Three efficient methods for the synthesis of a series of Cu(Ⅱ) and Cu(Ⅰ) complexes based on imidazo[1,5-a]pyridine derivatives were developed.These methods include the following:(ⅰ)Cu(Ⅱ) salts were used as metal s...Three efficient methods for the synthesis of a series of Cu(Ⅱ) and Cu(Ⅰ) complexes based on imidazo[1,5-a]pyridine derivatives were developed.These methods include the following:(ⅰ)Cu(Ⅱ) salts were used as metal sources and N,N-dimethylformamide was employed as a solvent as well as a reductant to produce Cu(Ⅰ) complexes.(ⅱ) An iodide-containing compound was utilized as a ligand and iodide source to prepare complexes.An in situ metalligand reaction occurred and an iodide-bridged copper complex was generated.(ⅲ) A series of aldehydes were added to the reaction systems to induce in situ metal-ligand reactions between the aldehydes and the imidazo[1,5-a]pyridine derivatives,producing polydentate ligand scaffolds.Eight complexes were prepared and characterized.The catalytic activities of these complexes toward the ketalization of ketones by ethylene glycol were investigated.With the exception of complex4,the remaining seven complexes all showed high catalytic activity.The lower activity of 4 may be due to the larger radius of bridging iodide ions and the shorter Cu(Ⅰ)…Cu(Ⅰ) distance.CCDC:2357696,1·2CH_(2)Cl_(2);2357697,2;2018292,3;2092192,4;2092190,5;2155557,6;2406155,7;2406156,8·EtOH.展开更多
In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole st...In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole stress gauge was adopted to measure the mining-induced stress. In the in situ stress measuring, the technique of improved hollow inclusion cells was adopted, which can realize complete temperature compensation. Based on the measuring results, the distribution model of in situ stress was established and analyzed. The in situ stress measuring result shows that the maximum horizontal stress is 1.75-2.45 times of vertical stress and almost 1.83 times of the minimum horizontal stress in this mineral field. And the mining-induced stress measuring result shows that, according to the magnitude of front abutment pressure the stress region can be separated into stress-relaxed area, stress- concentrated area and initial stress area. At the -50 m mining level of this mine, the range of stress-relaxed area is 0-3 m before mining face; the range of stress-concentrated area is 3-55 m before mining face, and the maximum mining-induced stress is 16.5-17.5 MPa, which is 15-20 m from the mining face. The coefficient of stress concentration is 1.85.展开更多
Controlled release NPK compound fertilizers were prepared by means of in situ polymerization of monomers on the surface of fertilizer granules at room temperature. Methacrylate, α-methyl acrylic acid, and ethylene di...Controlled release NPK compound fertilizers were prepared by means of in situ polymerization of monomers on the surface of fertilizer granules at room temperature. Methacrylate, α-methyl acrylic acid, and ethylene dimethylacrylate were used as monomers, Dibenzoyl peroxide as initiator, and cobalt naphthenate, and triethyl amine as promoters. The structures of coating materials were characterized by IR spectra. The thermogravimetric analysis result indicated that the coating materials were of good thermal stability. The mean thickness of single coating measured with screw gauge was ca. 140 μm. The morphologies of uncoated and coated fertilizer granules analyzed by using scanning electron microscopy were changed from porosities and gullies to hills and plain. The release rate of coated compound fertilizers in water could be controlled by the hydrophicity and thickness of coating. The increase in coating hydrophicity caused the increase in release rate of fertilizer. The increase in thickness of coating slowed the release rate.展开更多
Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes o...Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes on this basis.In situ oxidation conditions experimental results show that the best condition for preparing the TiO2-Al2O3/Ti composite membrane is under 800°C for 2 h,and the microstructure and pore sizes of the TiO2-Al2O3/Ti composite membranes are affected obviously.The thickness and composition of the TiO2/Ti composite membranes are determined by SEM and XRD completely.The pore size distribution of the composite membrane is measured by bubble pressure method,the most probable aperture is about 3.12μm,while the average pore size of defect free TiO2-Al2O3/Ti is about 3.23μm.After ultrasonic treatment,the slight weight change of membranes reveals no observable change,which indicates that TiO2-Al2O3/Ti composite membranes maintain a good stability.展开更多
To study the stereostructure by X-ray and the technology of extracting acankoreanogenin from the leaves of Acanthopanax graeilistylus W. W. Smith （AGS）, the crystal structure was measured with a Bruker APEX-Ⅱ area-...To study the stereostructure by X-ray and the technology of extracting acankoreanogenin from the leaves of Acanthopanax graeilistylus W. W. Smith （AGS）, the crystal structure was measured with a Bruker APEX-Ⅱ area-detector diffractometer instrument and the technology of extracting in combination hydrolysis in situ （ECHS） was compared with these of traditional methods. The crystal belongs to the monoclinic system, space group P2b with unit cell parameters： a=（8.3652±0.0006） nm, b=（24.721±0.002） nm, and c=（14.5587±0.0011） nm, α=90°, β=97.850 （4） °, γ=90 °, V=2982.51 nm3, Dc= 1.179 mg/m3, and the molecular number （Z） of elementary structures was 2. The comparisons show that the extraction rate of acankoreanogenin with ECHS methods is much higher than that of traditional methods. Then, central composite design-response surface methodology （CCD-RSM） was adopted for optimizing the extraction rate of ECHS methods. The optimized values of extraction parameters are as follows： for the for extraction process of acid hydrolysis are that extraction time 110.8 min, solvent-herb ratio 11.5 and acid content 5.25%; the best extraction process of basic hydrolysis are that extract time 120 min, solvent-herb ratio 8.7 and the alkali content 8.79%. Finally, the extracts were purified with decolorizing carbon after alkali solution and acid-isolation and purity of acankoreanogenin was 98.7%.展开更多
The Qingshankou Formation shale oil in the Gulong Sag is an important oil and gas reservoir in the Daqing oilfield,with geological resources of 15.1 billion tons.The fabric of shale can reflect not only its genesis bu...The Qingshankou Formation shale oil in the Gulong Sag is an important oil and gas reservoir in the Daqing oilfield,with geological resources of 15.1 billion tons.The fabric of shale can reflect not only its genesis but also the nature of the reservoir space,its physical properties,oil content,and development value.Here,the characteristics of clay minerals in the Gulong shale oil reservoir were studied via electron microscopy,with the primary focus on the microfabrics and reservoir space;thereafter,the in situ accumulation was studied and discussed.Electron backscattering patterns revealed that nanometer pores and fissures were well developed in the Gulong shale oil reservoir.The nano pores were mostly 20-50 nm in diameter(median 20-30 nm),irregularly shaped,mostly,polygonal,and connected with nanofissures.The widths of nanofissures ranged mostly between 10-50 nm(median 20-30 nm);moreover,these fissures were mainly formed by F-F condensation of clay sheets(clay domains).The coagulation of clays was closely related to organic matter,especially algae.The clay colloids were negatively charged due to isocrystalline replacement;hence,metal cations were absorbed around the clay,forming a positive clay group.The positively charged clays subsequently adsorbed negatively charged humic acid(organic matter)and initially degraded algae to form an organic clay flocculant.When the organic clay flocculates reached the threshold for hydrocarbon generation and expulsion,the volume of organic matter decreased by 87%;thereafter,the generated and expelled hydrocarbon filled the nearby pores formed by this contraction.Moreover,the discharged hydrocarbon could not migrate due to capillary resistance(~12 MPa)of the nanopores;hence,the nanopores formed a unique continuous in situ reservoir within the Gulong shale oil.This study demonstrated that the Gulong shale oil reservoir is an actual clay-type shale reservoir with numerous nanopore and fissures.During coagulation,a large amount of organic matter(including layered algae)was absorbed by the clay,forming an organic clay condensate that could have provided the material foundation for hydrocarbon generation at a later stage.Thermal simulation experiments revealed that the volume of organic matter decreased sharply after hydrocarbon generation and expulsion.展开更多
The technical feasibility of in situ upgrading technology to develop the enormous oil and gas resource potential in low-maturity shale is widely acknowledged.However,because of the large quantities of energy required ...The technical feasibility of in situ upgrading technology to develop the enormous oil and gas resource potential in low-maturity shale is widely acknowledged.However,because of the large quantities of energy required to heat shale,its economic feasibility is still a matter of debate and has yet to be convincingly demonstrated quantitatively.Based on the energy conservation law,the energy acquisition of oil and gas generation and the energy consumption of organic matter cracking,shale heat-absorption,and surrounding rock heat dissipation during in situ heating were evaluated in this study.The energy consumption ratios for different conditions were determined,and the factors that influence them were analyzed.The results show that the energy consumption ratio increases rapidly with increasing total organic carbon(TOC)content.For oil-prone shales,the TOC content corresponding to an energy consumption ratio of 3 is approximately 4.2%.This indicates that shale with a high TOC content can be expected to reduce the project cost through large-scale operation,making the energy consumption ratio after consideration of the project cost greater than 1.In situ heating and upgrading technology can achieve economic benefits.The main methods for improving the economic feasibility by analyzing factors that influence the energy consumption ratio include the following:(1)exploring technologies that efficiently heat shale but reduce the heat dissipation of surrounding rocks,(2)exploring technologies for efficient transformation of organic matter into oil and gas,i.e.,exploring technologies with catalytic effects,or the capability to reduce in situ heating time,and(3)establishing a horizontal well deployment technology that comprehensively considers the energy consumption ratio,time cost,and engineering cost.展开更多
Superconducting thin films of YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7-x</sub>（Y-Ba-Cu-O） with Tc more than 85K have been deposited in situ by metalorganic chemical vapor deposition ...Superconducting thin films of YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7-x</sub>（Y-Ba-Cu-O） with Tc more than 85K have been deposited in situ by metalorganic chemical vapor deposition （MOCVD） on yttria stabilized zirconia（YSZ） substrates. The relationship of film orientation on substrate temperature and the lowest formation temperature region of superconducting phase have been obtained after changing the substrate temperature. The epitaxial relation between Y-Ba-Cu-O films and the YSZ su bstrates were discussed.展开更多
Two main types of in situ grain harvesttng machine are introduced. The comparison of their working principles and advantages are given. The limitations and prospects for stripper header are discussed.
Objective To compare the efficacy of toric implantable collamer lens(Toric-ICL)and femtosecond laser-assisted in situ keratomileusis(FS-LASIK)for myopia correction in patients with moderate to high myopia complicated ...Objective To compare the efficacy of toric implantable collamer lens(Toric-ICL)and femtosecond laser-assisted in situ keratomileusis(FS-LASIK)for myopia correction in patients with moderate to high myopia complicated with astigmatism.Methods We retrospectively collected data from 64 patients(aged 18-42 years)with moderate to high myopia complicated with astigmatism(128 eyes)undergoing either Toric-ICL(28 patients/56 eyes)or FS-LASIK(36 patients/72 eyes)at our department between January,2019 and December,2020.The changes of uncorrected distance visual acuity(UCVA),spherical equivalent(SE),mean astigmatism correction index(CI),corneal endothelial cell density(ECD)and intraocular pressure(IOP)following the procedures were compared between the two groups.Results In FS-LASIK group,all the eyes(72/72)achieved an UCVA≥1.0,similar to the rate in Toric-ICL group(55/56 eyes;P=0.2374).The postoperative SE was also comparable between FS-LASIK and Toric-ICL groups[0.43±0.06 D(range:-1.0 to 1.50 D)vs 0.38±0.05 D(range:-0.75 to 1.00 D);P=0.56].The mean astigmatism CI was significantly higher in FS-LASIK group than in Toric-ICL group(0.8561 vs 0.7176;P<0.0001),and 88.89%of the eyes in FS-LASIK group and 69.64%in Toric-ICL group had postoperative astigmatism≤0.50 D.No significant changes were observed in postoperative corneal ECD in FS-LASIK group,whereas ECD decreased significantly after the procedure in Toric-ICL group(P=0.0057).The patients undergoing Toric-ICL exhibited no significant changes of postoperative IOP,but the patients receiving FS-LASIK had significantly reduced IOP after the procedure(P<0.001).Conclusion Although the patients included in Toric-ICL group had higher myopia and astigmatism,Toric-ICL still showed better predictability and efficacy for astigmatic correction in Toric-ICL group.Toric-ICL is an effective and safe equivalent of FS-LASIK for correcting moderate myopia but can be more advantageous for correcting high myopia with astigmatism.展开更多
As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation ...As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation and fragmentation.This ultimately leads to a decrease in cell capacity.The trends of volume expansion and capacity change of the SiO/graphite(SiO/C)composite electrode during cycling were investigated via in situ expansion monitoring.First,a series of expansion test schemes were designed,and the linear relationship between negative electrode expansion and cell capacity degradation was quantitatively analyzed.Then,the effects of different initial pressures on the long-term cycling performance of the cell were evaluated.Finally,the mechanism of their effects was analyzed by scanning electron microscope.The results show that after 50 cycles,the cell capacity decreases from 2.556 mAh to 1.689 mAh,with a capacity retention ratio(CRR)of only 66.08%.A linear relationship between the capacity retention ratio and thickness expansion was found.Electrochemical measurements and scanning electron microscope images demonstrate that intense stress inhibits the lithiation of the negative electrode and that the electrode is more susceptible to irreversible damage during cycling.Overall,these results reveal the relationship between the cycling performance of SiO and the internal pressure of the electrode from a macroscopic point of view,which provides some reference for the application of SiO/C composite electrodes in lithium-ion batteries.展开更多
An experimental study and theoretical analysis were carried out to explore the ground-borne vibration generated by elevated high-speed railway in rock strata.Taking a typical rail line constructed on rock area in Chin...An experimental study and theoretical analysis were carried out to explore the ground-borne vibration generated by elevated high-speed railway in rock strata.Taking a typical rail line constructed on rock area in China as the research object,a set of field tests was performed on Rizhao-Lankao High-Speed Railway,the bridge and ground vibrations were measured as trains passed at 330−340 km/h,then the transferring law and spatial distribution under individual frequencies were investigated.The experiment results indicate that the bridge frequency spectrum exhibited relatively high-frequency vibration peaks caused by short-wavelength irregularity;ground vibration farther than 30 m away can be amplified with a higher frequency and numerous components.Furthermore,the wave propagation equation of a stratified rock strata was established based on direct-stiffness method to explore the vibration attenuation rules via frequency-domain analysis.It is found that the rock area has a weaker correlation between vibration transmissibility and frequency,thicker and harder rock strata loss their vibration attenuation capacity.It can be concluded that the high-speed railways induced vibration on rock strata shows a wide frequency band and large amplitude,the design of reducing vibration aimed at specific frequency is important according to next more detailed numerical study.展开更多
To study the influence of B4C particle size on the microstructure and damping capacities of(B_(4)C+Ti)/Mg composites,in situ reactive infiltration technique was utilized to prepare Mg-matrix composites.The microstruct...To study the influence of B4C particle size on the microstructure and damping capacities of(B_(4)C+Ti)/Mg composites,in situ reactive infiltration technique was utilized to prepare Mg-matrix composites.The microstructure,produced phases and damping capacities of the composites prepared with different particle size of B4C were characterized and analyzed.The results show that the reaction between B4C and Ti tends to be more complete when finer B_(4)C particle was used to prepare the composites.But the microstructure of the as-prepared composites is more homogenous when B4C and Ti have similar particle size.The strain-dependent damping capacities of(B_(4)C+Ti)/Mg composites improve gradually with the increase of strain amplitude,and composites prepared with coarser B4C particles tend to have higher damping capacities.The temperature-dependent damping capacities improve with increasing the measuring temperatures,and the kind of damping capacities of the composites prepared with 5mm B4C are inferior to those of coarser particles.The dominant damping mechanism for the strain-damping capacity is dislocation damping and plastic zone damping,while that for the temperature-damping capacity is interface damping or grain boundary damping.展开更多
Transformation-induced plasticity(TRIP)steel possesses high strength and formability,enabling the use of a thinner gauge material and allowing for the fabrication of complex shapes.In this research,we measured the eff...Transformation-induced plasticity(TRIP)steel possesses high strength and formability,enabling the use of a thinner gauge material and allowing for the fabrication of complex shapes.In this research,we measured the effect of bending temperatures on the microstructure and air-bending springback angle of TRIP steel at temperatures from 25 to 600C.Real-time in situ X-ray diffraction and scanning electron microscopy were used for pre-and postbending analysis.As the prebending temperature increased from 25C to 600C,the retained austenite(RA)volume fraction decreased,and the RA transformed to bainite at temperatures above 400C.The springback angle was positively correlated with the prebending RA volume fraction,with the smallest springback angle achieved at 400C.Additionally,the springback angle was positively correlated with the bending angle,because the RA transformation ratio contributed to increased strain hardening.Further microstructure analysis revealed that the RA became elongated in the tension direction as the bending temperatures increased.展开更多
The effects of adding alloy element zinc on the static and dynamic mechanical properties of copper-zinc alloy were investigated. Tensile and low cycle fatigue behaviors of the C11000 copper and H63 copper-zinc alloy w...The effects of adding alloy element zinc on the static and dynamic mechanical properties of copper-zinc alloy were investigated. Tensile and low cycle fatigue behaviors of the C11000 copper and H63 copper-zinc alloy were obtained by using a miniature tester that combined the functions of in situ tensile and fatigue testing. A piezoelectric actuator was adopted as the actuator for the fatigue testing, and the feasibility of the fatigue actuator was verified by the transient harmonic response analysis based on static tensile preload and dynamic sinusoidal load. The experimental results show that the yield strength and tensile strength of the C11000 copper are improved after adding 37%(mass fraction) zinc, and H63 copper-zinc alloy presents more obvious cyclic hardening behavior and more consumed irreversible plastic work during each stress cycle compared with C11000 copper for the same strain controlled cycling. Additionally, based on the Manson-Coffin theory, the strain-life equations of the two materials were also obtained. C11000 copper and H63 copper-zinc alloy show transition life of 16832 and 1788 cycles, respectively.展开更多
Two different kinds of experimental techniques were used to in-situ study the austenite formation during intercritical annealing in C-Mn dual phase steel. The microstructure evolution was observed by confocal laser sc...Two different kinds of experimental techniques were used to in-situ study the austenite formation during intercritical annealing in C-Mn dual phase steel. The microstructure evolution was observed by confocal laser scanning microscope, and the austenite isothermal and non-isothermal transformation kinetics were studied by dilatometry. The results indicate that banded structure is produced for the reason of composition segregation and the competition between recrystallization and phase transformation. Austenite prefers to nucleate not only at ferrite/ferrite grain boundaries, but also inside the grains of ferrite.Furthermore, the austenitizing process is accomplished mainly via migration of the existing austenite/ferrite interface rather than nucleation of new grains. The incubation process can be divided into two stages which are controlled by carbon and manganese diffusion, respectively. During the incubation process, the nucleation rate of austenite decreases, and austenite growth changes from two-dimensional to one-dimensional. The partitioning coefficient, defined as the ratio of manganese content in the austenite to that in the adjacent ferrite, increases with increasing soaking time.展开更多
Gossypium mustelinum [(AD)4] is one of five tetraploid species in Gossypium.Three pairs of nucleolar organizer regions(NOR) in(AD)4 were detected by FISH with 45S rDNA as a probe,they also were observed with genomic D...Gossypium mustelinum [(AD)4] is one of five tetraploid species in Gossypium.Three pairs of nucleolar organizer regions(NOR) in(AD)4 were detected by FISH with 45S rDNA as a probe,they also were observed with genomic DNA(gDNA) from Gossypium D genome species as probes.Of展开更多
When the crystal grows from solution,a sharp variated fluid layer of the solute concentration exists against crystal surface.The sharp variated fluid layer is defined the boundary layer in crystal growth.The molecular...When the crystal grows from solution,a sharp variated fluid layer of the solute concentration exists against crystal surface.The sharp variated fluid layer is defined the boundary layer in crystal growth.The molecular structure of the boundary layers plays a key role in crystal composition,morphology,growth rate and crystal growth mechanism.However,owing to the lacking of suitable probe technique,it is difficult to obtain the information of the moving construction of the boundary layers.Here,the laser Raman Microprobe combining with holographic phase contrast interferometric microphotography is used to probe in situ the molecular structure of the boundary layers during the crystal growth processes of KH 2PO 4(KDP) and KD 2PO 4(DKDP).In supersaturations ranging from 1% to 14%,Raman scattering states at the different positions within the boundary layers have been investigated,and compared with the bands of different concentration solutions alone using laser Raman spectroscopy between 600 and 1350cm -1 .The changes in band parameters of the phosphates within the boundary layers of crystal growth are different from those in solution alone.The influence of the solution concentration on the band parameters of anion phosphate within the layers is nonlinear.With increasing supersaturation,the full width at half height of the P=O 2 symmetric stretch band increases.The new 918(938)cm -1 H(D)O P OH(D) asymmetric stretch,1120(DKDP 1200)cm -1 O P O asymmetric stretch,and extremely weak 1210cm -1 P O H in plane deformation bands appear in the characteristic boundary layers.These new bands show that the cations have direct effects on the phosphate group(aggregates).Under the driving of concentration gradient field of supersaturation,the effects of cations cause the changes of O P O bond angle,atomic charge redistribution,and lead to readjust geometry of anion phosphate group and desolvation.The trend of readjust is close to the geometry of the crystal structure unit and the formation of the cations phosphate crystallization unit.展开更多
The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension d...The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension driven convection (Marangoni Convection) become the main convection form.But the Marangoni convection forms,starting condition,development process and its influence on crystal growth are still unclear now.At the present time,Many studies focused on simulating liquid Marangoni convection or numerical simulation.However,few studies concerned on real melt,especially on oxide melt. In this paper,an in situ observation is carried out to study the start and development of Marangoni convection of Bi 12 SiO 20 melt in a 2mm diameter loop like platinum crucible.The different states of steady convection and the transition from steady to oscillatory convection are observed.The critical Marangoni number is obtained as 22433 and it agreed with a dependence Ma c=2884Pr 0.638 for high Prandtl number melt.The authors also obtained a dependence of convection oscillatory frequency on melt temperature.It increases with temperature rising.展开更多
文摘Three efficient methods for the synthesis of a series of Cu(Ⅱ) and Cu(Ⅰ) complexes based on imidazo[1,5-a]pyridine derivatives were developed.These methods include the following:(ⅰ)Cu(Ⅱ) salts were used as metal sources and N,N-dimethylformamide was employed as a solvent as well as a reductant to produce Cu(Ⅰ) complexes.(ⅱ) An iodide-containing compound was utilized as a ligand and iodide source to prepare complexes.An in situ metalligand reaction occurred and an iodide-bridged copper complex was generated.(ⅲ) A series of aldehydes were added to the reaction systems to induce in situ metal-ligand reactions between the aldehydes and the imidazo[1,5-a]pyridine derivatives,producing polydentate ligand scaffolds.Eight complexes were prepared and characterized.The catalytic activities of these complexes toward the ketalization of ketones by ethylene glycol were investigated.With the exception of complex4,the remaining seven complexes all showed high catalytic activity.The lower activity of 4 may be due to the larger radius of bridging iodide ions and the shorter Cu(Ⅰ)…Cu(Ⅰ) distance.CCDC:2357696,1·2CH_(2)Cl_(2);2357697,2;2018292,3;2092192,4;2092190,5;2155557,6;2406155,7;2406156,8·EtOH.
基金Projects(10702072, 10632100) supported by the National Nature Science Foundation of China
文摘In order to obtain the distribution rules of in situ stress and mining-induced stress of Beiminghe Iron Mine, the stress relief method by overcoring was used to measure the in situ stress, and the MC type bore-hole stress gauge was adopted to measure the mining-induced stress. In the in situ stress measuring, the technique of improved hollow inclusion cells was adopted, which can realize complete temperature compensation. Based on the measuring results, the distribution model of in situ stress was established and analyzed. The in situ stress measuring result shows that the maximum horizontal stress is 1.75-2.45 times of vertical stress and almost 1.83 times of the minimum horizontal stress in this mineral field. And the mining-induced stress measuring result shows that, according to the magnitude of front abutment pressure the stress region can be separated into stress-relaxed area, stress- concentrated area and initial stress area. At the -50 m mining level of this mine, the range of stress-relaxed area is 0-3 m before mining face; the range of stress-concentrated area is 3-55 m before mining face, and the maximum mining-induced stress is 16.5-17.5 MPa, which is 15-20 m from the mining face. The coefficient of stress concentration is 1.85.
基金Supported by Natural Science Foundation of China(30571086)
文摘Controlled release NPK compound fertilizers were prepared by means of in situ polymerization of monomers on the surface of fertilizer granules at room temperature. Methacrylate, α-methyl acrylic acid, and ethylene dimethylacrylate were used as monomers, Dibenzoyl peroxide as initiator, and cobalt naphthenate, and triethyl amine as promoters. The structures of coating materials were characterized by IR spectra. The thermogravimetric analysis result indicated that the coating materials were of good thermal stability. The mean thickness of single coating measured with screw gauge was ca. 140 μm. The morphologies of uncoated and coated fertilizer granules analyzed by using scanning electron microscopy were changed from porosities and gullies to hills and plain. The release rate of coated compound fertilizers in water could be controlled by the hydrophicity and thickness of coating. The increase in coating hydrophicity caused the increase in release rate of fertilizer. The increase in thickness of coating slowed the release rate.
基金Projects(212006065,21666018)supported by the National Natural Science Foundation of China
文摘Al2O3 ceramic powder was applied to modify the large pores defects on the surface of the porous metal Ti support,in situ oxidation method was a convenient method to prepare defect free ceramic/Ti composite membranes on this basis.In situ oxidation conditions experimental results show that the best condition for preparing the TiO2-Al2O3/Ti composite membrane is under 800°C for 2 h,and the microstructure and pore sizes of the TiO2-Al2O3/Ti composite membranes are affected obviously.The thickness and composition of the TiO2/Ti composite membranes are determined by SEM and XRD completely.The pore size distribution of the composite membrane is measured by bubble pressure method,the most probable aperture is about 3.12μm,while the average pore size of defect free TiO2-Al2O3/Ti is about 3.23μm.After ultrasonic treatment,the slight weight change of membranes reveals no observable change,which indicates that TiO2-Al2O3/Ti composite membranes maintain a good stability.
基金Project(11JJ2042)supported by the Natural Science Foundation of Hunan Province,ChinaProject supported by the "Twelfth Five-Year" Key Discipline of Hunan University of Chinese Medicine-Pharmaceutical Analysis Science,China+1 种基金Project(11K048)supported by the Innovation Platform and Open Foundation Program of Higher Colleges of Hunan Province,ChinaProject(K1207010-21)supported by the Changsha City Science and Technology Bureau Key Projects,China
文摘To study the stereostructure by X-ray and the technology of extracting acankoreanogenin from the leaves of Acanthopanax graeilistylus W. W. Smith （AGS）, the crystal structure was measured with a Bruker APEX-Ⅱ area-detector diffractometer instrument and the technology of extracting in combination hydrolysis in situ （ECHS） was compared with these of traditional methods. The crystal belongs to the monoclinic system, space group P2b with unit cell parameters： a=（8.3652±0.0006） nm, b=（24.721±0.002） nm, and c=（14.5587±0.0011） nm, α=90°, β=97.850 （4） °, γ=90 °, V=2982.51 nm3, Dc= 1.179 mg/m3, and the molecular number （Z） of elementary structures was 2. The comparisons show that the extraction rate of acankoreanogenin with ECHS methods is much higher than that of traditional methods. Then, central composite design-response surface methodology （CCD-RSM） was adopted for optimizing the extraction rate of ECHS methods. The optimized values of extraction parameters are as follows： for the for extraction process of acid hydrolysis are that extraction time 110.8 min, solvent-herb ratio 11.5 and acid content 5.25%; the best extraction process of basic hydrolysis are that extract time 120 min, solvent-herb ratio 8.7 and the alkali content 8.79%. Finally, the extracts were purified with decolorizing carbon after alkali solution and acid-isolation and purity of acankoreanogenin was 98.7%.
基金National Science and Technology Major project“Main controlling factors of large lithologic reservoir formation and favorable zone evaluation(2017ZX05001-002)”。
文摘The Qingshankou Formation shale oil in the Gulong Sag is an important oil and gas reservoir in the Daqing oilfield,with geological resources of 15.1 billion tons.The fabric of shale can reflect not only its genesis but also the nature of the reservoir space,its physical properties,oil content,and development value.Here,the characteristics of clay minerals in the Gulong shale oil reservoir were studied via electron microscopy,with the primary focus on the microfabrics and reservoir space;thereafter,the in situ accumulation was studied and discussed.Electron backscattering patterns revealed that nanometer pores and fissures were well developed in the Gulong shale oil reservoir.The nano pores were mostly 20-50 nm in diameter(median 20-30 nm),irregularly shaped,mostly,polygonal,and connected with nanofissures.The widths of nanofissures ranged mostly between 10-50 nm(median 20-30 nm);moreover,these fissures were mainly formed by F-F condensation of clay sheets(clay domains).The coagulation of clays was closely related to organic matter,especially algae.The clay colloids were negatively charged due to isocrystalline replacement;hence,metal cations were absorbed around the clay,forming a positive clay group.The positively charged clays subsequently adsorbed negatively charged humic acid(organic matter)and initially degraded algae to form an organic clay flocculant.When the organic clay flocculates reached the threshold for hydrocarbon generation and expulsion,the volume of organic matter decreased by 87%;thereafter,the generated and expelled hydrocarbon filled the nearby pores formed by this contraction.Moreover,the discharged hydrocarbon could not migrate due to capillary resistance(~12 MPa)of the nanopores;hence,the nanopores formed a unique continuous in situ reservoir within the Gulong shale oil.This study demonstrated that the Gulong shale oil reservoir is an actual clay-type shale reservoir with numerous nanopore and fissures.During coagulation,a large amount of organic matter(including layered algae)was absorbed by the clay,forming an organic clay condensate that could have provided the material foundation for hydrocarbon generation at a later stage.Thermal simulation experiments revealed that the volume of organic matter decreased sharply after hydrocarbon generation and expulsion.
文摘The technical feasibility of in situ upgrading technology to develop the enormous oil and gas resource potential in low-maturity shale is widely acknowledged.However,because of the large quantities of energy required to heat shale,its economic feasibility is still a matter of debate and has yet to be convincingly demonstrated quantitatively.Based on the energy conservation law,the energy acquisition of oil and gas generation and the energy consumption of organic matter cracking,shale heat-absorption,and surrounding rock heat dissipation during in situ heating were evaluated in this study.The energy consumption ratios for different conditions were determined,and the factors that influence them were analyzed.The results show that the energy consumption ratio increases rapidly with increasing total organic carbon(TOC)content.For oil-prone shales,the TOC content corresponding to an energy consumption ratio of 3 is approximately 4.2%.This indicates that shale with a high TOC content can be expected to reduce the project cost through large-scale operation,making the energy consumption ratio after consideration of the project cost greater than 1.In situ heating and upgrading technology can achieve economic benefits.The main methods for improving the economic feasibility by analyzing factors that influence the energy consumption ratio include the following:(1)exploring technologies that efficiently heat shale but reduce the heat dissipation of surrounding rocks,(2)exploring technologies for efficient transformation of organic matter into oil and gas,i.e.,exploring technologies with catalytic effects,or the capability to reduce in situ heating time,and(3)establishing a horizontal well deployment technology that comprehensively considers the energy consumption ratio,time cost,and engineering cost.
文摘Superconducting thin films of YBa<sub>2</sub>Cu<sub>3</sub>O<sub>7-x</sub>（Y-Ba-Cu-O） with Tc more than 85K have been deposited in situ by metalorganic chemical vapor deposition （MOCVD） on yttria stabilized zirconia（YSZ） substrates. The relationship of film orientation on substrate temperature and the lowest formation temperature region of superconducting phase have been obtained after changing the substrate temperature. The epitaxial relation between Y-Ba-Cu-O films and the YSZ su bstrates were discussed.
文摘Two main types of in situ grain harvesttng machine are introduced. The comparison of their working principles and advantages are given. The limitations and prospects for stripper header are discussed.
文摘Objective To compare the efficacy of toric implantable collamer lens(Toric-ICL)and femtosecond laser-assisted in situ keratomileusis(FS-LASIK)for myopia correction in patients with moderate to high myopia complicated with astigmatism.Methods We retrospectively collected data from 64 patients(aged 18-42 years)with moderate to high myopia complicated with astigmatism(128 eyes)undergoing either Toric-ICL(28 patients/56 eyes)or FS-LASIK(36 patients/72 eyes)at our department between January,2019 and December,2020.The changes of uncorrected distance visual acuity(UCVA),spherical equivalent(SE),mean astigmatism correction index(CI),corneal endothelial cell density(ECD)and intraocular pressure(IOP)following the procedures were compared between the two groups.Results In FS-LASIK group,all the eyes(72/72)achieved an UCVA≥1.0,similar to the rate in Toric-ICL group(55/56 eyes;P=0.2374).The postoperative SE was also comparable between FS-LASIK and Toric-ICL groups[0.43±0.06 D(range:-1.0 to 1.50 D)vs 0.38±0.05 D(range:-0.75 to 1.00 D);P=0.56].The mean astigmatism CI was significantly higher in FS-LASIK group than in Toric-ICL group(0.8561 vs 0.7176;P<0.0001),and 88.89%of the eyes in FS-LASIK group and 69.64%in Toric-ICL group had postoperative astigmatism≤0.50 D.No significant changes were observed in postoperative corneal ECD in FS-LASIK group,whereas ECD decreased significantly after the procedure in Toric-ICL group(P=0.0057).The patients undergoing Toric-ICL exhibited no significant changes of postoperative IOP,but the patients receiving FS-LASIK had significantly reduced IOP after the procedure(P<0.001).Conclusion Although the patients included in Toric-ICL group had higher myopia and astigmatism,Toric-ICL still showed better predictability and efficacy for astigmatic correction in Toric-ICL group.Toric-ICL is an effective and safe equivalent of FS-LASIK for correcting moderate myopia but can be more advantageous for correcting high myopia with astigmatism.
基金supported by the Fundamental Research Funds for the Central Universities(WK2090000055)Anhui Provincial Natural Science Foundation of China(2308085QG231).
文摘As a negative electrode material for lithium-ion batteries,silicon monoxide(SiO)suffers from dramatic volume changes during cycling,causing excessive stress within the electrode and resulting in electrode deformation and fragmentation.This ultimately leads to a decrease in cell capacity.The trends of volume expansion and capacity change of the SiO/graphite(SiO/C)composite electrode during cycling were investigated via in situ expansion monitoring.First,a series of expansion test schemes were designed,and the linear relationship between negative electrode expansion and cell capacity degradation was quantitatively analyzed.Then,the effects of different initial pressures on the long-term cycling performance of the cell were evaluated.Finally,the mechanism of their effects was analyzed by scanning electron microscope.The results show that after 50 cycles,the cell capacity decreases from 2.556 mAh to 1.689 mAh,with a capacity retention ratio(CRR)of only 66.08%.A linear relationship between the capacity retention ratio and thickness expansion was found.Electrochemical measurements and scanning electron microscope images demonstrate that intense stress inhibits the lithiation of the negative electrode and that the electrode is more susceptible to irreversible damage during cycling.Overall,these results reveal the relationship between the cycling performance of SiO and the internal pressure of the electrode from a macroscopic point of view,which provides some reference for the application of SiO/C composite electrodes in lithium-ion batteries.
基金Project(2016YFE0205200)supported by the National Key Research and Development Program of ChinaProjects(U1734207,51978585)supported by the National Natural Science Foundation of China。
文摘An experimental study and theoretical analysis were carried out to explore the ground-borne vibration generated by elevated high-speed railway in rock strata.Taking a typical rail line constructed on rock area in China as the research object,a set of field tests was performed on Rizhao-Lankao High-Speed Railway,the bridge and ground vibrations were measured as trains passed at 330−340 km/h,then the transferring law and spatial distribution under individual frequencies were investigated.The experiment results indicate that the bridge frequency spectrum exhibited relatively high-frequency vibration peaks caused by short-wavelength irregularity;ground vibration farther than 30 m away can be amplified with a higher frequency and numerous components.Furthermore,the wave propagation equation of a stratified rock strata was established based on direct-stiffness method to explore the vibration attenuation rules via frequency-domain analysis.It is found that the rock area has a weaker correlation between vibration transmissibility and frequency,thicker and harder rock strata loss their vibration attenuation capacity.It can be concluded that the high-speed railways induced vibration on rock strata shows a wide frequency band and large amplitude,the design of reducing vibration aimed at specific frequency is important according to next more detailed numerical study.
基金Project(51901095)supported by the National Natural Science Foundation of China。
文摘To study the influence of B4C particle size on the microstructure and damping capacities of(B_(4)C+Ti)/Mg composites,in situ reactive infiltration technique was utilized to prepare Mg-matrix composites.The microstructure,produced phases and damping capacities of the composites prepared with different particle size of B4C were characterized and analyzed.The results show that the reaction between B4C and Ti tends to be more complete when finer B_(4)C particle was used to prepare the composites.But the microstructure of the as-prepared composites is more homogenous when B4C and Ti have similar particle size.The strain-dependent damping capacities of(B_(4)C+Ti)/Mg composites improve gradually with the increase of strain amplitude,and composites prepared with coarser B4C particles tend to have higher damping capacities.The temperature-dependent damping capacities improve with increasing the measuring temperatures,and the kind of damping capacities of the composites prepared with 5mm B4C are inferior to those of coarser particles.The dominant damping mechanism for the strain-damping capacity is dislocation damping and plastic zone damping,while that for the temperature-damping capacity is interface damping or grain boundary damping.
基金This research was funded by Faculty of Engineering,King Mongkut’s Institute of Technology Ladkrabang.
文摘Transformation-induced plasticity(TRIP)steel possesses high strength and formability,enabling the use of a thinner gauge material and allowing for the fabrication of complex shapes.In this research,we measured the effect of bending temperatures on the microstructure and air-bending springback angle of TRIP steel at temperatures from 25 to 600C.Real-time in situ X-ray diffraction and scanning electron microscopy were used for pre-and postbending analysis.As the prebending temperature increased from 25C to 600C,the retained austenite(RA)volume fraction decreased,and the RA transformed to bainite at temperatures above 400C.The springback angle was positively correlated with the prebending RA volume fraction,with the smallest springback angle achieved at 400C.Additionally,the springback angle was positively correlated with the bending angle,because the RA transformation ratio contributed to increased strain hardening.Further microstructure analysis revealed that the RA became elongated in the tension direction as the bending temperatures increased.
基金Projects(51275198,51422503)supported by the National Natural Science Foundation of ChinaProject(2012YQ030075)supported by Special Funds for Development of National Major Scientific Instruments and Equipments,China+1 种基金Project(NECT-12-0238)supported by Program for New Century Excellent Talents in University,ChinaProject(20150520108JH)supported by Young Scientist Fund of Jilin Province of China
文摘The effects of adding alloy element zinc on the static and dynamic mechanical properties of copper-zinc alloy were investigated. Tensile and low cycle fatigue behaviors of the C11000 copper and H63 copper-zinc alloy were obtained by using a miniature tester that combined the functions of in situ tensile and fatigue testing. A piezoelectric actuator was adopted as the actuator for the fatigue testing, and the feasibility of the fatigue actuator was verified by the transient harmonic response analysis based on static tensile preload and dynamic sinusoidal load. The experimental results show that the yield strength and tensile strength of the C11000 copper are improved after adding 37%(mass fraction) zinc, and H63 copper-zinc alloy presents more obvious cyclic hardening behavior and more consumed irreversible plastic work during each stress cycle compared with C11000 copper for the same strain controlled cycling. Additionally, based on the Manson-Coffin theory, the strain-life equations of the two materials were also obtained. C11000 copper and H63 copper-zinc alloy show transition life of 16832 and 1788 cycles, respectively.
基金Project(2013AA031601)supported by the National High Technology Research and Development Program of ChinaProject(2012BAF04B01)supported by the National Science and Technology Pillar Program During the 12th Five-year Plan Period of China
文摘Two different kinds of experimental techniques were used to in-situ study the austenite formation during intercritical annealing in C-Mn dual phase steel. The microstructure evolution was observed by confocal laser scanning microscope, and the austenite isothermal and non-isothermal transformation kinetics were studied by dilatometry. The results indicate that banded structure is produced for the reason of composition segregation and the competition between recrystallization and phase transformation. Austenite prefers to nucleate not only at ferrite/ferrite grain boundaries, but also inside the grains of ferrite.Furthermore, the austenitizing process is accomplished mainly via migration of the existing austenite/ferrite interface rather than nucleation of new grains. The incubation process can be divided into two stages which are controlled by carbon and manganese diffusion, respectively. During the incubation process, the nucleation rate of austenite decreases, and austenite growth changes from two-dimensional to one-dimensional. The partitioning coefficient, defined as the ratio of manganese content in the austenite to that in the adjacent ferrite, increases with increasing soaking time.
文摘Gossypium mustelinum [(AD)4] is one of five tetraploid species in Gossypium.Three pairs of nucleolar organizer regions(NOR) in(AD)4 were detected by FISH with 45S rDNA as a probe,they also were observed with genomic DNA(gDNA) from Gossypium D genome species as probes.Of
文摘When the crystal grows from solution,a sharp variated fluid layer of the solute concentration exists against crystal surface.The sharp variated fluid layer is defined the boundary layer in crystal growth.The molecular structure of the boundary layers plays a key role in crystal composition,morphology,growth rate and crystal growth mechanism.However,owing to the lacking of suitable probe technique,it is difficult to obtain the information of the moving construction of the boundary layers.Here,the laser Raman Microprobe combining with holographic phase contrast interferometric microphotography is used to probe in situ the molecular structure of the boundary layers during the crystal growth processes of KH 2PO 4(KDP) and KD 2PO 4(DKDP).In supersaturations ranging from 1% to 14%,Raman scattering states at the different positions within the boundary layers have been investigated,and compared with the bands of different concentration solutions alone using laser Raman spectroscopy between 600 and 1350cm -1 .The changes in band parameters of the phosphates within the boundary layers of crystal growth are different from those in solution alone.The influence of the solution concentration on the band parameters of anion phosphate within the layers is nonlinear.With increasing supersaturation,the full width at half height of the P=O 2 symmetric stretch band increases.The new 918(938)cm -1 H(D)O P OH(D) asymmetric stretch,1120(DKDP 1200)cm -1 O P O asymmetric stretch,and extremely weak 1210cm -1 P O H in plane deformation bands appear in the characteristic boundary layers.These new bands show that the cations have direct effects on the phosphate group(aggregates).Under the driving of concentration gradient field of supersaturation,the effects of cations cause the changes of O P O bond angle,atomic charge redistribution,and lead to readjust geometry of anion phosphate group and desolvation.The trend of readjust is close to the geometry of the crystal structure unit and the formation of the cations phosphate crystallization unit.
文摘The convection in melt crystal growth influences the crystal integrity deeply.During space crystal growth,the buoyancy driven convection has been eliminated for the microgravity environment,therefroe,surface tension driven convection (Marangoni Convection) become the main convection form.But the Marangoni convection forms,starting condition,development process and its influence on crystal growth are still unclear now.At the present time,Many studies focused on simulating liquid Marangoni convection or numerical simulation.However,few studies concerned on real melt,especially on oxide melt. In this paper,an in situ observation is carried out to study the start and development of Marangoni convection of Bi 12 SiO 20 melt in a 2mm diameter loop like platinum crucible.The different states of steady convection and the transition from steady to oscillatory convection are observed.The critical Marangoni number is obtained as 22433 and it agreed with a dependence Ma c=2884Pr 0.638 for high Prandtl number melt.The authors also obtained a dependence of convection oscillatory frequency on melt temperature.It increases with temperature rising.
