because of the high computational cost and unfavorable scaling with the number of electrons of high-level quantum mechanical methods, approaches to explicitly treat the local environment need careful consideration. Two problems must be tackled to reduce computational cost. First, the number of configurations representing the solvent distribution should be limited as much as possible. Second, the size of the explicit region should be kept relatively small. The purpose of this study is to develop efficient computational approaches to select representative configurations and to limit the explicit solvent region to reduce the computational cost for later(higher-level) quantum mechanical calculations. For this purpose, an ensemble of solvent configurations around a 1-methyl-8-oxyquinolinium betaine(QB) dye molecule was generated using Monte Carlo simulations and molecular mechanics force fields. Then, a fitness function was developed using data from inexpensive electronic structure calculations to reduce the number of configurations. Specific solvent molecules were also selected for explicit treatment based on a distance criterion, and those not selected were treated as background charges. The configurations and solvent molecules selected proved to be good representatives of the entire ensemble; thus, expensive electronic structure calculations need to be performed only on this subset of the system, which significantly reduces the computational cost.
文摘Nine 5 (β substituted stylryl) salicyladehyde derivatives were prepared by PTC Witting reactions in the paper . The stereochemistry of the Witting reactions and the substituted effect on the UV spectra of salicyladehyde derivaties have been reported . It was observed that the spectra undergo a red shift as the conjugative effect of substituted becomes stronger . A good linear relationship between the shift of UV of p substituted compounds and conjugation effect was obtained.It showed that the Hammett equation may be applied to the UV frequencies of the title compounds.
文摘The Fourier Transform Infrared(FTIR)and Fourier transform Raman(FT-Raman)spectra of 1,3-Diphenyl Propenone were recorded in the regions 4000~400 and 4000~100 cm^-1,respectively,in the solid phase.Molecular electronic energy,geometrical structure,harmonic vibrational spectra was computed at the DFT/6-31G(d,p)and three parameter hybrid functional Lee-Yang-Parr/6-31G(d,p)levels of theory.The vibrational studies were interpreted in terms of potential energy distribution(PED).The results were compared with experimental values with the help of scaling procedures.Most of the modes have wave numbers in the expected range and are in good agreement with computed values and also the molecular properties of Mulliken population analysis have been calculated.Besides,thermodynamic properties were performed.
基金supported by the National Natural Science Foundation of China (40771133)
文摘The second-order small slope approximation （SSA2） method is introduced to study the Doppler characteristics from time-evolving sea surfaces. Simulation results show better agreement between the SSA2 model and the numerical method for both vertical and horizontal polarizations, meaning that SSA2 gives a satisfactory prediction of the spectral difference between two po- larizations; while such discrepancy cannot be captured using the lowest-order SSA （SSA1） model. In particular, the Doppler shifts and spectral widths for different incident angles, wind directions and polarizations are analyzed, demonstrating correct variations with respect to such parameters. Those observations prove that the SSA2 provides an efficient and relatively fast tool for sea surface Doppler spectral analysis.
文摘Based upon our previous work [Commun. Theor. Phys.. 40,702 (2003)], we developed the closed orbit theory from two degrees of freedom to three non-separable degrees of freedom and calculated the recurrence spectra of Li Rydberg atom in strong perpendicular electric and magnetic fields. The Fourier transformed spectra of Li atom has allowed direct comparison between the resonance peaks and the scaled action values of closed orbits, whereas the nonhydrogenic resonance can be explained in terms of the new orbits created by the core scattering. The semiclassical result is in good agreement with the quantum one, which suggests that our calculation is correct.
基金Project supported by China National Fund for Distinguished Young Scientists （51125029）, China Foundation for the Author of National Excellent Doctoral Dissertation （200338）, Intersection Subject Program of Xi＇an Jiaotong University （xjj2012132）, Fundamental Research Fund for the Central Universities （xjj2010160）, China National Science Foundation for Young Scientists （51307133）.
文摘For atmospheric pressure plasma jets(APPJ),the gas temperature is essential for their applications.A spectral diagnosis of APPJ’s gas temperature is conducted in this work.The optical emission spectra of helium APPJ are captured by using an optical spectrometer system.Then,the grating secondary spectrum of OH(A2∑+(ν=0)→X2П(ν=0))are used to diagnose the gas temperature of plasmas because the spectrum has excellent resolution.Meanwhile,the vibrational temperatures are estimated by using the vibration sequence of N2band(SPS,the second positive system).On the basis of the method,some important conclusions were obtained.First,the spectral identifying indicates that the grating primary spectrum covers a whole wavelength range from 200 nm to 900 nm,and that the grating secondary spectrum overlaps with the primary spectrum from 400 nm to 900 nm.Second,the gas temperature(about 320 K)is close to the room temperature,while the vibrational temperature of the N2(SPS)is about 5 000 K.The trend of the two temperatures changing with the applied voltage is discussed in the end.
基金supported by the National Key Development Program (2016YFB1102704)Natural Science Foundation of Liaoning Province (2015020115)+1 种基金National Natural Science Foundation of China (U1609209)National Science Fund for Distinguished Youth Scholars (51625504)
文摘Development of a prototype of a portable optical sensing system is presented for fast detecting of samples’fluorescence spectra.A compact configuration is achieved by integrating a small spectrometer,a microcontroller,a Universal Serial Bus(USB)Host Shield,a network module,and a web server.The fluorescence spectra of a tested sample can be obtained.Then the test data are sent through network communication to our Cloud Server which can store the data for further analyses.With this configuration,test results can be revealed in a short time and downloaded by users to their laptops,tablets or cellphones anytime and anywhere.
基金This research is supported by the Natural Science Foundation of Inner Mongolia （200607010912）.
文摘AIM: To provide a basis for nuclear magnetic resonance (NMR) characterization of polypeptide compounds. METHODS: The 1 H, 13 C NMR and 2D NMR spectra were used to characterize Thymopentin. By using infrared(IR), ultraviolet(UV), mass spectrometry(MS) techniques, along with 1 H-1 H correlation spectrometry (COSY) and distorsionless enhancement by polarization transfer (DEPT), the proton and carbon-13 spectra were assigned completely. RESULTS: The Thymopentin was characterized based on the methods described above. CONCLUSION: The target molecule is confirmed and the structure is identified.
